CN102512910A - Smoke heat exchange process for recycling evaporated water of gas desulfurization system - Google Patents

Smoke heat exchange process for recycling evaporated water of gas desulfurization system Download PDF

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Publication number
CN102512910A
CN102512910A CN2011103747323A CN201110374732A CN102512910A CN 102512910 A CN102512910 A CN 102512910A CN 2011103747323 A CN2011103747323 A CN 2011103747323A CN 201110374732 A CN201110374732 A CN 201110374732A CN 102512910 A CN102512910 A CN 102512910A
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heat exchange
flue gas
smoke
desulphurization system
level
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CN2011103747323A
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CN102512910B (en
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盛海强
程常杰
莫建松
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Zhejiang Tianlan Environmental Protection Technology Co Ltd
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Zhejiang Tianlan Environmental Protection Technology Co Ltd
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Abstract

The invention discloses a smoke heat exchange process for recycling evaporated water of a gas desulfurization system. The smoke heat exchange process comprises the following steps of: outlet smoke cooling, original smoke cooling and outlet smoke heating, wherein underground water or industrial water is used as a heat exchange medium, the heat exchange medium is subjected to primary heat exchange together with outlet smoke exiting from an absorption tower of the gas desulfurization system so as to cool and dewater the outlet smoke, smoke condensed water generated after the primary heat exchange is subjected to precipitation through a settling pond so as to be recycled by the gas desulfurization system, the heat exchange medium subjected to the primary heat exchange is subjected to secondary heat exchange with original smoke entering the absorption tower of the gas desulfurization system so as to cool the original smoke, the heat exchange medium subjected to secondary heat exchange is used for heating air so as to carry out tertiary heat exchange, and then enters into the gas desulfurization system so as to be recycled, and the heated air is mixed with the outlet smoke subjected to the primary heat exchange so as to be used as purified smoke for emission. Compared with the conventional smoke heat exchange system, the smoke heat exchange process has the advantages of remarkably reducing the smoke water content and the dust content, greatly reducing the operation cost, recycling the smoke condensed water, and being high in heat utilization rate.

Description

The flue gas heat exchange technology that a kind of desulphurization system evaporation water is recycled
Technical field
The present invention relates to coal-burned industrial boiler stove and coal-fired plant flue gas desulfur technology, specifically is the flue gas heat exchange technology that a kind of desulphurization system evaporation water is recycled.
Background technology
In the wet desulfurization system, the washing process of the hot flue gas in the spray column needs the evaporation large quantity of moisture, and this makes that the fresh water (FW) consumption of desulphurization system is very big.Simultaneously, remove the reasons such as restriction, fluctuation of operating conditions, demister flushing of fog effect in actual use owing to demister, absorption tower outlet flue gas generally contains part water droplet and slurries.A large amount of water vapours enter atmosphere through the outlet flue gas, have increased the water consumption of desulphurization system, and simultaneously, the part slurries that carry in the flue gas are taken out of with flue gas, will increase outlet exhaust gas dust content.In addition, in exhaust pass,,, will cause bigger corrosion to flue and follow-up equipment because this part drop is acid because droplet impact walling of flue and cooling condensation cause flue part ponding.
For avoiding the exhaust pass corrosion, adopt smoke re-heater (GGH) to improve exit gas temperature usually, to prevent flue gas with water condensate corrosion exhaust pass; But because GGH easy blocking; Most of desulfurization project are abandoned, and simultaneously, absorption tower outlet flue gas is after heating up; The slurries drop that it carries will still be present in the flue gas, increase dust content in the flue gas.
Summary of the invention
The present invention is directed in the above-mentioned existing desulphurization system problems such as the fresh water (FW) consumption is big, equipment corrosion, a kind of flue gas heat exchange technology of utilizing water to recycle as the desulphurization system evaporation water of heat transferring medium is provided.
The flue gas heat exchange technology that a kind of desulphurization system evaporation water is recycled; Comprise that outlet flue gas cool-down, former flue gas cool-down and outlet flue gas heat up; Adopt underground water or other water for industrial uses as heat transferring medium; Heat transferring medium carries out the heat exchange of I level with the outlet flue gas that goes out the desulphurization system absorption tower, and the outlet flue gas cool-down is dewatered, and the flue gas condensing water that produces after the heat exchange of I level is used for desulphurization system slurry, demister flushing, filter cloth washing etc. through post precipitation; Heat transferring medium after the heat exchange of I level carries out the heat exchange of II level with the former flue gas that gets into the desulphurization system absorption tower, and former flue gas is lowered the temperature; Heat transferring medium after the heat exchange of II level heats air and carries out the heat exchange of III level, gets into being used to of desulphurization system slurry, demister flushing, filter cloth washing etc. then; Air after III level heat exchange heating mixes with the outlet flue gas after the heat exchange of I level, as clean fume emission; The place is provided with steam pipework at III level heat exchanger, when cause when the coolant-temperature gage of II level heat exchange hangs down, III level heat exchanger being carried out thermal compensation owing to former flue-gas temperature fluctuation.
Described former flue gas is after II level heat exchange cooling, and temperature preferably is controlled at less than 120 ℃.
The outlet flue gas on described desulphurization system absorption tower is after the air Hybrid Heating, and temperature preferably is controlled at more than 70 ℃.
Droplet content is less than 50mg/Nm in the described clean flue gas 3
Technology of the present invention will go out the outlet flue gas cool-down on desulphurization system absorption tower earlier, and the most of drop in the flue gas removes through condensation, and it is recycled, and be employed in the method for sneaking into hot-air in the outlet flue gas again the outlet flue gas is heated.Compare tradition only to the technology of outlet flue gas heating, technology provided by the invention can significantly reduce desulphurization system water consumption, with 2 * 300MW fired power generating unit, 2000000Nm 3/ h exhaust gas volumn, 50 ℃ of calculating of exit gas temperature, if reduce to 40 ℃ to exit gas temperature, saturated vapor condensation water quantity 50t/h nearby only.In addition; Than adopting GGH directly to heat the technology of outlet flue gas; Method provided by the invention dewaters more thorough, also can solve because the flue gas band is starched the outlet exhaust gas dust content problem of higher that causes, simultaneously; The method heating outlet flue gas of hot-air is sneaked in employing, has avoided the susceptible to plugging problem of similar GGH.
The advantage of technology of the present invention is: adopt water as heat transferring medium, utilize the heat outlet flue gas that absorbs from former flue gas, improved the heat energy utilization rate; Outlet flue gas condensing water is recycled through the preliminary sedimentation tank post precipitation, adds water behind the hot-air and also gets into desulphurization system and carry out reuse, has avoided water resource waste.
Description of drawings
Fig. 1 is the device sketch map of process implementing example of the present invention.
1-I level heat exchanger, 2-II level heat exchanger, 3-III level heat exchanger, 4-gas mixer, 5-sedimentation basin, 6-absorption tower
The specific embodiment
The present invention adopts device as shown in Figure 1; Practical implementation is following: adopt water as heat transferring medium; Carry out the heat exchange of I level through I level heat exchanger 1 and the outlet flue gas that goes out desulphurization system absorption tower 6; The outlet flue gas is lowered the temperature and dewatered, and the flue gas condensing water that produces after the heat exchange of I level gets into desulphurization system through sedimentation basin 5 post precipitations and is back to desulphurization system slurry, demister flushing, filter cloth washing etc.; Water after 1 heat exchange of I level heat exchanger gets into II level heat exchanger 2, lowers the temperature to getting into absorption tower 6 former flue gases; Water through 2 heat exchange of II level heat exchanger gets into III level heat exchanger 3, and air is heated, and gets into being used to of desulphurization system slurry, demister flushing, filter cloth washing etc. then; Air after the heating mixes with the outlet flue gas through gas mixer 4, as clean fume emission; The place is provided with steam pipework at III level heat exchanger, when cause when the coolant-temperature gage of II level heat exchange hangs down, carrying out thermal compensation, to satisfy the exit gas temperature requirement owing to former flue-gas temperature fluctuation.

Claims (7)

1. the flue gas heat exchange technology recycled of a desulphurization system evaporation water; It is characterized in that step is following: heat transferring medium and the outlet flue gas that goes out the desulphurization system absorption tower are carried out the heat exchange of I level; The outlet flue gas cool-down is dewatered, and the flue gas condensing water that produces after the heat exchange of I level is back to desulphurization system through post precipitation; Heat transferring medium after the heat exchange of I level carries out the heat exchange of II level with the former flue gas that gets into the desulphurization system absorption tower, and former flue gas is lowered the temperature; Heat transferring medium after the heat exchange of II level heats air and carries out the heat exchange of III level, and the heat transferring medium after the heat exchange of III level gets into the desulphurization system reuse; Air after the heating mixes with outlet flue gas after the heat exchange of I level, as clean fume emission.
2. the flue gas heat exchange technology that desulphurization system evaporation water according to claim 1 is recycled, it is characterized by: described heat transferring medium is underground water or water for industrial use.
3. the flue gas heat exchange technology that desulphurization system evaporation water according to claim 1 is recycled is characterized by: the increase steam pipework is vulcanized and is tasted in the heat exchange of described III level.
4. the flue gas heat exchange technology that desulphurization system evaporation water according to claim 1 is recycled, it is characterized by: the outlet flue gas on described desulphurization system absorption tower is after the air Hybrid Heating, and temperature is more than 70 ℃.
5. the flue gas heat exchange technology that desulphurization system evaporation water according to claim 1 is recycled is characterized by: described former flue gas is after II level heat exchange cooling, and temperature is less than 120 ℃.
6. the flue gas heat exchange technology that desulphurization system evaporation water according to claim 1 is recycled is characterized by: the air after described III level heat exchange heating, temperature is greater than 85 ℃.
7. the flue gas heat exchange technology that desulphurization system evaporation water according to claim 1 is recycled, it is characterized by: droplet content is less than 50mg/Nm in the described clean flue gas 3
CN 201110374732 2011-11-23 2011-11-23 Smoke heat exchange process for recycling evaporated water of gas desulfurization system Active CN102512910B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105536456A (en) * 2016-01-13 2016-05-04 北京亿盛源电力技术有限公司 Wet desulphurization and flue gas emission system and method thereof
CN105833688A (en) * 2016-05-06 2016-08-10 山东岱荣节能环保科技有限公司 Energy-saving clean emission device for coke oven underground flue gas
CN106669342A (en) * 2017-01-09 2017-05-17 南京龙源环保有限公司 Novel demisting system
CN106693641A (en) * 2017-01-25 2017-05-24 浙江环兴机械有限公司 System integrating with waste heat recovery, dedusting, deodorization, desulfurization, denitration and white smoke removing and treating method of system
CN112933902A (en) * 2021-01-28 2021-06-11 广东科洁环保工程技术有限公司 Sintering flue gas desulfurization denitration waste heat utilization equipment

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1887412A (en) * 2005-06-28 2007-01-03 王宇 Method of preventing wet desulfurized fume from dewing corrosion
CN201164790Y (en) * 2008-01-22 2008-12-17 王敏 Gas-liquid contact non-phase-change intermediate medium heat exchange wet-type desulfurizer

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1887412A (en) * 2005-06-28 2007-01-03 王宇 Method of preventing wet desulfurized fume from dewing corrosion
CN201164790Y (en) * 2008-01-22 2008-12-17 王敏 Gas-liquid contact non-phase-change intermediate medium heat exchange wet-type desulfurizer

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105536456A (en) * 2016-01-13 2016-05-04 北京亿盛源电力技术有限公司 Wet desulphurization and flue gas emission system and method thereof
CN105833688A (en) * 2016-05-06 2016-08-10 山东岱荣节能环保科技有限公司 Energy-saving clean emission device for coke oven underground flue gas
CN105833688B (en) * 2016-05-06 2018-03-02 山东岱荣节能环保科技有限公司 The energy-saving clean tapping equipment of coke oven underground flue gas
CN106669342A (en) * 2017-01-09 2017-05-17 南京龙源环保有限公司 Novel demisting system
CN106693641A (en) * 2017-01-25 2017-05-24 浙江环兴机械有限公司 System integrating with waste heat recovery, dedusting, deodorization, desulfurization, denitration and white smoke removing and treating method of system
CN112933902A (en) * 2021-01-28 2021-06-11 广东科洁环保工程技术有限公司 Sintering flue gas desulfurization denitration waste heat utilization equipment

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