CN102492356A - Mirror back protective coating for colored coated mirror - Google Patents
Mirror back protective coating for colored coated mirror Download PDFInfo
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- CN102492356A CN102492356A CN2011103978826A CN201110397882A CN102492356A CN 102492356 A CN102492356 A CN 102492356A CN 2011103978826 A CN2011103978826 A CN 2011103978826A CN 201110397882 A CN201110397882 A CN 201110397882A CN 102492356 A CN102492356 A CN 102492356A
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Abstract
The invention discloses a mirror back protective coating for a colored coated mirror. The mirror back protective coating for the colored coated mirror comprises a primer and a finish, wherein the primer comprises 25 to 32 weight percent of acrylic modified alkyd resin with the solid content of 50 percent, 8 to 15 weight percent of epoxy resin with the solid content of between 48 and 52 percent, and 6 to 10 weight percent of amino resin; and the finish comprises 30 to 40 weight percent of acrylic modified alkyd resin with the solid content of 50 percent, 5 to 10 weight percent of epoxy resin with the solid content of between 48 and 52 percent, and 4 to 8 weight percent of amino resin. Heavy metal compounds with anticorrosion performance are not used in the mirror back protective coating, so the coating is environment-friendly. The coating can be prepared by a large-scale curtain coating molding process, can be quickly oven-dried, can be completely cured after being roasted at the temperature of between 80 and 100 DEG C for 4 to 6 minutes, has excellent physical and chemical properties, and is favorable for large-scale industrialized production.
Description
Technical field
The present invention relates to a kind of coating composition, relate in particular to a kind of mirror-back protective coating that is used for colored mirror coating.
Background technology
Growing along with science and technology, the kind of stained glass is more and more rich and varied, and people's life also can become colorful colourful because of his interspersing and decorating.Stained glass is the tinting material (being MOX mostly) that in the prescription of simple glass, adds 0.4%-0.7%, as: chromic oxide (being green after the adding), Manganse Dioxide (being purple after the adding) and powder blue (being blue after the adding) etc.Adopt the direct tinting material that in glass, adds not only little in batches with the mode of producing stained glass, and cost is high, price also is difficult to market and accepts.A kind of novel stained glass mirror just rises from market now; This stained glass only need be at surface of ordinary glass vapor deposition or the colored metal of magnetron sputtering one deck; Can make glass demonstrate the color of riot of color, as: rich and honour yellow, VT and champagne gold etc.Not only embodiment is flexible to produce this stained glass, also have in batches little, wide in variety, cost is low and meet characteristics such as market development demand.Be the metal level of protection colour developing, not only need plate one deck stainless steel again outside it, outermost layer also need apply a coating again to realize the long-term protection to metal level.Therefore, this protective cover is to concern the color metallized glass critical material in work-ing life.
Chinese invention patent ZL200510122934.3 discloses a kind of paint for vacuum film coating, and this coating is by hydroxyl polyhutadiene, POLYMETHYLENE POLYPHENYLISOCYANATE, encapsulant and solvent composition.Wherein the hydroxyl polyhutadiene is divided into two portions; The number of institute's hydroxyl can be identical or inequality in each molecule of first part's hydroxyl polyhutadiene and second section hydroxyl polyhutadiene, and the mole number of the contained OH group of the relative first part of mole number hydroxyl polyhutadiene of the contained NCO group of POLYMETHYLENE POLYPHENYLISOCYANATE is excessive.React in solvent by the excessive POLYMETHYLENE POLYPHENYLISOCYANATE of the relative OH group of first part's hydroxyl polyhutadiene earlier and generate the compound that is connected with the NCO group on the molecular chain with the NCO group; Add encapsulant then and make NCO group sealing, add second section hydroxyl mixed with polybutadiene at last and make after evenly.Have good gloss, hardness, sticking power and temperature tolerance though this is filmed, only can be used for the preceding bottom surface of goods vacuum platings such as fiberglass plastic, metal and apply, be particularly suited for using vacuum plating priming paint as automobile, motorcycle head lamp.
Chinese invention patent ZL200510134909.7 discloses a kind of ultraviolet-curing paint that is used for metal plating surface protection.This coating is made up of the epoxy acrylate of weight percentage 10%-30%, the urethane acrylate of 5%-20%, the compound sticking power enhancement resin of 10%-30%, thinner and the reactive thinner of 5%-20%, the light trigger of 1%-10% and the auxiliary agent of 0.1%-1% of 30%-65%.Epoxy acrylate and urethane acrylate are all as living oligomer; It is the mixture of thermoplastic acrylic resin and cellulosic resin that compound sticking power is promoted resin, and the acrylic monomer of phosphoric acid modification is arranged in the used monomer of synthetic thermoplastic vinyl resin.
Chinese invention patent application 200610015046.6 discloses a kind of surface-coated coating that is used for vacuum plating.This coating is formed, and is added to 100% with mixed solvent oil by the mixed fatty acid of 30%-45%, 8% component such as polyvalent alcohol, 8% mixed phenol urea formaldehyde, 3% coumarone resin, 2% modified chlorinated polyolefin and 8% isocyanic ester.
Protective cover is used in above-mentioned several kinds of vacuum platings, all has certain advantage, as: excellent adhere to, gloss and chemical resistant properties etc.But these coating are mainly used in spraying, can't be applicable to the production requirement of colored mirror coating heavy industrialization streamlined operation, simultaneously, also can't satisfy the execution conditions of the low-temperature quick-dry of system mirror industry needs.
Summary of the invention
The object of the present invention is to provide a kind of mirror-back protective coating that is used for colored mirror coating, the priming paint of coating and finish paint all have acrylic acid modified alkyd resin, epoxy resin and aminoresin, and the metal level of ability and colored mirror coating forms outstanding adhesion.The production requirement of colored mirror coating large-scale industry streamlined operation can not only be satisfied, the execution conditions of the low-temperature quick-dry of system mirror industry needs can also be satisfied.
The mirror-back protective coating that is used for colored mirror coating provided by the invention comprises priming paint and finish paint, and priming paint and finish paint include acrylic acid modified alkyd resin, epoxy resin and aminoresin.
Acrylic acid modified alkyd resin is the Synolac by one or more acrylic monomer modifications in Bing Xisuandingzhi, TEB 3K, Hydroxyethyl acrylate, methylacrylic acid, vinylformic acid, ethyl acrylate, isobornyl methacrylate and the NSC 20956.These monomers can separately or mix Synolac is carried out modification, also can carry out modification to Synolac again after the first polymerization.Preferential selection, acrylic monomer is modification by copolymerization or esterification modification to the mode of Synolac modification.
Epoxy resin is preferential select as: but be not limited only to Racemic glycidol fundamental mode epoxy resin, Resorcinol bisglycidyl ether type epoxy resin, Phloroglucinol monomethyl ether triglycidyl ether type epoxy resin, aromatic amine Racemic glycidol fundamental mode epoxy resin a kind of or several kinds.
Aminoresin is preferential select as: but be not limited only to urea-formaldehyde resin, terpolycyantoamino-formaldehyde resin and aniline formaldehyde resin or its combination.
Among the present invention, colored mirror coating mirror-back protective coating also comprises pigment, filler, auxiliary agent and solvent.Pigment, filler that those of ordinary skills can need according to the guidance selection of textbook (as: " coating process (third edition) ", Chemical Industry Press, 1997), and required auxiliary agent and solvent.
The another kind of mirror-back protective coating that is used for colored mirror coating provided by the invention; Comprise priming paint and finish paint, priming paint and finish paint include solid content 48%-52% acrylic acid modified alkyd resin, solid content 48%-52% epoxy resin, aminoresin, pigment, filler, auxiliary agent and solvent.
Pigment is selected from iron pigment and (as: but is not limited only to; Iron oxide red, iron oxide yellow and iron oxide black), contain zinc pigment and (as: but be not limited only to; Zinc oxide and zinc sulphide), titanyl phthalocyanine pigment (as: but is not limited only to; The titanium cyanines are blue green with the titanium cyanines), titanium dioxide pigment (as: but being not limited only to rutile type and anatase titanium dioxide) and charcoal blacks (as: but be not limited only to, high-carbon black pigment, middle colour carbon black, hang down colour carbon black and high wear-resistant carbon black).These pigment can use separately, or press the arbitrary proportion combination and use.
Filler as: but be not limited only to permanent white, talcum powder, sal epsom, Magnesium Silicate q-agent and potter's clay.These materials use separately or after pressing the arbitrary proportion mixing.
Auxiliary agent comprises the compsn of anti, siccative, silane coupling agent and/or titanate coupling agent.
Anti as; But be not limited only to methyl ethyl ketoxime, butyraldehyde oxime and kautschin.
Silane coupling agent as: be limited to 3-aminopropyl triethoxysilane, 3-glycidyl ether oxygen propyl trimethoxy silicane, 3-methacryloxypropyl trimethoxy silicon, 3-mercaptopropyltriethoxysilane, N-β (aminoethyl)-3-mercaptopropyl trimethoxysilane and N-β (aminoethyl)-3-aminopropyl methyl dimethoxysilane but lose.
Titanate coupling agent as: but be not limited only to sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanic acid ester, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester, sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester, tetra isopropyl two (dioctyl phosphorous acid acyloxy) titanic acid ester and sec.-propyl three oleic acid acyloxy titanic acid ester.
Siccative as: but be not limited only to cobalt iso-octoate and cobalt naphthenate.
Solvent as: but be not limited only to toluene, YLENE, 1,2,4-trimethylbenzene; 1,3,5-trimethylbenzene, ethylbenzene, propyl benzene, n-propyl alcohol, Virahol, propyl carbinol, isopropylcarbinol, vinyl acetic monomer, N-BUTYL ACETATE and isobutyl acetate.These solvents separately or press arbitrary proportion combination use.
Another kind of colored mirror coating mirror-back protective coating of the present invention comprises priming paint and finish paint.Wherein, primer composition is following:
The component of finish paint is following:
Term involved in the present invention is identical with notion as the one of which.
Described " solid content " promptly refers to the weight percentage of contained resin solid in the resin.
Described " pigment ", " pigment extender ", " auxiliary agent " and " solvent " are material commonly used in the paint field.
The beneficial effect that technical scheme of the present invention realizes:
The mirror-back protective coating that is used for colored mirror coating provided by the invention comprises priming paint and finish paint, in priming paint and finish paint, includes acrylic acid modified modified alkyd resin, epoxy resin and aminoresin.Add advantages such as acrylic acid modified alkyd resin has not only kept the application property of Synolac good, smears the fullness ratio height, snappiness is good, have again that vinyl resin is dried soon concurrently, Bao Sebao light, high weatherable characteristics.The adding of aminoresin can make hydroxyl, the carboxylic acid group of coating in hot setting process neutralized alcohol acid resin that crosslinking reaction takes place, and can carry out esterification with the epoxy group(ing) in the epoxy resin again, thereby forms fine and close cross-linked network.Simultaneously, the aminoresin in the finish paint also can carry out crosslinking curing with the resin of priming paint in solidification process, thereby realizes the coupling of priming paint and finish paint, improves the provide protection to metal substrate greatly, and gives suitable hardness of coating and scraping and wiping resistance performance.
Coating of the present invention does not adopt the heavy metal compound with Corrosion Protection, and is environmentally friendly.Coating of the present invention can adopt extensive curtain to drench moulding process, and can realize flash baking, under 80 ℃ of-100 ℃ of baking conditions, gets final product completely solidified in 4 minutes-6 minutes, and has good physicochemical property, helps large-scale industrial production.
Embodiment
Below describe technical scheme of the present invention in detail.The embodiment of the invention is only unrestricted in order to technical scheme of the present invention to be described; Although the present invention is specified with reference to preferred embodiment; Those of ordinary skill in the art is to be understood that; Can make amendment or be equal to replacement the technical scheme of invention, and not break away from the spirit and the scope of technical scheme of the present invention, it all should be encompassed in the claim scope of the present invention.
The used reagent of the present invention is not if clearly indicate, then all available from Sigma-aldrich (Sigma-Aldrich).
Embodiment 1
According to listed in the table 1 acrylic acid modified alkyd resin, epoxy resin, aminoresin, pigment, filler, solvent are stirred by weight being fed in the stainless steel cylinder; Be fed into the sand mill medium sand then and be milled to fineness less than 25 μ m; Add various film coalescence aid again by weight percent in the table; Like anti, silane coupling agent and/or titanate coupling agent, siccative, stir and filter.
Table 1 priming paint allocation sheet (weight percent)
Embodiment 2
According to listed in the table 2 modified alkyd resin, acrylate resin, resol, cross-linked resin, pigment, filler, solvent are stirred by weight being fed in the stainless steel cylinder; Be fed into the sand mill medium sand then and be milled to fineness less than 25 μ m; Add various film coalescence aid again by weight percent in the table; Like anti, silane coupling agent and/or titanate coupling agent, siccative, stir and filter.
Table 2
Embodiment 3
Priming paint of the present invention and finish paint are diluted to working viscosity 25s-35s (being coated with-4 glasss, 25 ℃) with YLENE when construction, stir, and pour into then and drench in the paint bath, adjust the width that drenches the lacquer cutter and make dry film reach specified requirement.Earlier colored coatings curtain is drenched priming paint curtain pouring finish paint again, after about 80 ℃ of oven dry in-100 ℃, 4 minutes-6 minutes, detect, the paint film property that is used for the mirror back of the body supercoat of colored mirror coating reaches the performance index of table 3.
Table 3
Claims (8)
1. a mirror-back protective coating that is used for colored mirror coating comprises priming paint and finish paint, it is characterized in that said priming paint and said finish paint include acrylic acid modified alkyd resin, epoxy resin and aminoresin;
Said priming paint comprises the solid content 48%-52% acrylic acid modified alkyd resin of weight percent 25-32, solid content 48%-52% epoxy resin and the 6-10 aminoresin of 8-15;
Said finish paint comprises the solid content 48%-52% acrylic acid modified alkyd resin of weight percent 30-40, solid content 48%-52% epoxy resin and the 4-8 aminoresin of 5-10.
2. the mirror-back protective coating that is used for colored mirror coating according to claim 1 is characterized in that said priming paint and said finish paint also comprise pigment, filler, auxiliary agent and solvent.
3. the mirror-back protective coating that is used for colored mirror coating according to claim 2 is characterized in that the set of dispense ratio of said priming paint is:
4. the mirror-back protective coating that is used for colored mirror coating according to claim 2 is characterized in that the set of dispense ratio of said finish paint is:
5. the mirror-back protective coating that is used for colored mirror coating according to claim 2 is characterized in that described acrylic acid modified alkyd resin is the Synolac by one or more acrylic monomer modifications in Bing Xisuandingzhi, TEB 3K, Hydroxyethyl acrylate, methylacrylic acid, vinylformic acid, ethyl acrylate, isobornyl methacrylate and the NSC 20956.
6. the mirror-back protective coating that is used for colored mirror coating according to claim 2 is characterized in that the resin modified mode of described vinylformic acid Dichlorodiphenyl Acetate is modification by copolymerization or esterification modification.
7. the mirror-back protective coating that is used for colored mirror coating according to claim 2 is characterized in that described epoxy resin is selected from a kind of of Racemic glycidol fundamental mode epoxy resin, Resorcinol bisglycidyl ether type epoxy resin, Phloroglucinol monomethyl ether triglycidyl ether epoxy resin and aromatic amine Racemic glycidol fundamental mode epoxy resin or several kinds.
8. the mirror-back protective coating that is used for colored mirror coating according to claim 2 is characterized in that described aminoresin is selected from a kind of of urea-formaldehyde resin, terpolycyantoamino-formaldehyde resin and aniline formaldehyde resin or several kinds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103978826A CN102492356A (en) | 2011-12-05 | 2011-12-05 | Mirror back protective coating for colored coated mirror |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103978826A CN102492356A (en) | 2011-12-05 | 2011-12-05 | Mirror back protective coating for colored coated mirror |
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| Publication Number | Publication Date |
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| CN102492356A true CN102492356A (en) | 2012-06-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2011103978826A Pending CN102492356A (en) | 2011-12-05 | 2011-12-05 | Mirror back protective coating for colored coated mirror |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103087625A (en) * | 2013-01-31 | 2013-05-08 | 安徽蓝柯复合材料有限公司 | High-adhesion silver paint |
| CN103540228A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Seal primer for switch cabinet and preparation method thereof |
| CN103540227A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Alkyd resin finishing coat for instrument cabinet and preparation method thereof |
| CN103555019A (en) * | 2013-09-25 | 2014-02-05 | 天长市天泰光电科技有限公司 | Anti-aging heat radiation paint for LED lamp and preparation method thereof |
| CN103666202A (en) * | 2013-09-10 | 2014-03-26 | 铜陵市肆得科技有限责任公司 | Environment-friendly oily antirust paint and preparation method thereof |
| CN104073124A (en) * | 2014-07-10 | 2014-10-01 | 安徽梦谷纤维材料科技有限公司 | Wear-resistant and corrosion-resistant coating |
| CN104371515A (en) * | 2014-10-23 | 2015-02-25 | 安徽省实防新型玻璃科技有限公司 | Waterborne coating used for glass door and having wear-resistant and sound-insulation functions and preparation method of waterborne coating |
| CN104877514A (en) * | 2014-12-04 | 2015-09-02 | 北京金汇利应用化工制品有限公司 | Amino resin stoving varnish containing water-borne acrylic modified alkyd resin and preparation method thereof |
| CN104893519A (en) * | 2015-05-11 | 2015-09-09 | 广德加点化工有限公司 | Modified aqueous alkyd resin coating |
| CN105062321A (en) * | 2015-09-08 | 2015-11-18 | 王际宽 | Aluminum product surface treatment paint and preparation method thereof |
| CN105131793A (en) * | 2015-09-07 | 2015-12-09 | 王际宽 | Preparation method for paint for ion sheet material |
| CN106423799A (en) * | 2015-10-09 | 2017-02-22 | 江苏柚尊家居制造有限公司 | Teak furniture painting process |
| CN109321106A (en) * | 2018-11-05 | 2019-02-12 | 肇庆市哈力化工有限公司 | A kind of car light of electrocar snoot plated film paint and preparation method thereof |
| CN109337490A (en) * | 2018-07-26 | 2019-02-15 | 广东鑫皇冠新材料有限公司 | A kind of mirror-back protective coating and preparation method thereof with anti-corrosive properties |
| CN109354513A (en) * | 2018-10-31 | 2019-02-19 | 北京小米移动软件有限公司 | Ceramic material and its preparation method and application |
| CN109423212A (en) * | 2017-07-04 | 2019-03-05 | 天津市新丽华色材有限责任公司 | A kind of colour mirror back lacquer |
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| CN101781514A (en) * | 2010-02-03 | 2010-07-21 | 江苏柏鹤涂料有限公司 | Mirror back protective coating for copper-free silver mirror |
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| CN101392140A (en) * | 2008-11-05 | 2009-03-25 | 天津市新丽华色材有限责任公司 | Super fast curing silver mirror back top coating |
| CN101392139A (en) * | 2008-11-05 | 2009-03-25 | 天津市新丽华色材有限责任公司 | Super fast curing silver mirror back priming paint coating |
| CN101781514A (en) * | 2010-02-03 | 2010-07-21 | 江苏柏鹤涂料有限公司 | Mirror back protective coating for copper-free silver mirror |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103087625A (en) * | 2013-01-31 | 2013-05-08 | 安徽蓝柯复合材料有限公司 | High-adhesion silver paint |
| CN103666202B (en) * | 2013-09-10 | 2016-08-10 | 铜陵市肆得科技有限责任公司 | A kind of environment-friendlyoily oily antirust paint and preparation method thereof |
| CN103666202A (en) * | 2013-09-10 | 2014-03-26 | 铜陵市肆得科技有限责任公司 | Environment-friendly oily antirust paint and preparation method thereof |
| CN103555019A (en) * | 2013-09-25 | 2014-02-05 | 天长市天泰光电科技有限公司 | Anti-aging heat radiation paint for LED lamp and preparation method thereof |
| CN103540228A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Seal primer for switch cabinet and preparation method thereof |
| CN103540227A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Alkyd resin finishing coat for instrument cabinet and preparation method thereof |
| CN104073124A (en) * | 2014-07-10 | 2014-10-01 | 安徽梦谷纤维材料科技有限公司 | Wear-resistant and corrosion-resistant coating |
| CN104371515A (en) * | 2014-10-23 | 2015-02-25 | 安徽省实防新型玻璃科技有限公司 | Waterborne coating used for glass door and having wear-resistant and sound-insulation functions and preparation method of waterborne coating |
| CN104877514A (en) * | 2014-12-04 | 2015-09-02 | 北京金汇利应用化工制品有限公司 | Amino resin stoving varnish containing water-borne acrylic modified alkyd resin and preparation method thereof |
| CN104893519A (en) * | 2015-05-11 | 2015-09-09 | 广德加点化工有限公司 | Modified aqueous alkyd resin coating |
| CN105131793A (en) * | 2015-09-07 | 2015-12-09 | 王际宽 | Preparation method for paint for ion sheet material |
| CN105062321A (en) * | 2015-09-08 | 2015-11-18 | 王际宽 | Aluminum product surface treatment paint and preparation method thereof |
| CN106423799A (en) * | 2015-10-09 | 2017-02-22 | 江苏柚尊家居制造有限公司 | Teak furniture painting process |
| CN109423212A (en) * | 2017-07-04 | 2019-03-05 | 天津市新丽华色材有限责任公司 | A kind of colour mirror back lacquer |
| CN109337490A (en) * | 2018-07-26 | 2019-02-15 | 广东鑫皇冠新材料有限公司 | A kind of mirror-back protective coating and preparation method thereof with anti-corrosive properties |
| CN109354513A (en) * | 2018-10-31 | 2019-02-19 | 北京小米移动软件有限公司 | Ceramic material and its preparation method and application |
| CN109354513B (en) * | 2018-10-31 | 2021-07-06 | 北京小米移动软件有限公司 | Ceramic material and preparation method and application thereof |
| CN109321106A (en) * | 2018-11-05 | 2019-02-12 | 肇庆市哈力化工有限公司 | A kind of car light of electrocar snoot plated film paint and preparation method thereof |
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