CN102533007A - Anion water-based emulsion coating and preparation method thereof - Google Patents
Anion water-based emulsion coating and preparation method thereof Download PDFInfo
- Publication number
- CN102533007A CN102533007A CN2011104214006A CN201110421400A CN102533007A CN 102533007 A CN102533007 A CN 102533007A CN 2011104214006 A CN2011104214006 A CN 2011104214006A CN 201110421400 A CN201110421400 A CN 201110421400A CN 102533007 A CN102533007 A CN 102533007A
- Authority
- CN
- China
- Prior art keywords
- based emulsion
- water
- negative ion
- ion water
- emulsion coatings
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses anion water-based emulsion coating which comprises the following components in percentage by weight: 30-40% of water-based emulsion, 7-13% of filler, 13-26% of pigment, 0.2-2% of thickener, 0.05-0.2% of tripolyphosphate, 0.1-1% of mildew preventive, 5-7% of anion material, 0.5-2% of coalescing agent, 0.1-1% of hydroxyethyl cellulose, 0.3-3% of auxiliary assistant, and the remaining water; and the auxiliary assistant is selected from one of dispersant, defoamer and multifunctional assistant. The anion water-based emulsion coating can radiate anion and oxygen ion and can simultaneously absorb various harmful materials such as benzene, formaldehyde, uranium and the like so as to effectively purify the indoor environment and ensure the physical and psychological health of people in the living space. The invention further discloses a preparation method of the anion water-based emulsion coating.
Description
Technical field
The present invention relates to a kind of aqueous emulsion paint, particularly a kind of negative ion water-based emulsion coatings; The invention still further relates to the preparation method of this negative ion water-based emulsion coatings.
Background technology
Aqueous emulsion paint is through being permitted years of development, though haveing breakthrough aspect health, the environmental protection, with respect to common coating, only be that organic flux and the harmful substance contents such as heavy metal and formaldehyde of self are controlled.Yet when this series products itself and other finishing material are used simultaneously, can not effectively prevent the toxic substance of other material production.
Summary of the invention
The technical problem that the present invention will solve is: provide a kind of and can radiate oxonium ion, can absorb objectionable impuritiess such as various benzene, formaldehyde, uranium simultaneously, reach the negative ion water-based emulsion coatings of effective purification of indoor environment.
In order to achieve the above object, the technical scheme of negative ion water-based emulsion coatings employing of the present invention is:
Negative ion water-based emulsion coatings is characterized in that comprising by weight percentage the water-based emulsion of following component: 30-40%, the filler of 7-13%; The pigment of 13-26%, the thickening material of 0.2-2%, the tri-polyphosphate of 0.05-0.2%; The mould inhibitor of 0.1-1%, the anion material of 5-7%, the film coalescence aid of 0.5-2%; 0.1-1 Natvosol, the auxiliary addition agent of 0.3-3%, surplus is a water; Said auxiliary addition agent is selected from least a in dispersion agent, skimmer and the multifunctional assistant.
This negative ion water-based emulsion coatings can radiate negative ion, oxonium ion, can absorb objectionable impuritiess such as various benzene, formaldehyde, uranium simultaneously, reaches effective purification of indoor environment, the physical and mental health of underwriter in the space of life.
As a kind of optimal way of technique scheme, said water-based emulsion is a modified plant gum, and the preparation method of modified plant gum comprises following steps:
A) the intensification deionized water drops into vegetable jelly subsequently and makes its dissolving to 80-85 ℃;
B) drop into behind the vegetable jelly 1 hour, add an organosilane monomer, catalytic promoter and plant monomer, and be warming up to 220-240 ℃, constant temperature 4.5-5.5 hour subsequently;
C) regulate the Ph value to 6-7;
Wherein, the consumption of the material of above-mentioned each step calculates by weight and is respectively: 300 parts in water, vegetable jelly 150-180 part, an organosilane monomer 35-40 part, 25 parts of plant monomers, catalytic promoter 0.5-0.8 part; Said plant monomer is and the corresponding plant monomer of vegetable jelly;
In addition, said modified plant gum has following character:
Outward appearance: milky white liquid;
Solid content: 45-48%;
Ph value: 6-7;
Use is coated with-4 glasss of viscosity that measures: 16-20s.
In the preferred embodiment, the raw material of modified plant gum is degradable vegetable jelly, thereby can further reduce the content of heavy metal ion in the water-soluble emulsion coating.Through detecting, this negative ion water-based emulsion coatings has following character:
Volatile organic content≤3.6g/L;
Free formaldehyde content≤0.013k/kg;
Dissoluble lead content≤0.11mg/kg;
The separated content of solubility: do not measure;
Soluble chromium content≤0.49mg/kg;
Soluble mercury content≤0.37mg/kg
Negative ion quantity >=600ion/cc.
The technical problem that the present invention further will solve is, a kind of preparation method of negative ion water-based emulsion coatings is provided, and comprises following steps:
1) aqueous solution, Natvosol and the ammoniacal liquor with tri-polyphosphate drops in the deionized water, fully stirs to reach even thick liquid;
2) drop into auxiliary addition agent, pigment and filler successively;
3) material is fully stirred, and be ground to fineness less than 80 μ m;
4) add anion material and water-based emulsion and stirring;
5) add film coalescence aid, and utilize ammoniacal liquor adjustment Ph value to 8-9;
6) fully stir under at rotating speed less than 800 rev/mins condition;
7) drop into thickening material and regulate viscosity;
8) mix colours making sheet behind the adding mould inhibitor.
Embodiment
Below in conjunction with embodiment preferred implementation of the present invention is further explained.
Embodiment the 1, the 2nd, as the example of the preferred implementation of the water-based emulsion in the negative ion water-based emulsion coatings.
Embodiment 1:
With the guar gum is the feedstock production modified plant gum, and its preparation method comprises following steps:
A) intensification 300g deionized water to 80 ℃ drops into the 150g guar gum subsequently and makes its dissolving;
B) drop into behind the guar gum 1 hour, add 35g methyl chlorosilane, 0.5g catalytic promoter and 25g guar-bean monomer, and be warming up to 220 ℃, constant temperature is 4.5 hours subsequently;
C) regulate Ph value to 6.
The modified plant gum of present embodiment product has following character:
Outward appearance: milky white liquid;
Solid content: 45%;
Ph value: 6;
Viscosity: 20s (being coated with-4 glasss);
Calcium ion stability: qualified;
Brushing resistance ability: good;
Film forming properties: good.
Embodiment 2:
With the fenugreek gum is the feedstock production modified plant gum.
Prepare modified plant gum according to the following steps:
A) intensification 300g deionized water to 85 ℃ drops into the 180g fenugreek gum subsequently and makes its dissolving;
B) drop into behind the fenugreek gum 1 hour, add 35g propyltrichlorosilan, 0.8g catalytic promoter and 25g tonka-bean monomer, and be warming up to 240 ℃, constant temperature is 5.5 hours subsequently;
C) regulate Ph value to 7.
The modified plant gum of present embodiment product has following character:
Outward appearance: milky white liquid;
Solid content: 48%;
Ph value: 7;
Viscosity: 16s (being coated with-4 glasss);
Calcium ion stability: qualified;
Brushing resistance ability: good;
Film forming properties: good.
What the detection method of above mentioned Calcium ion stability adopted is following steps:
The modified plant gum that in the 10ml test tube, adds 5ml adds the calcium chloride solution of 1ml 5wt% then, shakes up and leaves standstill, and after 1 hour, 24 hours, observes, and as finding layering, phenomenons such as deposition flocculation are defective, otherwise then are qualified.
As some preferred exemplary of the vegetable jelly of raw material, except guar gum and fenugreek gum that embodiment 1,2 mentions, can also be sesbania gum or flax gum.
In addition, the methyl chlorosilane among the embodiment 1 is replaceable to be the propyltrichlorosilan among the embodiment 2, otherwise also can.Thereby as a kind of summary, so long as an organosilane monomer all can solve the technical problem that the present invention will solve.That is to say, except methyl chlorosilane and propyltrichlorosilan, also can select in phenyl chlorosilane, methyl ethylene chlorosilane, ethyl trichlorosilane, vinyl trichloro silane and the γ-chloropropyl trichloro-silane any for use.
Embodiment 3-embodiment 5 is preferred exemplary of preparation negative ion water-based emulsion coatings.
Embodiment 3:
Press the negative ion of formulation shown in the table 1 water-based emulsion coatings, said preparation method comprises following steps:
1) aqueous solution, Natvosol and the ammoniacal liquor with tri-polyphosphate drops in the deionized water, fully stirs to reach even thick liquid;
2) drop into auxiliary addition agent, pigment and filler successively;
3) material is fully stirred, and be ground to fineness less than 80 μ m;
4) add anion material and water-based emulsion and stirring;
5) add film coalescence aid, and utilize ammoniacal liquor adjustment Ph value to 8-9;
6) fully stir under at rotating speed less than 800 rev/mins condition;
7) drop into thickening material and regulate viscosity;
8) mix colours making sheet behind the adding mould inhibitor.
Table 1
| Component | Content (wt%) | Remarks |
| Water | 34.3 | |
| 10% the tripolyphosphate aqueous solution | 0.5 | The aqueous solution of 10wt% |
| Natvosol 30000s | 0.1 | 30000s |
| 5040 dispersion agents | 0.1 | Shenzhen Hai Chuan chemical company |
| The AMP-95 multifunctional assistant | 0.1 | U.S. Mykrolis Corp |
| The 309A skimmer | 0.1 | Shenzhen Hai Chuan chemical company |
| White titanium pigment | 15 | Rutile-type |
| Zinc sulfide white | 7 | 800 orders |
| Ultrafine heavy calcium | 3 | 800 orders |
| Talcum powder | 4 | 800 orders |
| Water-based emulsion | 30 | The modified plant gum of embodiment 1 |
| Secondary ionic material | 5 | |
| Film coalescence aid | 0.5 | The Yi Siman chemical industry |
| Ammoniacal liquor | 0.1 | |
| Thickening material (polyurethanes) | 0.1 | Shenzhen Hai Chuan chemical company |
| Mould inhibitor | 0.1 | Shenzhen Hai Chuan chemical company |
Embodiment 2:
Repeat embodiment 1, difference is that prescription prepares shown in the use table 2.
Table 2
| Component | Content (wt%) | Remarks |
| Water | 25 | ? |
| 10% the tripolyphosphate aqueous solution | 1.1 | The aqueous solution of 10wt% |
| Natvosol 30000s | 0.2 | 30000s |
| 5040 dispersion agents | 0.2 | Shenzhen Hai Chuan chemical company |
| The AMP-95 multifunctional assistant | 0.1 | U.S. Mykrolis Corp |
| The 309A skimmer | 0.2 | Shenzhen Hai Chuan chemical company |
| White titanium pigment | 17 | Rutile-type |
| Zinc sulfide white | 5 | 800 orders |
| Ultrafine heavy calcium | 5 | 800 orders |
| Talcum powder | 6 | 800 orders |
| Water-based emulsion | 32 | The modified plant gum of embodiment 2 |
| Secondary ionic material | 6.6 | |
| Film coalescence aid | 1 | The Yi Siman chemical industry |
| Ammoniacal liquor | 0.2 | |
| Thickening material (polyurethanes) | 0.3 | Shenzhen Hai Chuan chemical company |
| Mould inhibitor | 0.1 | Shenzhen Hai Chuan chemical company |
Embodiment 3:
Repeat embodiment 1, difference is that prescription prepares shown in the use table 3.
Table 3
| Component | Content (wt%) | Remarks |
| Water | 21.5 | |
| The tripolyphosphate aqueous solution | 2 | The aqueous solution of 10wt% |
| Natvosol | 1 | 30000s |
| 5040 dispersion agents | 1 | Shenzhen Hai Chuan chemical company |
| The AMP-95 multifunctional assistant | 1 | U.S. Mykrolis Corp |
| The 309A skimmer | 1 | Shenzhen Hai Chuan chemical company |
| White titanium pigment | 13 | Rutile-type |
| Ultrafine heavy calcium | 6 | 800 orders |
| Talcum powder | 7 | 800 orders |
| Water-based emulsion | 35 | The modified plant gum of embodiment 1 |
| Secondary ionic material | 7 | |
| Film coalescence aid | 2 | The Yi Siman chemical industry |
| Ammoniacal liquor | 0.5 | |
| Thickening material (polyurethanes) | 1 | Shenzhen Hai Chuan chemical company |
| Mould inhibitor | 1 | Shenzhen Hai Chuan chemical company |
Embodiment 6:
The product that embodiment 3-5 is made detects, and obtains data as shown in table 4:
Table 4
| ? | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Volatile organic content | <3.6g/L | <3.6g/L | <3.6g/L |
| Free formaldehyde content | <0.013g/kg | <0.013g/kg | <0.013g/kg |
| Dissoluble lead content | <0.11mg/kg | <0.11mg/kg | <0.11mg/kg |
| Soluble cadmium content | Do not detect | Do not detect | Do not detect |
| Soluble chromium content | <0.49mg/kg | <0.49mg/kg | <0.49mg/kg |
| Soluble mercury content | <0.37mg/kg | <0.37mg/kg | <0.37mg/kg |
| Negative ion quantity | 1200/cm 3 | 1200/cm 3 | 1200/cm 3 |
Combine embodiment that the present invention has been done detailed explanation above; But the present invention is not limited to this; The technician in any present technique field under the prerequisite of aim of the present invention, can make various distortion and modification to it in the ken that is possessed.
Claims (9)
1. negative ion water-based emulsion coatings is characterized in that comprising by weight percentage the water-based emulsion of following component: 30-40%, the filler of 7-13%; The pigment of 13-22%, the thickening material of 0.1-1%, the tri-polyphosphate of 0.05-0.2%; The mould inhibitor of 0.1-1%, the anion material of 5-7%, the film coalescence aid of 0.5-2%; 0.1-1 Natvosol, the auxiliary addition agent of 0.3-3%, surplus is a water; Said auxiliary addition agent is selected from least a in dispersion agent, skimmer and the multifunctional assistant.
2. negative ion water-based emulsion coatings according to claim 1 is characterized in that: comprise following component by weight percentage: 32% water-based emulsion, 11% filler; 22% pigment, 0.3% thickening material, 0.11% tri-polyphosphate; 0.1% mould inhibitor, 6.6% anion material, 1% film coalescence aid; Other auxiliary agents of 0.5%, surplus are water; Said other auxiliary agents comprise 0.2% dispersion agent, 0.1% multifunctional assistant, 0.2% skimmer.
3. negative ion water-based emulsion coatings according to claim 1 and 2 is characterized in that: said filler is ultrafine heavy calcium and/or talcum powder.
4. negative ion water-based emulsion coatings according to claim 1 and 2 is characterized in that: said pigment is white titanium pigment and/or zinc sulfide white.
5. negative ion water-based emulsion coatings according to claim 1 and 2 is characterized in that: said water-based emulsion is a modified plant gum, and the preparation method of modified plant gum comprises following steps:
The intensification deionized water drops into vegetable jelly subsequently and makes its dissolving to 80-85 ℃;
Dropped into behind the vegetable jelly 1 hour, and added an organosilane monomer, catalytic promoter and plant monomer, and be warming up to 220-240 ℃, constant temperature 4.5-5.5 hour subsequently;
Regulate the Ph value to 6-7;
Wherein, the consumption of the material of above-mentioned each step calculates by weight and is respectively: 300 parts in water, vegetable jelly 150-180 part, an organosilane monomer 35-40 part, 25 parts of plant monomers, catalytic promoter 0.5-0.8 part; Said plant monomer is and the corresponding plant monomer of vegetable jelly;
In addition, said modified plant gum has following character:
Outward appearance: milky white liquid;
Solid content: 45-48%;
Ph value: 6-7;
Use is coated with-4 glasss of viscosity that measures: 16-20s.
6. negative ion water-based emulsion coatings according to claim 1 and 2 is characterized in that: said thickening material is the polyurethanes thickening material.
7. the preparation method of negative ion water-based emulsion coatings is characterized in that comprising following steps:
The aqueous solution, Natvosol and the ammoniacal liquor of tri-polyphosphate are dropped in the deionized water, and fully stirring reaches even thick liquid;
Drop into auxiliary addition agent, pigment and filler successively;
Material is fully stirred, and be ground to fineness less than 80 μ m;
Add anion material and water-based emulsion and stirring;
Add film coalescence aid, and utilize ammoniacal liquor adjustment Ph value to 8-9;
Fully stir under at rotating speed less than 800 rev/mins condition;
Drop into thickening material and regulate viscosity;
Mix colours making sheet after adding mould inhibitor.
8. the preparation method of negative ion water-based emulsion coatings according to claim 7 is characterized in that: in step 1), the aqueous solution of tri-polyphosphate is the aqueous solution of 10wt% tri-polyphosphate.
9. the preparation method of negative ion water-based emulsion coatings according to claim 7 is characterized in that: in step 1), the viscosity of Natvosol is 30000s.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110421400.6A CN102533007B (en) | 2011-12-16 | 2011-12-16 | Anion water-based emulsion coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110421400.6A CN102533007B (en) | 2011-12-16 | 2011-12-16 | Anion water-based emulsion coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102533007A true CN102533007A (en) | 2012-07-04 |
| CN102533007B CN102533007B (en) | 2014-02-26 |
Family
ID=46341099
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110421400.6A Expired - Fee Related CN102533007B (en) | 2011-12-16 | 2011-12-16 | Anion water-based emulsion coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102533007B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103084326A (en) * | 2013-02-01 | 2013-05-08 | 江声 | Coating method of molecular resonance membrane (MRM) material powder sprayed on element |
| CN104449306A (en) * | 2013-09-24 | 2015-03-25 | 丹阳恒安化学科技研究所有限公司 | Technique for processing latex paint |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1810899A (en) * | 2005-01-27 | 2006-08-02 | 上海富臣化工有限公司 | Antiseptic wall paint capable of eliminating bad smell |
| CN101343452A (en) * | 2008-08-12 | 2009-01-14 | 无锡市虎皇漆业有限公司 | High-efficiency insect-disinfestation environment friendly paint and preparation thereof |
| CN101684221A (en) * | 2008-09-26 | 2010-03-31 | 杨录真 | Anion healthy paint |
-
2011
- 2011-12-16 CN CN201110421400.6A patent/CN102533007B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1810899A (en) * | 2005-01-27 | 2006-08-02 | 上海富臣化工有限公司 | Antiseptic wall paint capable of eliminating bad smell |
| CN101343452A (en) * | 2008-08-12 | 2009-01-14 | 无锡市虎皇漆业有限公司 | High-efficiency insect-disinfestation environment friendly paint and preparation thereof |
| CN101684221A (en) * | 2008-09-26 | 2010-03-31 | 杨录真 | Anion healthy paint |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103084326A (en) * | 2013-02-01 | 2013-05-08 | 江声 | Coating method of molecular resonance membrane (MRM) material powder sprayed on element |
| CN104449306A (en) * | 2013-09-24 | 2015-03-25 | 丹阳恒安化学科技研究所有限公司 | Technique for processing latex paint |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102533007B (en) | 2014-02-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102863874B (en) | Water-base epoxy zinc-rich priming paint and preparation method thereof | |
| CN104341880B (en) | aqueous fluorocarbon coating and preparation method thereof | |
| CN105253977B (en) | A kind of environmental protection flocculant of reduction COD and its preparation method and application | |
| CN104356935A (en) | Water-based organosilicon coating and preparation method thereof | |
| CN1810899A (en) | Antiseptic wall paint capable of eliminating bad smell | |
| CN104046179B (en) | A kind of aqueous rust-proof coatings and preparation method thereof | |
| CN105219195B (en) | A kind of compound sliver paint of aqueous colorful and preparation method thereof | |
| CN102977695A (en) | Environment-friendly interior wall coating material with calcined shell powder as base stock and preparation method of environment-friendly interior wall coating material | |
| CN101684221A (en) | Anion healthy paint | |
| CN106928791A (en) | A kind of environment-friendly water-based acrylic modified alkyd protective paint for spray coating mechanical equipment and material and preparation method thereof | |
| CN104119800B (en) | Water-based coating compositions of special efficacy health indoor wall and preparation method thereof | |
| CN105017906A (en) | Water-in-water multi-color water paint and preparation method thereof | |
| CN105482079A (en) | Non-ionic waterborne epoxy curing agent and preparation method thereof | |
| CN103131283A (en) | Water-based indoor facing smokeless fire-retardant paint | |
| CN102533007B (en) | Anion water-based emulsion coating and preparation method thereof | |
| CN105463472A (en) | Water-soluble antirust agent | |
| CN104119708A (en) | Inorganic zinc-rich anticorrosive paint | |
| CN102702871A (en) | Water-based paint and preparation method thereof | |
| CN107021532B (en) | Graphene paint mist treating agent, preparation method and use method thereof | |
| CN113122030A (en) | Diatomite modified inorganic water-based paint and preparation method thereof | |
| CN102363704A (en) | Aqueous blocking agent and its preparation method | |
| CN105776459B (en) | Environment-friendly type flocculant and its preparation method and application suitable for Painting Shop circulating water treatment | |
| CN102532336B (en) | Modified vegetable glue, preparation method thereof and application of modified vegetable glue to preparation of emulsion paint | |
| WO2015100582A1 (en) | Aqueous inorganic zinc-rich primer and preparation method thereof | |
| CN106147418B (en) | Water paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140226 Termination date: 20151216 |
|
| EXPY | Termination of patent right or utility model |