CN102517118A - Preparation method for efficient sulfur-fixing agent - Google Patents

Preparation method for efficient sulfur-fixing agent Download PDF

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Publication number
CN102517118A
CN102517118A CN 201110405478 CN201110405478A CN102517118A CN 102517118 A CN102517118 A CN 102517118A CN 201110405478 CN201110405478 CN 201110405478 CN 201110405478 A CN201110405478 A CN 201110405478A CN 102517118 A CN102517118 A CN 102517118A
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CN
China
Prior art keywords
fixing agent
efficient sulfur
preparation
calcium chloride
coal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 201110405478
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Chinese (zh)
Inventor
王立群
雷威
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
XI'AN RUIJINYUAN ENERGY TECHNOLOGY Co Ltd
Original Assignee
XI'AN RUIJINYUAN ENERGY TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by XI'AN RUIJINYUAN ENERGY TECHNOLOGY Co Ltd filed Critical XI'AN RUIJINYUAN ENERGY TECHNOLOGY Co Ltd
Priority to CN 201110405478 priority Critical patent/CN102517118A/en
Publication of CN102517118A publication Critical patent/CN102517118A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a preparation method for an efficient sulfur-fixing agent, which relates to the fields of circulating fluidized bed boiler combustion, desulfurization and ash modification. The efficient sulfur-fixing agent is burned together with coal, so that a hydraulic gelled material is generated; the calcium oxide content of marlite is (35-44) percent; and a mineralizer can be added into the marlite, and is a uniform mixture of a small amount of fluorite powder which contains (60-40) percent of calcium fluoride and calcium chloride-containing waste residues discharged by a chemical plant serving as auxiliary materials. Due to the adoption of the preparation method, an optimal desulfurization effect is achieved for a circulation fluidized bed boiler, burning residues can be modified into a 100 percent efficiently-utilized hydraulic gelled material in a furnace, the burning thermal efficiency of the boiler is increased, and the problem of coking in the furnace caused by coal burning is solved. A use method disclosed by the invention has the advantages of simple process, high efficiency, environmental friendliness and convenience for using.

Description

A kind of preparation method of efficient sulfur-fixing agent
Technical field
The present invention relates to a kind of fluid fuel, relate in particular to a kind of preparation method of efficient sulfur-fixing agent.
Background technology
Coal water slurry be a kind of coal-based liquid state for oil fuel, be divided into conventional coal water slurry, Coal Slurry and low heat value coal water slurry.Why coal slurry fuel can replace oil, and its important characteristic can atomize rapidly for making coal water slurry as oil with pump delivery and atomizing rapidly in stove exactly, often needs the low coal water slurry of viscosity, and the low concentration that certainly will influence coal slurry of viscosity.Concentration is low, and unit volume heat energy just reduces, so " high density, LV " becomes technological difficulties.
Summary of the invention
The purpose of this invention is to provide that a kind of technology is simple, efficient, the preparation method of environmental protection, coal based fluid fuel easy to use.
For achieving the above object; The solution that the present invention adopts is: a kind of preparation method of efficient sulfur-fixing agent; It is characterized in that: described method comprises burning in circulating fluid bed boiler, solid sulphur and lime-ash modification, generates hydraulic cementing materials behind this efficient sulfur-fixing agent and the coal combustion; The basal component of said efficient sulfur-fixing agent is the dead meal of the used Wingdale in cement mill---muddy limestone, and this malmy calcium oxide content is (35-44) %; Said muddy limestone also can add mineralizer, this mineralizer by fluorite powder and/or chemical plant row contain the waste residue of calcium chloride, this fluorite powder fluorinated calcium is (60-40) %, it is (40-30) % that this waste residue contains calcium chloride; Said sulphur-fixing agent is to be major ingredient with the muddy limestone, and being arranged the waste residue that contains calcium chloride with a spot of fluorite powder and/or chemical plant is the uniform mixture that auxiliary material is formed.
The present invention makes circular fluid bed that best sweetening effectiveness arranged and can make the modification in stove of incendiary resistates become the 100% efficient hydraulic cementing materials that utilizes; The combustion thermal efficiency of boiler is improved; Also solved coking problem in the coal-fired stove that is brought, method of use technology of the present invention is simple, efficient, environmental protection, easy to use.
Embodiment
A kind of preparation method of efficient sulfur-fixing agent, described method may further comprise the steps:
Step 1: burning in circulating fluid bed boiler, solid sulphur and lime-ash modification generate hydraulic cementing materials behind this efficient sulfur-fixing agent and the coal combustion;
Step 2: the basal component of said efficient sulfur-fixing agent is the dead meal of the used Wingdale in cement mill---muddy limestone, and this malmy calcium oxide content is (35-44) %;
Step 3: said muddy limestone also can add mineralizer, this mineralizer by fluorite powder and/or chemical plant row contain the waste residue of calcium chloride, this fluorite powder fluorinated calcium is (60-40) %, it is (40-30) % that this waste residue contains calcium chloride; Said sulphur-fixing agent is to be major ingredient with the muddy limestone, and being arranged the waste residue that contains calcium chloride with a spot of fluorite powder and/or chemical plant is the uniform mixture that auxiliary material is formed.
The present invention makes circular fluid bed that best sweetening effectiveness arranged and can make the modification in stove of incendiary resistates become the 100% efficient hydraulic cementing materials that utilizes; The combustion thermal efficiency of boiler is improved; Also solved coking problem in the coal-fired stove that is brought, method of use technology of the present invention is simple, efficient, environmental protection, easy to use.
The above embodiment is not whole or unique embodiment of the present invention, and the conversion of any equivalence that those of ordinary skills take technical scheme of the present invention through reading specification sheets of the present invention is claim of the present invention and contains.

Claims (1)

1. the preparation method of an efficient sulfur-fixing agent is characterized in that: described method comprises burning in circulating fluid bed boiler, solid sulphur and lime-ash modification, generates hydraulic cementing materials behind this efficient sulfur-fixing agent and the coal combustion; The basal component of said efficient sulfur-fixing agent is the dead meal of the used Wingdale in cement mill---muddy limestone, and this malmy calcium oxide content is (35-44) %; Said muddy limestone also can add mineralizer, this mineralizer by fluorite powder and/or chemical plant row contain the waste residue of calcium chloride, this fluorite powder fluorinated calcium is (60-40) %, it is (40-30) % that this waste residue contains calcium chloride; Said sulphur-fixing agent is to be major ingredient with the muddy limestone, and being arranged the waste residue that contains calcium chloride with a spot of fluorite powder and/or chemical plant is the uniform mixture that auxiliary material is formed.
CN 201110405478 2011-12-08 2011-12-08 Preparation method for efficient sulfur-fixing agent Pending CN102517118A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201110405478 CN102517118A (en) 2011-12-08 2011-12-08 Preparation method for efficient sulfur-fixing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 201110405478 CN102517118A (en) 2011-12-08 2011-12-08 Preparation method for efficient sulfur-fixing agent

Publications (1)

Publication Number Publication Date
CN102517118A true CN102517118A (en) 2012-06-27

Family

ID=46288193

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 201110405478 Pending CN102517118A (en) 2011-12-08 2011-12-08 Preparation method for efficient sulfur-fixing agent

Country Status (1)

Country Link
CN (1) CN102517118A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105585263A (en) * 2015-12-23 2016-05-18 中国建筑材料科学研究总院 Preparation method of cement clinker

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105585263A (en) * 2015-12-23 2016-05-18 中国建筑材料科学研究总院 Preparation method of cement clinker
CN105585263B (en) * 2015-12-23 2018-01-16 中国建筑材料科学研究总院 The preparation method of clinker

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Application publication date: 20120627