CN102504400B - Anti-perspective logistics storage and transportation self-adhesive film - Google Patents

Anti-perspective logistics storage and transportation self-adhesive film Download PDF

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CN102504400B
CN102504400B CN201110341364.2A CN201110341364A CN102504400B CN 102504400 B CN102504400 B CN 102504400B CN 201110341364 A CN201110341364 A CN 201110341364A CN 102504400 B CN102504400 B CN 102504400B
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kilogram
kilograms
defoamer
mlldpe
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CN102504400A (en
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陈建朝
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XIAMEN JUFU PLASTIC PRODUCTS CO Ltd
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XIAMEN JUFU PLASTIC PRODUCTS CO Ltd
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Abstract

The invention discloses an anti-perspective logistics storage and transportation self-adhesive film. The film can be a single-layer structure and formed by mixing 0.2-5% of a defoaming agent, 40-99.6% of LLDPE (Linear Low Density Polyethylene), 0-50% of MLLDPE (Mixed Linear Low Density Polyethylene) and 0.2-5% of polyisobutene. The film can also be an A/B type double-layer structure and composed of 10% of an A layer and 90% of a B layer or composed of 20% of the A layer and 80% of the B layer or composed of 30% of the A layer and 70% of the B layer, wherein the defoaming agent is added into both the A layer and the B layer. The film can also be an A/B/C type three-layer structure and composed of 10% of the A layer, 80% of the B layer and 10% of a C layer or composed of 20% of the A layer, 60% of the B layer and 20% of the C layer or composed of 30% of the A layer, 40% of the B layer and 30% of the C layer, wherein the defoaming agent is added into the A layer, the B layer and the C layer. In the event of being not dried, the film disclosed by the invention is capable of keeping original weight, eliminating film bubbles and ensuring quality.

Description

Anti-perspective logistics accumulating self-adhesive film
Technical field
The present invention relates to a kind of Anti-perspective logistics accumulating self-adhesive film.
Background technology
Plastic material is subject to the time of tide to contain micro-moisture, if do not eliminated, can form bubble or water wave at processed product surface, and the performance of goods and outward appearance are impacted.And utilize electrothermal drying machinery to eliminate the traditional technology of moisture, and need to shift to an earlier date dried feed to cause and produce inconvenience, exist and extend goods process period and cause production efficiency low, the weak points such as electric quantity consumption, processing environment deterioration, production cost increase.So the plastic material making moist is produced film and had the dual problem that affects quality, increases cost, how to address these problems, become a great problem of pendulum in face of dealer.
Logistics accumulating self-adhesive film mostly adopts polyethylene and polyisobutene to mix and produces, and when polyethylene is subject to the time of tide, direct production film can produce bubble or water wave and affect quality.If material is dried, cause a series of problem of degradation under cost increase and production efficiency of drying.
Therefore, research and develop a kind of these product starting material that can solve and be subject to the time of tide, direct production and do not affect the novel technique of output and quality, is necessary in fact.
Summary of the invention
The object of the present invention is to provide a kind of Anti-perspective logistics accumulating self-adhesive film, in material need not oven dry situation, can keep former weight, can eliminate film bubble again, ensure the quality of products.
In order to reach above-mentioned purpose, solution of the present invention is:
Anti-perspective logistics accumulating self-adhesive film, for single layer structure, by weight percentage, by 0.2~5% defoamer (masterbatch), 40~99.6%LLDPE(linear low density polyethylene), 0~50%MLLDPE(metallocene linear-low density polyethylene) and 0.2~5% polyisobutene mix.
Anti-perspective logistics accumulating self-adhesive film, is A/B type bilayer structure, by weight percentage, 10%A layer and 90%B layer, consists of, and in A layer and B layer, all adds defoamer; Wherein, A layer by weight percentage, by 0.1~1% defoamer (masterbatch), 0~9.7%LLDPE(linear low density polyethylene), 0~6% MLLDPE(metallocene linear-low density polyethylene) and 0.2~3% polyisobutene mix; B layer by weight percentage, by 0.2~5% defoamer (masterbatch), 30~89.8%LLDPE(linear low density polyethylene), 0~50%MLLDPE(metallocene linear-low density polyethylene) and 0~5% polyisobutene mix.
Anti-perspective logistics accumulating self-adhesive film, is A/B type bilayer structure, by weight percentage, 20%A layer and 80%B layer, consists of, and in A layer and B layer, all adds defoamer; Wherein, A layer by weight percentage, by 0.1~2% defoamer (masterbatch), 0~19.7%LLDPE(linear low density polyethylene), 0~15% MLLDPE(metallocene linear-low density polyethylene) and 0.2~3% polyisobutene mix; B layer by weight percentage, by 0.2~5% defoamer (masterbatch), 20~79.8%LLDPE(linear low density polyethylene), 0~50%MLLDPE(metallocene linear-low density polyethylene) and 0~5% polyisobutene mix.
Anti-perspective logistics accumulating self-adhesive film, is A/B type bilayer structure, by weight percentage, 30%A layer and 70%B layer, consists of, and in A layer and B layer, all adds defoamer; Wherein, A layer by weight percentage, by 0.1~2% defoamer (masterbatch), 0~29.7%LLDPE(linear low density polyethylene), 0~25% MLLDPE(metallocene linear-low density polyethylene) and 0.2~3% polyisobutene mix; B layer by weight percentage, by 0.2~5% defoamer (masterbatch), 10~69.8%LLDPE(linear low density polyethylene), 0~50%MLLDPE(metallocene linear-low density polyethylene) and 0~5% polyisobutene mix.
Anti-perspective logistics accumulating self-adhesive film, is A/B/C type three-decker, by weight percentage, 10%A layer, 80%B layer and 10%C layer, consists of, and in A layer, B layer and C layer, all adds defoamer; Wherein, A layer by weight percentage, by 0.1~1% defoamer (masterbatch), 0~9.7%LLDPE(linear low density polyethylene), 0~6% MLLDPE(metallocene linear-low density polyethylene) and 0.2~3% polyisobutene mix; B layer by weight percentage, by 0.2~5% defoamer (masterbatch), 25~79.8%LLDPE(linear low density polyethylene), 0~50%MLLDPE(metallocene linear-low density polyethylene) mix; C layer by weight percentage, by 0.1~1% defoamer (masterbatch), 0~9.9%LLDPE(linear low density polyethylene), 0~6% MLLDPE(metallocene linear-low density polyethylene) and 0~3% polyisobutene mix.
Anti-perspective logistics accumulating self-adhesive film, is A/B/C type three-decker, by weight percentage, 20%A layer, 60%B layer and 20%C layer, consists of, and in A layer, B layer and C layer, all adds defoamer; Wherein, A layer by weight percentage, by 0.1~2% defoamer (masterbatch), 0~19.7%LLDPE(linear low density polyethylene), 0~15% MLLDPE(metallocene linear-low density polyethylene) and 0.2~3% polyisobutene mix; B layer by weight percentage, by 0.2~5% defoamer (masterbatch), 5~59.8%LLDPE(linear low density polyethylene), 0~50%MLLDPE(metallocene linear-low density polyethylene) mix; C layer by weight percentage, by 0.1~2% defoamer (masterbatch), 0~19.9%LLDPE(linear low density polyethylene), 0~15% MLLDPE(metallocene linear-low density polyethylene) and 0~3% polyisobutene mix.
Anti-perspective logistics accumulating self-adhesive film, is A/B/C type three-decker, by weight percentage, 30%A layer, 40%B layer and 30%C layer, consists of, and in A layer, B layer and C layer, all adds defoamer; Wherein, A layer by weight percentage, by 0.1~2% defoamer (masterbatch), 0~29.7%LLDPE(linear low density polyethylene), 0~25% MLLDPE(metallocene linear-low density polyethylene) and 0.2~3% polyisobutene mix; B layer by weight percentage, by 0.2~3% defoamer (masterbatch), 0~39.8%LLDPE(linear low density polyethylene), 0~37%MLLDPE(metallocene linear-low density polyethylene) mix; C layer by weight percentage, by 0.1~2% defoamer (masterbatch), 0~29.9%LLDPE(linear low density polyethylene), 0~25% MLLDPE(metallocene linear-low density polyethylene) and 0~3% polyisobutene mix.
Described defoamer is plastic defoaming agent, also claims plastic defoaming mother material or moisture absorption masterbatch, is to aim to solve to take a kind of new function masterbatch that PE, PP, ABS, PS, nylon develops as the bubble problem of raw-material plastics in the course of processing.This masterbatch, before plastics processing, by a small amount of interpolation and simple mixing, and need not pass through drying process, just can forming process, have easy to usely, and enhance productivity, the advantage of reduction energy consumption.
Adopt after such scheme, no matter the present invention is individual layer, extrude structure, double-layer coextrusion structure or three-layer co-extruded structure, as long as increase defoamer in each layer, defoamer, in material need not oven dry situation, can guarantee production efficiency, can eliminate film bubble again, ensure the quality of products, reduce costs.
Embodiment
Embodiment mono-:
Anti-perspective logistics accumulating self-adhesive film, for single layer structure, individual layer expressing technique formula (every 100 kilograms of proportioning ratios): by 0.2~5 kilogram of defoamer (masterbatch), 40~99.6 kilograms of LLDPE(linear low density polyethylenes), 0~50 kilogram of MLLDPE(metallocene linear-low density polyethylene) and 0.2~5 kilogram of polyisobutene mix.
Embodiment bis-:
Anti-perspective logistics accumulating self-adhesive film, is A/B type bilayer structure, double-layer coextrusion technical recipe (every 100 kilograms of proportioning ratios): 10 kilograms, A layer, 90 kilograms, B layer; A layer is by 0.1~1 kilogram of defoamer (masterbatch), 0~9.7 kilogram of LLDPE(linear low density polyethylene), 0~6 kilogram of MLLDPE(metallocene linear-low density polyethylene) and 0.2~3 kilogram of polyisobutene mix; B layer is by 0.2~5 kilogram of defoamer (masterbatch), 30~89.8 kilograms of LLDPE(linear low density polyethylenes), 0~50 kilogram of MLLDPE(metallocene linear-low density polyethylene) and 0~5 kilogram of polyisobutene mix.
Embodiment tri-:
Anti-perspective logistics accumulating self-adhesive film, is A/B type bilayer structure, double-layer coextrusion technical recipe (every 100 kilograms of proportioning ratios): 20 kilograms, A layer, 80 kilograms, B layer; A layer is by 0.1~2 kilogram of defoamer (masterbatch), 0~19.7 kilogram of LLDPE(linear low density polyethylene), 0~15 kilogram of MLLDPE(metallocene linear-low density polyethylene) and 0.2~3 kilogram of polyisobutene mix; B layer is by 0.2~5 kilogram of defoamer (masterbatch), 20~79.8 kilograms of LLDPE(linear low density polyethylenes), 0~50 kilogram of MLLDPE(metallocene linear-low density polyethylene) and 0~5 kilogram of polyisobutene mix.
Embodiment tetra-:
Anti-perspective logistics accumulating self-adhesive film, is A/B type bilayer structure, double-layer coextrusion technical recipe (every 100 kilograms of proportioning ratios): 30 kilograms, A layer, 70 kilograms, B layer; A layer is by 0.1~2 kilogram of defoamer (masterbatch), 0~29.7 kilogram of LLDPE(linear low density polyethylene), 0~25 kilogram of MLLDPE(metallocene linear-low density polyethylene) and 0.2~3 kilogram of polyisobutene mix; B layer is by 0.2~5 kilogram of defoamer (masterbatch), 10~69.8 kilograms of LLDPE(linear low density polyethylenes), 0~50 kilogram of MLLDPE(metallocene linear-low density polyethylene) and 0~5 kilogram of polyisobutene mix.
Embodiment five:
Anti-perspective logistics accumulating self-adhesive film, is A/B/C type three-decker, three-layer co-extruded technical recipe (every 100 kilograms of proportioning ratios): 10 kilograms, 10 kilograms, A layer, 80 kilograms, B layer and C layer; A layer is by 0.1~1 kilogram of defoamer (masterbatch), 0~9.7 kilogram of LLDPE(linear low density polyethylene), 0~6 kilogram of MLLDPE(metallocene linear-low density polyethylene) and 0.2~3 kilogram of polyisobutene mix; B layer is by 0.2~5 kilogram of defoamer (masterbatch), 25~79.8 kilograms of LLDPE(linear low density polyethylenes), 0~50 kilogram of MLLDPE(metallocene linear-low density polyethylene) mix; C layer is by 0.1~1 kilogram of defoamer (masterbatch), 0~9.9 kilogram of LLDPE(linear low density polyethylene), 0~6 kilogram of MLLDPE(metallocene linear-low density polyethylene) and 0~3 kilogram of polyisobutene mix.
Embodiment six:
Anti-perspective logistics accumulating self-adhesive film, is A/B/C type three-decker, three-layer co-extruded technical recipe (every 100 kilograms of proportioning ratios): 20 kilograms, 20 kilograms, A layer, 60 kilograms, B layer and C layer; A layer is by 0.1~2 kilogram of defoamer (masterbatch), 0~19.7 kilogram of LLDPE(linear low density polyethylene), 0~15 kilogram of MLLDPE(metallocene linear-low density polyethylene) and 0.2~3 kilogram of polyisobutene mix; B layer is by 0.2~5 kilogram of defoamer (masterbatch), 5~59.8 kilograms of LLDPE(linear low density polyethylenes), 0~50 kilogram of MLLDPE(metallocene linear-low density polyethylene) mix; C layer is by 0.1~2 kilogram of defoamer (masterbatch), 0~19.9LLDPE(linear low density polyethylene), 0~15 kilogram of MLLDPE(metallocene linear-low density polyethylene) and 0~3 kilogram of polyisobutene mix.
Embodiment seven:
Anti-perspective logistics accumulating self-adhesive film, is A/B/C type three-decker, three-layer co-extruded technical recipe (every 100 kilograms of proportioning ratios): 30 kilograms, 30 kilograms, A layer, 40 kilograms, B layer and C layer; A layer is by 0.1~2 kilogram of defoamer (masterbatch), 0~29.7 kilogram of LLDPE(linear low density polyethylene), 0~25 kilogram of MLLDPE(metallocene linear-low density polyethylene) and 0.2~3 kilogram of polyisobutene mix; B layer is by 0.2~3 kilogram of defoamer (masterbatch), 0~39.8 kilogram of LLDPE(linear low density polyethylene), 0~37 kilogram of MLLDPE(metallocene linear-low density polyethylene) mix; C layer is by 0.1~2 kilogram of defoamer (masterbatch), 0~29.9 kilogram of LLDPE(linear low density polyethylene), 0~25 kilogram of MLLDPE(metallocene linear-low density polyethylene) and 0~3 kilogram of polyisobutene mix.
Sum up, the present invention, in material need not oven dry situation, can not guarantee production efficiency, can eliminate film bubble again, ensures the quality of products, and reduces costs.

Claims (6)

1. Anti-perspective logistics accumulating self-adhesive film, is A/B type bilayer structure, and double-layer coextrusion technical recipe is in every 100 kilograms of proportioning ratios: 10 kilograms, A layer, 90 kilograms, B layer; A layer is mixed as masterbatch, 0~9.7 kilogram of LLDPE, 0~6 kilogram of MLLDPE and 0.2~3 kilogram of polyisobutene by 0.1~1 kilogram of defoamer; B layer is mixed as masterbatch, 30~89.8 kilograms of LLDPE, 0~50 kilogram of MLLDPE and 0~5 kilogram of polyisobutene by 0.2~5 kilogram of defoamer.
2. Anti-perspective logistics accumulating self-adhesive film, is A/B type bilayer structure, and double-layer coextrusion technical recipe is in every 100 kilograms of proportioning ratios: 20 kilograms, A layer, 80 kilograms, B layer; A layer is mixed as masterbatch, 0~19.7 kilogram of LLDPE, 0~15 kilogram of MLLDPE and 0.2~3 kilogram of polyisobutene by 0.1~2 kilogram of defoamer; B layer is mixed as masterbatch, 20~79.8 kilograms of LLDPE, 0~50 kilogram of MLLDPE and 0~5 kilogram of polyisobutene by 0.2~5 kilogram of defoamer.
3. Anti-perspective logistics accumulating self-adhesive film, is A/B type bilayer structure, and double-layer coextrusion technical recipe is in every 100 kilograms of proportioning ratios: 30 kilograms, A layer, 70 kilograms, B layer; A layer is mixed as masterbatch, 0~29.7 kilogram of LLDPE, 0~25 kilogram of MLLDPE and 0.2~3 kilogram of polyisobutene by 0.1~2 kilogram of defoamer; B layer is mixed as masterbatch, 10~69.8 kilograms of LLDPE, 0~50 kilogram of MLLDPE and 0~5 kilogram of polyisobutene by 0.2~5 kilogram of defoamer.
4. Anti-perspective logistics accumulating self-adhesive film, is A/B/C type three-decker, and three-layer co-extruded technical recipe is in every 100 kilograms of proportioning ratios: 10 kilograms, 10 kilograms, A layer, 80 kilograms, B layer and C layer; A layer is mixed as masterbatch, 0~9.7 kilogram of LLDPE, 0~6 kilogram of MLLDPE and 0.2~3 kilogram of polyisobutene by 0.1~1 kilogram of defoamer; B layer is mixed as masterbatch, 25~79.8 kilograms of LLDPE, 0~50 kilogram of MLLDPE by 0.2~5 kilogram of defoamer; C layer is mixed as masterbatch, 0~9.9 kilogram of LLDPE, 0~6 kilogram of MLLDPE and 0~3 kilogram of polyisobutene by 0.1~1 kilogram of defoamer.
5. Anti-perspective logistics accumulating self-adhesive film, is A/B/C type three-decker, and three-layer co-extruded technical recipe is in every 100 kilograms of proportioning ratios: 20 kilograms, 20 kilograms, A layer, 60 kilograms, B layer and C layer; A layer is mixed as masterbatch, 0~19.7 kilogram of LLDPE, 0~15 kilogram of MLLDPE and 0.2~3 kilogram of polyisobutene by 0.1~2 kilogram of defoamer; B layer is mixed as masterbatch, 5~59.8 kilograms of LLDPE, 0~50 kilogram of MLLDPE by 0.2~5 kilogram of defoamer; C layer is mixed as masterbatch, 0~19.9LLDPE, 0~15 kilogram of MLLDPE and 0~3 kilogram of polyisobutene by 0.1~2 kilogram of defoamer.
6. Anti-perspective logistics accumulating self-adhesive film, is A/B/C type three-decker, and three-layer co-extruded technical recipe is in every 100 kilograms of proportioning ratios: 30 kilograms, 30 kilograms, A layer, 40 kilograms, B layer and C layer; A layer is mixed as masterbatch, 0~29.7 kilogram of LLDPE, 0~25 kilogram of MLLDPE and 0.2~3 kilogram of polyisobutene by 0.1~2 kilogram of defoamer; B layer is mixed as masterbatch, 0~39.8 kilogram of LLDPE, 0~37 kilogram of MLLDPE by 0.2~3 kilogram of defoamer; C layer is mixed as masterbatch, 0~29.9 kilogram of LLDPE, 0~25 kilogram of MLLDPE and 0~3 kilogram of polyisobutene by 0.1~2 kilogram of defoamer.
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CN104311987A (en) * 2014-11-12 2015-01-28 厦门聚富塑胶制品有限公司 Production process for gas-phase anti-rust self-adhesion stretch film
CN104859244B (en) * 2015-04-30 2018-04-27 江苏优珀斯材料科技有限公司 A kind of waterproof roll self-adhesion strength high temperature resistant nylon composite membrane and its processing method
CN104817753A (en) * 2015-05-21 2015-08-05 广东威林工程塑料有限公司 PE material for high-adsorbability PIB treating powder and preparation method of PE material
CN107216538A (en) * 2016-08-31 2017-09-29 广东天元实业集团股份有限公司 A kind of degradable double-layer plastic courier bag and preparation method thereof
CN111483203A (en) * 2020-04-21 2020-08-04 珠海徐太日用品有限公司 High-barrier packaging film with self-adhesion function and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN1415468A (en) * 2002-09-02 2003-05-07 江苏琼花高科技股份有限公司 Method for preparing new protective film without incohesion
CN101044203A (en) * 2004-10-08 2007-09-26 埃克森美孚化学专利公司 Combinations of tackifier and polyalphaolefin oil

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
CN1415468A (en) * 2002-09-02 2003-05-07 江苏琼花高科技股份有限公司 Method for preparing new protective film without incohesion
CN101044203A (en) * 2004-10-08 2007-09-26 埃克森美孚化学专利公司 Combinations of tackifier and polyalphaolefin oil

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