CN102503965B - Rare earth complex with light conversion function and preparation method thereof - Google Patents
Rare earth complex with light conversion function and preparation method thereof Download PDFInfo
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- CN102503965B CN102503965B CN201110315824.4A CN201110315824A CN102503965B CN 102503965 B CN102503965 B CN 102503965B CN 201110315824 A CN201110315824 A CN 201110315824A CN 102503965 B CN102503965 B CN 102503965B
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- formula
- rare earth
- light
- transition function
- earth compounding
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- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 39
- 150000002910 rare earth metals Chemical class 0.000 title claims abstract description 35
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims description 9
- 229910052693 Europium Inorganic materials 0.000 claims description 32
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 32
- 150000001875 compounds Chemical class 0.000 claims description 27
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- 238000013329 compounding Methods 0.000 claims description 21
- 239000007787 solid Substances 0.000 claims description 18
- 230000007704 transition Effects 0.000 claims description 17
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 15
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 13
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 13
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 239000003960 organic solvent Substances 0.000 claims description 8
- 125000002941 2-furyl group Chemical group O1C([*])=C([H])C([H])=C1[H] 0.000 claims description 7
- 125000000175 2-thienyl group Chemical group S1C([*])=C([H])C([H])=C1[H] 0.000 claims description 7
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 6
- 229910052771 Terbium Inorganic materials 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 3
- 150000002825 nitriles Chemical class 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 238000000935 solvent evaporation Methods 0.000 claims description 2
- 239000003446 ligand Substances 0.000 abstract description 10
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 abstract description 7
- -1 life sciences Substances 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 6
- 125000000524 functional group Chemical group 0.000 abstract description 3
- 230000003595 spectral effect Effects 0.000 abstract description 3
- 238000001308 synthesis method Methods 0.000 abstract 2
- 239000003814 drug Substances 0.000 abstract 1
- 239000007850 fluorescent dye Substances 0.000 abstract 1
- 230000031700 light absorption Effects 0.000 abstract 1
- 238000004458 analytical method Methods 0.000 description 16
- 150000001793 charged compounds Chemical class 0.000 description 8
- 239000002131 composite material Substances 0.000 description 8
- 230000005284 excitation Effects 0.000 description 8
- 238000001819 mass spectrum Methods 0.000 description 8
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 8
- 239000012265 solid product Substances 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 5
- 238000010189 synthetic method Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000008635 plant growth Effects 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Natural products C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 230000008033 biological extinction Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000029553 photosynthesis Effects 0.000 description 2
- 238000010672 photosynthesis Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000695 excitation spectrum Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000002189 fluorescence spectrum Methods 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 238000005424 photoluminescence Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000006862 quantum yield reaction Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- TXBBUSUXYMIVOS-UHFFFAOYSA-N thenoyltrifluoroacetone Chemical compound FC(F)(F)C(=O)CC(=O)C1=CC=CS1 TXBBUSUXYMIVOS-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
Claims (8)
Priority Applications (1)
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CN201110315824.4A CN102503965B (en) | 2010-12-31 | 2011-10-17 | Rare earth complex with light conversion function and preparation method thereof |
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CN201010620242.2 | 2010-12-31 | ||
CN201010620242 | 2010-12-31 | ||
CN201110315824.4A CN102503965B (en) | 2010-12-31 | 2011-10-17 | Rare earth complex with light conversion function and preparation method thereof |
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CN102503965A CN102503965A (en) | 2012-06-20 |
CN102503965B true CN102503965B (en) | 2014-07-09 |
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CN201110315824.4A Active CN102503965B (en) | 2010-12-31 | 2011-10-17 | Rare earth complex with light conversion function and preparation method thereof |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102964367B (en) * | 2012-12-07 | 2015-02-18 | 中国计量学院 | Rare earth complex luminescent material and preparation method thereof |
CN103745981A (en) * | 2013-12-04 | 2014-04-23 | 广东普加福光电科技有限公司 | Ultraviolet response type rare earth light conversion film and application thereof |
CN103694265B (en) * | 2013-12-31 | 2015-04-15 | 中国计量学院 | Novel light-emitting beta-diketone rare earth complex crystal form material |
CN103694993B (en) * | 2013-12-31 | 2015-04-15 | 中国计量学院 | Beta-diketone rare earth complex red fluorescent material |
CN106967100B (en) * | 2017-04-07 | 2019-04-09 | 盐城工学院 | A kind of preparation method of rare earth organic light conversion agents Eu (BMPD) nL and anti-aging light conversion film |
CN106967101B (en) * | 2017-04-07 | 2019-04-09 | 盐城工学院 | A kind of rare earth organic light conversion agents and anti-aging light conversion film |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1557907A (en) * | 2004-02-03 | 2004-12-29 | 复旦大学 | Rare earth complexes containing dipyridyl derivatives and their use as electroluminescent materials |
CN101522787A (en) * | 2006-10-18 | 2009-09-02 | 桑维克股份有限公司 | Fluorescent resin composition and solar battery module using the same |
CN101671457A (en) * | 2009-09-29 | 2010-03-17 | 苏州福斯特光伏材料有限公司 | Ethene-vinyl acetate composition and application thereof |
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2011
- 2011-10-17 CN CN201110315824.4A patent/CN102503965B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1557907A (en) * | 2004-02-03 | 2004-12-29 | 复旦大学 | Rare earth complexes containing dipyridyl derivatives and their use as electroluminescent materials |
CN101522787A (en) * | 2006-10-18 | 2009-09-02 | 桑维克股份有限公司 | Fluorescent resin composition and solar battery module using the same |
CN101671457A (en) * | 2009-09-29 | 2010-03-17 | 苏州福斯特光伏材料有限公司 | Ethene-vinyl acetate composition and application thereof |
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CN102503965A (en) | 2012-06-20 |
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Address after: 210093 Hankou Road, Jiangsu, China, No. 22, No. Co-patentee after: trina solar Ltd. Patentee after: NANJING University Address before: 210093 Hankou Road, Jiangsu, China, No. 22, No. Co-patentee before: CHANGZHOU TRINA SOLAR ENERGY Co.,Ltd. Patentee before: Nanjing University Address after: 210093 Hankou Road, Jiangsu, China, No. 22, No. Co-patentee after: TRINASOLAR Co.,Ltd. Patentee after: NANJING University Address before: 210093 Hankou Road, Jiangsu, China, No. 22, No. Co-patentee before: trina solar Ltd. Patentee before: Nanjing University |