CN102480979A - Process for production of milk packed in container - Google Patents

Process for production of milk packed in container Download PDF

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Publication number
CN102480979A
CN102480979A CN2010800358384A CN201080035838A CN102480979A CN 102480979 A CN102480979 A CN 102480979A CN 2010800358384 A CN2010800358384 A CN 2010800358384A CN 201080035838 A CN201080035838 A CN 201080035838A CN 102480979 A CN102480979 A CN 102480979A
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Prior art keywords
milk
container
cow
value
sterilization
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Pending
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CN2010800358384A
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藤井友幸
富仓繁
福井健
兼田正义
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Toyo Seikan Group Holdings Ltd
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Toyo Seikan Kaisha Ltd
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Publication of CN102480979A publication Critical patent/CN102480979A/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C3/00Preservation of milk or milk preparations
    • A23C3/02Preservation of milk or milk preparations by heating
    • A23C3/023Preservation of milk or milk preparations by heating in packages

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Dairy Products (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • Non-Alcoholic Beverages (AREA)

Abstract

A process for producing milk packed in a container, which is characterized by comprising filling milk in an air-impermeable container such as a metallic can, sealing the container, and thermally sterilizing the milk at a temperature ranging from 125 to 135 DEG C for 0.5 to 5 minutes at a F0 value of 4 or more and a C value of 65 or less while shaking the container.

Description

The manufacturing approach of container dress cow's milk
Technical field
The present invention relates to the manufacturing approach of container dress cow's milk, the manufacturing approach of the container that particularly can preserve for a long time at normal temperatures dress cow's milk.
Background technology
Along with popularizing of automatic selling-machine in recent years, in order to make container dress cow's milk through circulations such as automatic selling-machines, known have the container dress cow's milk that can preserve for a long time at normal temperatures.The container that can preserve for a long time at normal temperatures dress cow's milk like this must carry out pasteurization, and this pasteurization is that pressure cooking (retort) sterilization through the long period is carried out.In the patent documentation 1 a kind of manufacturing approach is disclosed for example; This method is the emulsified state that keeps butter oil for stable; The fat globule of cow's milk homogenizing to diameter below 1 micron reached more than 95%; This cow's milk is filled sealing in the air impermeability container, under 115-118 ℃ temperature heat treated 15-20 minute then.
If container dress cow's milk is carried out such pressure cooking sterilization, react the metachromasia that is called as brown stain through casein in the milk composition and lactose, also can generate the membranaceous agglutinator of Beancurd sheet shape at the head space surface element of container.Such brown stain makes degraded appearance, and membranaceous in addition agglutinator also makes degraded appearance, makes simultaneously to go into larynx sense variation when drinking cow's milk, and the commodity value of cow's milk is reduced.
When making the container dress cow's milk that to preserve for a long time at normal temperatures; As the method that prevents above-mentioned such brown stain; Method below disclosing in the patent documentation 2: in whole operations of the homogenization process before pasteurization, filling sealing process etc.; Cow's milk is handled the container that to have filled cow's milk and sealing then under 110-120 ℃ temperature pasteurization 10-30 minute in the temperature below 80 ℃.But in the patent documentation 2, do not have any open for the problem that how to solve because of the generation of the membranaceous agglutinator that produced in pasteurization 10-30 under 110-120 ℃ temperature minute.
In addition; Even as preserving the manufacturing approach of carrying out the also non-discoloring container dress of pressure cooking sterilization processing cow's milk at normal temperatures for a long time; Method below disclosing in the patent documentation 3: sodium hydrogensulfite and/or the potassium metabisulfite that in cow's milk, adds all 0.001-0.02% weight also mixes, this cow's milk carried out the homogenizing processing; Perhaps in the cow's milk that homogenizing is handled, add sodium hydrogensulfite and/or the potassium metabisulfite and the mixing of all 0.001-0.02% weight; This cow's milk is filled sealing in the air impermeability container, carry out pasteurization and handle.But in the patent documentation 3, pasteurization is (paragraph) that under 115-125 ℃ temperature, carries out through 5-30 minute sterilization processing, does not have any open for the generation problem that how to solve the membranaceous agglutinator that is produced by this pasteurization.
The purpose of patent documentation 4 is; Use the pressure cooking bactericidal assay to provide to follow good breast sense to have excellent beverage flavor and the sense of taste and, wherein disclose through the pressure cooking sterilizer and in 130 ℃ to 140 ℃ scope, carried out 8 minutes methods of heating treatment of maximum with the manufacturing approach that contains newborn tinned drink of limpid sense.But in the patent documentation 4; Containing newborn tinned drink is in coffee, cocoa, black tea, soup etc., to add breast; And be defined as and be filled in (paragraph) in the canned container; Even in an embodiment, the content of cow's milk also is no more than the 10-12% weight of jar content, is not the object of the manufacturing approach that the present invention relates to---the container dress cow's milk that can preserve for a long time at normal temperatures.Therefore, the brown stain that takes place when container carries out the pressure cooking sterilization for cow's milk itself is packed into and this problem how to tackle of generation of membranaceous agglutinator do not disclose the method for any this problem of solution.
Disclose a kind ofly when the beverage that contains plastic containers such as cow's milk dress milk composition is carried out sterilization in the patent documentation 5, container-packed beverage has been slided, prevented the method for the generation of membranaceous agglutinator thus through using heat water-spraying's formula slip pressure cooking bactericidal assay.But this method is under 124 ℃ of sterilization temperatures, to carry out 35 minutes pressure cooking sterilization (paragraph); When container contents is cow's milk; Though can prevent the generation of membranaceous agglutinator, tone can not fully keep the whiteness of cow's milk, can't satisfy target of the present invention---L *The value more than 92, a *The value below-1.0, b *Value is the value (paragraph table 12) below 12.
The prior art document
Patent documentation
Patent documentation 1: the special public clear 62-19810 communique of Japan
Patent documentation 2: japanese kokai publication hei 5-227883 communique
Patent documentation 3: japanese kokai publication hei 5-137503 communique
Patent documentation 4: TOHKEMY 2001-275632 communique
Patent documentation 5: TOHKEMY 2008-220207 communique
Summary of the invention
The problem that invention will solve
The present invention is in view of the above-mentioned problem points of technology in the past, can preserve the also nondiscolouring and do not generate the manufacturing approach of the container dress cow's milk of membranaceous agglutinator of pressure cooking sterilization processing at normal temperatures for a long time even provide.
The method of dealing with problems
For solving above-mentioned problem; The inventor has carried out lucubrate and experiment repeatedly; The result finds: while if being filled the back container that vibrates of sealing in air impermeability containers such as metal can, cow's milk carries out high temperature, though handle the cow's milk nondiscolouring through the pressure cooking sterilizer; Do not generate membranaceous agglutinator yet, thereby accomplished the present invention.
That is, the of the present invention the 1st to constitute be the manufacturing approach of container dress cow's milk, it is characterized in that, cow's milk is filled sealing in the air impermeability container after, in 125-135 ℃ temperature range, carry out 0.5 minute-5 minutes F while this container is vibrated 0Value is more than 4, the C value is the pasteurization below 65.
The 2nd formation of the present invention is the manufacturing approach of container dress cow's milk; It is characterized in that; In the 1st constitutes, increase, above-mentioned pasteurization is to use the pressure cooking sterilizer of heat water-spraying's formula or hot water spray formula, and the container of having filled above-mentioned cow's milk and seal is slided in the horizontal direction and carries out.
The 3rd formation of the present invention is the manufacturing approach of container dress cow's milk, it is characterized in that, in the 1st or the 2nd constitutes, increases, and the temperature range of above-mentioned pasteurization is 125 ℃-130 ℃.
The 4th formation of the present invention is the manufacturing approach of container dress cow's milk, it is characterized in that, increases in each in above-mentioned 1-the 3rd constitutes, and above-mentioned air impermeability container is a metal can.
The invention effect
Constitute according to the 1st of the invention described above, while through making 0.5 minute-5 minutes F of container vibration in 125-135 ℃ temperature range, carrying out that fill after sealing 0Value more than 4, C value are the pasteurization below 65, and the cow's milk variable color of manufacturing is few, does not also generate the membranaceous agglutinator of Beancurd sheet shape, the container dress cow's milk of the excellence that can obtain preserving for a long time at normal temperatures.In addition,, therefore compare, can the generation of heating stink be suppressed at Min. with the pressure cooking sterilization in the past of under 110-120 ℃ temperature, carrying out 10-30 minute pasteurization because sterilizing time is short.
According to the 2nd formation of the present invention, carry out the slip sterilization of horizontal direction through the pressure cooking sterilizer that uses heat water-spraying's formula or hot water spray formula, compare with other pressure cooking method for disinfection, can the generation of membranaceous agglutinator be suppressed at Min..
According to the 3rd formation of the present invention, be 125 ℃-130 ℃ through the temperature range that makes pasteurization, need not to worry compressive resistance, can directly adopt normally used pressure cooking sterilizer.
According to the 4th formation of the present invention, use metal can as the air impermeability container, can prevent the container deformation that high temperature causes thus, the content that causes because of oxidation in the time of can also preventing container dress cow's milk is circulated at normal temperatures for a long time is corrupt.
The accompanying drawing summary
Fig. 1 is the sectional view that shows an example of the device that is used for the embodiment of the present invention method.
Fig. 2 is the sectional view that shows another example of the device that is used for the embodiment of the present invention method.
The mode that carries out an invention
Following with reference to accompanying drawing, the mode that is used for embodiment of the present invention is described.
In this specification, be called the milk beverage that the term of cow's milk comprises cow's milk, skimmed milk, modified milk, whipping cream, evaporated milk, sterilization sour milk beverage and added emulsifying agent, stabilizing agent etc.
The present invention is applicable to the manufacturing approach of the container dress cow's milk of in the air impermeability container, filling sealing; In pasteurization,, cow's milk makes 0.5 minute-5 minutes F of this container vibration in 125-135 ℃ temperature range, carrying out while being filled the sealing back in the air impermeability container 0Value is more than 4, the C value is the pasteurization below 65.The tone that should reach does, when just making the back, and L *Value is more than 92, and is preferred more than 93, more preferably more than 94, and also preferred a *The value for below-1.0, b *Value is below 12.About above-mentioned sterilizing value F 0Value, F 0Value is to be Japanese rules more than 4---the minimum of defined on the food hygiene law, F 0Value is to get final product more than 4.But, depend on method for disinfection, if carry out F 0Be worth excessive pasteurization, then the whiteness of cow's milk is insufficient, has to be difficult to reach L *The tendency of value more than 92.In addition, even to L *Value is influence not, also is excessive sterilization, thereby meaningless.About above-mentioned C value, shown in the embodiment, the C value is promptly to obtain the above-mentioned good color tone that should reach below 65 as described later.Therefore, as stated, among the present invention, the pasteurization condition is in 125-135 ℃ temperature range, to carry out 0.5 minute-5 minutes, in this scope, sets and can realize F 0Value is that sterilizing value and the C value more than 4 is the temperature and time below 65.
C value described here is also referred to as cooking value (cooking value), is expression food composition etc. because the index of the degree of hot change (deterioration etc.) is defined by following formula:
C = ∫ 0 t 10 T - Tref z dt
The t=processing time, T=initial temperature, Tref=fiducial temperature (100 ℃), z=z value (25 ℃).(source: light beautiful jade テ Network ノ Block Star Network ス (light beautiful jade technical manual) 16 " pressure cooking food " 235-236 page or leaf, light beautiful jade " new food engineering change version " 60 pages " brown stain goat breast Z value ")
When sterilization temperature is lower than 125 ℃, for obtaining required F 0Value, C value, sterilizing time is elongated, is difficult to prevent fully variable color.On the other hand, if sterilization temperature surpasses 135 ℃, the pressure that then the pressure cooking sterilizer is relevant further raises, and is harsh use for the pressure cooking sterilizer of normally used formation.Therefore need to reduce the continuous use under the HTHP; Perhaps changing to the tough and tensile pressure cooking sterilizer that can tolerate continuous use constitutes; And be limited to 135 ℃ on the sterilization temperature that need not to consider compressive resistance, can directly use common employed pressure cooking sterilizer, preferred 130 ℃.
The air impermeability container that uses in the manufacturing approach as container dress cow's milk of the present invention is even from carrying out 0.5-5 minute F in above-mentioned 125-135 ℃ temperature range 0Value more than 4, the high temperature of C value below the 65 corrupt viewpoint of content also indeformable, that cause because of oxidation in the time of also can preventing container dress cow's milk is circulated are at normal temperatures for a long time considered; Metal can is best, also can use air impermeability and stable on heating plastic containers.
The method of embodiment of the present invention is according to conventional method cow's milk to be filled in the container, and the head space of container with inert gas replacements such as nitrogen and sealing, is vibrated and carries out high temperature while will fill the container of cow's milk and sealing then.The pressure cooking method for disinfection can enumerate from heat water-spraying's formula of top spray hot water or from the side with pressure cooking sterilization, steam pressurized cooking disinfection or the hot water pressure cooking sterilization etc. of the hot water spray formula of hot water spray; From suppressing the viewpoint consideration that membranaceous agglutinator generates, the pressure cooking sterilization of preferred above-mentioned heat water-spraying's formula or hot water spray formula.In addition, make the method for container vibration can be rotation, shake, the slip of preferred levels direction particularly in order to prevent the generation of membranaceous agglutinator, be preferably the pressure cooking sterilizer slip in the horizontal direction of using heat water-spraying's formula or hot water spray formula.
When carrying out sterilization through heat water-spraying's formula or hot water spray formula pressure cooking sterilizer; Before heating, sterilization, drainage procedure finish; Before and after the sterilization frame that always will be mounted with container dress cow's milk carries out or about etc. the slip of horizontal direction; Like this, can forcibly stir surface, effectively prevent the generation of membranaceous agglutinator as the cow's milk of container contents.
The sliding condition of sterilization frame is according to beverage contents and difference, and the slip number of times is set at 5 times/minute-90 times/minute scope.The slip number of times lacks than 5 times/minute, and then the static condition of content is elongated, is easy to generate the separation of fatty lactoprotein or the generation of membranaceous agglutinator, and the slip number of times is than more than 90 times/minute, and then the motion of container becomes fierce, possibly cause the overturning of container.Preferred scope is 40 times/minute-80 times/minute.Sliding stroke is preferably the scope of 50-100mm.
Acceleration during slip is preferably set to the acceleration of 0.2G-5G.When acceleration ratio 0.2G hanged down, the stirring of content was insufficient, was easy to generate the separation of fatty lactoprotein or produced membranaceous agglutinator, and acceleration surpasses 5G, and the motion that brings of then sliding becomes big, preferably adopts the formation of tough and tensile pressure cooking sterilizer.Preferred acceleration range is 0.4G-2G.
Fig. 1 and Fig. 2 are the sectional views of an example that shows the device of the method be used for embodiment of the present invention.
Fig. 1 shows the sterilization frame slide mechanism that relies on the cylinder mode.
Among Fig. 1, A1 is pressure cooking sterilizer (retort) body, and A2 is brace tables such as track.On this brace table A2, this travelling carriage A4 goes up multilayer and carries sterilization frame (pallet) A5 travelling carriage A4 via roller A3 frame, accommodates a lot of container dress cow's milk among this sterilization frame (pallet) A5 side by side.
A6 is a cylinder, and A7 is the fixed station that is used for fixing cylinder A6, and the other end of cylinder A6 is connected with the driving shaft A8 that gives prominence to from travelling carriage A4 via the sealing mechanism A9 of pressure cooking sterilizer body A1.
During driving, if drive cylinder A7, then travelling carriage A4 front-rear reciprocation movement slides the container dress cow's milk front and back that hold on the travelling carriage A4, and filler obtains stirring.
Fig. 2 representes to rely on the sterilization frame slide mechanism of crank mode.Among Fig. 2, identical inscape with Fig. 1 is used the symbolic representation identical with Fig. 1, omits its explanation.
Among Fig. 2, A10 is a motor, and A11 is the crank mechanism with motor A10 driving, and during driving, if CD-ROM drive motor A10, then travelling carriage A4 makes the front and back slip of container dress cow's milk equally and obtains stirring with Fig. 1 through crank mechanism A11 front-rear reciprocation movement.
Embodiment
[evaluation]
1. the variable color after the sterilization
Spectrophotometric color measurement instrument " CM-3500d " through ミ ノ Le タ manufacturing. reverberation is measured the L of the cow's milk after the filling sealing sterilization in metal can just *Value, a *Value, b *Value.
2. the membranaceous agglutinator after the sterilization generates
Visual Confirmation has just been filled the cow's milk after the sealing sterilization in metal can membranaceous agglutinator generates degree.
[content, container, filling condition]
1. content
Commercially available 1L wrapper cow's milk is repacked.
2. container
Attenuate (the strand り ご I) processing that stretches of use is coated with polyester film on the two sides of no tin-coated steel metallic plate laminated metal sheet; Make the metal can of inner capacities 200ml; On the other hand, use the aluminium metal sheet that on face, is coated with polyester film to make crown cap as inner face side.
3. filling condition
5 ℃ of filling temps
Loading 185ml
Enclose the oxygen amount through nitrogen and steam displacement head space, making the oxygen residual quantity is below the 0.5ml.
Embodiment 1
With heat water-spraying's formula horizontal direction slip pressure cooking sterilizer; Under the condition of amplitude 75mm, sliding stroke 71rpm, the metal can of the cow's milk of packing into to be slided in beginning pressure cooking sterilization, the time that is warming up to 100 ℃ is 3 minutes; Heating-up time by 100 ℃ of reaching sterilization temperatures is 3.5 minutes; Then, under 125 ℃ of sterilization temperatures, carry out 5 minutes pasteurization, the F that the result reaches 0Value is 8.9, and the C value is 51.2.
Then, to the L of cow's milk after the above-mentioned pressure cooking sterilization *Value, a *Value, b *Value and membranaceous agglutinator generate and estimate.
Embodiment 2
In embodiment 1, making sterilization temperature is that 127 ℃, sterilizing time (sterilization retention time) are 2 minutes, in addition carries out pasteurization according to the same terms, the F that the result reaches 0Value is 4.0, and the C value is 26.3, carries out same evaluation.
Embodiment 3
In embodiment 2, making sterilizing time (sterilization retention time) is 3 minutes, in addition carries out pasteurization according to the same terms, the F that the result reaches 0Value is 6.5, and the C value is 36.0, carries out same evaluation.
Embodiment 4
In embodiment 3, the amplitude that makes slip is that 210mm, sliding stroke are 50rpm, in addition carries out pasteurization according to the same terms, the F that the result reaches 0Value is 6.4, and the C value is 34.3, carries out same evaluation.
Embodiment 5
In embodiment 3, making sterilizing time (sterilization retention time) is 3 minutes and 20 seconds, in addition carries out pasteurization according to the same terms, the F that the result reaches 0Value is 7.4, and the C value is 38.8, carries out same evaluation.
Embodiment 6
In embodiment 1, making sterilization temperature is 132 ℃, and sterilizing time (sterilization retention time) is 1 minute, in addition carries out pasteurization according to the same terms, the F that the result reaches 0Value is 6.0, and the C value is 28.0, carries out same evaluation.
Embodiment 7
In embodiment 1, sterilizer is adopted hot water spray formula horizontal direction slip pressure cooking sterilizer, making sterilization temperature is that 127 ℃, sterilizing time (sterilization retention time) are 3 minutes, in addition carries out pasteurization according to the same terms, the F that the result reaches 0Value is 6.7, and the C value is 38.5, carries out same evaluation.
Embodiment 8
With steam-type horizontal direction slip pressure cooking sterilizer, under the condition of amplitude 75mm, sliding stroke 71rpm, in beginning pressure cooking sterilization, slide; The time that is warming up to 100 ℃ is 2 minutes; 100 ℃ down keep 5 minutes after, make by 100 ℃ of heating-up times that are warming up to sterilization temperature be 2.0 minutes, under 127 ℃ of sterilization temperatures, carry out 1 minute pasteurization then; As a result, the F that reaches 0Value is 5.0, and the C value is 35.1.
Then, carry out the L value of cow's milk after the above-mentioned pressure cooking sterilization and the evaluation that membranaceous agglutinator generates.
Embodiment 9
In embodiment 8, making sterilization temperature is that 135 ℃, sterilizing time (sterilization retention time) are 0.5 minute, in addition carries out pasteurization according to the same terms, the F that the result reaches 0Value is 11.6, and the C value is 49.3, carries out same evaluation.
Embodiment 10
In the rotary pressure cooking sterilizer of hot water, import 115 ℃ hot water, import accomplish after, when beginning to heat up, carry out the rotation that per minute 8 changes.Making the time from being directed into of 115 ℃ of hot water import to be accomplished is 3 minutes, and 115 ℃ of heating-up times to sterilization temperature are 4 minutes, under 127 ℃ of sterilization temperatures, carries out 2 minutes 3 seconds pasteurization then, the F that the result reaches 0Value is 10.9, and the C value is 58.6.
Then, carry out the L value of cow's milk after the above-mentioned pressure cooking sterilization and the evaluation that membranaceous agglutinator generates.
Comparative example 1
In embodiment 5,, carry out pasteurization, the F that the result reaches beginning not slide in the pressure cooking sterilization with heat water-spraying's formula horizontal direction slip pressure cooking sterilizer 0Value is 6.4, and the C value is 36.2, carries out same evaluation.
Comparative example 2
In embodiment 1, make that the heating-up time to sterilization temperature is 2.0 minutes from 100 ℃, making sterilization temperature is that 115 ℃, sterilizing time (sterilization retention time) are 23 minutes, in addition carries out pasteurization according to the same terms, the F that the result reaches 0Value is 6.2, and the C value is 102.6, carries out same evaluation.
Comparative example 3
In embodiment 8, making sterilization temperature is 132 ℃, in addition carries out pasteurization according to the same terms, the F that the result reaches 0Value is 11.6, and the C value is 60.0, carries out same evaluation.
Comparative example 4
In embodiment 8, do not slide when beginning the pressure cooking sterilization with steam-type horizontal direction slip pressure cooking sterilizer, making sterilization temperature is that 125 ℃, sterilizing time (sterilization retention time) are 6 minutes, carries out pasteurization, the F that the result reaches 0Value is 15.4, and the C value is 91.0, carries out same evaluation.
Evaluation result is as shown in table 1.
[table 1]
Figure BPA00001511282700121

Claims (4)

1. the manufacturing approach of container dress cow's milk is characterized in that, cow's milk is filled sealing in the air impermeability container after, in 125-135 ℃ temperature range, carry out 0.5 minute-5 minutes F while this container is vibrated 0Value is more than 4, the C value is the pasteurization below 65.
2. the manufacturing approach of the container of claim 1 dress cow's milk is characterized in that, said pasteurization is through using the pressure cooking sterilizer of heat water-spraying's formula or hot water spray formula, and the container of having filled said cow's milk and sealing is slided in the horizontal direction and carries out.
3. the manufacturing approach of claim 1 or 2 container dress cow's milk is characterized in that the temperature range of said pasteurization is 125 ℃-130 ℃.
4. the manufacturing approach of each container dress cow's milk among the claim 1-3 is characterized in that said air impermeability container is a metal can.
CN2010800358384A 2009-08-06 2010-06-15 Process for production of milk packed in container Pending CN102480979A (en)

Applications Claiming Priority (3)

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JP2009-183514 2009-08-06
JP2009183514A JP5621224B2 (en) 2009-08-06 2009-08-06 Method for producing containerized milk
PCT/JP2010/060107 WO2011016288A1 (en) 2009-08-06 2010-06-15 Process for production of milk packed in container

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CN102480979A true CN102480979A (en) 2012-05-30

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CA2862551A1 (en) * 2012-01-03 2013-07-11 Nestec S.A. Thermally processed, shelf-stable dairy-based compositions and methods for making same
JP6745077B2 (en) * 2015-08-26 2020-08-26 キリンビバレッジ株式会社 Beverage containing UHT pasteurized milk with excellent milk feel

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Application publication date: 20120530