CN102464863A - Color pavement cementing material and application thereof - Google Patents
Color pavement cementing material and application thereof Download PDFInfo
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- CN102464863A CN102464863A CN2010105358363A CN201010535836A CN102464863A CN 102464863 A CN102464863 A CN 102464863A CN 2010105358363 A CN2010105358363 A CN 2010105358363A CN 201010535836 A CN201010535836 A CN 201010535836A CN 102464863 A CN102464863 A CN 102464863A
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- road surface
- colored
- agglutinate
- color pavement
- colored road
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Abstract
The invention discloses a color pavement cementing material and an application thereof. The color pavement cementing material comprises, by weight, 100 parts of a bisphenol A epoxy resin, 30-100 parts of a polyamide curing agent, and 5-30 parts of polypropylene glycol diglycidyl ether or benzyl alcohol. The application of the color pavement cementing material of the present invention in color pavement paving is that: the bisphenol A epoxy resin, the polyamide curing agent, and the polyethylene glycol diglycidyl ether or the benzyl alcohol are mixed uniformly to prepare the color pavement cementing material, and the color pavement cementing material is mixed with the color aggregate to prepare the color pavement mixing material, wherein the color pavement mixing material is provided for paving the color pavement. With the color pavement cementing material of the present invention, the color pavement is easily paved, the use performance of the color pavement cementing material is improved, and the service life of the color pavement is prolonged.
Description
Technical field
The invention relates to a kind of colored road surface agglutinate and application thereof, the preparation of this agglutinate is simple, quality and mechanical property are better.
Background technology
Colored road surface has the function of beautifying the environment and warning traffic.About the existing both at home and abroad a lot of researchs of colored road surface agglutinate, main achievement is: the pigment that 1) adds required color to common stellar coal decolouring is again processed chromatic cementing agent; 2) process chromatic cementing agent with petroleum resin+polymkeric substance+perfume oil+pigment etc.; 3) with resin+solidifying agent+dyestuff, it is colored glued to process reaction-curable.The characteristics of first kind and second kind chromatic cementing agent are: all need under hot conditions, produce, complex process, cost height, production process contaminate environment and chromatic cementing agent color are not bright-coloured, not lasting.The disclosed chromatic cementing agent of CN03135423.8 mixes with epoxy resin (E-51 or E-44 or E-42)+solidifying agent (modified aliphatic 593)+epoxy resin dilution toughner (phthalic acid lipid) and pigment, belongs to the third reaction-curable chromatic cementing agent.The characteristics of this type chromatic cementing agent are: the construction of under normal temperature condition, producing and pave the way, technology is simple, pollute little, the agglutinate good mechanical performance; But color is bright-coloured not enough and lasting, simultaneously, finds that in use when the disclosed chromatic cementing agent of CN03135423.8 was used for laying of roadway, along with the prolongation of time, the mechanical properties decrease of agglutinate was obvious, and then influenced the work-ing life of colored road surface.
Summary of the invention
To the deficiency of prior art, the present invention provides a kind of colored road surface agglutinate and application, when being convenient to the colored road surface making, improves the use properties of colored road surface agglutinate, prolongs the work-ing life of colored road surface.
Colored road surface agglutinate of the present invention is following in the composition of weight part:
100 parts of bisphenol A epoxide resins
30~100 parts of polyamide curing agents
5~30 parts of polypropylene glycol diglycidyl ether or phenylcarbinols
Described bisphenol A epoxide resin can be selected the commercial goods, is the bisphenol A epoxide resin of E-51, E-44 or E-42 etc. like model, also can be by the existing method preparation in this area.
Described polyamide curing agent can be selected the commercial goods, as model be 650,651, V125 or 600 etc. polyamide curing agent, also can be by the existing method preparation in this area.
Described polypropylene glycol diglycidyl ether is that W 166 and epichlorohydrin reaction make, and the molecular weight of W 166 is generally 500~2000, can use the commercial goods polypropylene glycol diglycidyl ether, also can be by existing method preparation.
The application of colored road surface agglutinate of the present invention in the colored road surface making; Bisphenol A epoxide resin, polyamide curing agent and polypropylene glycol diglycidyl ether or phenylcarbinol are mixed; Process the colored road surface agglutinate; Be mixed and made into the colored road surface compound with colored aggregate then, be used to lay colored road surface.Colored aggregate is a colored ceramic particle, and its technical indicator should satisfy the road with requiring; By the different constructional methods of paving the way, the weight ratio of colored road surface agglutinate and colored aggregate is (5-15): 100, promptly 5: 100-15: 100.
Colored road surface agglutinate of the present invention belongs to the expansion product of the third type; Except advantages such as production and technology under normal temperature condition are simple; Also have the following advantages: 1) since selected solidifying agent difference make produce and construction process in the irritating smell of the irritating smell that produces and product littler, not only protected environment but also improved product quality; 2) because selected solidifying agent difference makes that snappiness, cohesiveness and the water tolerance of product are better; 3) because selected additive (polypropylene glycol diglycidyl ether or phenylcarbinol) has increased the ether network ratio in the epoxy resin cured product cross-linked network structure; Thereby reduce the fragility of epoxy resin cured product and improved the snappiness of cured article; This additive participates in curing reaction; Its cured article mechanical property is more stable, and cracking resistance and impact property are better, and can prolong greatly work-ing life; 4) owing to adopted colored aggregate to make color more bright-coloured lasting; 5) to the different road situation several kinds of different arrangement and method for construction are provided, have enriched the kind of color shop agglutinate.
Embodiment
It is following that colored road surface of the present invention prepares process with agglutinate: join mixing tank in required ratio and mix at the following epoxy resin of normal temperature condition and additive, add epoxy curing agent more in proportion and mix once more and get final product.When carrying out agglutinate production and compound mix,, arrange agglutinate production and compound mix and construction speed properly according to envrionment temperature.
Provide the colored road surface agglutinate composition proposal of several kinds of concrete application schemes below.
Embodiment 1:
Title | Model | Parts by weight |
Epoxy resin | E-51 | 100 |
Solidifying agent | 650 | 50-100 |
Additive | Polypropylene glycol diglycidyl ether | 5-30 |
Embodiment 2:
Title | Model | Parts by weight |
Epoxy resin | E-44 | 100 |
Solidifying agent | 650 | 50-100 |
Additive | Polypropylene glycol diglycidyl ether | 5-30 |
The characteristics of the colored road surface agglutinate of embodiment 1 and embodiment 2 are comparison thickness, are mainly used in to be coated with
Spread formula making mode road surface pavement.
Embodiment 3:
Title | Model | Umber |
Epoxy resin | E-51 | 100 |
Solidifying agent | 650 | 50-100 |
Additive | Phenylcarbinol | 5-30 |
Embodiment 4:
Title | Model | Umber |
Epoxy resin | E-51 | 100 |
Solidifying agent | 651 | 30-70 |
Additive | Phenylcarbinol | 5-30 |
The characteristics of the colored road surface agglutinate of embodiment 3 and embodiment 4 are that the curing speed ratio is very fast, are applicable to
Require piece speed open to traffic occasion.
Embodiment 5:
Title | Model | Umber |
Epoxy resin | E-51 | 100 |
Solidifying agent | 651 | 30-70 |
Additive | Polypropylene glycol diglycidyl ether | 5-30 |
The colored road surface agglutinate viscosity and the adaptive phase of embodiment 5 are moderate, are fit to the compound mix mode making coloured silk of constructing
The look road surface.
Alternative: (pressing the composition system of CN03135423.8 embodiment 1)
Title | Model | Umber |
Epoxy resin | E-44 | 71 |
Solidifying agent | 593 | 15.1 |
Additive | Witcizer 300 | 10 |
Embodiment and alternative agglutinate performance relatively (are waited to hand over ramming material fully to solidify the back and are detected its cured article
Mechanical property :)
The longevity test of surfacing: the ordinary enterprises internal transportation Surface of Trial Pavement of embodiment 1 and alternative making, 6 months no disrepair phenomenons in the road surface of embodiment 1, the breakage in 6 months of the road surface of alternative is obviously.
Claims (9)
1. colored road surface agglutinate is characterized in that in the composition of weight part following:
100 parts of bisphenol A epoxide resins
30~100 parts of polyamide curing agents
5~30 parts of polypropylene glycol diglycidyl ether or phenylcarbinols.
2. according to the described colored road surface agglutinate of claim 1, it is characterized in that: the model of bisphenol A epoxide resin is E-51, E-44 or E-42.
3. according to the described colored road surface agglutinate of claim 1, it is characterized in that: the model of polyamide curing agent is 650,651, V125 or 600.
4. according to the described colored road surface agglutinate of claim 1, it is characterized in that: polypropylene glycol diglycidyl ether is that W 166 and propylene oxide reaction make.
5. according to the described colored road surface agglutinate of claim 4, it is characterized in that: the molecular weight of W 166 is 500~2000.
6. the application of the said colored road surface agglutinate of the arbitrary claim of claim 1 to 5 in the colored road surface making.
7. according to the described application of claim 6; It is characterized in that: bisphenol A epoxide resin, polyamide curing agent and polypropylene glycol diglycidyl ether or phenylcarbinol are mixed; Process the colored road surface agglutinate; Be mixed and made into the colored road surface compound with colored aggregate then, be used to lay colored road surface.
8. according to the described application of claim 6, it is characterized in that: colored aggregate is a colored ceramic particle.
9. according to claim 6 or 8 described application, it is characterized in that: the weight ratio of colored road surface agglutinate and colored aggregate is (5-15): 100.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201010535836.3A CN102464863B (en) | 2010-11-04 | 2010-11-04 | Color pavement cementing material and application thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201010535836.3A CN102464863B (en) | 2010-11-04 | 2010-11-04 | Color pavement cementing material and application thereof |
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CN102464863A true CN102464863A (en) | 2012-05-23 |
CN102464863B CN102464863B (en) | 2015-01-21 |
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CN201010535836.3A Active CN102464863B (en) | 2010-11-04 | 2010-11-04 | Color pavement cementing material and application thereof |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103627140A (en) * | 2013-11-01 | 2014-03-12 | 鲲鹏建设集团有限公司 | Cementing material for durable colored pavement and preparation method thereof |
CN103756613A (en) * | 2013-12-27 | 2014-04-30 | 吴媛媛 | Cementing material for colored pavement and preparation method thereof |
CN106555370A (en) * | 2016-11-23 | 2017-04-05 | 刘浩杰 | A kind of construction method on chromatic ceramics road surface |
CN108690543A (en) * | 2017-03-31 | 2018-10-23 | 索马龙株式会社 | Epoxy adhesive |
CN110591398A (en) * | 2019-09-17 | 2019-12-20 | 云南畅坦科技有限公司 | Colored chemically modified resin asphalt and preparation method thereof |
CN112778949A (en) * | 2020-12-31 | 2021-05-11 | 山西省交通科技研发有限公司 | Environment-friendly adhesive capable of being mixed for construction and preparation method thereof |
CN112831301A (en) * | 2020-12-31 | 2021-05-25 | 山西省交通科技研发有限公司 | High-light-reflection environment-friendly colorful anti-skid pavement and preparation method thereof |
CN117107633A (en) * | 2023-08-26 | 2023-11-24 | 宁波天意卓越新材料科技有限公司 | Steel bridge deck pavement structure of color sidewalk and preparation method thereof |
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CN1220284A (en) * | 1998-11-13 | 1999-06-23 | 湖北省化学研究所 | Epoxy resin compound for electrostatic prevention and its preparation |
JP3138526B2 (en) * | 1992-03-19 | 2001-02-26 | エスケー化研株式会社 | High durability ceramic colored resin laminate |
CN101121812A (en) * | 2007-07-27 | 2008-02-13 | 华南理工大学 | Epoxy resin base fast repairing material and preparation method thereof |
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JP3138526B2 (en) * | 1992-03-19 | 2001-02-26 | エスケー化研株式会社 | High durability ceramic colored resin laminate |
CN1220284A (en) * | 1998-11-13 | 1999-06-23 | 湖北省化学研究所 | Epoxy resin compound for electrostatic prevention and its preparation |
CN101121812A (en) * | 2007-07-27 | 2008-02-13 | 华南理工大学 | Epoxy resin base fast repairing material and preparation method thereof |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103627140A (en) * | 2013-11-01 | 2014-03-12 | 鲲鹏建设集团有限公司 | Cementing material for durable colored pavement and preparation method thereof |
CN103627140B (en) * | 2013-11-01 | 2015-06-03 | 鲲鹏建设集团有限公司 | Cementing material for durable colored pavement and preparation method thereof |
CN103756613A (en) * | 2013-12-27 | 2014-04-30 | 吴媛媛 | Cementing material for colored pavement and preparation method thereof |
CN103756613B (en) * | 2013-12-27 | 2015-08-19 | 浙江杰立建设集团有限公司 | For the consolidating material and preparation method thereof of colored road surface |
CN106555370A (en) * | 2016-11-23 | 2017-04-05 | 刘浩杰 | A kind of construction method on chromatic ceramics road surface |
CN108690543A (en) * | 2017-03-31 | 2018-10-23 | 索马龙株式会社 | Epoxy adhesive |
TWI775810B (en) * | 2017-03-31 | 2022-09-01 | 日商索瑪爾股份有限公司 | epoxy resin adhesive |
CN110591398A (en) * | 2019-09-17 | 2019-12-20 | 云南畅坦科技有限公司 | Colored chemically modified resin asphalt and preparation method thereof |
CN112778949A (en) * | 2020-12-31 | 2021-05-11 | 山西省交通科技研发有限公司 | Environment-friendly adhesive capable of being mixed for construction and preparation method thereof |
CN112831301A (en) * | 2020-12-31 | 2021-05-25 | 山西省交通科技研发有限公司 | High-light-reflection environment-friendly colorful anti-skid pavement and preparation method thereof |
CN117107633A (en) * | 2023-08-26 | 2023-11-24 | 宁波天意卓越新材料科技有限公司 | Steel bridge deck pavement structure of color sidewalk and preparation method thereof |
CN117107633B (en) * | 2023-08-26 | 2024-05-17 | 宁波天意卓越新材料科技有限公司 | Steel bridge deck pavement structure of color sidewalk and preparation method thereof |
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