CN102499901B - Hairdressing, hair brightening and hair styling composition - Google Patents
Hairdressing, hair brightening and hair styling composition Download PDFInfo
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Abstract
The invention discloses hairdressing, hair brightening and hair styling composition, which comprises (a) colorful grains, (b) at least one type of hair styling polymer, and (c) at least one grease with refractive index nd<25> >=1.460. The average particle size of the colorful grains is 300 mum to 5000mum, the colorful grains comprise (i) spherical, ellipsoidal or irregularly-shaped colorful grains and (ii) circular, triangular, polygonal or irregularly-shaped platy colorful grains, the weight percentage of the hair styling polymer in the composition ranges from 0.1% to 20%, and the average molecular weight of the hair styling polymer is larger than 5000. The hairdressing, hair brightening and hair styling composition leads hairs of a user to be glossy, beautifies and decorates the hair of the user, leads hair styles to be formed or kept, and is applicable to preparing hair styling or modeling products such as gel water, gel, elastin, pomade, hair cream, hair styling liquid, gelatin or hair styling cream and the like.
Description
Technical field
The present invention relates to hair setting composition field, particularly bright Hairstyling composition of a kind of hair caring.
Background technology
In life, a glossy hair of health is that people wish to obtain daily, the fine image of beautiful health is respectfully presented to the world, and to make hair style keep particular form or the shape of certain hour has been people's demands widely.For this reason, modal method is by a kind of composition sprayed or is applied on hair, and these Hairstyling compositions have temporary transient fixed effect, they can water or shampoo remove.Can keep the raw material of giving fixed effect for compositions of shape or form generally to have fluoropolymer resin for hair provides, they be generally to use with forms such as hair gel, gel, elastin, pomade, suppurative mastitis, style keeping liquid, gel or mousses.
Along with social progress, people's range of activity is also continuing increase, therefore represent own unique individual character and glamour by different hair styles in different occasions, particularly in the public arena of wedding celebration and dinner party, therefore people are also more and more higher to the performance requirement of approved product.About the aspect of performance at Hairstyling composition, people's main wish is to keep hair style, also requires the hair quality health after sizing beautiful simultaneously, also in hair style, decorates some ornaments simultaneously, reaches distinguished effect, and has certain firmness.But people also notice, Hairstyling composition in the market make hair feel coarse, be difficult to arrange.Now great majority have the hair styling product of good sizing ability, its shortcoming be dry rear or really up to the mark, rough, moulding is stiff, or too sticky, feel is bad.And not obvious in the raising of the glossiness of hair after use of Hairstyling composition in the market, more do not there is the performance of decoration hair.As described by adding solid particle to deposit to the volume that is used for increasing hair on hair in patent CN200880105146.5, CN02819536.1, and the particle mean size of the solid particle adding is less than 80 μ m, these solid particles deposit on hair and can observe, and do not have the effect of decoration and moist nourishing hair.And describe by adding the grease of high refractive index to increase the glossiness of hair in patent CN201010112214.X, but because the grease of most high refractive index in hair cleaning process has all been rinsed, cannot deposit on hair, the effect that therefore increases hair gloss degree is just difficult to get a desired effect.
Therefore, people wish to obtain a kind of Hairstyling composition with good maintenance hair style ability and don't infringement hair, it can give the sizing ability that hair is good, and can significantly increase the glossiness of hair, there is the function of good decoration and moist nourishing hair simultaneously, and can remove from hair easily by hair washing process.And the compositions of prior art cannot provide such characteristic and performance.
Summary of the invention
For addressing the above problem, the object of this invention is to provide bright Hairstyling composition of a kind of hair caring, it can reach decoration, moist nourishing hair, increase the multiple effect of hair brightness.
The object of the present invention is achieved like this: bright Hairstyling composition of a kind of hair caring, is characterized in that comprising:
(a) colour particles, has the particle mean size of 300 μ m to 5000 μ m, is selected from following at least one: (i) spherical, elliposoidal or difform colour particles; (ii) circle, triangle, polygon or difform lamellar colour particles;
(b) at least one hair fixing copolymer, the weight percent content in compositions is 0.1% to 20%, mean molecule quantity is greater than 5000;
(c) at least one index of refraction
grease.
The present invention, by adding the appearance of larger particle mean size to have the colour particles of gloss and different color, can observe significantly to reach at hair, particularly, under light or daylight, can reflect dazzling light, to reach distinguished effect; The soft colour particles of part is in use extruded fragmentation simultaneously, discharges nutrient substance and moistens nourishing hair, reaches decoration and moist nourishing hair double effects.And by adding the grease of high refractive index, directly use on hair, the grease of the high refractive index that can not cause through cleaning process runs off, thereby the grease of high refractive index is deposited on hair completely, the performance of the grease of complete performance high refractive index.But, this patent is surprising discovery especially, by above-mentioned two class materials and hair fixing copolymer are combined, not only can bring into play the existing characteristic that uses material, can also increase colour particles firmness on hair, but also can increase the characteristic that uses material by different proportionings and content, play the effect of Synergistic, reach than the inaccessiable effect of above-mentioned any material of independent use, thereby reach not obtainable required performance and effects of prior art compositions.
The present invention gives hair gloss, gives hair beautifying and decorating, and hair style style is shaped or keeps, and is applicable to prepare hair fixing or moulding product as hair gel, gel, elastin, pomade, suppurative mastitis, style keeping liquid, gel or Hairsetting frost etc.
Detailed description of the invention
Essential component of the present invention will be described below.Also comprise that being in addition applicable to various non-exclusionism optional and preferred ingredient of the present invention describes.The present invention can contain any required or optional component as described herein and/or qualifications or by they form, or is substantially made up of them.
spherical, elliposoidal or difform colour particles
Compositions of the present invention comprises colour particles.That described colour particles has is spherical, elliposoidal or irregular external shape, has the particle mean size of 300 μ m to 5000 μ m; Can water absorption and swelling in aqueous solution, and after water absorption and swelling, be soft, can be broken by the suitable extruding of outside, discharge the active substance of inner parcel.With regard to elliposoidal or irregular shape, the ratio of maximum major axis and minimum minor axis is less than 10, is preferably less than 8, is more preferably less than 5.
Described colour particles is coloured or with pearly-lustre, and colored particle is selected from a kind of in blueness, purple, redness, green, yellow, white, the color such as orange and their combination in any.This colored particle can not given hair coloring effect by hair, and in use colored particle is broken, and therefore the color of colored particle and the color of hair do not have inevitable contacting.Described colored particle is parcel property particle, and suitable wrapped liquid substance is selected from the nutritional substances such as grease, vitamin, aminoacid, protein, protein derivatives, plant extract, silicone compounds, wetting agent, conditioner and their mixture.
Available colored particle limiting examples is: shades of colour particle diameter 80 μ m to the 5000 μ m solid particles such as (Lipo chemicals inc) Lipo Sphere 0260, Lipo Sphere0256, Lipo Sphere 0263, Lipo Sphere 0259, Lipo Sphere 0261, Lipo Sphere 0257, LipoSphere 0262, Lipo Sphere 0258, Lipo Sphere Glitter; Shades of colour particle diameter 80 μ m to the 5000 μ m colored particles such as the colored soft pearl of (Pu, Shanghai grace biochemistry) PUENSOMES 24/30, the colored soft pearl of PUENSOMES 30/40, the colored soft pearl of PUENSOMES 40/60, the colored soft pearl of PUENSOMES 60/80, PUENSOMES 18/30 colored soft pearl.
circle, triangle, polygon or difform lamellar colour particles
Compositions of the present invention comprises lamellar colour particles.Described lamellar colour particles has circle, triangle, polygon or irregular external shape, has the particle mean size of 300 μ m to 5000 μ m; Can not water absorption and swelling in aqueous solution and in aqueous solution, show as rigid, can not be broken by the suitable extruding of outside.With regard to irregular shape, the ratio of maximum major axis and minimum minor axis is less than 10, is preferably less than 8, is more preferably less than 5.
Described lamellar colour particles surface can be with colored coating or surperficial without any coating, coloured lamellar colour particles is selected from following color but is not limited to the following stated color, as a kind of in: blueness, purple, redness, green, yellow, white, the color such as orange and their combination in any, this coloured lamellar colour particles can be attached to hair surface, firmly adheres to hair surface by hair fixing copolymer.
Available coloured lamellar colour particles limiting examples is: (Fuding Ge Lite pigment company limited of Tai Zhu group) glitter powder: JR004 seven is color purple, JR005 seven is color blue, JR006 seven is color green, JR007 seven handsels are green, JR008 seven handsel indigo plants, JR105 powder enamel Huang, JR205 powder enamel golden red, JR305 powder enamel is purplish red, JR405 powder enamel indigo plant, JR505 powder enamel is green, TS001 1/24, TS004 1/24, TS005 1/24, TS105 1/24, TS108 1/24, TS205 1/24, TS208 1/24, TS305 1/24, TS310 1/24, TS405 1/24, TS410 1/24, TS505 1/24, TS605 1/24, TS607 1/24, TS704 1/24, TS705 1/24, TS904 1/24, TS905 1/24, TL001 1/24, TL104 1/24, TL105 1/24, TL205 1/24, TL306 1/24, TL407 1/24, TL507 1/24, TP105 1/24, TP206 1/24, TP209 1/24, TP305 1/24, TP406 1/24, TP408 1/24, TP504 1/24, TP604 1/24, TP904 1/24, TW006 1/24, TW106 1/24, TW206 1/24, TW208 1/24, TW306 1/24, TW406 1/24, TW506 1/24, TR204 1/24, TR508 1/24, TR209 1/24, TY209 1/24, (credit Dexing, Shenzhen Science and Technology Ltd.) glitter powder: golden serial glitter powder, color series glitter powder, radium-shine serial glitter powder, fluorescence series glitter powder, monochromatic glitter powder paillette, silver color series glitter powder, seven-color serial glitter powder, illusion-colour series glitter powder, aluminum material glitter powder, the series of products such as (smooth and prosperous handicraft company limited) glitter powder, copper bronze, luminescent powder, pearl essence, aluminum argentum powder, fluorescent material, paillette, technique adjuvant, radium-shine powder.
anion hair styling polymer
Normally used anion hair styling polymer is the polymer of the group that comprises derived from carboxylic acid, sulfonic acid or phosphoric acid, and the mean molecule quantity of polymer is about 5000 to 5000000.Carboxylic acid is by monocarboxylic acid or dicarboxylic acids monomer, for example, provide corresponding to those monomers of (1) formula:
Wherein: n is 0 to 10 integer, A
1for methylene, be optionally connected on the carbon atom of unsaturated group by hetero atom (as: oxygen or sulfur), or in the time that n is greater than 1, be connected on adjacent methylene R
7for hydrogen atom or phenyl or benzyl, R
8for hydrogen atom or low alkyl group or carboxyl, R
9for hydrogen atom, low alkyl group ,-CH
2-COOH or phenyl or benzyl.In formula described above, preferably low alkyl group is group, particularly methyl and the ethyl of 1 to 4 carbon atom.
Preferably wrapping carboxylic anion hair styling polymer according to the present invention is:
A: homopolymer or the copolymer, particularly Allied Colloid company of acrylic or methacrylic acid or their salt
e or K series of products; The Utrahold series of products of BASF AG; Reten421,423 or 425 series of products and the acrylic acid of their sodium-salt forms and the copolymer of acrylamide of Hercules company, multi-hydroxy carboxy acid's sodium salt.
B: acrylic or methacrylic acid and monoene key monomer (as: ethylene, styrene, vinyl esters), the copolymer of acrylic or methacrylic acid esters, what it was optional uses polyalkylene glycol grafting, or being crosslinked of option.What meet also has: acrylic or methacrylic acid (C
1-C
4alkyl) copolymer of ester, vinyl pyrrolidone, acrylic or methacrylic acid (C
1-C
20alkyl) terpolymer of ester (as dodecyl ester), the terpolymer of methacrylic acid/ethyl acrylate/tert-butyl acrylate.
Available anion hair styling polymer limiting examples is: (BASF):
strong,
mAEX or MAE, Luviset CA66,
the series of products such as A; (ISP):
eS 425,
lM series; (LUBRIZOL): Fixate
tMpLUS, Fixate
tMg-100, Fixate
tMsuperhold and Fixate
tMfreestyle polymer.
amphion hair fixing copolymer
(1). the present invention usefully at least contains dialkyl aminoalkyl (methyl) acrylate of Radix Betae alkalization of following formula unit or the polymer of dialkyl aminoalkyl (methyl) acrylamide:
Wherein R
1represent hydrogen atom or there is C
1-C
3alkyl, R
2represent to have C
1-C
4alkylidene, Y represent O or-NH-, R
3and R
4represent independently of one another hydrogen atom or there is C
1-C
4alkyl, with a kind of cationic derivative, it is connected on one or more aliphatic chains and the cationic surfactant of optional quaternized nitrogen-atoms forms by least containing one, or formed amine or ammonium group forming section polymer chain or be connected on it by the cationic polymer of polyamines, poly-amino polyamide or poly--(quaternary ammonium) type.
The both sexes styling polymer that contains above formula unit () normally exists with the form of copolymer, and it also at least includes following formula unit (two) except said units ():
CH
2=R
1c-COO-R
5(2)
Wherein R
1represent hydrogen atom or there is C
1-C
3alkyl, R
5represent to have C
4-C
24alkyl or alkenyl or there is C
4-C
24cycloalkyl.
Also can use ter-polymers, quadripolymer or five yuan of polymer, they also contain following formula unit (three) except unit (one) and (two):
CH
2=R
1c-COO-R
6(3)
Wherein R
1represent hydrogen atom or there is C
1-C
3alkyl, R
6represent to have C
1-C
4alkyl or alkenyl.
With respect to the gross weight of both sexes styling polymer, formula () unit preferred content is 25% to 45% weight, and formula (two) unit preferred content is 5% to 65% weight, and formula (three) unit preferred content is up to 50% weight.
Particularly preferred polymer is the copolymer that contains formula (), (two) and (three) unit, and wherein Y represents oxygen atom, R
2represent group-CH
2-CH
2-, R
1, R
3and R
4represent methyl, R
5represent to have C
4-C
18alkyl, R
6represent to have C
1-C
3alkyl.The molecular weight of this both sexes styling polymer is preferably 5000 to 1000000.The typical structure thing of this both sexes styling polymer is levied as shown in the formula shown in structure I and II:
Structure I
Structure I I
Available amphion hair fixing copolymer limiting examples is: Yukaforme, the Diaformer series styling polymer of Mitsubishi Chemical company supply, mainly comprises: Yukaforme FH, Yukaforme 202, Yukaforme AMPHOSET, Diaformer Z-731, Diaformer Z-712, Diaformer Z-631, Diaformer Z-631A, Diaformer Z-632, Diaformer Z-651 etc.; TC-AMPHOT701, the serial styling polymer of TC-AMPHOT 702 of Guangzhou Tianci Advanced Materials Co., Ltd's supply; Meet the serial styling polymer such as the WX-690, the WX-691 that also comprise Zhejiang Wei Xiang Fine Chemical Co., Ltd supply, WX-692, WX-801B, WX-600, WX-700, WX-800 of this architectural feature.
(2). meet the polymer of the amphion unit being derived by following formula also comprising of requirement performance of the present invention:
Wherein R1 represents polymerisable unsaturated group, as acrylate, methacrylate, acrylamide or methacryloyl amine groups, x and y represent 1 to 3 integer independently, R2 and R3 represent hydrogen, methyl, ethyl or propyl group independently, R4 and R5 represent hydrogen atom or alkyl independently, and the total number of carbon atoms sum of R4 and R5 is no more than 10.
Most preferred both sexes styling polymer comprises octyl group acryloyl group amine/acrylate/butyl amino-ethyl methacrylate copolymer, methacryl ethyl betanin/acrylate copolymer.
Available amphion hair fixing copolymer limiting examples is: AMPHOMER, AMPHOMET LV71 and the AMPHMER LV47 of National Starch & Chemical supply.Also include Yukaforme 301, Yukaforme SM, Yukaforme 510, Yukaforme M-75, the Yukaforme250S of Mitsubishi Chemical supply.
nonionic hair fixing copolymer
The useful nonionic styling polymer of the present invention is at least to contain following formula unit polymer 1., and it is the NVP construction unit shown in the 1. or construction unit polymerization of the NVP construction unit shown in 1. and the following general formula vinyl acetate shown in 2. obtains by following general formula by following general formula.
It is 1. wherein 100: 0 to 30: 70 with molar ratio 2..
Be suitable for nonionic styling polymer of the present invention, wherein nonionic polymer molecules amount is generally 500 to 3000000, is preferably nonionic polymer molecules amount 5000 to 2000000.
Available nonionic hair fixing copolymer limiting examples is: PVP or polyvinyl pyrrolidone (PVPK-15, PVP K-30, PVP K-60PVP K-90, PVP K-120, supplier ISP) (Luviskol K-12, Luviskol K-17, Luviskol K-30, Luviskol K-60, Luviskol K-80, Luviskol K-90, supplier Basf); PVP/VA (PVP/VA S-630, PVP/VA-535, PVP/VA-635, PVP/VA W-735, PVP/VA-335, PVP/VA-235, supplier ISP) (Luviskol VA-64, Luviskol VA-73W, supplier Basf).
cationic hair styling polymer
Being applicable to cationic polymer of the present invention has:
(1) vinyl pyrrolidone/quaternised dialkyl aminoalkyl acrylate or methacrylate ester copolymer.
(2) cellulose ether derivative that contains quaternary ammonium group.
(3) cationic polysaccharides.
(4) common molecular weight is 20000 to 3000000 cyclic polymer, in this type of ring-type quaternary ammonium polymer, preferably dimethyl diallyl ammonium chloride homopolymer (is supplied with MERQUAT 100, molecular weight is less than 100000), and dimethyl diallyl ammonium chloride/acrylamide copolymer (molecular weight is greater than 500000, is supplied with MERQUAT550 by CALGON company).
(5) homopolymerization being produced by acrylate or methacrylate or copolymer, and at least contain one with lower unit:
Wherein R1 be H or-CH
3, A contains C
1-C
6straight or branched alkyl group, or contain C
1-C
4hydroxyalkyl group, R2, R3 and R4 represent respectively to have C
1-C
18alkyl group or benzyl group, R5 and R6 represent H or have C
1-C
6alkyl, X represents methyl ester sulfate or halogen ion, for example chloride ion or bromide ion.
Operable polymer monomers belongs to the family that comprises following compound conventionally: Arrcostab, vinyl pyrrolidone and the vinyl esters of the acrylamide being replaced by one or more low alkyl groups on acrylamide, MAAm, two acetone-acrylamide, nitrogen and MAAm, acrylic acid and methacrylate.
Available cationic hair styling polymer is: acrylamide/β-methacrylyl oxygen ethyl-trimethyl formate ammonium sulfate copolymer; with acrylic-amino Acetoxon hydrochlorate/acrylate copolymer; be 10000 to 1000000, be preferably 15000 to 500000 crosslinked grafted cation copolymer with molecular weight, and obtained by following compound copolymerization: at least one cosmetic monomer, methacrylate dimethylamino ethyl ester, Polyethylene Glycol and poly-undersaturated cross-linking agent.
(6) other spendable cationic polymer is polyalkyleneimine, particularly polyethylene imine based, on chain, contain the polymer of vinylpyridine unit and vinylpyridine unit, the condensation substance of polyamide and table chlorhydrin, poly--(quaternary ureylene) and chitin derivative.
Based on cationic polymer, its molecular weight is generally 5000 to 3000000, and the molecular weight that is preferably cationic polymer is 5000 to 1500000.
Available cationic hair styling polymer limiting examples is: Gafquat734, Gafquat 440B, the Gafquat755N product of International Specialty Products company (ISP) supply, Quaternium 37, Quaternium 38, Quaternium 42, Quaternium 49; The commodity CELQUAT H 100 by name of National Starch & Chemical supply and the poly-Ployquaternium 4 of CELQUATL 200.
a kind of index of refraction
grease
Be suitable for natural origin high refractive index of the present invention
grease, the straight or branched that it has 6-40 carbon atom, has more than one unsaturated bond, is liquid under room temperature, and 25 DEG C of indexs of refraction with respect to pure water are more than 1.46.Preferably index of refraction is more than 1.47.
Be suitable for natural origin high refractive index of the present invention
oils and fats, is 0.1%-20.00% by weight percentage, preferably at 0.3%-15.00%, more preferably at 0.5%-10%.
Available natural origin high refractive index
grease limiting examples is: (CrodamolSTS of standing grain major company): PPG-3 benzylic ether myristate, (Kunshan Shuan You company, International Specialty Products company): Oleum Ricini maleate, amyl salicylate, nonanedioyl two (ethyl salicylate), benzyl salicylate, butyl capryl alcohol salicylate, C12-15 alcohol salicylate, decoyl salicylic acid, dipropylene glycol salicylate, ethylhexyl salicylate, ethylene glycol salicylate, 1, 6-hexanediol two salicylates, hexyl lauryl alcohol salicylate, 1-Hexyl salicylate, salicylic acid isodecyl ester, isopropyl benzylalcohol salicylate, menthol salicylate, methyl salicylate, myristyl alcohol salicylate, phenyl salicytate, silandiol salicylate, tridecyl alcohol salicylate etc., olive oil, Oleum Ricini, Oleum Arachidis hypogaeae semen, Fructus Canarii albi oleic acid esters in the last of the ten Heavenly stems, two oleic acid phosphate ester, oleyl alcohol ether-5 phosphate ester, olein, linoleic acid Malaysia ester, linolenic acid Malaysia ester, arachidic acid glyceride, Oleum Ricini Malaysia ester and all kinds of natural oil olive oil that contains these unsaturated fatty acids alcohol esters, Oleum sesami, safflower oil, American Avocado Tree oil etc., preferably methyl salicylate, phenyl salicytate, benzyl salicylate, PPG-3 benzylic ether myristate, Oleum Ricini maleate, tridecyl alcohol salicylate etc.
optional components
Be suitable for additive of the present invention and be selected from anion, cation, nonionic and zwitterionic surfactant, essence, antiseptic, screening agent, pigment, solvent, conditioner, vitamin and protein, anion, cation, nonionic and amphoteric ion polymer the hair fixing copolymer occurring in aforesaid claim, mineral, plant and synthetic grease, reagent and any other additive of conventionally guaranteeing in cosmetic composition, wetting agent etc.
solvent
Select solvent used in the present invention according to transformable factor as other performance requirement of all the other components, compositions.
For the non-limitative example of solvent of the present invention be: water, contain 1 to 6 carbon atom lower alcohol as ethanol and isopropyl alcohol, polyhydroxy-alcohol is as propylene glycol, 1,3 butylene glycol, pentanediol, hexanediol, dipropylene glycol, glycerol, Pyrusussuriensis (sugar) alcohol, maltose alcohol, polyglyceryl ether and composition thereof.Described solvent is selected from one or both and the two or more mixture in above-mentioned solvent.
conditioner
In amphoteric hair caring-fixing composite of the present invention, can comprise conditioner.Suitable conditioner includes fatty alcohol, fatty acid and mineral oil.
Be that carbon number is approximately 10 to approximately 30 for fatty alcohol of the present invention, be preferably the fatty alcohol of approximately 16 to 22 carbon atoms.These fatty alcohol can be the alcohol of straight or branched, are mainly saturated fatty alcohol.The non-limitative example of fatty alcohol comprises decanol, undecyl alcohol, lauryl alcohol, myristyl alcohol, spermol, stearyl alcohol, isooctadecanol, different spermol, behenyl alcohol, triacontanol and their mixture.Particularly preferred fatty alcohol is spermol, stearyl alcohol, isooctadecanol, different spermol, behenyl alcohol, triacontanol and their mixture.Be that carbon number is approximately 10 to approximately 30 for fatty acid of the present invention, be preferably the fatty acid of approximately 16 to 22 carbon atoms.These fatty acids can be the acid of straight or branched, are mainly saturated fatty acids.The non-limitative example of fatty acid comprises lauric acid, myristic acid, Palmic acid, stearic acid, behenic acid, isostearic acid and their mixture.Be particularly preferably Palmic acid, stearic acid, behenic acid, isostearic acid and their mixture.Be that carbon number is approximately 10 to approximately 40 for mineral oil of the present invention, be preferably the mineral oil of approximately 12 to 22 carbon atoms.These mineral oil can be the mineral oil of straight or branched, are mainly saturated mineral oil.The non-limitative example of mineral oil comprises paraffin oil, white mineral oil, dodecane, Fancol ID, hexadecane, 2-Methylpentadecane, eicosane, tetracontane, different tetracontane and their mixture.Be particularly preferably white mineral oil, Fancol ID, 2-Methylpentadecane, different tetracontane and their mixture.
antiseptic
Amphoteric hair caring-fixing composite of the present invention also comprises antiseptic.
Non-limitative example for antiseptic of the present invention is DMDM Hydantoin (dihydroxymethyl dimethyl hydantoin), Kathon CG (mixture of methyl chloride generation-isothiazolone and Methylisothiazolinone), NEOLONE 950 (MIT and MI), imidazolidinyl urea, two imidazolidinyl urea, phenoxyethanol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate, butyl p-hydroxybenzoate (p-Hydroxybenzoic acid isopropyl ester, p-Hydroxybenzoic acid isobutyl ester and composition thereof).
Embodiment further illustrates the present invention below:
Following embodiment further describes and has implemented embodiment of the present invention within the scope of the invention.These embodiment are only for setting forth bright Hairstyling composition of hair caring of the present invention, are not limitation of the present invention.
The representative of Hairsetting cream composition of the present invention below:
Prepare 9 kinds of hair setting compositions, wherein 6 kinds all contain colour particles, hair fixing copolymer, a kind of index of refraction
the compositions of grease is bright Hairstyling composition of hair caring of the present invention; Wherein 3 kinds for hair setting composition is prior art compositions, is reference group compound.According to the performance characteristics of polymer, carry out different polymer active substance weight configuration proportion combinations, can prepare the Hairstyling composition product of various performance characteristics and cost performance.
The preparation of preparation is summarized in following table 1.
Table 1
1.CS 25, the peaceful 2.SC 96 of supply business, supplier Ciba.
3.PVP K 90, supplier ISP. 4.PVP/VA W-735, supplier ISP.
5.D-pantothenylol, supplier DSM. 6.TR2041/24, Fuding Ge Lite pigment company limited of Tai Zhu group of supplier
7.Sphere 0260, supplier Lipo chemicals inc.
The preparation of bright Hairstyling composition of hair caring: by conventional mixing and emulsifying technology equipment, by water and oil phase mixing and emulsifying, add colour particles, SC 96, essence and antiseptic etc. in the time of 60 DEG C to 70 DEG C under the high temperature of 80 DEG C to 100 DEG C, stir.Bright Hairstyling composition of hair caring, in the time of the temperature of 60 DEG C to 70 DEG C, is still fluid state, under this state, a bright hair caring Hairstyling composition is filled in final packaging.Be cooled to after room temperature, described compositions becomes nonfluid.
After bright Hairstyling composition of 9 kinds of hair carings of above-mentioned gained packed with same package thing, giving 100 people's assessment panel assesses, appraisal procedure is to allow appraiser and this series products usually using, under identical using method, assess, and assessment result is carried out to grade classification, be divided into respectively 1 (extreme difference), 2 (poor), five grades of 3 (satisfactions), 4 (good) to 5 (fine).Gained assessment result is in table 2.
Result shows, bright Hairstyling composition of hair caring of the present invention all has significantly better performance than the existing Hairstyling composition of reference example at most of aspect of performances.
Table 2
Claims (1)
1. bright Hairstyling composition of hair caring, is characterized in that comprising:
(a) colour particles, there is the particle mean size of 300 μ m to 5000 μ m, spherical, elliposoidal or difform colour particles, described spherical, elliposoidal or difform colour particles soft the used external pressure that shows as in compositions makes its fragmentation, be enclosed with active substance or do not wrap up any material, the weight percent content of colour particles in compositions is 0.05% to 20%; (b) at least one hair fixing copolymer, weight percent content in compositions is 0.1% to 20%, mean molecule quantity is greater than 5000, described hair fixing copolymer is selected from nonionic hair fixing copolymer, and described nonionic hair fixing copolymer is selected from the homopolymer of vinyl acetate and copolymer, homopolymer and the copolymer of acrylate, the vinyl lactam homopolymer that differs from Kollidone 90F, vinyl lactam copolymer; (c) at least one index of refraction
grease, weight percent content is 0.5%-10%, is selected from methyl salicylate, phenyl salicytate, benzyl salicylate, PPG-3 benzylic ether myristate, Oleum Ricini maleate and tridecyl alcohol salicylate.
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|---|---|---|---|
| CN201110453458.9A CN102499901B (en) | 2011-12-29 | 2011-12-29 | Hairdressing, hair brightening and hair styling composition |
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|---|---|---|---|
| CN201110453458.9A CN102499901B (en) | 2011-12-29 | 2011-12-29 | Hairdressing, hair brightening and hair styling composition |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1422144A (en) * | 2000-03-31 | 2003-06-04 | 宝洁公司 | Leave-in hair cosmetic compositions for enhancing volume containing microspheres |
| CN101795661A (en) * | 2007-08-30 | 2010-08-04 | 宝洁公司 | Leave-in hair styling product with particles for improving hair volume |
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| CN101040827A (en) * | 2006-03-21 | 2007-09-26 | 莱雅公司 | Cosmetic or dermatologic compositions containing microspheres |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1422144A (en) * | 2000-03-31 | 2003-06-04 | 宝洁公司 | Leave-in hair cosmetic compositions for enhancing volume containing microspheres |
| CN101795661A (en) * | 2007-08-30 | 2010-08-04 | 宝洁公司 | Leave-in hair styling product with particles for improving hair volume |
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