CN102558963B - Radiation curing printing ink capable of being directly jetted on surface of ultraviolet curing coating and preparation method thereof - Google Patents
Radiation curing printing ink capable of being directly jetted on surface of ultraviolet curing coating and preparation method thereof Download PDFInfo
- Publication number
- CN102558963B CN102558963B CN 201210002446 CN201210002446A CN102558963B CN 102558963 B CN102558963 B CN 102558963B CN 201210002446 CN201210002446 CN 201210002446 CN 201210002446 A CN201210002446 A CN 201210002446A CN 102558963 B CN102558963 B CN 102558963B
- Authority
- CN
- China
- Prior art keywords
- methyl
- ink
- phenyl
- test
- ultraviolet curing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention discloses radiation curing printing ink capable of being directly jetted on the surface of an ultraviolet curing coating and a preparation method thereof. The jet ink comprises components including 5-20 wt% of oligomer, 60-85 wt% of reactive diluent, 1-8wt% of photoinitiator, 5-15 wt% of adhesion enhancer, 0.2-5 wt% of pigment, and 0.1-5 wt% of other agent. The jet ink contains special adhesion enhancer, can be directly jetted and printed on the surface of the ultraviolet curing coating, has good adhesion to the ultraviolet curing coating, has good physical and chemical properties in such as hardness, chemical test resistance, ultraviolet test, thermal shock test and buffer solution test resistance, can be applied to ultraviolet curing coatings of various hard or soft materials such as plastics, steel, glass and fabrics without needing to coat other coatings or protecting layers, and has wide applicability.
Description
Technical field
The present invention relates to jetted ink and the preparation method of radiation-curable, more particularly, the present invention be more particularly directed to a kind of jetted ink that is applied in the lip-deep radiation-curable of UV-light (UV) solidified coating and preparation method thereof, and this jetted ink has good adhesion property in the UV coating.
Background technology
The share sustainable growth of digital technology in printing market, wherein, the market position of radiation curable ink jet inks has occupied obvious advantage, and this is conducive to enlarge its share in this emerging market.The significant advantage of radiation curable ink jet inks is mainly reflected in high speed printing, environmental protection, chemistry and physics patience, light permanency and the aspect such as the material scope of application widely, and these have all promoted the development of radiation curable ink jet inks.
Be accompanied by the appearance of various emerging Application Areass, market proposes new performance requriements---the radiation curable ink jet inks of high adhesion property, particularly a kind of radiation curable ink jet inks that can have at ultraviolet curing varnish well attached ability to radiation curable ink jet inks.Yet the product that does not also occur at present reaching test request on the domestic and international market is being sold, main because: 1), ultraviolet curable coating surface compact degree is high, hardness is large, and upper strata painting printing ink well interlock adheres to; 2), the present common type of painting printing ink is Weak solvent type, solvent-borne type and radiation-curable, these several printing ink are effectively ethanol-tolerant friction all, even radiation-curable printing ink effect is slightly good, does not also reach test request; 3) even the ink film over-all properties is good, but the vividness of printing ink is inadequate, is difficult to reach market demands.
Summary of the invention
The objective of the invention is to solve jetted ink in the poor industry difficult problem of the poor and dry rear ink film wear resisting property of ultraviolet curable coating surface adhesion force, provide a kind of novel environment-friendly and can be on ultraviolet curable coating surface direct high-wear resistance UV curable ink of ink-jet and preparation method thereof.
A kind of can be on ultraviolet curable coating surface the direct radiation curable ink of ink-jet, comprise following component ratio:
Described oligopolymer is hyperbranched polyester acrylic ester.
Described reactive thinner is one or more mixture in (methyl) esters of acrylic acid, vinyl-based, vinyl ethers, epoxies etc.
Described (methyl) esters of acrylic acid reactive thinner is selected from the 2-phenoxyethyl acrylate, ethoxyquin phenoxy group acrylate, 3,3,5-trimethylcyclohexyl acrylate, adjacent phenyl phenoxyethyl acrylate, 2-(p-cumyl-phenoxy group)-ethyl propylene acid esters, ethoxy ethoxy ethyl propylene acid esters, ring TriMethylolPropane(TMP) methylal〔Su〕 acrylate, the tetrahydrofurfuryl acrylate, lauric acid (methyl) acrylate, stearic acid (methyl) acrylate, isodecyl (methyl) acrylate, 2-phenoxy group ethyl-methyl acrylate, the isotridecyl methacrylic ester, the benzyl acrylate, 3-hydroxyl-2,2-dimethyl propyl-3-hydroxyl-2,2-dimethyl propyl ester diacrylate, isobornyl (methyl) acrylate, tristane dimethanol diacrylate, dioxy land surround omega-diol diacrylate, (ethoxyquin) 1, the 6-hexanediyl ester, propylene glycol diacrylate, tripropylene glycol diacrylate, 1, the 4-butylene glycol diacrylate, (the third oxidation) neopentylglycol diacrylate, ethoxyquin dihydroxyphenyl propane two (methyl) acrylate, (ethoxyquin-) 2-methyl isophthalic acid, the ammediol diacrylate, 2-butyl-2-ethyl-1,3-PD diacrylate, ethylene glycol dimethacrylate, TEGDMA, the Diethylene Glycol dimethacrylate, 2-HEMA phosphoric acid ester, three (2-hydroxyethyl) isocyanuric acid triacrylate, (ethoxyquin) Viscoat 295, the third oxidation Viscoat 295, pentaerythritol triacrylate, the glycerol propoxylate triacrylate, (ethoxyquin) trimethylolpropane trimethacrylate, (ethoxyquin) tetramethylol methane tetraacrylate, two-trimethylolpropane tetra-acrylate, the third oxidation tetramethylol methane tetraacrylate, one or more mixture in the dipentaerythritol acrylate etc.
Described vinyl-based reactive thinner is selected from (methyl) vinylbenzene, vinyl pyrrolidone, vinyl-acetic ester, (methyl) acrylate, vinylformic acid (different) monooctyl ester, vinylformic acid (different) butyl ester, Ethyl acrylate, (methyl) Hydroxyethyl acrylate, (methyl) Propylene glycol monoacrylate, the vinylformic acid hydroxy butyl ester etc. one or more mixture.
Described vinyl ethers reactive thinner is selected from n-propyl vinyl ether, isopropyl-ethylene base ether, n-butyl vinyl ether, IVE, 2-ethylhexyl vinyl ether, octadecyl vinyl ether, cyclohexyl vinyl ether, allyl vinyl ether, the hydroxyethyl vinyl ether, hydroxy butyl vinyl ether, vinyl ether, 1,4-butyleneglycol divinyl ether, 1,6-hexylene glycol divinyl ether, the neopentyl divinyl ether, the nonanediol divinyl ether, the cyclohexanedimethanol divinyl ether, the Diethylene Glycol divinyl ether, the triethylene glycol divinyl ether, the TriMethylolPropane(TMP) divinyl ether, the tetramethylolmethane divinyl ether, 1-indanyl vinyl ether, the trimethylolpropane tris vinyl ether, the tetramethylolmethane trivinyl ether, tetramethylolmethane tetrem alkene ether, one or more mixture in Dipentaerythritol six vinyl ether etc.
Described epoxies reactive thinner be selected from 3-ethyl-3-methylol butylene oxide ring, 3-ethyl-3-phenoxymethyl butylene oxide ring, 3,3 '-[oxygen base dimethylene] two [3-ethyl] butylene oxide ring, 3-ethyl-3-[(2-ethyl hexyl oxy) methyl] one or more mixture in the butylene oxide ring etc.
Described light trigger is 2-hydroxyl-2-phenyl methyl phenyl ketone; 2-methoxyl group-2-phenyl methyl phenyl ketone; 2-oxyethyl group-2-phenyl methyl phenyl ketone; 2-isopropoxy-2-phenyl methyl phenyl ketone; 2-butoxy-2-phenyl methyl phenyl ketone; 2-isobutoxy-2-phenyl methyl phenyl ketone; 2-phenyl-2-metaphenoxy acetophenone; α; α-diethoxy acetophenone; α; α-diisopropoxy methyl phenyl ketone; α; α-di-secondary butyl phenyl ether ethyl ketone; α; α-two isobutoxy methyl phenyl ketone; α; α-two [(1-methoxyl group) propoxy-] methyl phenyl ketone; α; α-two cyclohexyloxy methyl phenyl ketone; 2-hydroxy-2-methyl-1-phenyl-1-acetone; 1-hydroxyl-cyclohexyl benzophenone; 2-hydroxy-2-methyl-1-[4-(2-hydroxyl-oxethyl) phenyl]-1-acetone; 2-hydroxy-2-methyl-1-(4-isopropyl phenyl)-1-acetone; 2-hydroxy-2-methyl-1-phenylol-1-acetone; 2-hydroxy-2-methyl-1-[4-(2-vinylformic acid oxyethyl group) phenyl]-1-acetone; 2-hydroxy-2-methyl-1-(4-first sulfydryl phenyl)-1-acetone; 2-hydroxy-2-methyl-1-[4-(2-hydroxyl second sulfydryl) phenyl]-1-acetone; 2-hydroxy-2-methyl-1-[4-(N; the N-dimethylamino) phenyl]-1-acetone; 2-hydroxy-2-methyl-1-(4-dodecylphenyl)-1-acetone; 2-methyl isophthalic acid-(4-first sulfydryl phenyl)-2-morpholine-1-acetone; 2-benzyl-2; 2-dimethylamino-1-(4-morpholinyl phenyl)-1-butanone; α; alpha, alpha-dimethyl oxygen base-α-phenyl methyl phenyl ketone; 2-methyl isophthalic acid-phenyl-2-morpholine-1-acetone; 2-methyl isophthalic acid-(4-p-methoxy-phenyl)-2-morpholine-1-acetone; 2-methyl isophthalic acid-[4-(N; the N-dimethylamino) phenyl]-2-morpholine-1-acetone; 1-phenyl-2-benzyl-2; 2-dimethylamino-1-butanone; 2-propenyl-2; 2-dimethylamino-1-(4-morpholinyl phenyl)-1-butanone; 2; 4; 6-Three methyl Benzene formyl diphenyl phosphine oxide; 2; 4; 6-Three methyl Benzene formylphenyl diethyl phosphonate; two (2; 4; 6-Three methyl Benzene formyl) phenyl phosphine oxide; two (2; 6-dimethoxy benzoyl)-(4 '; 4 ' dimethyl octyl group-2) phosphine oxide; benzophenone; the tetramethyl-Michler's keton; the tetraethyl-Michler's keton; the first and second basic Michler's ketons; isopropyl thioxanthone; the 2-chlorothiaxanthenone; 2; the 4-diethyl thioxanthone; 2-benzoyl methyl benzoate; 4-benzoyl-4 '-methyl-diphenyl sulfide; 4-(N; the N-dimethylamino) ethyl benzoate; 4-(N, N-dimethylamino) the different monooctyl ester of phenylformic acid; diazonium salt; diaryl group iodized salt; triaryl sulfonium salts; the alkyl sulfosalt; iron arene salt; sulfonyloxy ketone; one or more mixture in the triaryl silica ether etc.
Described sticking power rising agent is the acroleic acid esterification oligopolymer.
Described pigment is selected from azo pigment, phthalocyanine pigment and the heterocyclic pigment etc. one or more mixture.
Described a kind of can in the surperficial directly preparation method of the radiation curable ink of ink-jet of ultraviolet curable coating, comprising the steps:
1) with pigment, reactive thinner and dispersant, makes pigment abundant wetting dispersion in system, the mill base of preparation favorable dispersity;
2) ground mill base, oligopolymer, sticking power rising agent, auxiliary agent and light light lead agent are mixed to make the radiation curable ink jet inks of excellent property;
3) with ultra-fine filter screen printing ink is filtered, can obtain radiation curable ink jet inks.
Described a kind of can in the surperficial directly preparation method of the radiation curable ink of ink-jet of ultraviolet curable coating, comprising the steps:
1) reactive thinner, oligopolymer, light trigger, sticking power rising agent and auxiliary agent are mixed preparation UV gloss oil;
2) pigment and dispersion agent are added successively carry out the radiation curable ink jet inks that abundant wetting dispersion makes excellent property in the UV gloss oil;
3) with ultra-fine filter screen printing ink is filtered, can obtain radiation curable ink jet inks.
The invention has the beneficial effects as follows:
One, a kind of radiation curable ink jet inks of the present invention has high adhesion property, this kind printing ink has excellent sticking power on the ultraviolet curable coating surface, solve after the ultraviolet-curing paint drying the low and industry difficult problem that is difficult to adhere to of its film densification and surface energy.
Two, direct ink-jet refers to behind material surface spraying priming paint and ultraviolet light cured paint radiation curable ink jet inks provided by the invention on the ultraviolet curable coating surface; directly carry out printing pattern on the ultraviolet curable coating surface; pattern uses as the top layer, no longer does protective layer.
Three, direct ink-jet can also reduce product turnover time and the frequency to radiation curable ink jet inks on the UV surface, realize that product is behind Painting Shop disposable spray finishing priming paint and UV finish paint, forward printing pattern between spray-painting vehicle to, the purpose of direct goods dispatch is to enhance productivity.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail.
All contain a kind of sticking power rising agent in the composition of the radiation curable ink of the direct ink-jet in ultraviolet curable coating of the present invention surface.
Embodiment one
The composition of the red radiation curable ink of table one and proportioning table
Grind the pigment dispersion color paste that obtains higher concentration with pigment, part reactive thinner and dispersant and at grinding, stirring, dispersion multi-purpose machine, add again oligopolymer, light trigger, other auxiliary agents, remaining activity thinner etc., and disperse with the ultra-sonic dispersion instrument, with ultra-fine filter screen printing ink is filtered at last, can obtain radiation curable ink jet inks.
The present embodiment pigment red 122 belongs to heterocyclic pigment.Process of lapping uses is that the SDF-400 of Shandong dragon Xinghua worker machinery Group Co.,Ltd grinds, stirs, disperses multi-purpose machine, and milling time is 2～20 hours, is stirred under 7000 rev/mins the rotating speed to carry out; Dispersion process is to analyse the DS-2510DTH ultra-sonic dispersion instrument that ultrasonic instrument company limited produces with the Shanghai life, and jitter time is 30～60 minutes.Dispersion agent SOLSPERSE32000 and 22000 is produced by U.S. Lu Borun petrochemical corporation (complex).Test result sees Table five.
Embodiment two
The composition of the yellow radiation curable ink of table two and proportioning table
Reactive thinner, oligopolymer, light trigger, sticking power rising agent and auxiliary agent added successively in the black reaction device to mix and grind, stir, disperse multi-purpose machine to be stirred in rotating speed with SDF-400 be 2000 rev/mins of lower dispersions 2～5 hours, add again pigment 188 and hyper-dispersant and carry out abundant wetting dispersion 1～20 hour, rotating speed is 7000 rev/mins, with ultra-fine filter screen printing ink is filtered at last, can obtain radiation curable ink jet inks.
Pigment red 188 belongs to heterocyclic pigment, and dispersion agent SOLSPERSE 32000 and 22000 is produced by U.S. Lu Borun petrochemical corporation (complex).Test result sees Table five.
Embodiment three
The composition of table three cyan radiation curable ink and proportioning table
The preparation method of cyan radiation curable ink is with example one, and wherein the C.I. pigment Blue 15 belongs to phthalocyanine pigment, and dispersion agent SOLSPERSE 78000 is produced by U.S. Lu Borun petrochemical corporation (complex).Test result sees Table five.
Embodiment four
The composition of table four black radiation curable ink and proportioning table
The preparation method of black radiation curable ink is with example one, and wherein Pigment black 15 belongs to heterocycle pigment, and dispersion agent SOLSPERSE 78000 and SOLSPERSE 5000 are produced by U.S. Lu Borun petrochemical corporation (complex).Test result sees Table five.
Embodiment one to four is rear after tested all to have good tack and superior wear resistance at ultraviolet curable coating, can satisfy actual mass production requirement, and specific targets are as shown in the table:
The fundamental property of UV jetted ink and ink film performance test result among table five embodiment
The printing ink fundamental property is tested by following instrument in the table five:
1, viscosity is used NDJ-8S digital display rotary viscosity measuring;
2, surface tension adopts the OCA15EC video optics contact angle measurement test of German Dataphysics company;
3, grain size utilizes the JL-1177 type laser granularity distribution tester test of Jingxin Power Testing Apparatus Co., Ltd., Chengdu;
4, specific conductivity is to be tested with the DDS-12A type digital display conductivity meter that AudioCodes skill company limited produces by the Shenzhen;
5, the pH value uses the PHS-3C type digital display acidometer of Hangzhou Ao Lilong Instr Ltd. to measure.
The test request of ink performance is as follows in the table five:
1, hundred lattice are tested: delineate chess lattice with 1mm spacing intersection with icking tool on sample China ink layer first, the vertical direction brute force is drawn 3 times after pasting with the test gummed paper again, and obscission can not be arranged.
2, drug-resistant test: specimen is positioned on the trier, periodically adding alcohol makes it keep humidity, apply under the 500g gravity condition with 35 times at the test eraser and to come and go/minute speed commutes friction sample China ink layer, rub come and go for 250 times after the sample China ink layer can not have and to come off or the heavy wear phenomenon.
3, pencil hardness test: with the board UNIF of Mitsubishi type pencil, loading 1000g counterweight, pencil-lead and ink film face angle at 45 °, pencil-lead comes and goes 4 times and comes and goes miles of relative movement at every turn at ink film is 15mm, without scratching.
4, UV resistant test: after half of specimen sheet covered with black belt, place the specimen sheet under the ultraviolet test lamp 20cm position to place and take out after 60 hours, normal temperature was placed 5 hours.Test front/rear, sample can not have fade, variable color, be full of cracks etc. be bad.
5, anti-damping fluid test: the buffered soln placement of specimen being put into pH=4.6 was taken out after 12 hours, wash, dry, normal temperature places after 4 hours, draw the chess lattice with the 2mm spacing on sample China ink layer, the vertical direction brute force is drawn 1 time after pasting with the test gummed paper again.Before and after the experiment, sample can not have and fades, variable color, be full of cracks, bubbles, comes off, twists and by phenomenons such as nail scratches.
6, brine spray test: it is 35 ℃, the brine spray experimental machine of the environment of 5%NaCl that specimen is put into temperature, place take out after 48 hours, wash, dry, normal temperature places after 5 hours, draw the chess lattice with the 2mm spacing on sample China ink layer, the vertical direction brute force is drawn 1 time after pasting with the test gummed paper again.Before and after the experiment, sample can not have and fades, variable color, be full of cracks, bubbles, comes off, twists and by phenomenons such as nail scratches.
7, thermal shock test: specimen is put into the thermal shock experiment machine, the control temperature is-40 ℃ and places after 1 hour, the control temperature is 75 ℃ and placed 1 hour, so repeatedly, take out after doing altogether 24 circulations, normal temperature was placed after 4 hours, and with 2mm spacing delineation chess lattice, the vertical direction brute force is drawn 1 time after pasting with the test gummed paper again on sample China ink layer.Before and after the experiment, sample can not have and fades, variable color, be full of cracks, bubbles, comes off, twists and by phenomenons such as nail scratches.
8, vibrate wear-resisting test: sample is put into the vibrating trough that contains water, chemical lubricants and abrasive material, vibrated wear-resisting 35 minutes.After the experiment, the ink film on the sample is without coming off.
Above-described only is preferred implementation of the present invention, should be pointed out that for the person of ordinary skill of the art, under the prerequisite that does not break away from the invention design, can also make some distortion and improvement, and these all belong to protection scope of the present invention.
Claims (1)
1. an energy is characterized in that at the surperficial directly radiation curable ink of ink-jet of ultraviolet curable coating, comprises following component ratio:
Hyperbranched polyester acrylic ester 10.0wt%;
1,6 hexanediol diacrylate 17.0wt%;
Tetrahydrofuran (THF) acrylate 11.0wt%;
Viscoat 295 13.0wt%;
Iso-bornyl acrylate 30.0wt%;
Acroleic acid esterification oligopolymer 12.5wt%;
2-methyl isophthalic acid-(4-first sulfydryl phenyl)-2-morpholine-1-acetone 3.0wt%;
2-hydroxy-2-methyl-1-phenyl-1-acetone 1.0wt%;
Pigment 122 2.0wt%;
SOLSPERSE32000 0.2wt%；
SOLSPERSE22000 0.1wt%；
Wherein, SOLSPERSE 32000 and SOLSPERSE 22000 are SOLSPERSE 32000 and SOLSPERSE 22000 dispersion agents of being produced by U.S. Lu Borun petrochemical corporation (complex).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210002446 CN102558963B (en) | 2012-01-04 | 2012-01-04 | Radiation curing printing ink capable of being directly jetted on surface of ultraviolet curing coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210002446 CN102558963B (en) | 2012-01-04 | 2012-01-04 | Radiation curing printing ink capable of being directly jetted on surface of ultraviolet curing coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102558963A CN102558963A (en) | 2012-07-11 |
| CN102558963B true CN102558963B (en) | 2013-10-23 |
Family
ID=46405631
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201210002446 Active CN102558963B (en) | 2012-01-04 | 2012-01-04 | Radiation curing printing ink capable of being directly jetted on surface of ultraviolet curing coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102558963B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6299272B2 (en) | 2013-04-25 | 2018-03-28 | 株式会社リコー | Photopolymerizable composition, photopolymerizable inkjet ink, ink cartridge, coated product |
| CN104327217B (en) * | 2014-08-20 | 2017-05-31 | 昆山博益鑫成高分子材料有限公司 | A kind of ultraviolet light polymerization non-silicon mould release and preparation method thereof |
| CN104497811B (en) * | 2014-12-12 | 2017-01-18 | 惠州市至上新材料有限公司 | Alkali-washable UV (ultraviolet) paint for mobile phone glass screens and preparation method thereof |
| CN104817882B (en) * | 2015-05-07 | 2018-03-20 | 东莞市赛维印刷实业有限公司 | Ink and the adhesive label using the ink |
| CN107337957A (en) * | 2017-08-21 | 2017-11-10 | 王艺霖 | A kind of preparation method of wear-resisting ink composite |
| CN109337450A (en) * | 2018-09-26 | 2019-02-15 | 上海乘鹰新材料有限公司 | General resin-free color paste of UV and preparation method thereof |
| CN109359498B (en) * | 2018-09-29 | 2022-04-22 | 东莞市科佳电路有限公司 | Method for storing bad board information by two-dimensional code |
| CN109517432A (en) * | 2018-11-13 | 2019-03-26 | 长沙新宇高分子科技有限公司 | A kind of composition of the acylphosphine oxide containing liquid and its application |
| CN111073386B (en) * | 2019-12-11 | 2023-04-07 | 康达新材料(集团)股份有限公司 | LED-UV curing gravure ink, and preparation method and application thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4181815B2 (en) * | 2002-07-30 | 2008-11-19 | トッパン・フォームズ株式会社 | Release sheet using UV curable release ink |
| CN102093782B (en) * | 2011-03-30 | 2013-01-23 | 北京神彩优维喷墨材料科技有限公司 | Ultraviolet-cured digital painting ink and preparation method thereof |
-
2012
- 2012-01-04 CN CN 201210002446 patent/CN102558963B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN102558963A (en) | 2012-07-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102558963B (en) | Radiation curing printing ink capable of being directly jetted on surface of ultraviolet curing coating and preparation method thereof | |
| CN102417760B (en) | Radiation-curable ink-jet ink and preparation method thereof | |
| CN101407651B (en) | UV curing color decorative coating | |
| CN102153899B (en) | Ultraviolet-curable water-based colored paint composition | |
| CN108165091A (en) | UV jet ink compositions | |
| CN102732094B (en) | LED-UV surface light source light-curing silk-screen printing ink composition and preparation method thereof | |
| CN102719143B (en) | Light-emitting diode (LED)-ultraviolet (UV) area light source curing outdoor silk screen printing ink composition and preparation method thereof | |
| CN111320895A (en) | UV-LED curing inkjet ink and preparation method thereof | |
| CN101993629A (en) | Transfer printing type ultraviolet light curing ink composition, preparation method thereof and mobile phone casing using ink composition | |
| CN104610873A (en) | Single-component light-curing colored paint as well as preparation method and using method thereof | |
| CN107250298B (en) | Ink set for inkjet recording and inkjet printing method | |
| KR20120111875A (en) | Fast drying inkjet-ink composition, not-melting coating layer | |
| CN101284955A (en) | Dual-cured coating composition and method for preparation thereof | |
| CN105452399A (en) | Nonaqueous inkjet ink composition and printed matter obtained using same | |
| CN109517440A (en) | 3 D-printing material and its preparation method and application | |
| CN108912839A (en) | A kind of environment-friendly type LED photocuring 3D light metamagnetism ink | |
| CN102827500A (en) | Scratch-resistant and wear-resistant composition and preparation method and application thereof | |
| CN105419599B (en) | A kind of high solid aliphatic acrylic polyurethane coating and preparation method | |
| CN102925003B (en) | Gravure snowflake ultraviolet (UV) oil ink with anti-fake function | |
| CN114736556B (en) | High-glossiness UV offset printing ink and preparation method thereof | |
| CN108373650A (en) | A kind of aqueous PET ink for screen printing and preparation method thereof | |
| CN101348620B (en) | UV anaerobic double curing coating | |
| CN104830210B (en) | A kind of aqueous sprinkling paint | |
| CN102719137B (en) | Special jet ink for PVC (polyvinyl chloride) cable | |
| CN103146298A (en) | Ultraviolet coating and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 523878 Changan City, Guangdong Province town on the corner management area Patentee after: Guangdong wins smart group Limited by Share Ltd Address before: 523878 Changan City, Guangdong Province town on the corner management area Patentee before: Dongguan Janus Precision Components Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210118 Address after: No. 3000, Taidong Road, Huangdai Town, Xiangcheng District, Suzhou City, Jiangsu Province Patentee after: SUZHOU TAIKAN MACHINERY Co.,Ltd. Address before: 523878 corner management area, Changan Town, Guangdong, Dongguan Patentee before: GUANGDONG JANUS INTELLIGENT GROUP Corp.,Ltd. |