CN102479881A - Method for printing identification code on solar cell and method for recording manufacturing process parameters of solar cell - Google Patents

Method for printing identification code on solar cell and method for recording manufacturing process parameters of solar cell Download PDF

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Publication number
CN102479881A
CN102479881A CN2011102366432A CN201110236643A CN102479881A CN 102479881 A CN102479881 A CN 102479881A CN 2011102366432 A CN2011102366432 A CN 2011102366432A CN 201110236643 A CN201110236643 A CN 201110236643A CN 102479881 A CN102479881 A CN 102479881A
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China
Prior art keywords
solar cell
identification code
cell substrate
bus
zone
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CN2011102366432A
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CN102479881B (en
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简荣吾
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Inventec Solar Energy Corp
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Inventec Solar Energy Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention relates to a method for printing an identification code on a solar cell and a method for recording the process parameters of the solar cell, wherein the method for printing the identification code comprises the following steps: providing a batch of semi-finished products of the solar cell substrate, wherein the semi-finished products refer to all processes of a light absorption surface of the solar cell substrate; and printing the metal paste on the back of the batch of solar cell substrates in a screen printing mode to form a first bus (busbar), a second bus and an identification code for identifying the wafer. Compared with the prior art, the method of the invention has the advantages of easy process and no need of increasing equipment cost. Moreover, when the yield of the solar cell is reduced, a tester can analyze and search problems according to the process parameter data of each solar cell substrate, and timely adjust the process parameters to optimize the quality of the solar cell.

Description

Solar cell is printed the method for identification code and is write down the method for its process parameter
Technical field
The present invention system goes up the method for printing identification code (identification) about a kind of at solar cell (solar cell), is meant the method for when wire mark conducting resinl solar cell surface, printing the method for identification code simultaneously and combining this identification code recording solar base plate process parameter especially.
Background technology
In recent years, because the new line of environmental consciousness and the exhaustion gradually of other energy make countries in the world begin to pay attention to the utilization of the renewable energy resources.The renewable energy resources comprise: sources such as solar energy, wind energy, water ability or biological energy source can deficient resource.And the Taiwan located in subtropical zone, sunshine is abundant, therefore in Taiwan, utilizes the exploitation of solar cell (solar cell) as solar energy source, and the photoelectric conversion efficiency of solar energy is improved, and is the focus of each industrial research now.
Because the processing procedure of solar cell (solar cell) is comparatively simple compared to manufacture of semiconductor.Based on the consideration on the cost, be used for preparing the wafer of solar cell, and it is the same to be unlike in the preparation semiconductor integrated circuit, the mode that meeting scans with laser is to each wafer imprinting identification code (identification).
Therefore, in the process of preparation solar cell, also have no way of learning the individually process parameter of each wafer.But in the middle of the preparation process, the parameter of processing procedure possibly done adjustment slightly or a little difference is arranged according to condition of different, for example: the concentration of diffusion process ion, the concentration of acid & alkali liquid, etched time or the like.
If in the preparation process,, and cause when the solar cell yield descends by the gross because wherein one processing procedure goes wrong; Be difficult in time from existing data and data analysis; Find out corresponding wafer problem place, make when readjusting process parameter to have the certain difficulty degree.In addition, and for example after the solar cell shipment, client terminal to discover defective products problem because solar battery sheet does not have the imprinting identification code, therefore also can't be found out the problem that corresponding processing procedure takes place, and also has no way of finding out corresponding improvement measure certainly.
Summary of the invention
The present invention provides the method in solar cell printing identification code that a kind of processing procedure is simple, cost is low.
The present invention provides a kind of method that combines the identification code recording solar base plate process parameter of said method printing in addition.
A kind of solar cell is printed the method for identification code, comprising:
The semi-finished product of one batch of solar cell substrate are provided, and these semi-finished product are meant that this solar cell substrate accomplished all processing procedures of extinction face; And
Metal paste is printed on this batch solar cell substrate back side with the wire mark mode, forms the identification code of first bus (bus bar), second bus and an identification wafer.
In one embodiment of the invention; First and second above-mentioned bus is divided into first to the 3rd zone with the solar cell substrate back panel; Identification code is selected from wherein a kind of of group that graphic sign, figure notation, literal and combination in any thereof form, is distributed between those zones.
In one embodiment of the invention, the above-mentioned method in solar cell printing identification code further comprises carries out sintering processes to solar cell, so that first bus and second bus and solar cell substrate form nurse contact electrode difficult to understand.
A kind of method of record solar ability battery process parameter, this method comprises:
The semi-finished product of solar cell substrate are provided, and these semi-finished product are meant that this solar cell substrate accomplished all processing procedures of extinction face;
Metal paste is printed on this solar cell substrate back side with the wire mark mode, forms the identification code of first bus (bus bar), second bus and an identification wafer; And
Write down the identification code and the process parameter of this solar cell substrate, the parameter of solar cell in the preparation process can be write down and build file.
Beneficial effect of the present invention: method of the present invention not only processing procedure is easy, does not also need to increase equipment cost again.And when the yield of solar cell descended, the testing staff can be according to the process parameter data of each sheet solar cell substrate, analyzed and searched problem, and adjust process parameter in good time, made the best in qualityization of solar cell.
For let above and other objects of the present invention, feature and advantage can be more obviously understandable, hereinafter is special lifts preferred embodiment, and cooperates appended graphicly, elaborates as follows.
Description of drawings
Fig. 1 shows the employed half tone of embodiment of the invention printing solar cell.
Fig. 2 A to 2B shows the rearview of embodiment of the invention solar cell substrate.
Embodiment
Reach technological means and the effect that predetermined goal of the invention is taked for further setting forth the present invention; Below in conjunction with accompanying drawing and preferred embodiment; The solar cell that proposes according to the present invention is printed embodiment, structure, characteristic and the effect of the method for identification code, specify as after.
In the solar cell processing procedure, one batch of solar cell substrate can form electrode at the solar base plate extinction face and the back side after in regular turn through cleaning, structuring (texturing), diffusion, insulation and coating anti reflection layer, connect extraneous circuit.Please see figures.1.and.2 simultaneously; The invention is characterized in; Metal paste is formed first bus 21 (rear side bus bar) and second bus 22 with the back side 20 that the wire mark mode is printed on solar cell substrate 2, and also the identification code 23 with an identification wafer is printed on the solar cell substrate 2.
Fig. 1 prints first bus 21, second bus 22 and identification code 23 employed half tones 1 on solar cell substrate.By finding out among the figure, except the pattern openings 12 of the pattern openings 11 that defines first bus 21, second bus 22, also defined the pattern openings 13 of identification code 23 on the half tone 1.As can be seen from the surface, the first bus 21 and the second bus 22 to the pattern of openings 11 and 12 form two rows of openings fair.
The pattern openings 11,12 of first bus 21 and second bus 22 also is divided into three zones with half tone 1.The upper area of the pattern openings 11 of first bus 21 be first area 101, the first buses 11 and second bus 22 pattern openings 11, be that the lower zone of the pattern openings 12 of second area 102, the second buses 22 is the 3rd zone 103 between 12.
The first and the 3rd zone 101,103 can be according to demand, selected arbitrarily units zone or the tens zone represented.For example in the embodiment of the invention,, represent tens zone and units zone respectively with first area 101 and the 3rd zone 103.Yet the identification of identification code 23 tens and units in fact also can be selected different differentiating methods according to demand.
It should be noted that; Please with reference to Fig. 2; For in the wire mark processing procedure, scraper plate is just advanced once and can first bus 21, second bus 22 and identification code 23 all be printed on the solar cell substrate back side 20 to a direction, reaches the purpose of saving the processing procedure time; The embodiment of the invention mainly is through changing the position of scraper plate starting point and terminal point, giving different chips other identification code 23.So, in the embodiment of the invention, the opening 13 that only the 101 and the 3rd zone 103 is provided with the identification code pattern in the first area.
Identification code pattern openings 13 can be selected from wherein a kind of of group that graphic sign, figure notation, literal and combination in any thereof form.Graphic sign can be any geometries such as circular, square or triangle.In addition, also can use Arabic numerals or Roman number, perhaps adopt one, two, three ... And so on literal numbering.
The pattern openings 13 of the identification code 23 of present embodiment comprises a plurality of pictorial symbolizations 130 and numeric character 132; The user can be according to the numbering of each wafer; Be selected from the opening 132 that sees through pictorial symbolization 130, numeric character 132, the control scraper plate changes the position of Origin And Destination.By seeing on the drawing, scraper plate (or in the opposite direction) is from top to bottom advanced once, can the metal paste of first bus 21, second bus 22 and identification code 23 be printed on the solar cell substrate back side 20.
Fig. 2 A has shown the dorsal view of the solar base plate 2 of different sheets in the embodiment of the invention with Fig. 2 B.When utilizing half tone 1; When the control scraper plate is printed on the solar cell substrate back side 20 with metal paste from top to bottom; Promptly to represent tens be 9 if start position be " 9 " (printing out " 9 " in the first area 101 and the graphic sign of going together); And the terminal point of scraper plate motion during for " 9 " (print out in the 3rd zone 103 " 9 " with go together graphic sign), promptly representing units is 9.In other words, the wafer identification sign indicating number 23 of this sheet solar cell substrate 2 is " 99 ", shown in Fig. 2 A.
The rest may be inferred, and when the identification code 23 of a slice solar cell substrate 2 was " 98 " under printing, scraper plate was the starting point setting in motion with " 9 " in the zone 101 of half tone 1, and the destination county up to " 8 " in zone 103 stops, shown in Fig. 2 B.In other words, during wire mark,, can arrange out the situation of identification code from 99 ~ 00 through the Origin And Destination position of control scraper plate motion.Utilize method provided by the present invention, can number at least 100 solar cell substrate 2.Therefore, when carrying out the solar cell processing procedure, enough make each sheet solar cell all have its identification code 23 separately with a collection of solar cell substrate 2.
Certainly, in another embodiment, also can represent the identification code numbering with numeral merely.For example, it is starting point that scraper plate is selected a numeric character a from this tens zone, and when marching to the units zone, selecting another numeric character b is terminal point, and a and b represent 0 ~ 9 wherein arbitrary numeral, and then identification code is " ab " by interpretation promptly
Though be to write identification code in the embodiment of the invention with the decimal system, be not limited in this example, with other mode, for example octadic or hexadecimal also are fine.In addition, also can utilize the different patterns mark to distinguish tens and units, for example, the graphic sign of representing tens is square, and represents the graphic sign of units to use circular.
Because in the wire mark process, pictorial symbolization, literal or the numeral that identification code 13 may take place not seal is complete and cause erroneous judgement.Therefore, another kind of mode is with the foundation of the distance between graphic sign and the datum line as read-write.
In first area 101, set first datum line 1010, and the graphic sign in the first area 101 and the distance of first datum line 1010 are dA, promptly equal A unit distance, in the embodiment of the invention, first datum line 1010 is the edge of first bus 11.
In the 3rd zone 103, set second datum line 1030, be the border of solar cell substrate 2, and be positioned at the 3rd regional 103 graphic sign, with second datum line 1030 unit number apart be B, then the interpretation mode of identification code is " (A-1) (B-1) ".For example, among Fig. 2 A, A=10 is so the identification code 23 of B=10 this film solar cell substrate is " 99 ".In embodiments of the present invention, the identification code 23 of solar cell substrate 2 all is to come interpretation with the pattern recognition machine.
The composition of printing the metal paste of first bus 11, second bus 12 and identification code 13 comprises conductive metal powder, glass (pottery) powder and organic compound.Conductive metal powder can be selected from silver, aluminium, copper, silicon etc.Glass (pottery) powder helps slurry whole sintering and tack like PbO, B2O3, SiO2 etc.Organic compound then helps making metal paste to be printed on the solar cell substrate surface.
After the wire mark program; Also need pass through sintering processes again; Also be about to solar cell substrate 1 and be positioned in the annealing boiler tube, be heated to about 700 ~ 800 ℃, make metal diffusing to the solar cell substrate 2 of first bus 21, second bus 22 form good nurse contact difficult to understand with as electrode.
The present invention in fact also provides a kind of process parameter to batch solar cell substrate to increase the method for record relative position parameter.In the processing procedure process; Though the process parameter of same batch of solar cell is identical; But; During at the phosphorous diffusion processing procedure or with electricity slurry coating anti reflection rete, because the location parameter that solar cell substrate is placed difference to some extent, also possibly be one of the reason that causes the difference of solar cell usefulness.
Past is not owing to number the individual slices solar cell; Be difficult to analyze owing to the different differences that cause in position; Use method of the present invention to after the individual slices solar cell numbering; Before effect test, can write down the process parameter and the identification code of this batch solar cell through the solar cell after the sintering processes earlier.In case when finding that the usefulness of solar cell is not so good as expection, can see through the processing procedure experience that identification code is grasped this sheet solar cell, follow the trail of the reason of usefulness reduction, and adjust process parameter in good time to improve the usefulness and the quality of solar cell.
Certainly, imprinting identification code also can be applied to other pattern printing process on solar cell substrate.As: with the wire mark mode etching formula slurry (etch paste) or implanted slurry (doped paste) are printed in solar base plate, simultaneously with the identification code imprinting on solar cell substrate, also be feasible mode.
In sum, a kind of printing identification code provided by the present invention (identification) has advantage in method and the application of solar cell (solar cell):
(1) processing procedure is easy, and need not increase equipment cost.The method of printing identification code provided by the present invention may be incorporated in the original wire mark processing procedure of solar cell, and the process of printing identification code does not need complicated technology yet.If in the picture semiconductor integrated circuit processing procedure, the mode that adopts laser to scan is come each sheet solar cell substrate imprinting identification code, the cost of equipment is increased.But, adopt method of the present invention, then need pay the additional apparatus cost hardly.
(2) the process parameter correction is easier.Because each sheet solar cell substrate all has identification code separately, make that the parameter of each sheet solar cell substrate in the preparation process can be by record and build file.When the yield of solar cell descended, the testing staff can be according to the process parameter data of each sheet solar cell substrate, analyzed and searched problem, and adjust process parameter in good time, made the best in qualityization of solar cell.
The above only is embodiments of the invention, is not the present invention is done any pro forma restriction; Though the present invention discloses as above with embodiment; Yet be not in order to limiting the present invention, anyly be familiar with the professional and technical personnel, in not breaking away from technical scheme scope of the present invention; When the technology contents of above-mentioned announcement capable of using is made a little change or is modified to the equivalent embodiment of equivalent variations; In every case be not break away from technical scheme content of the present invention, to any simple modification, equivalent variations and modification that above embodiment did, all still belong in the scope of technical scheme of the present invention according to technical spirit of the present invention.

Claims (11)

1. a solar cell is printed the method for identification code, comprising:
The semi-finished product of one batch of solar cell substrate are provided, and these semi-finished product are meant that this solar cell substrate accomplished all processing procedures of extinction face; And
Metal paste is printed on this batch solar cell substrate back side with the wire mark mode, forms the identification code of first bus (bus bar), second bus and an identification wafer.
2. the method for claim 1; It is characterized in that: this first and second bus is divided into first to the 3rd zone with this solar cell substrate back panel; This identification code is selected from wherein a kind of of group that graphic sign, figure notation, literal and combination in any thereof form, is distributed between these zones.
3. method as claimed in claim 2; It is characterized in that: when printing this individual wafer identification code; This method more comprises the position that changes the scraper plate Origin And Destination; Give each solar cell substrate different identification codes, and this first bus, second bus and this identification code are that this scraper plate is advanced to a direction and once printed.
4. method as claimed in claim 3 is characterized in that: the tens zone is represented in this first area, the 3rd Regional Representative's units zone; This identification code is represented with numeric character; It is starting point that this scraper plate is selected a numeric character a from this tens zone, and when marching to this units zone, selecting another numeric character b is terminal point; A and b are 0 ~ 9 any numeral wherein, and then this identification code is " ab " by interpretation.
5. method as claimed in claim 3; It is characterized in that: this identification code is made up of a plurality of graphic signs; The tens zone is represented in this first area, and the 3rd Regional Representative's units zone is if this graphic sign in this first area and the unit number apart of one first datum line are A; This graphic sign and one second datum line unit number apart in the 3rd zone are B, and then this identification code is " (A-1) (B-1) " by interpretation.
6. method as claimed in claim 3 is characterized in that: this identification code is come interpretation with the pattern recognition machine.
7. the method for claim 1; It is characterized in that: this first, second bus and this identification code are printed on before this solar cell substrate back side with the wire mark mode; More comprise a half tone is provided; This half tone defines first bus, second bus and identification code pattern openings in wherein, and this identification code pattern openings is selected from a kind of in the group that graphic sign, figure notation, literal and combination in any thereof form.
8. the method for claim 1, it is characterized in that: the composition of this metal paste comprises conductive metal powder, glass powder and organic compound.
9. the method that a record solar can the battery process parameter, this method comprises:
The semi-finished product of solar cell substrate are provided, and these semi-finished product are meant that this solar cell substrate accomplished all processing procedures of extinction face;
Metal paste is printed on this solar cell substrate back side with the wire mark mode, forms the identification code of first bus (bus bar), second bus and an identification wafer; And
Write down the identification code and the process parameter of this solar cell substrate, the parameter of solar cell in the preparation process can be write down and build file.
10. method as claimed in claim 9 is characterized in that: when being formed on this identification code on this solar cell substrate back side, metal paste is printed on this solar cell substrate back side with the wire mark mode, forms the identification code of those individual slices.
11. method as claimed in claim 9; It is characterized in that: when being formed on this identification code on this solar cell substrate back side; Etching formula slurry or implanted slurry are printed on this solar cell substrate with the wire mark mode, form the identification code of those individual slices.
CN201110236643.2A 2010-11-30 2011-08-17 Method for printing identification code on solar cell and method for recording manufacturing process parameters of solar cell Expired - Fee Related CN102479881B (en)

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TW099141610 2010-11-30
TW099141610A TWI431787B (en) 2010-11-30 2010-11-30 Method and application for the solar cell id scribe during screen printing process

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CN102479881B CN102479881B (en) 2015-04-08

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104134399A (en) * 2014-07-11 2014-11-05 晶澳太阳能有限公司 Solar photovoltaic module anti-counterfeiting marking method and solar photovoltaic module with anti-counterfeiting marking function
CN105374898A (en) * 2014-08-22 2016-03-02 新日光能源科技股份有限公司 Solar cell marking method
CN105514457A (en) * 2016-01-25 2016-04-20 宁波博大梧桐电池科技有限公司 Method for manufacturing informationalized alkaline zinc-manganese dioxide batteries
CN108538757A (en) * 2018-03-27 2018-09-14 韩华新能源(启东)有限公司 A kind of solar cell processing procedure retroactive method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070163634A1 (en) * 2005-07-14 2007-07-19 Kyocera Corporation Solar cell, manufacturing method and manufacturing management system thereof, and solar cell module
WO2010094344A1 (en) * 2009-02-23 2010-08-26 Applied Materials, Inc. Method and apparatus for screen printing a multiple layer pattern
CN101395724B (en) * 2006-02-28 2010-10-27 Q-细胞公司 Solar cell marking method, and solar cell

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070163634A1 (en) * 2005-07-14 2007-07-19 Kyocera Corporation Solar cell, manufacturing method and manufacturing management system thereof, and solar cell module
CN101395724B (en) * 2006-02-28 2010-10-27 Q-细胞公司 Solar cell marking method, and solar cell
WO2010094344A1 (en) * 2009-02-23 2010-08-26 Applied Materials, Inc. Method and apparatus for screen printing a multiple layer pattern

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104134399A (en) * 2014-07-11 2014-11-05 晶澳太阳能有限公司 Solar photovoltaic module anti-counterfeiting marking method and solar photovoltaic module with anti-counterfeiting marking function
CN105374898A (en) * 2014-08-22 2016-03-02 新日光能源科技股份有限公司 Solar cell marking method
CN105514457A (en) * 2016-01-25 2016-04-20 宁波博大梧桐电池科技有限公司 Method for manufacturing informationalized alkaline zinc-manganese dioxide batteries
CN108538757A (en) * 2018-03-27 2018-09-14 韩华新能源(启东)有限公司 A kind of solar cell processing procedure retroactive method

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CN102479881B (en) 2015-04-08
TWI431787B (en) 2014-03-21
TW201222838A (en) 2012-06-01

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