CN102491465A - Flocculant and preparation method thereof - Google Patents

Flocculant and preparation method thereof Download PDF

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Publication number
CN102491465A
CN102491465A CN2011103807396A CN201110380739A CN102491465A CN 102491465 A CN102491465 A CN 102491465A CN 2011103807396 A CN2011103807396 A CN 2011103807396A CN 201110380739 A CN201110380739 A CN 201110380739A CN 102491465 A CN102491465 A CN 102491465A
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Prior art keywords
flocculation agent
carbide slag
tai
ace
ferric sulfate
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CN2011103807396A
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Chinese (zh)
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CN102491465B (en
Inventor
郭娟丽
吕滨
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ELION ECOLOGICAL RESTORATION Co.,Ltd.
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Elion Resources Group Co Ltd
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Abstract

The invention discloses a flocculant. The flocculant comprises, by weight, 75-90% of calcium hydrate, 0.8-15% of iron sulfate, and 5-14.2% of aluminum sulfate. The flocculant of the invention, which can effectively remove turbidities and harm substances of metallic ions and the like, has the advantages of nontoxicity, harmlessness, no secondary pollution, fast flocculation, low price, and use convenience.

Description

A kind of flocculation agent and preparation method thereof
Technical field
The invention belongs to water treatment field, particularly be used for flocculation agent of municipal sewage treatment and Industrial Wastewater Treatment and preparation method thereof.
Background technology
China's water pollution and water source crisis are serious day by day.Water supply gets and sewage purification have become one of main difficult problem that China faces.The enhancing of Along with people's environmental consciousness and China's implementation of sustainable development; Prevent to pollute and protect the work of environment to cause the great attention of governments at all levels; Treatment of Industrial Water and environmental protection requirement improve constantly, and the water conditioner kind is enriched constantly, and performance improves constantly.The flocculation of flocculation agent accounts for critical role in wastewater treatment.
At present, along with the fast development of industry, the task of wastewater treatment is complicated day by day, and the deficiency of single flocculation agent highlights day by day, so efficient composite flocculation agent will become flocculation agent research from now on and the focus of using.Traditional flocculation agent is some inorganic single flocculation agents, and they are Tai-Ace S 150, alum, exsiccated ammonium alum, iron(ic)chloride, ferric sulfate or ferrous sulfate hydrate.These flocculation agents are well used in process such as purify waste water very early.That traditional flocculation agent exists is powerless to sour water, add and excessively make water become muddy, produce shortcomings such as the wadding piece is little.
Summary of the invention
In order to solve the problems of the technologies described above, the present invention provides a kind of flocculation agent, and objectionable impuritiess such as metals ion can be effectively removed in efficiently turbidity removal again; Simultaneously should nontoxic, harmless, the non-secondary pollution of prescription, flocculation is fast, cheap, easy to use; The present invention also provides a kind of production technique of above-mentioned flocculation agent, and this technology has simple possible, characteristics easy and simple to handle.
Flocculation agent provided by the invention, its composition that contains and following at the shared weight percent of flocculation agent:
Calcium hydroxide 75%-90%;
Ferric sulfate 0.8-15%;
Tai-Ace S 150 5%-14%.
Preferably, hydrolysis prepares in the carbide slag that produces behind the acetylene said calcium hydroxide from calcium carbide.
Preferably, its composition that contains and shared weight percent are following:
Calcium hydroxide 90%;
Ferric sulfate 1%;
Tai-Ace S 150 3%;
The present invention also provides the method for the above-mentioned flocculation agent of preparation, and step is following:
1) pulverize carbide slag, the hydrolysis of power taking stone prepares the carbide slag that produces behind the acetylene and in kibbler, pulverizes;
2) mix according to each component percentage composition, takes by weighing carbide slag, ferric sulfate and Tai-Ace S 150 mixing stirring.
Compare prior art, and flocculation agent of the present invention is a kind of composite inorganic flocculation agent, its existing effect that is better than single inorganic flocculating agent has the effect of neutralizing acid wastewater again.The present invention has realized the comprehensive utilization of refuse; And product has raw material and is easy to get; Use simple, cost is low, temperature influence is little, flocs unit is strong to the avidity of mikrobe, can effectively remove suspended substance in the water, colloid, aerobic bacteria etc., and to effects such as environment are nontoxic.The present invention specifically has following advantage:
1. flocculation agent provided by the invention is when handling sewage and trade effluent, and it is big to form flco, and flocculation efficiency is high; Settling velocity is fast; Filterableness is good, and the neutralizing acid wastewater can effectively be removed mud, total plate count and a large amount of metals ion (experimental data is seen table 1).Therefore, the present invention can be widely used in sewage and trade effluent.
2. because the part material of flocculation agent of the present invention is a carbide slag,, flocculation agent of the present invention is easy to get advantage with low cost so having raw material; With carbide slag produce flocculant in next life, can reduce production costs, can turn waste into wealth again, improve environment, for Comprehensive Utilization for Carbide Slag has been opened up a new way.
3. production technique of the present invention, production unit are simple, working condition is to carry out under the normal temperature and pressure, belong to energy-saving and emission-reducing technique.In the whole process of production, no waste gas, waste liquid, waste residue produce, and belong to green recycling economy industry.
Embodiment
Below in conjunction with specific embodiment the present invention is described further so that those skilled in the art can better understand the present invention and implementing, but the embodiment that lifts not conduct to qualification of the present invention.
Embodiment 1
The component and the weight percentage of present embodiment flocculation agent are following:
Calcium hydroxide 75%;
Ferric sulfate 15%;
Tai-Ace S 150 5%;
Other compositions (other impurity in the carbide slag is not to flocculation contribution effect) 5%.
Its production technique, concrete steps are following:
(1) pulverizes carbide slag
Getting a certain amount of carbide slag pulverizes it in kibbler.
(2) mix
According to each component percentage composition, take by weighing a certain amount of carbide slag, ferric sulfate and Tai-Ace S 150 mixing stirring.
Embodiment 2
The component and the weight percentage of present embodiment flocculation agent are following:
Calcium hydroxide 90%;
Ferric sulfate 1%;
Tai-Ace S 150 3%;
Other compositions (other impurity in the carbide slag is not to flocculation contribution effect) 6%.
The production technique of flocculation agent, concrete steps are following:
(1) pulverizes carbide slag
Getting a certain amount of carbide slag pulverizes it in kibbler.
(2) mix
According to each component percentage composition, take by weighing a certain amount of carbide slag, ferric sulfate and Tai-Ace S 150 mixing stirring.
Embodiment 3:
The component and the weight percentage of present embodiment flocculation agent are following:
Calcium hydroxide 80%;
Ferric sulfate 0.8%;
Tai-Ace S 150 14%;
Other compositions (other impurity in the carbide slag is not to flocculation contribution effect) 5.2 %.
The production technique of flocculation agent, concrete steps are following:
(1) pulverizes carbide slag
Getting a certain amount of carbide slag pulverizes it in kibbler.
(2) mix
According to each component percentage composition, take by weighing a certain amount of carbide slag, ferric sulfate and Tai-Ace S 150 mixing stirring.
Embodiment 1 ~ 3 described flocculation agent is used for WWT, the flocculation principle of flocculation agent: carbide slag is to the coagulation of the mud OH that has been not supply -, and provided a large amount of Ca 2+, Ca 2+Through compression double electric layer, destroyed the stability of mud granule, thereby mud granule is condensed, OH -And Ca (OH) 2Coagulation to sewage sludge does not directly work, and wherein Tai-Ace S 150, ferric sulfate play booster action in flocculation process, makes flocculating effect better.Ca in the carbide slag (OH) 2Can generate the precipitation of hydroxide of metals ion with metals ion in the waste water and reaction, make that institute's metal ion reduces in the water.Simultaneously, the Ca in the carbide slag (OH) 2Show alkalescence, can be used for the quinaldine acid wastewater.
Experimental data after the processing is following:
Table 1 flocculation agent is handled the experimental data of sewage
Figure 251339DEST_PATH_IMAGE002
Annotate: sewage source is in Dongyuan County, Dalate Banner, Ordos City sewage work
The above embodiment is the preferred embodiment that proves absolutely that the present invention lifts, and protection scope of the present invention is not limited thereto.Being equal to that the technician in present technique field is done on basis of the present invention substitutes or conversion, all within protection scope of the present invention.Protection scope of the present invention is as the criterion with claims.

Claims (4)

1. a flocculation agent is characterized in that, composition that it contains and shared weight percent are following:
Calcium hydroxide 75%-90%;
Ferric sulfate 0.8-15%;
Tai-Ace S 150 3%-14%.
2. flocculation agent according to claim 1 is characterized in that, said calcium hydroxide prepares the calcium hydroxide in the carbide slag that produces behind the acetylene for the calcium carbide hydrolysis.
3. flocculation agent according to claim 1 is characterized in that, composition that it contains and shared weight percent are following:
Calcium hydroxide 90%;
Ferric sulfate 1%;
Tai-Ace S 150 3%.
4. prepare the method for each described flocculation agent of claim 1 ~ 3, it is characterized in that, step is following:
1) pulverize carbide slag, the hydrolysis of power taking stone prepares the carbide slag that produces behind the acetylene and in kibbler, pulverizes;
2) mix according to each component percentage composition, takes by weighing carbide slag, ferric sulfate and Tai-Ace S 150 mixing stirring.
CN 201110380739 2011-11-25 2011-11-25 Flocculant and preparation method thereof Active CN102491465B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN102491465B CN102491465B (en) 2013-05-22

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105540797A (en) * 2016-01-22 2016-05-04 浙江正洁环境科技有限公司 Efficient water-treatment composite flocculant
CN108821413A (en) * 2018-07-10 2018-11-16 无锡锐众环保科技有限公司 A kind of coagulant of efficient process COD
CN109534421A (en) * 2018-12-26 2019-03-29 渭南市华州区天鸿商贸有限公司 A kind of compound emulsion carbide slag slurry
CN111349722A (en) * 2020-03-06 2020-06-30 广西壮族自治区农业科学院 Precipitation flocculant and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3552848B2 (en) * 1996-06-14 2004-08-11 榮 畑山 Dredged solid-liquid separation soil improvement method
WO2010083149A2 (en) * 2009-01-13 2010-07-22 Access Business Group International Llc Gravity feed water treatment system
CN102040301A (en) * 2009-10-19 2011-05-04 中国科学院生态环境研究中心 Method for treating municipal waste leachate membrane concentrated solution
CN102040309A (en) * 2009-10-19 2011-05-04 中国科学院生态环境研究中心 Combined treatment process for urban garbage percolate
CN102139971A (en) * 2011-01-26 2011-08-03 中国石油大学(华东) Method and process for advanced treatment of well drilling effluent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3552848B2 (en) * 1996-06-14 2004-08-11 榮 畑山 Dredged solid-liquid separation soil improvement method
WO2010083149A2 (en) * 2009-01-13 2010-07-22 Access Business Group International Llc Gravity feed water treatment system
CN102040301A (en) * 2009-10-19 2011-05-04 中国科学院生态环境研究中心 Method for treating municipal waste leachate membrane concentrated solution
CN102040309A (en) * 2009-10-19 2011-05-04 中国科学院生态环境研究中心 Combined treatment process for urban garbage percolate
CN102139971A (en) * 2011-01-26 2011-08-03 中国石油大学(华东) Method and process for advanced treatment of well drilling effluent

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105540797A (en) * 2016-01-22 2016-05-04 浙江正洁环境科技有限公司 Efficient water-treatment composite flocculant
CN108821413A (en) * 2018-07-10 2018-11-16 无锡锐众环保科技有限公司 A kind of coagulant of efficient process COD
CN109534421A (en) * 2018-12-26 2019-03-29 渭南市华州区天鸿商贸有限公司 A kind of compound emulsion carbide slag slurry
CN111349722A (en) * 2020-03-06 2020-06-30 广西壮族自治区农业科学院 Precipitation flocculant and application thereof
CN111349722B (en) * 2020-03-06 2023-02-10 广西壮族自治区农业科学院 Precipitation flocculant and application thereof

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