CN102468590B - Making method for electric connector - Google Patents

Making method for electric connector Download PDF

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Publication number
CN102468590B
CN102468590B CN201010547192.XA CN201010547192A CN102468590B CN 102468590 B CN102468590 B CN 102468590B CN 201010547192 A CN201010547192 A CN 201010547192A CN 102468590 B CN102468590 B CN 102468590B
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electric connector
making method
electrode
cnt
tube
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CN102468590A (en
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张衍智
郑志丕
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Foxconn Kunshan Computer Connector Co Ltd
Hon Hai Precision Industry Co Ltd
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Foxconn Kunshan Computer Connector Co Ltd
Hon Hai Precision Industry Co Ltd
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Abstract

The invention provides a kind of making method for electric connector, comprise the following steps: the insulated substrate of the upper and lower surface providing to be provided with to be oppositely arranged and some holes of running through upper and lower surface, and arrange one first electrode, the second electrode respectively in these substrate both sides, make the first electrode, the second electrode corresponding with hole respectively; In each hole, instillation contains the dispersion liquid of carbon nanotube powder in right amount respectively, and a predetermined voltage is applied between first, second electrode, carbon nanotube powder swimming in the carbon nanotube dispersion liquid making this target hole interior, and then become carbon nanotube along hole direction boundling.

Description

Making method for electric connector
[technical field]
The present invention is about a kind of making method for electric connector, and espespecially one utilizes CNT (carbon nano-tube) to make the making method for electric connector of terminal.
[background technology]
Since CNT (carbon nano-tube) be Japanese physicist Sumio Iijima 1991 observe with report after, every field produces unprecedented interest to CNT (carbon nano-tube), and then drops into more resource to study nanometer technology.The 354th 56th ~ 58 pages, it " nature " periodical is published please refer on November 7th, 1991.Because material shows very outstanding physics and chemical characteristic under nano-scale, therefore nanosecond science and technology become every field pursue and the Holy grail developed, every field is there's no one who doesn't or isn't fallen over each other and is dropped into the development & application of CNT (carbon nano-tube), to giving existing product innovation life.
But CNT (carbon nano-tube), before the application can doing entity, must first be processed and be assembled.For example, in the field of Conventional nano carbon pipe, used a kind of so-called plane formula electrophoresis to process CNT (carbon nano-tube), to reaching the object of application further, as shown in Figure 1.Substantially, this mode carries out dielectrophoresis with plane electrode, CNT (carbon nano-tube) to be assembled between two electrodes, forms the two-dimension plane structure of bridge joint two electrode.And the CNT (carbon nano-tube) of this planar structure, only be applicable to being applied on nanometric electronic components, nano-transistor and some chemical sensors, be not suitable for the application that other need stereochemical structure, terminal as electric connector field needs for chip module connection and printed circuit board (PCB) usually, its form is all stereochemical structure usually, therefore adopts above-mentioned so-called plane formula electrophoresis obviously can not CNT (carbon nano-tube) be used in electrical connectors easily.
U.S. Patent Bulletin US6,626, be contained among connector body although 684 disclose a kind of CNT (carbon nano-tube) of cylindrical-shaped structure that adopts with the electric connector of transmitting signals, so this patent unexposedly how to prepare so a kind of electric connector, in fact, as previously mentioned, a kind of like this CNT (carbon nano-tube) of cylindrical-shaped structure that uses be obtained by no means easy.
Therefore, be necessary to provide a kind of making method for electric connector, to overcome the defect of related art techniques.
[summary of the invention]
The technical problem that the present invention will solve is to provide a kind of making method for electric connector, can obtain the CNT (carbon nano-tube) of stereochemical structure easily with transmitting signals.
For solving the problems of the technologies described above, the invention provides a kind of making method for electric connector, comprise the following steps: the insulated substrate of the upper and lower surface providing to be provided with to be oppositely arranged and some holes of running through upper and lower surface, and arrange one first electrode, the second electrode respectively in these substrate both sides, make the first electrode, the second electrode corresponding with hole respectively; In each hole, instillation contains the dispersion liquid of carbon nanotube powder in right amount respectively, and a predetermined voltage is applied between first, second electrode, carbon nanotube powder swimming in the CNT (carbon nano-tube) dispersion liquid making this target hole interior, and then become CNT (carbon nano-tube) along hole direction boundling.
Compared with prior art, the having the following advantages of the present invention: the electric connector that can obtain the CNT (carbon nano-tube) containing stereochemical structure easily.
[accompanying drawing explanation]
Fig. 1 is that prior art is with the schematic diagram of plane formula dielectrophoresis process CNT (carbon nano-tube).
Fig. 2 (a), (b) is CNT (carbon nano-tube) of the present invention upright boundling forming method basic principle schematic.
Fig. 3 A, B are the schematic diagram of the upright boundling forming method of CNT (carbon nano-tube) of the present invention.
Fig. 4 is the photo of the carbon nanotubes according to the shaping collection of CNT (carbon nano-tube) of the present invention upright boundling forming method.
Fig. 5 is the stereogram of the electric connector utilizing the upright boundling forming method of CNT (carbon nano-tube) of the present invention to manufacture.
Fig. 6 is the cutaway view of the electric connector of Fig. 5.
[embodiment]
Fig. 1 to Fig. 4 discloses the principle that making method for electric connector of the present invention utilizes.
Please refer to Fig. 2 (a), shown in (b), because CNT (carbon nano-tube) can be subject to galvanic couple polarization in various degree under the impact of additional AC field, this phenomenon is called as dielectric property.And CNT (carbon nano-tube) is after receiving galvanic couple polarization, just can by Jie's driven by power, the CNT (carbon nano-tube) that galvanic couple is polarized carries out swimming in dispersion liquid, more can carry out assembling and arranging along the direction of extra electric field.Therefore we claim this phenomenon to be dielectrophoresis.
Fig. 2 (a) discloses CNT (carbon nano-tube) by galvanic couple; Fig. 2 (b) then discloses by the CNT (carbon nano-tube) of galvanic couple under the effect of electric field, just arranges along the direction of electric field.
Fig. 3 A is then for the present invention utilizes " vertical type dielectrophoresis " to reach the integrated method becoming the integrated bundle of nanometer with cluster nano carbon pipe.So-called " vertical type dielectrophoresis " refers to be different from conventional planar dielectrophoresis, utilizes the method can obtain the cluster nano carbon pipe of rising structure.
According to the method, when needing the cluster nano carbon pipe obtaining rising structure, first one object 11 is provided, this object 11 is provided with target hole 11a, this hole can be made according to the method for prior art, as for the arrangement of target hole 11a, can need according to actual the aspect being arranged in matrix or any other realistic user demand.Then the first electrode 10, second electrode 12 is set respectively in object 11 both sides, and makes two electrodes corresponding with target hole 11a.
According to the preferred embodiment of the present invention, this the second electrode 12 is the conductor of a column or needle-like, can certainly be other any shapes, the first electrode 10 can be coordinated to form electric field (or power line), and its diameter preferably comparatively this target hole 11a be little, for controlling the diameter with the leading carbon nanotubes be formed.Certainly, the cross section of this second electrode 12 can also be any geometry, such as ring-type or polygon-shaped.And by second electrode 12 in this different shape cross section, control the shape of CNT (carbon nano-tube) that generates.Preferably be arranged to a plate-like structure above second electrode 12, so that drop pull-up is formed fluid column, increase liquor capacity and the carbon pipe quantity of carrying out dielectrophoresis.
Although it may be noted that the second electrode 12 that embodiment discloses only has an electrode, in the utilization of reality, this second electrode 12 can also coordinate the shape of the arrangement of target hole 11a or array to carry out deploying.Such as, when target hole 11a is arranged in the matrix of standard, then these electric two electrodes 12 can also be arranged in corresponding matrix, to form carbon nanotubes in the target hole 11a that each is corresponding simultaneously.
Next, then the third step dripping the dispersion liquid 13 put containing carbon nanotube powder 13a in this target hole 11a is carried out.And the preparation of the dispersion liquid 13 of CNT (carbon nano-tube) 13a should be contained, then hold and illustrate after a while.
After completing in the target hole 11a of this object 11 dispersion liquid 13 of instillation containing CNT (carbon nano-tube) 13a, just at first and second electrode 10, a suitable alternating voltage is applied to pass this dispersion liquid 13 between 12, with the CNT (carbon nano-tube) 13a in this dispersion liquid 13 integrated in this target hole 11a, to form the integrated bundle 14 of CNT (carbon nano-tube) accumulating pencil, as please refer to shown in Fig. 4.
And as shown in Figure 3 B, during the course, the indivedual CNT (carbon nano-tube) 13a in CNT (carbon nano-tube) dispersion liquid 13 can as Fig. 2 (a), b () be mode shownschematically, gradually under the effect of dielectrophoretic force, move towards centre, and accumulate nano-sized carbon bundle after a certain time.Can see, in Fig. 3 B, for the CNT (carbon nano-tube) dispersion liquid 13 in hole 11a, the electric field of this voltage formation is a vertical electric field, its electric field is vertically, or or rather, is perpendicular in hole 11a and treats the corresponding dispersion liquid containing carbon nanotube powder 13a.
As shown in Figure 4, utilizing the carbon nanotubes that vertical type dielectrophoresis method of the present invention is generated, is a stereochemical structure.The two dimensional surface carbon tubular construction generated with existing use plane formula dielectrophoresis method has great difference, namely first CNT (carbon nano-tube) is made into stereo structure.Therefore its existing range of application can be broken through.
Because CNT (carbon nano-tube) is in the process of dispersion, because the volume of itself and quality are very little, the Fan Dewali between carbon pipe and carbon pipe becomes very powerful in comparison, makes carbon pipe be easy to intertwine.When therefore will do actual assembling application, preferably first processed, the CNT (carbon nano-tube) making each very thin disperses to be separated each other.
According to the present invention, should be with the alcohol of the distilled water+50% of 50% containing preparation of dispersion liquid 13, then add the carbon nanotube powder crossed through overpickling, and carry out ultrasonic waves shake and wash 1.5 hours.Utilize aforesaid mode to carry out the dispersion of CNT (carbon nano-tube), very good effect can be reached.
By the vertical type dielectrophoresis approach application of the present invention's exposure above in electric connector field, as connected the electric connector of CPU and circuit board, a kind of new making method for electric connector and electric connector namely can be obtained.In view of the principle and the product aspect that have detailed vertical type dielectrophoresis method above, hereafter only how simple declaration applies to electric connector field.
Can with reference to the product structure of figure 5 to Fig. 6, first need to provide a substrate 2, this substrate be provided be oppositely arranged upper and lower surperficial 20,22 and run through some holes 24 on upper and lower surface, one first electrode 10 is provided afterwards, be placed on substrate 2 lower surface 22 side, and make this bottom electrode corresponding with some holes 10; Next in each hole 24, the appropriate dispersion liquid 13 containing carbon nanotube powder is instilled from substrate 2 upper surface 20 side respectively; Then one second electrode 12 is provided, is placed on substrate 2 upper surface 20 side, and make this bottom electrode 12 corresponding with some holes 24; Next again, between first, second electrode, apply a predetermined voltage, make the carbon nanotube powder swimming in the CNT (carbon nano-tube) dispersion liquid in this target hole, and then along hole 24 direction boundling slabbing CNT (carbon nano-tube) 14.
It may be noted that, in concrete manufacture electric connector process, not necessarily need as disclosing when telling about vertical type dielectrophoresis Method And Principle, object to be placed on above the first electrode above, this is because we know, the volume of CNT (carbon nano-tube) itself and quality are very little, under electronic building brick high density, compact trend, on instillation substrate, the amount of the dispersion liquid containing carbon nanotube powder of hole is considerably less, and hole is also very tiny, therefore due to siphonic effect, dispersion liquid instillation substrate 2 does not need to worry that it can spill from substrate 2 lower surface 22 side after hole 24.
In the manufacture method of electric connector of the present invention, because the carbon nanotubes that vertical type dielectrophoresis method obtains in the form of sheets, therefore this hole 24 is preferably arranged to finedraw shape.Especially, substrate 2 is provided with the guide channel 26 be connected with hole 24 from upper surface 20 side, and from upper surface on lower surface direction, the funnel-form that this guide channel 26 is big up and small down.The benefit of such setting has: conveniently dispersion liquid is instilled hole 24 on substrate 2; Be convenient to the second electrode 12 of needle-like near finedraw shape hole 24; And be convenient to dock with the CPU containing tin ball.
The manufacture method of the electric connector of the present invention, is also included in the step upper and lower surface affixing respectively one deck viscose 28, naturally these viscoses 28 need corresponding hole 24 be provided with some openings.The object arranging mucigel is: these mucigels can be utilized directly to reach fixing and fixing between electric connector and CPU between electric connector and circuit board.In addition, the CNT (carbon nano-tube) extension that boundling is shaping protrudes from the viscose of lower surface so that dock with the pad on circuit board.

Claims (10)

1. a making method for electric connector, comprises the following steps:
(1) insulated substrate of the upper and lower surface providing to be provided with to be oppositely arranged and some holes of running through upper and lower surface, and arrange one first electrode, the second electrode respectively in these substrate both sides, make the first electrode, the second electrode arranges the same hole both sides of what;
(2) in each hole, instillation contains the dispersion liquid of carbon nanotube powder in right amount respectively;
(3) between first, second electrode, apply a predetermined voltage, the carbon nanotube powder swimming in the CNT (carbon nano-tube) dispersion liquid making this target hole interior, and then become CNT (carbon nano-tube) along hole direction boundling.
2. making method for electric connector as claimed in claim 1, is characterized in that: the preparation of CNT (carbon nano-tube) dispersion liquid is mixed carbon nanotube powder and suitable water and alcohol.
3. making method for electric connector as claimed in claim 2, is characterized in that: the volume ratio of described water and alcohol is between 1:3 and 1:1.
4. making method for electric connector as claimed in claim 2 or claim 3, is characterized in that: described water is distilled water.
5. making method for electric connector as claimed in claim 1 or 2, is characterized in that: before preparation CNT (carbon nano-tube) dispersion liquid, carry out acid treatment to this carbon nanotube powder.
6. making method for electric connector as claimed in claim 1, is characterized in that: described hole is finedraw shape.
7. making method for electric connector as claimed in claim 6, is characterized in that: described substrate is provided with the guide channel be connected with hole from upper surface side.
8. making method for electric connector as claimed in claim 7, is characterized in that: from upper surface on lower surface direction, the funnel-form that this guide channel is big up and small down.
9. making method for electric connector as claimed in claim 1, it is characterized in that: be also included on upper and lower surface and affix one deck viscose respectively, on this upper and lower two-layer viscose, corresponding hole is provided with some openings.
10. making method for electric connector as claimed in claim 9, is characterized in that: the shaping CNT (carbon nano-tube) of boundling extends the viscose protruding from lower surface.
CN201010547192.XA 2010-11-16 2010-11-16 Making method for electric connector Active CN102468590B (en)

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CN102468590B true CN102468590B (en) 2015-10-07

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105305126A (en) * 2015-11-20 2016-02-03 华为技术有限公司 Electric connector and communication equipment

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1308393A (en) * 2000-02-10 2001-08-15 富士康(昆山)电脑接插件有限公司 Manufacture of socket connector
CN1691440A (en) * 2004-04-20 2005-11-02 富士康(昆山)电脑接插件有限公司 Method for making electric connector and products thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8038479B2 (en) * 2008-12-05 2011-10-18 Nanoridge Materials Carbon nanotube-based electrical connectors

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1308393A (en) * 2000-02-10 2001-08-15 富士康(昆山)电脑接插件有限公司 Manufacture of socket connector
CN1691440A (en) * 2004-04-20 2005-11-02 富士康(昆山)电脑接插件有限公司 Method for making electric connector and products thereof

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