CN102553283B - Organic steam condensation adsorption recovery system powered by solar photovoltaics - Google Patents

Organic steam condensation adsorption recovery system powered by solar photovoltaics Download PDF

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CN102553283B
CN102553283B CN201110428903.6A CN201110428903A CN102553283B CN 102553283 B CN102553283 B CN 102553283B CN 201110428903 A CN201110428903 A CN 201110428903A CN 102553283 B CN102553283 B CN 102553283B
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oil
recovery system
ice chest
absorbing cylinder
oil gas
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CN102553283A (en
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黄维秋
周昊
郭强
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Jiangsu Daheng environmental protection equipment manufacturing Co.,Ltd.
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Changzhou University
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Abstract

The invention discloses an organic steam condensation adsorption recovery system powered by solar photovoltaics. A solar photovoltaic power supply system is connected each electric equipment in the organic steam condensation adsorption recovery system and comprises a solar photovoltaic cell panel connected with a photovoltaic electric energy controller, and the photovoltaic electric energy controller is also connected with an output protective device, a storage battery pack and an auxiliary power supply system by different ports; the storage battery pack is connected with the output protective device and the auxiliary power supply system; alternating current is inputted into four ports of a power factor correction (PFC) rectifier, and the four ports are connected with the auxiliary power supply system, the output protective device, alternating-current mains supply and a diesel generator set respectively; and the organic steam condensation adsorption recovery system comprises an oil gas collecting tube, a gas suction fan, a buffering tank, a freezing cabinet, a compressor, a condenser and two adsorption cylinders. Due to the integration adoption of a composite process of condensation, adsorption and recovery, the recovery efficiency is improved, the content of organic steam in tail gas is reduced, and pollution is avoided.

Description

Solar photovoltaic powered organic vapor condensation adsorption recovery system
Technical field
The present invention relates to environmental protection and field of energy-saving technology, refer in particular to a kind of based on solar photovoltaic powered and reclaim the system of the various organic vapors such as oil gas by condensation and absorption integrated technique.
Background technology
In fields such as oil, petrochemical industry, paint (coating), traffic, because being very easy to volatilization in the processes such as production, storage, transportation, sale, use, the various volatile organic matters (VOCs) such as gasoline produce very serious organic vapor discharge.The a large amount of evaporations of this organic vapor are also directly discharged into atmosphere, not only cause serious quantity loss and Quality Down (thereby having brought great economic loss), and have seriously polluted atmospheric environment and left great disaster hidden-trouble.The improvement of organic exhaust gas and recycling treatment, the first key technology is how to separate VOCs and air.The separation method of VOCs and air has absorption process, absorption method, condensation method and embrane method etc. at present.Various VOCs recovery methods all have pluses and minuses and the scope of application.For example, absorption process oil-gas recovery method contacts with absorbent by oil gas, air Mixture, different solubility according to different component in absorbent, be that oil-gas component is dissolved in this absorbent formation solution (rich absorbent), undissolvable constituent of air is retained in gas phase, so the component of former mist is separated.Therefore absorption process has obvious advantage for the oil gas of processing high concentration, large flow, the quality of recovering effect depends primarily on absorbent.Absorption method is conducive to control in recovery system tail gas gas concentration in very low level, but its exist heat of adsorption obviously, desorb is more difficult, reach the problems such as time of equilibrium adsorption is long, therefore be particularly suitable for reclaiming the oil gas of low concentration, low discharge, and should serve as the subsequent treatment of some group technology.Absorption method reclaims high-concentration oil vapor or other VOCs, while being particularly useful for reclaiming ketone, ester class, alcohols and unsaturated hydrocarbons, active carbon layer deteriorated (charing) may occurring and even catch fire.Condensation method can directly be recovered to oil product, for the oil gas of processing high concentration, middle flow, has obvious advantage.But simple condensation method condensation temperature will be lower than below-70 ℃, just can guarantee that the rate of recovery reaches 90% left and right, correspondingly refrigeration system is more complicated.Meanwhile, also use low temperature material and increase the links such as insulation, defrosting, cost of investment and operating cost are all higher.Membrane separation process Investigation of Petroleum Vapor Recovery Technology, as a new technology, is in research and development, especially high performance membrane material is developed.At present, domestic and international useful organic film separates and reclaims VOCs, but film is short service life, and investment and operating cost are larger.For this reason, the integrated technology of different recovery methods is just becoming the emphasis of people's research.Integrated technology, because combine rightly the advantage of two or more technology, reaches the technology complementation of height, not only can relatively easily realize effective control of exhaust of oil, technical costs can also be reduced greatly.
In current oil-gas recovery method, no matter be single method or integrated approach, the relevant device in its retracting device is as refrigeration compressor, vavuum pump, and its power resources such as watch-dog are the electric main adopting mostly, energy consumption is larger, and the operating cost that oil gas reclaims is higher.And solar energy is to utilize clean reproducible energy the most widely, it is ripe that solar photovoltaic powered technology has been tending towards, and cost is in continuous reduction, this technology can less or not rely on civil power, both can complete oil-gas recovery device supply of electric power, can also provide electric power to systems such as the air-conditioning of affiliated structures, illuminations.In short of electricity or there is no the place of civil power, more can bring into play the effect of its uniqueness.Utilize the VOCs retracting device of Driven by Solar Energy more energy-conservation, because solar energy power generating is just in time synchronizeed with the running time of petrochemical industry, oil VOCs retracting device.
At present, adopt condensation adsorption integrated technology to reclaim the system of oil gas at home and abroad, its oil-gas recovery device power resources are all to adopt electric main.Chinese Patent Application No. is 200710060342.2 disclosed petrol station photoelectric complementary absorption condensation adsorption variable frequency oil gas recycling methods, and its oil gas removal process is comprised of 2 links of 3 techniques of 2 kinds of energy.2 kinds of energy are solar energy and the conventional electric power energy, solar energy provides the energy for the oil gas absorption vacuum equipment of recovery process and the circulating pump of solvent absorption process, and the conventional electric power energy is to provide the energy for refrigeration plant and other equipment of condensation recovery process, the direct current that solar panel is converted to still needs to convert to alternating current and is supplied to consumer again.3 techniques are solvent absorption, condensation absorption, the absorption of the oil gas degree of depth.The one-level oil gas of centralized recovery when 2 links are RTC unloading reclaims link and the nozzle secondary oil gas that oiling is reclaimed to client vehicles reclaims link, and it is to enter solvent absorption device, condensation absorption plant, oil gas degree of depth adsorbent equipment through oil collecting pipe to reclaim successively that one-level reclaims the oil gas that link collects, and the oil gas that secondary recovery link produces only enters oil gas degree of depth adsorbent equipment through oil collecting pipe and reclaims.Separately having Chinese Patent Application No. is the adsorption variable frequency oil gas recycling method of 200710060338.6 disclosed moving condensations and light-electricity complementary, the method is that an oil gas that produces oil gas while utilizing the oil truck of Tape movement condensed oil-gas reclaimer to complete by oil truck to gas station's tank unloading reclaims, the fixed absorption oil-gas recovery device in gas station complete to through absorb, condensed oil-gas reclaimer tail gas after treatment carries out that secondary oil gas reclaims and nozzle is the oil gas recovery that user produces while refueling, and solar energy is only also to provide energy for gas station's absorption oil-gas recovery device, also need to be supplied to again consumer after DC-AC conversion.
Summary of the invention
The present invention seeks to recycle for the not enough one that provides of prior art is provided that clean energy resource, environmental protection, automaticity are high, easy to operate, compact conformation, take up an area little, the solar photovoltaic powered organic vapor condensation adsorption recovery system of construction install convenience.
The technical scheme that realizes the object of the invention is: comprise solar photovoltaic powered system and organic vapor condensation adsorption recovery system two parts, solar photovoltaic powered system connects each consumer in organic steam condensing adsorption recovery system, solar photovoltaic powered system comprises the solar photovoltaic cell panel being connected with the first port of photovoltaic Power Controller, and the second port of photovoltaic Power Controller is connected with output protecting device, the 3rd port is connected with batteries, the 4th port is connected with secondary power system, secondary power system connects monitoring and display system, batteries is connected with secondary power system with output protecting device respectively, and four ports that exchange input PFC rectifier are connected with secondary power system, output protecting device, electric main, diesel generating set respectively, organic vapor condensation adsorption recovery system comprises oil gas discharge, suction fan, surge tank, ice chest, compressor, condenser and two absorbing cylinders, the outlet of oil gas discharge is connected with the import of suction fan, the outlet of suction fan is connected with the import of surge tank through the second check-valves, the outlet of surge tank is connected with ice chest, ice chest and compressor, condenser, expansion valve has formed refrigerating circuit, ice chest bottom is connected with oil storage tank by oil exit pipe, ice chest upside outlet line is via first, the second DC driven anti-explosion electric valve is respectively with in parallel first, the entrance point of the second absorbing cylinder is connected, first, the second absorbing cylinder bottom is respectively through the 3rd, the 4th DC driven anti-explosion electric valve is connected with the entrance point of vavuum pump, the port of export of vavuum pump is connected with the entrance point of vapour liquid separator, and the port of export of vapour liquid separator is connected with the entrance point of ice chest.
The invention has the advantages that:
1, removal process of the present invention is comprised of 2 techniques of 2 kinds of energy.2 kinds of energy remain solar energy and the conventional electric power energy, but the solar energy in the present invention is main power source, for all devices in recovery system provides the energy, and employing direct current supply, do not need direct current and exchange conversion, and the conventional electric power energy is just as the supplementary energy when solar energy is not enough.2 techniques are cryogenic condensation and absorbing process, and these 2 process units are all the fixed or skid-mounted device connecting successively, the VOCs gas that oil gas reclaims discharge collection all needs to process successively through cryogenic condensation and adsorbent equipment, then the tail gas of emission compliance.The basic various fields such as petrochemical industry, oil, chemical industry, traffic, building decoration that solve give off the recovery problem of a large amount of VOCs foul gas when producing, selling and uying various oil products, chemical products, and the three wastes (waste water,waste gas and industrial residue) discharge of can not regenerating.
2, utilize Driven by Solar Energy, play dual energy-conservation effect, solar energy power generating is just in time synchronizeed with the running time of petrochemical industry, oil VOCs retracting device, therefore the present invention adopts solar energy power generating and battery DC power-supply system, and composition autonomous power supply system, for organic vapor is administered retracting device power supply, can effectively alleviate power tense problem, in conjunction with diesel generating set, can not rely on electric main completely, be specially adapted to the gas station in short of electricity region, field.
3, compressor, vavuum pump and the bleed blower fan of the DC driven of adjustable speed on organic vapor condensation adsorption recovery system, have been used, direct current and the energy loss that exchanges conversion have been avoided, and by speed governing, can reduce the start-stop time of compressor, improve control characteristic and the systematic function of organic vapor condensate recovery system, improved energy-saving effect and the operational efficiency of system.What provide due to photovoltaic cell is all direct current, as long as output voltage is accomplished to the numerical value of regulation, just can be for each consumer provides direct current power, and reduced by interchange and transferred direct current to or by direct current, transferred to the AC-DC conversion times of interchange, reduced conversion loss.Solar energy power generating is directly used in and drives various direct-flow electricity utilization apparatus, than changing solar energy power generating into alternating current, then give various AC electric equipment power supplies, can save 2% ~ 5% of retracting device total energy consumption.
4, the adsorbent in absorbing cylinder has adopted the new and effective adsorbent of the applicable absorption oil-gas components such as polymeric adsorbent, modified silica-gel or active carbon compound adsorbent, improved the Adsorption and desorption characteristics of adsorbent, avoided that traditional acticarbon heat of adsorption is obvious, desorb is difficult, reached the problems such as time of equilibrium adsorption is long.
5, organic vapor condensation adsorption is administered integrated condensation, the absorption recovery combination process applied of recovery system, improved organic efficiency, reduced tail gas organic vapor content, make a whole set of recovery system to discharge of pollutant sources point ambient atmosphere removing pollutant rate >=98%(to oil gas: atmosphere pollution purifying rate >=99%), for the chemical industry pollutant that has recovery value, the VOCs rate of recovery >=95%(oil gas recovery rate: >=99%).
6, the present invention is designed to complete skid closed box type complete machine structure, and floor space is few, and complete machine realizes human oriented design, and automaticity is high.
7, the present invention is to the various occasions with VOCs discharge; carry out performance optimization; realization is to having petrochemical industry, the oil of recovery value, the VOCs of chemical industry pollutant to reclaim; breaking out of fire and poisoning danger have been reduced; also can prevent from polluting, protection of the environment, is beneficial to health; there is stronger social benefit, environmental benefit and economic benefit.
Accompanying drawing explanation
Fig. 1 is structure connection diagram of the present invention (being recovered as example with oil gas);
I-organic vapor condensation adsorption recovery system; II-solar photovoltaic powered system;
1. oil gas discharge, 2. the DC driven suction fan of adjustable speed, 3, 4. check-valves, 5. surge tank, 6. safety valve, 7. Pressure gauge, 8. ice chest, 9. the DC driven compressor of adjustable speed, 10. condenser, 11. expansion valves, 12, 13. absorbing cylinders, 14 ~ 17. DC driven anti-explosion electric valves, 18, 19. check-valves, 20, 24. fire-retardant breather valves, the DC driven vavuum pump of 21. adjustable speeds, 22. vapour liquid separators, 23. oil storage tanks, 25. oil exit pipes, 26. photovoltaic battery panels, 27. photovoltaic Power Controllers, 28. output protecting devices, 29. secondary power systems, 30. batteries, 31. monitoring and display systems, 32. exchange input PFC rectifier, 33. electric mains, 34. diesel generating sets.
The specific embodiment
As Fig. 1, the present invention includes solar photovoltaic powered system II (supply module) and organic vapor condensation adsorption recovery system I (recycling module) two parts.Solar photovoltaic powered system II connects the various consumers in organic steam condensing adsorption recovery system I, and so that dc source to be provided, organic vapor condensation adsorption recovery system I adopts solar energy power generating and battery direct current supply.
Solar photovoltaic powered system II comprises solar photovoltaic cell panel 26, photovoltaic Power Controller 27, batteries 30, exchanges the compositions such as input PFC rectifier 32, monitoring and display system 31 and output protecting device 28.Solar photovoltaic cell panel 26 is connected with the first port of photovoltaic Power Controller 27; the second port of photovoltaic Power Controller 27 is connected with output protecting device 28; the 3rd port of photovoltaic Power Controller 27 is connected with batteries 30, and the 4th port is connected with secondary power system 29.Secondary power system 29 is directly connected with monitoring and display system 31; The first port of batteries 30 is connected with output protecting device 28, and the 3rd port is connected with secondary power system 29; Four connectivity ports that exchange input PFC rectifier 32 are connected with secondary power system 29, output protecting device 28, electric main 33, diesel generating set 34 respectively.
Utilize gas station's awning and office's ceiling or other vacant physical spaces that solar panel 26 is installed, for organic vapor condensation adsorption recovery system I provides the energy.Photovoltaic cell in photovoltaic battery panel 26 is polycrystalline silicon material.When having solar irradiation; photovoltaic battery panel 26 converts solar energy to the direct current energy of current source type; by photovoltaic Power Controller 27, the unstable DC voltage conversion of photovoltaic cell output is become to burning voltage or electric current; to guarantee continous-stable power-supplying, then by output protecting device 28, export direct current and be supplied to each consumer in organic vapor condensation adsorption recovery system I.When organic vapor condensation adsorption recovery system I electric load is closed or when power consumption is less than photovoltaic power generation quantity, the unnecessary electrical power storage that photovoltaic battery panel 26 produces is in batteries 30, and batteries 30 plays a part energy storage, regulate and distribute electric energy and to the large electric current of terminal instantaneous relase.When not having solar energy or solar energy inadequate; by batteries 30 supplementary powers; the consumer of being exported direct current and be supplied to organic vapor condensation adsorption recovery system I by output protecting device 28, the battery in batteries 30 is plumbic acid maintenance-free battery or solar energy storage colloid storage battery.Some input secondary power system 29 of the stable DC electricity that photovoltaic Power Controller 27 is converted to, then the monitoring and display system 31 that is whole device by this system is powered.When there is no solar energy, batteries 30 also can be secondary power system 29 and powers.In supply module, be also connected with and exchange input PFC rectifier 32; when solar energy is not enough; after the storage of electrical energy of batteries 30 uses; exchange input PFC rectifier 32 and will automatically connect electric main 33 or diesel generating set 34; AC rectification is become to direct current and be supplied to output protecting device 28 and secondary power system 29; electric main 33 is as solar powered supplementary energy when not enough, guarantees whole organic vapor condensation adsorption recovery system I power supply continuing.
Solar photovoltaic powered system II in the present invention has the functions such as recharging converter, MPPT maximum power point tracking control, output short circuit protection, the protection of battery over-discharge, overvoltage protection, island protect, overtemperature protection, overload protection, monitoring display.The main protection output short-circuit of output protecting device 28, battery over-discharge etc., 31 of monitoring and display systems are mainly used in monitoring and show photovoltaic cell output voltage, power, electric weight, battery tension, charging current, system output dc voltage, current and other parameters.If after the storage of electrical energy of batteries 30 uses, exchange input PFC rectification circuit 32 and can automatically connect electric main 33 or diesel generating sets 34, continue to keep organic vapor condensation adsorption recovery system I to power after converting alternating current to direct current.
Organic vapor condensation adsorption recovery system I is comprised of 3 continuous links, be oil gas collection section, oil gas cryogenic condensation exhausting section and oil gas degree of depth adsorption section, comprise oil gas discharge 1, suction fan 2, surge tank 5, ice chest 8, compressor 9, condenser 10, absorbing cylinder 12,13 etc.Organic vapor condensation adsorption recovery system I is designed to complete skid closed box type complete machine structure, control button and Displaying Meter are set on the panel of complete machine structure, in fully sheathed case, by the control of motor-driven valve automatic or manual, be equipped with photoelectricity touch sensitive panel the comfortable interface of control on the spot can be provided.Explosion-proof electrostatic material and technological requirement are selected in being connected between recovery system and the each equipment of solar photovoltaic powered system II.The inside of recovery system connects selects electrostatically conductive oil-tolerant metal hose, is conveniently connected and installed.Simple in structure, compact, floor space is few.Complete machine is realized human oriented design, and automaticity is high, and complete machine operated valve member is little.
Above-mentioned oil gas collection section comprises suction fan 2 and surge tank 5 and collecting pipe, and the oil gas sucking through suction fan 2 is sent in surge tank 5 by pipeline, and adjusting gas flow and flow velocity in surge tank 5 make oil gas enter ice chest 8 with more stable fluidised form.Oil gas cryogenic condensation exhausting section comprises ice chest 8 and the cryogenic condensation unit being connected with ice chest 8, the oil gas that is reclaimed discharge introducing ice chest 8 by oil gas reclaims through the condensation of cryogenic condensation unit, its rate of recovery reaches 80% left and right, produce the tail gas that reclaims oil product and contain a small amount of oil gas, reclaim oil product and get to oil storage tank 23 by the oil exit pipe of ice chest below.Oil gas degree of depth absorption exhausting section comprises 2 absorbing cylinders 12,13 and vavuum pump 21, utilize suitable adsorbent in absorbing cylinder, to adsorb the oil gas reclaiming in the tail gas being flowed out by ice chest, absorbing cylinder adopts 2 alternate runs, alternately vacuum desorption, thereby adsorbent can be used for a long time, and after desorb, the recirculation of high-concentration oil vapor out enters oil gas and reclaims discharge and enter cryogenic condensation recovery system again and reclaimed by cryogenic condensation.
The outlet of oil gas discharge 1 is connected with the import of suction fan 2, and the outlet of suction fan 2 connects check-valves 4, through check-valves 4, with the import of surge tank 5, is connected, and is also connected with the check-valves 3 of cross-over connection between the import of oil gas discharge 1 and surge tank 5; On surge tank 5, be provided with Pressure gauge 6 and safety valve 7.Between the import of the outlet of surge tank 5 and ice chest 8, by ball valve, be connected; Ice chest 8 bottoms are connected with oil storage tank 23 by oil exit pipe 25, ice chest 8 upside outlet lines are connected with the entrance point of absorbing cylinder 12,13 in parallel respectively via DC driven anti-explosion electric valve 14,15, and ice chest 8 has also formed refrigerating circuit with compressor 9, condenser 10, expansion valve 11.From tail gas further degree of depth absorption in absorbing cylinder 12 or 13 of ice chest 8, the tail gas of absorbing cylinder 12,13 connects fire-retardant breather valve 20 through check- valves 18,19 respectively, by fire-retardant breather valve 20, be discharged in atmosphere, prevent that outside burning things which may cause a fire disaster from being introduced in recovery system and oil tank and being caused the accident by breather pipe; Absorbing cylinder 12,13 bottoms are connected with the entrance point of vavuum pump 16 through DC driven anti-explosion electric valve 16,17 respectively; The port of export of vavuum pump 21 is connected with the entrance point of vapour liquid separator 22, and the port of export of vapour liquid separator 22 is connected with the entrance point of ice chest 8; Fire-retardant breather valve 24 is installed on oil storage tank 23, prevents that outside burning things which may cause a fire disaster from being introduced in recovery system and oil tank and being caused the accident by breather pipe.
Ice chest 8 adopts segmentation condensation structure, is divided into precooling backheat section, preposition precooling zone and rearmounted condensation segment.The task of precooling backheat section is fully to reclaim the cold of tail gas, and preposition precooling zone is chilled to 4 ℃ of left and right in advance by recovery gas, with as far as possible by the moisture removal reclaiming in gas.Generally for oil gas, reclaim, rearmounted condensation segment condensation segment temperature control is in-40~-50 ℃ (in order to make the concentration of emission of retracting device be controlled at very low level) or-20~-30 ℃ (for the cost of investment and the energy consumption that make retracting device are controlled at low level).Thereby the most of oil gas in oil gas and air Mixture is condensed, and in ice chest 8, isolates liquid oil droplet and enter oil storage tank 23.Ice chest 8 afterbodys arrange demister, and the oil droplet in vaporific oil gas is separated as far as possible.According to condensation temperature technological requirement, adopted and met environmental-protecting performance, security performance, economic performance, and the R404a of non-corrosiveness, chemical stability and good thermal stability, R507, R407c or R410a cold-producing medium.Compressor 9, vavuum pump 21 and suction fan 2 adopt the direct current supply of adjustable speed, avoid direct current and the energy loss link that exchanges conversion, have improved control characteristic and the systematic function of recovery system, improve the energy-saving effect of system.Carry high-vacuum desorption function, vavuum pump 21 can be dry vacuum pump or wet vacuum pump, as slide sheet type, rotary-vane vaccum pump, or dry type scroll vacuum pump.Vavuum pump 21 operations can operate by automatic or manual, and its desorption time is set according to service condition, is generally 30 ~ 40min.Adsorbent in absorbing cylinder 12,13 has adopted the new and effective adsorbent of the applicable absorption oil-gas components such as polymeric adsorbent, modified silica-gel or active carbon compound adsorbent, adsorbent carries from desorb function, after adsorbent absorption is saturated, utilize vavuum pump 21 to carry out desorb, improved the Adsorption and desorption characteristics of adsorbent, avoided that traditional acticarbon heat of adsorption is obvious, desorb is difficult, reached the problems such as time of equilibrium adsorption is long.
During the work of organic vapor condensation adsorption recovery system I, adopt the combination process route adsorbing after first cryogenic condensation.Utilize oil gas discharge 1 and bleed blower fan 2, oil gas is introduced to surge tank 5, in surge tank 5, regulate oil gas flow and flow velocity, make oil gas enter ice chest 8 with more stable fluidised form.Between oil gas discharge 1 and surge tank 5, be also provided with the check-valves 3 of cross-over connection, when retracting device is for occasions such as gas stations, likely do not need bleed blower fan 2, but directly oil gas is introduced to surge tank 5 by oil gas discharge 1.In the refrigerating circuit being formed by ice chest 8, compressor 9, condenser 10, expansion valve 11, after cold-producing medium pressurizes by compressor 9, enter condenser 10 condensations, after expansion valve 11 expansion coolings, enter ice chest 9 evaporation endothermics again, thereby make oil gas by heat exchanger, lower the temperature, be condensed into liquid state at ice chest 9, then the liquid oil product that condensation obtains enters into oil storage tank 23 by the oil exit pipe 25 of ice chest 8 belows, thereby oil gas major part is recovered.Generally for oil gas, reclaim, condensation segment temperature control is in-40~-50 ℃ (in order to make the concentration of emission of retracting device be controlled at very low level) or-20~-30 ℃ (for the cost of investment and the energy consumption that make retracting device are controlled at low level).From a small amount of oil gas tail gas not being recovered further degree of depth absorption in absorbing cylinder 12,13 respectively of ice chest 8.Absorbing cylinder 12,13 parallel connections, and as absorber-desorption device, be used alternatingly in turn.Detailed process is: when absorbing cylinder 12 is in adsorbed state, absorbing cylinder 13 during in desorption state, DC driven anti-explosion electric valve 14,17 is opened, DC driven anti-explosion electric valve 15,16 cuts out, now from the tail gas of ice chest 8, enter further degree of depth adsorption treatment in absorbing cylinder 12, then tail gas is through check-valves 18, and fire-retardant breather valve 20 is discharged in atmosphere.Meanwhile, adsorb the oil gas in saturated absorbing cylinder 13, by DC driven anti-explosion electric valve 17, utilize the fine pumping of vavuum pump 16, and be desorbed out.When absorbing cylinder 12 absorption reaches capacity, after absorbing cylinder 13 desorbs complete, will switch, and be about to DC driven anti-explosion electric valve 14,17 and close, DC driven anti-explosion electric valve 15,16 is opened, now absorbing cylinder 12 is just converted to vacuum desorption state, and absorbing cylinder 13 is just converted to adsorbed state.By manufacturing process determination, be generally 30 ~ 40min the switching time of absorbing cylinder 12,13.The high-concentration oil vapor that vavuum pump 21 is released separates after sealing fluid through vapour liquid separator 22, returns to ice chest 8 and carries out condensation recycling, thereby realize oil gas, all reclaims.

Claims (4)

1. a solar photovoltaic powered organic vapor condensation adsorption recovery system, comprise solar photovoltaic powered system and organic vapor condensation adsorption recovery system two parts, it is characterized in that: solar photovoltaic powered system connects each consumer in organic steam condensing adsorption recovery system;
Described solar photovoltaic powered system comprises the solar photovoltaic cell panel (26) that solar energy is converted to direct current energy being connected with the first port of photovoltaic Power Controller (27), and the second port of photovoltaic Power Controller (27) is connected with output protecting device (28), the 3rd port is connected with batteries (30), the 4th port is connected with secondary power system (29); Secondary power system (29) connects monitoring and display system (31), batteries (30) is connected with secondary power system (29) with output protecting device (28) respectively, and four ports that exchange input PFC rectifier (32) are connected with secondary power system (29), output protecting device (28), electric main (33), diesel generating set (34) respectively;
Described organic vapor condensation adsorption recovery system comprises oil gas discharge (1), suction fan (2), surge tank (5), ice chest (8), compressor (9), condenser (10) and two absorbing cylinders, the outlet of oil gas discharge (1) is connected with the import of suction fan (2), the outlet of suction fan (2) is connected through the import of the same surge tank of the second check-valves (4) (5), the outlet of surge tank (5) is connected with ice chest (8), ice chest (8) and compressor (9), condenser (10), expansion valve (11) has formed refrigerating circuit, ice chest (8) bottom is connected by the same oil storage tank of oil exit pipe (25) (23), ice chest (8) upside outlet line is via first, the second DC driven anti-explosion electric valve is respectively with in parallel first, the entrance point of the second absorbing cylinder is connected, first, the second absorbing cylinder bottom is respectively through the 3rd, the 4th DC driven anti-explosion electric valve is connected with the entrance point of vavuum pump (21), the port of export of vavuum pump (21) is connected with the entrance point of vapour liquid separator (22), and the port of export of vapour liquid separator (22) is connected with the entrance point of ice chest (8).
2. solar photovoltaic powered organic vapor condensation adsorption recovery system according to claim 1, is characterized in that: between the import of oil gas discharge (1) and surge tank (5), be connected the first check-valves (3); Surge tank (5) is provided with Pressure gauge (6) and safety valve (7); First, second absorbing cylinder connects through the 3rd, the 4th check-valves the first fire-retardant breather valve (20) being communicated with atmosphere respectively; Oil storage tank (23) is provided with the second fire-retardant breather valve (24).
3. solar photovoltaic powered organic vapor condensation adsorption recovery system according to claim 1, it is characterized in that: when having solar irradiation, photovoltaic battery panel (26) converts solar energy to direct current energy, by output protecting device (28), exports each consumer in described organic vapor condensation adsorption recovery system to; When described organic vapor condensation adsorption recovery system electric load is closed or when power consumption is less than photovoltaic power generation quantity, the unnecessary electrical power storage of photovoltaic battery panel (26) is in batteries (30); When there is no solar energy, batteries (30) is secondary power system (29) power supply; After the storage of electrical energy of batteries (30) uses; exchange input PFC rectifier (32) and connect electric main (33) or diesel generating set (34), AC rectification is become to direct current and be supplied to output protecting device (28) and secondary power system (29).
4. solar photovoltaic powered organic vapor condensation adsorption recovery system according to claim 1, it is characterized in that: regulate the middle oil gas flow of surge tank (5) and flow velocity to make oil gas enter ice chest (8), cold-producing medium enters condenser (10) condensation by compressor (9) pressurization, after expanding cooling, expansion valve (11) enters ice chest (8) evaporation endothermic, the fluid oil obtaining enters into oil storage tank (23) by oil exit pipe (25), the oil gas tail gas not being recovered in ice chest (8) is respectively first, degree of depth absorption in the second absorbing cylinder, when the first absorbing cylinder (12) is in absorption and the second absorbing cylinder (13) during in desorption state, first, the 4th DC driven anti-explosion electric valve is opened, second, the 3rd DC driven anti-explosion electric valve cuts out, the tail gas of ice chest (8) enters adsorption treatment in the first absorbing cylinder (12), the oil gas adsorbing in saturated the second absorbing cylinder (13) is desorbed out by the fine pumping of vavuum pump (21), when the first absorbing cylinder (12) absorption reaches capacity and after the second absorbing cylinder (13) desorb completes, the first, the 4th DC driven anti-explosion electric valve cuts out, second, third DC driven anti-explosion electric valve is opened, the first absorbing cylinder (12) is converted to vacuum desorption state, and the second absorbing cylinder (13) is converted to adsorbed state.
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CN103520947B (en) * 2013-09-29 2015-05-13 江苏中远环保科技有限公司 Method and device for recycling multicomponent oil gas separately with condensation method
CN105031962A (en) * 2015-08-31 2015-11-11 常州大学 Novel methyl alcohol waste gas recovery system adopting condensation and adsorption integration technology
CN107050912B (en) * 2017-01-13 2022-08-02 陕西延长石油(集团)有限责任公司 Gas-phase condensed liquid recovery system and method
CN113546435B (en) * 2021-08-03 2022-07-22 合肥茂腾环保科技有限公司 Organic solvent water mixing type pressurizing, cooling and separating system and method for flat panel display
CN114477064A (en) * 2022-02-23 2022-05-13 河南申越检测技术有限公司 Oil gas processing system of filling station

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