CN102458326A - Roll-shaped medical adhesive tape and manufacturing method therefor - Google Patents

Roll-shaped medical adhesive tape and manufacturing method therefor Download PDF

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Publication number
CN102458326A
CN102458326A CN2010800259707A CN201080025970A CN102458326A CN 102458326 A CN102458326 A CN 102458326A CN 2010800259707 A CN2010800259707 A CN 2010800259707A CN 201080025970 A CN201080025970 A CN 201080025970A CN 102458326 A CN102458326 A CN 102458326A
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Prior art keywords
adhesive tape
web
medical adhesive
woven fabrics
supporter
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CN2010800259707A
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CN102458326B (en
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几代渡
小池玲雄奈
藤泽博充
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Nichiban Co Ltd
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Nichiban Co Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/02Adhesive bandages or dressings
    • A61F13/0269Tapes for dressing attachment
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B17/00Surgical instruments, devices or methods, e.g. tourniquets
    • A61B17/08Wound clamps or clips, i.e. not or only partly penetrating the tissue ; Devices for bringing together the edges of a wound
    • A61B17/085Wound clamps or clips, i.e. not or only partly penetrating the tissue ; Devices for bringing together the edges of a wound with adhesive layer
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B46/00Surgical drapes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00Medicinal preparations characterised by special physical form
    • A61K9/70Web, sheet or filament bases ; Films; Fibres of the matrix type containing drug
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F2013/00361Plasters
    • A61F2013/00544Plasters form or structure
    • A61F2013/00553Plasters form or structure with detachable parts
    • A61F2013/00561Plasters form or structure with detachable parts with adhesive connecting means

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Engineering & Computer Science (AREA)
  • Surgery (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Biomedical Technology (AREA)
  • Epidemiology (AREA)
  • Medical Informatics (AREA)
  • Molecular Biology (AREA)
  • Vascular Medicine (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Medicinal Chemistry (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Chemical & Material Sciences (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Adhesive Tapes (AREA)

Abstract

Provided is a roll-shaped medical adhesive tape wherein an adhesive layer is formed on one surface of a support medium, which is rolled up into a roll shape. The support medium comprises a nonwoven fabric that is formed from synthetic resin fibers and has a thickness between 50 [mu]m and 200 [mu]m. Using thermic boring, recessed areas are formed in straight lines in the width direction, perpendicular to the direction the tape is rolled in, on the back surface of the support medium, said back surface being the side opposite the adhesive layer. The depth of the recessed areas is between 5% and 60% of the thickness of the support medium, and the spacing between the recessed areas is between 0.5 mm and 1.5 mm. The adhesive tape is rolled into a roll shape such that the adhesive layer contacts the back surface of the support medium.

Description

Web-like medical adhesive tape and manufacturing approach thereof
Technical field
The present invention relates to the web-like medical adhesive tape; In more detail; Relate to be that the medical adhesive tape of supporter is wound into web-like, tearing property of hands (character of tearing with hands), smooth tearing property (the horizontal tearing port of band is collinear probability), the good web-like medical adhesive tape of operability when wearing glove and manufacturing approach thereof not across release liner (being also referred to as " spacer ") with exoskeletal winding with the excellent non-woven fabrics of breathability and retractility.
Background technology
Medical adhesive tape is used for the protection of affected part and/or wound portion and gauze and/or absorbent cotton, conduit, pipe, compress etc. is fixed in skin surface.Usually, medical adhesive tape has the layer formation that is provided with adhesive phase in the one side that with paper, cloth, plastic foil etc. is the supporter of raw material.For example, the flexible vinyl chloride film is because obdurability, stress relaxation property, printing adaptability etc. are excellent and cheap, thus as the supporter of first aid rubber plaster by general.But such plastic foil is insufficient to the adaptability of skin surface, and flexibility, breathability are also insufficient.
Relative therewith, non-woven fabrics is because breathability is excellent and it is stuffy to be difficult for when pasting, thereby is suitable as the supporter of medical adhesive tape.And; In recent years having developed with polyurethane, polyester is the non-woven fabrics of the retractility of raw material; Through using these to have the supporter of the non-woven fabrics of retractility and breathability concurrently as adhesive tape; Thereby can obtain be difficult for to produce macule and/or itch, skin problem such as erythema and can follow the adhesive tape (for example, with reference to patent documentation 1 and 2) of motion of the skin of stickup.Be that the adhesive tape of supporter has as the excellent various characteristics (for example, with reference to patent documentation 3 and 4) of medical adhesive tape particularly with the excellent polyurethane non-woven fabrics of breathability and retractility.
Except above-mentioned various characteristics, the tearing property of hands that medical adhesive tape requires available hands to tear more.About giving adhesive tape, up to the present various report is arranged with tearing property of hands.Improve the example of tearing property of hands as punching on adhesive tape, for example, proposed on binding agent impregnation non-woven, to be provided with perforation or at least 1 direction, become the mode of row that the method (with reference to patent documentation 5 and 6) in hole is set with the end.
In addition, have pair non-woven fabrics to handle with chemical adhesive, thus be provided with incomplete perforation pattern and the instance (with reference to patent documentation 7) of adhesive tape.It can be the pit condition that does not connect that patent documentation 6 has also been put down in writing the hole.
But supporter is that the adhesive tape of non-woven fabrics generally is difficult to tear with hands, even can tear by enough handss, also exists and how to be torn such problem with the irregular state of its tear face (tearing the state of end irregularity).In addition, if on supporter, open perforation, then be difficult to keep the intensity of bonding sheet itself.If with processing non-woven fabrics such as chemical adhesives, then produce the such problem of function, feel that adhesive tape can not utilize non-woven fabrics for the intensity that improves bonding sheet.
On the other hand, have through being that the non-woven fabrics of 0.5~5mm carries out coinging and forms continuously or the depressed part of discontinuous pattern to thickness, thereby improve the instance (with reference to patent documentation 8) of tearing property of hands.This adhesive tape is applied to purposes such as cleaning, the cooking, wiping brush, and is different with the medical adhesive tape technical field, and can not realize that in coinging thickness is desired the tearing property of hands of medical adhesive tape, the smooth tearing property about 50~200 μ m.
Patent documentation 1: japanese kokai publication hei 2-14059 communique (corresponding to US 5,239,701 with EP0341875 A1)
Patent documentation 2: japanese kokai publication hei 9-560 communique (corresponding to EP 0749756 A2)
Patent documentation 3: japanese kokai publication hei 10-33585 communique
Patent documentation 4: japanese kokai publication hei 11-9623 communique
Patent documentation 5: the flat 9-502111 communique (corresponding to WO 95/06450 and US5,496,605) of the special table of Japan
Patent documentation 6: TOHKEMY 2007-330376 communique (corresponding to US 2007/0212520A1 and EP 1822261 A2)
Patent documentation 7: No. 3431628 communique of Japan Patent (corresponding to WO 93/15245, US5,496,603, US 5,631,073 and US 5,679,190)
Patent documentation 8: TOHKEMY 2000-345454 communique
Summary of the invention
The problem that invention will solve
The present invention makes in view of the above problems, though its problem provide tearing property of hands good, can tear the also good web-like medical adhesive tape of operability when wearing glove as the crow flies.
Be used to solve the method for problem
According to the present invention, a kind of web-like medical adhesive tape is provided, be that one side at supporter is formed with adhesive phase and is wound into the web-like medical adhesive tape of web-like, wherein,
(1) supporter comprises the non-woven fabrics that the synthetic resin fiber by the long 1~20mm of fiber forms,
(2) at the back side of supporter be the opposition side of adhesive phase, having formed on respect to the vertical width of coiling direction of band through hot piercing is depressed part linearity, that do not connect non-woven fabrics,
(3) degree of depth of this depressed part is 5~60% the degree of depth with respect to the thickness of supporter, this depressed part be spaced apart 0.5~1.5mm, and,
(4) mode that contacts with the back side of supporter with adhesive phase of adhesive tape is rolled-up and form web-like.
Through the present invention; Be provided in tearing property of the hands virtual test, the end check resistance of tearing of width is that 2.0~5.0N, tear propogation resistance are that the tensile strength of the coiling direction of 0.5~2.5N/25mm, band is that 5~50N/25mm, smooth tearing property are to be the above-mentioned web-like medical adhesive tape below the 1.0N more than 80%, to the glove bonding force.
Through the present invention, the thickness that non-woven fabrics is provided is that 50~200 μ m, its weight per unit area are 20~60g/m 2Above-mentioned web-like medical adhesive tape.
Through the present invention, also provide to comprise through utilizing the hot padding roller to carry out the manufacturing approach of web-like medical adhesive tape that hot piercing forms the operation of depressed part.
The effect of invention
Through the present invention, web-like medical adhesive tape and manufacturing approach thereof are provided, this web-like medical adhesive tape is a supporter with the non-woven fabrics that breathability is arranged, and tearing property of hands and smooth tearing property are good, and is good in the operability of wearing under the state of handbag.
Description of drawings
Fig. 1 is the key diagram that is presented at the shape of the sample strip of using in tearing property of the hands virtual test.
Fig. 2 is the figure that is presented at the assay device that uses in the mensuration of 10 operating times.
Fig. 3 is followed successively by the photo that the hands that embodiment 1, comparative example 2 and comparative example 3 are taken the test film after the tests of smooth tearing property tears near the shape the portion from left.
The specific embodiment
Web-like medical adhesive tape of the present invention (following only be called sometimes " adhesive tape ") has adhesive layer on the one side at least supporter.This supporter is made up of non-woven fabrics.
Below the preferred implementation of non-woven fabrics of the present invention is described.
It is that 1~20mm, fineness are that the fiber at 1~30 dawn is made that the non-woven fabrics that uses in the adhesive tape of the present invention is to use fiber length.Less than 1mm, the intensity when then forming the sheet of non-woven fabrics is low, grows up in 20mm like fruit fiber like fruit fiber length, and it is many that then interfibrous binding site becomes, the reduction of tearing property of hands.If fineness is less than 1 dawn, then the stiffness of non-woven fabrics is low and operability worsens, if greater than 30 dawn then stiffness becomes really up to the mark, thereby sometimes adhesive tape sticking sense of discomfort when the human body is become big.The weight per unit area of preferred non-woven fabrics is 20~60g/m 2, its thickness is 50~200 μ m.As employed fiber,,, for example can enumerate polyolefin such as polyethylene, polypropylene, PET polyester such as (PET), nylon, polyurethane etc. as its material so long as the synthetic fibers that have the character of heat fusing get final product.Soft in order for example to make, can cooperate wood pulp etc. with arbitrary ratio in these fibers.Under the situation that cooperates wood pulp, preferred synthetic fibers: the ratio of wood pulp is in the scope of 99: 1~70: 30 (weight ratio).
If in adhesive tape of the present invention, use the non-woven fabrics that becomes the net method for making to make through vertical with the horizontal orientation uniform airflow that can make fiber, then can the fiber appropriateness be cut off through hot piercing, tearing property of adversary is favourable.But,, also can use the non-woven fabrics of making through other method for makings as long as fiber, non-woven fabrics satisfy above-mentioned condition.On the other hand, as spun-bonded non-woven fabrics, the non-woven fabrics of making through the infinitely-great in fact method for making of the length that makes fiber since can be through hot piercing appropriate cut staple, so not preferred.
Preferred its weight per unit area of non-woven fabrics of the present invention is 20~60g/m 2, 30~50g/m more preferably 2If weight per unit area is less than 20g/m 2, then operability worsens because the stiffness of non-woven fabrics reduces.If weight per unit area is greater than 60g/m 2, then fiber hot adhesion point each other increases, and it is strong that non-woven fabrics becomes, and tends to the reduction of tearing property of hands.
Preferred its thickness of non-woven fabrics of the present invention is 50~200 μ m, more preferably 80~150 μ m.If thickness, then constitutes the fiber spacing of non-woven fabrics less than 50 μ m from shortening, interfibrous hot adhesion point increases, and it is strong that non-woven fabrics becomes, sometimes the reduction of tearing property of hands.On the other hand, if thickness, then constitutes the fiber spacing of non-woven fabrics greater than 200 μ m from elongated, interfibrous hot adhesion point excessively reduces, and non-woven fabrics tends to die down.The thickness of non-woven fabrics is measured under the pressure status that non-woven fabrics is applied 1kPa according to the JIS L of Japanese Industrial Standards 1096.
Through the non-woven fabrics that uses among the present invention is processed according to the hot piercing that the continuous pattern that is essentially linearity does not connect non-woven fabrics,, tears along straight line easily non-woven fabrics thereby being become.Through the degree of control hot piercing, can control tearing property of hands.The degree of depth of each depressed part that forms through hot piercing is not necessarily wanted evenly, but need be with respect to the thickness of non-woven fabrics in 5~60% scope.If the degree of depth is arranged greater than 60% depressed part, then the tensile strength of adhesive tape significantly reduces, if the depressed part of degree of depth less than 5% is arranged, then is difficult to give tearing property of hands.The degree of depth of perforation is meant the degree of depth apart from the depressed part of non-woven fabrics supporting body surface before the hot piercing.The degree of depth of depressed part is passed through the coiling direction of medical adhesive tape along band cut off, and the photo of the section of shooting depressed part is measured.
Through the scope that is spaced apart 0.5~1.5mm that each depressed part that forms is processed in hot piercing, be preferably the scope of 0.7~1.3mm.If the gap of each depressed part greater than 1.5mm, needs to confirm, selects to tear the position when then hands tears sometimes.If the gap of each depressed part is less than 0.5mm, then adjacent perforation interferes with each other, thereby possibly cross over a plurality of perforation when hands tears and to tear tearing port crooked.Consider from the viewpoint of tearing property of hands, the interval of each depressed part preferably along the coiling direction of band for all uniformly-spaced.The deepest part that the interval of each depressed part is meant adjacent depressed part is each other along the distance of the coiling direction of band.
As processing the method that forms depressed part through hot piercing, can adopt the processing, the processing that utilizes laser irradiation that utilize heated blade, utilizing the processing of hot padding roller etc., wherein preferably use the method for hot padding roller.For example; Can with along the width of roller the circumferencial direction of roller separate predetermined distance and projection be provided with the linearity continuous pattern the hot padding roller, with the backing roll subtend configuration of surface smoothing; Through sandwiching the non-woven fabrics supporter between these rollers and it is passed through between these rollers, thereby on supporter, form the depressed part of linearity.At this moment, need not pressurize to the non-woven fabrics supporter through roller.The degree of depth of the depressed part that forms through hot piercing can be adjusted through the interval of roller platen and backing roll.As roller platen, can use metallic roll.As backing roll, can use the stainless steel rider of surface smoothing and/or on arbor, be coated with the rubber rollers etc. of the surface smoothing of silicone rubber.
Roller platen need be heated to the fused temperature of synthetic fibers that forms non-woven fabrics in advance.Roller platen preferably is heated to the temperature between about 150 ℃~about 300 ℃ usually.Backing roll can not heat, but as required for fear of the heat affecting to roller platen, can be heated to the temperature identical with roller platen yet.
Through being provided with under the state more than the melting point that temperature partly is a fiber non-woven fabrics is carried out coinging in the surperficial projection of roller platen; Thereby fiber is towards the thickness direction fusion of non-woven fabrics and by membranization or cut-out, thereby produces depressed part at the thickness direction of non-woven fabrics.At this depressed part, because pars fibrosa ground is cut off thereby the tearing strength reduction.Therefore, tear adhesive tape along this depressed part and become easily, can tear adhesive tape with linearity in fact.
The section shape of the depressed part that forms through hot piercing processing so long as the shape of the tearing property of might as well being in the way get final product; Not restriction especially; Utilizing the hot padding roller to carry out under the situation of hot piercing processing; From the viewpoint of the easy property of guaranteeing and making of tearing property of hands, preferably processing section shape is the depressed part as the triangle roof type of general triangular such as equilateral triangle, isosceles triangle.
As the binding agent that uses in the adhesive phase, can use acrylic adhesive, rubber is binding agent, silicon-type binding agent etc., wherein, and the preferred little binding agent of skin irritation.
As acrylic adhesive; Can enumerate the homopolymer or the copolymer of long-chain (methyl) acrylate monomer of carbon numbers about 4~12 such as butylacrylate, 2-EHA, acrylic acid ester in the different ninth of the ten Heavenly Stems, or with (methyl) acrylic ester monomer be main constituent and can be in the scope of 2~50 weight % copolymerization have (methyl) but other monomeric copolymers that form more than a kind of copolymerization such as acrylic acid, vinyl acetate, styrene, vinyl pyrrolidone, acrylamide, 2-(Acryloyloxy)ethanol, Hydroxypropyl acrylate.
Acrylic adhesive can be with above-mentioned monomer in organic solvents such as toluene, hexane, ethyl acetate; With peroxide such as benzoyl peroxide etc. is initiator; Polymerization under nitrogen atmosphere and solvent type adhesive, also can be with above-mentioned monomer in water with emulsifying agent emulsifying disperse, then polymerization and must Emulsion Adhesive.Preferably after polymerization, before being applied to sheet or film support, through in acrylic adhesive, adding an amount of multifunctional resins such as epoxy resin, thereby make crosslinked polymer.
As rubber is binding agent, for example can enumerate, in rubber bases such as synthetic polyisoprenes rubber, SIS, cooperate tackifying resin, softening agent etc. and compositions.
The thickness of adhesive phase is generally 10~200 μ m, is preferably 20~100 μ m.Bonding force about binding agent; Adhesive tape phenolic resins plate bonding force (peeling force) (being meant according to " 180 degree draw I stripping Ga method (180 degree are peeled off method) " adhesive tape that measure, width 25mm of JIS Z 0237 bonding force to the phenolic resins plate) preferably is adjusted in the scope of 0.4~3.0N/cm more preferably is adjusted in the scope of 0.6~2.5N/cm.
The coating of binding agent can be carried out through following method: utilize reversing roll coater, comma roll coater, rod and be coated with apparatus for coating such as machine, will be that the binding agent liquid of medium directly is coated on the method on the supporter with organic solvent or water.Perhaps also can adopt following method: this binding agent liquid is coated on the so-called shaping pieces such as paper supporter, polyester film such as the last matter paper handled with removers such as organic siliconresins, cellophane; At the hot air apparatus inner drying; Then supporter is fitted on the adhesive phase, this adhesive phase is transferred to the method for the one side of supporter.
As the remover that can use in the present invention, chain alkyl side group series stripping agent, silicon-type remover etc. are arranged.As chain alkyl side group series stripping agent, can enumerate the copolymer of monomer and acrylic acid that stearyl acrylate ester, stearyl acrylamide, stearyl vinyl ethers etc. contain the straight chained alkyl of carbon number more than 12, vinyl acetate, acrylonitrile etc.; With polymer such as polyvinyl alcohol with chain alkyl composition side groupization such as alkane acyl chlorides, alkyl isocyanate polymer-modified.Can also use hydrogen atom with these alkyl to replace to fluorine atom and the fluorine series stripping agent.As the silicon-type remover, can enumerate with the polydimethylsiloxane is base polymer, and cooperation polymethyl hydrogen siloxane etc. carries out crosslinked and remover that get.Cross-linking reaction has condensed type and add-on type substantially.
Then, remove shaping piece, be wound into web-like with the mode that the back side of supporter directly contacts with adhesive phase.Do not giving on the cores such as being wound on paper tube under the mitigation condition of excess tension.In the coiling operation, cut into Rack with the rip cutting device, be wound into certain size then, the semi-finished product that perhaps will be wound into certain size cut into Rack with pipe cutting machine (core cutter), thereby process the web-like medical adhesive tape.
Web-like medical adhesive tape of the present invention; Consider from the viewpoint of tearing property of hands, after in tearing property of the hands virtual test stated, the end check resistance of tearing of width is preferably 2.0~5.0N; More preferably in the scope of 2.5~4.5N; In addition, the tear propogation resistance is preferably 0.5~2.5N/25mm, more preferably in the scope of 1.0~2.0N/25mm.
If width tear the end check resistance greater than 5.0N, then tearing property of hands is poor, if tear the end check resistance less than 2.0N, when then operating, tear because of carelessness easily when pasting, produces the obstacle in the practicality.In addition, the tear propogation resistance is desirably 0N (broad ways is torn fully in end check), as long as be 0.5~2.5N/25mm, then can tear with hands with having no problem.
Web-like medical adhesive tape of the present invention; Consider from the viewpoint of tearing property of hands; The width of adhesive tape is preferably in the scope of 9~100mm, more preferably in the scope of 12~50mm, and preferably in tearing property of hands virtual test; Not having difference from the distance that begins to break to the complete disruptive band flow direction, is being straight line laterally.Specifically, when continuously 10 being torn with hands, be that collinear probability (smooth tearing property) is more than 80% preferably with horizontal tearing port.The higher limit of this smooth tearing property is 100%, in most cases is 98%.If tearing port is not a straight line and to shake (the irregular state of tear face) big, appearance poor then, in addition, with 2 bands with point blank so that roughly orthogonal direction is pasted, adjacent band is interfered at the shake position, possibly be with overlapping.Be used at medical adhesive tape under the situation of purposes such as fixing of puncture needle, if this adhesive tape is overlapping because of carelessness, then when peeling off for 11 because overlapping part and 2 are stripped from simultaneously, possibly cause the pin accident of pulling out.
Web-like medical adhesive tape of the present invention, the tensile strength (A) of vertical (coiling direction) of band is preferably 5.0~50.0N/25mm, more preferably 10.0~20.0N/25mm.If tensile strength is less than 5.0N/25mm, then when being fixed with the material of thickness, possibility is owing to undercapacity breaks.On the other hand, if the tensile strength longitudinally of medical adhesive tape greater than 50.0N/25mm, then the intensity of non-woven fabrics uprises, the deterioration of tearing property of hands.
The uncoiling power (B) of web-like medical adhesive tape is preferably in the scope of 0.5~4.0N/25mm, more preferably in the scope of 1.0~2.5N/25mm.This uncoiling power is that the viewpoint from the uncoiling property of this adhesive tape is preferred in the above-mentioned scope.If the web-like medical adhesive tape satisfies its relation of tensile strength (A)>uncoiling power (B) longitudinally, then can when uncoiling, not break.
On-the-spot in medical treatment, doctor, the many medical adhesive tapes of under the state that wears medical glove on hand, operating of nurse.Web-like medical adhesive tape of the present invention imagined actual use wear glove the time service test in, when preferably using hands to tear to the adhesive force of glove as below the 1.0N/25mm.If this adhesive force surpasses 1.0N/25mm, then under the situation of tearing with hands continuously, band be difficult to peel band from glove, so operability significantly reduces excessively attached on the glove.This lower limit to the glove bonding force is generally 0.1N/25mm, in most cases is 0.2N/25mm.
Web-like medical adhesive tape of the present invention can be suitable as dressing band (dressing tape), surgery with adhesive tape etc., is used for directly being pasted on people's skin (skin) and the purposes used.
Embodiment
Below enumerate embodiment and comparative example is explained the present invention more specifically, but the invention is not restricted to these embodiment.
< test method >
(1) experimental atmosphere:
Experimental atmosphere is adjusted to 23 ± 2 ℃ of temperature, relative humidity 65 ± 5%, carries out the mensuration of various characteristics.Sample is regulated 24 hours in advance in identical atmosphere.
(2) tear end check resistance and tear propogation resistance through what tearing property of hands virtual test recorded:
On the sample strip of the web-like medical adhesive tape that cuts into 25 * 78mm width,, 1,1 ' attach oriented polypropylene band (OPP band) down above that as illustrated in fig. 1 with the isosceles trapezoid labelling.Use cupping machine (the system TENSILON RTC-1250 of ORIENTEC society); Grip separation is 10mm; Lax long limit (b) under the state of the trapezoid minor face (a) of straining sample strip, the retained part 2,2 ' that clamping is shown in Figure 1, the stress when mensuration was torn with draw speed 1000mm/ minute.
About data, obtain the initial load (tearing the end check resistance) and the meansigma methods (tear propogation resistance) of the more stable part of stress afterwards as peak load.
(3) tensile strength:
According to the JIS K of Japanese Industrial Standards 7115, with above-mentioned cupping machine the two ends of sample strip were directly stretched with grip separation 50mm, draw speed 300mm/ minute, obtain the peak load that shows before breaking.
(4) to the glove binding power test:
Putting on plastic glove (model: ポ リ salt PVC ニ Le system プ ラ ス チ Star Network グ ロ one Block パ ウ ダ one Off リ one No.50, (strain) republicanism) on hand; The volume adhesive plaster (web-like medical adhesive tape) of 25mm width is untied about 100mm length; Then thumb is placed on the back side of volume adhesive plaster; Forefinger is placed on the adhesive face of rolling up adhesive plaster, will be with and tears, make adhesive tape attached on the forefinger with hand.Then, control the end of band, use above-mentioned cupping machine to stretch, obtain glove and peel off required load, as to the glove bonding force with band with 300mm/ minute speed.5 examinees are carried out this test, ask its meansigma methods.
(5) 10 operating times:
Putting on plastic glove (model: ポ リ salt PVC ニ Le system プ ラ ス チ Star Network グ ロ one Block パ ウ ダ one Off リ one No.50, (strain) republicanism) on hand; Mensuration is with 10 required times of following operation repetition: on one side when the volume adhesive plaster (web-like medical adhesive tape) of 25mm width is untied with the hand long test film 5 of about 100mm of tearing, one side the top 10~20mm of this test film 5 sticked on the vertical glass plate 4 that is fixed in wooden stand 3 shown in Figure 2 (on the 75cm * 12cm) along vertical direction.5 examinees are made an experiment, ask its meansigma methods, 4 houses 5 below the arithmetic point are gone into.
(6) smooth tearing property:
The smooth tearing property of 10 test films that visualization has been torn with hands through aforesaid operations is obtained the neat shared ratio of (horizontal straight line) test film of tearing port.Make an experiment through 5 examinees, obtain its meansigma methods, go into and as the value of 5% spacing through 2 houses 3.For embodiment 1, comparative example 2 and comparative example 3, the example that the hands of the test film after the test of smooth tearing property is torn near the shape the portion is shown in Fig. 3.
(7) uncoiling power:
Uncoiling power is measured as follows: the sample that will be wound on the paper tube of 1 inch of diameter is loaded into uncoiling with in the roller; Fixedly roller is used in uncoiling on the bottom chuck of cupping machine (the system TENSILON RTC-1250 of ORIENTEC society); Speed uncoiling 300mm with per minute 300 ± 20mm is long, measures the load of this moment.
[embodiment 1] (manufacturing approach that volume is stumbled)
In the long 5mm of fiber, the polyester fiber at 2 dawn of fineness, mix wood pulp (PET/ pulp=8: 2), the applying unit area weight is 40g/m 2, thickness is that the non-woven fabrics of 100 μ m is as supporter.This non-woven fabrics is through the air lay manufactured.
Acrylic adhesive (copolymer of acrylic acid ester in the different ninth of the ten Heavenly Stems 83 weight %, acrylic acid methoxyl group nine glycol esters, 16 weight % and methacrylic acid nine glycol esters 1 weight %) solution coat is made that on shaping piece dry back weight is 30g/m 2The above-mentioned supporter (non-woven fabrics) of on the adhesive phase that forms like this, fitting adheres to it and processes adhesive tape.
Use is provided with the projection of roof type horizontal straight line that section is the isosceles triangle of 500 μ m for height 400 μ m, base at the roller upper process of width 300mm, diameter 200mm, and making adjacent leg-of-mutton distance is the roller platen that 500 μ m form.Make the backing roll subtend of the surface smoothing of roller platen and room temperature after the heating; When making the shaping piece side contacts backing roll of adhesive tape; Make this adhesive tape through between two rollers, thereby impress out wire roof type pattern anyhow at the opposition side (supporting honorable side) that binding agent is given face.Roller platen is heated to 270 ℃.The depressed part that forms is along the coiling direction (length direction of band; MD) be the 1mm spacing, penetration depth is 30~50 μ m.Penetration depth shows along the scope of coiling direction during with the penetration depth of 20 of 10cm measuring spaces.
The adhesive tape of making is like this peeled off shaping piece on one side, with the length of 7m be wound on the paper tube of 1 inch diameter on one side, cut into the 25mm width, make the web-like medical adhesive tape of exoskeletal winding.The composition of non-woven fabrics and the shape of depressed part are shown in table 1, and result of the test is shown in table 2.
[embodiment 2]
As supporter, use and only to use the long 5mm of fiber, the polyester fiber at 2 dawn of fineness to process weight per unit area to be 35g/m 2, thickness is the non-woven fabrics of 90 μ m, in addition, likewise makes the web-like medical adhesive tape with embodiment 1.The composition of non-woven fabrics and the shape of depressed part are shown in table 1, and result of the test is shown in table 2.
[embodiment 3]
As supporter, use and only to use the long 3mm of fiber, the polypropylene fibre at 1.5 dawn of fineness to process weight per unit area to be 40g/m 2, thickness is the non-woven fabrics of 120 μ m, and the temperature of roller platen is 150 ℃.The composition of non-woven fabrics and the shape of depressed part are shown in table 1, and result of the test is shown in table 2.
[embodiment 4]
As supporter, use in the long 8mm of fiber, the polyester fiber at 7 dawn of fineness and to mix wood pulp and Tencel (day silk) (PET/ pulp/Tencel=8: 1: 1) processes weight per unit area and is 40g/m 2, thickness is the non-woven fabrics of 150 μ m, in addition, likewise makes the web-like medical adhesive tape with embodiment 2.The composition of non-woven fabrics and the shape of depressed part are shown in table 1, and result of the test is shown in table 2.
[comparative example 1]
As supporter, use the long polypropylene fibre at infinitely great (∞), 5 dawn of fineness in fact of fiber to process weight per unit area and be 40g/m 2, thickness is the spun-bonded non-woven fabrics of 80 μ m, in addition, likewise makes the web-like medical adhesive tape with embodiment 2.Through spun-bond process, formed the non-woven fabrics of processing by the long infinitely-great in fact long fibre of fiber.The composition of non-woven fabrics and the shape of depressed part are shown in table 1, and result of the test is shown in table 2.
[comparative example 2]
Be polypropylene non-woven fabric, have the commercially available band that perforation is bored a hole that the composition of non-woven fabrics and the shape of perforation are shown in table 1 for supporter, result of the test is shown in table 2.
[comparative example 3]
Be polyester/process nonwoven pulp fabric, do not have the perforation or the commercially available band of depressed part that the composition and the shape of non-woven fabrics are shown in table 1 for supporter, result of the test is shown in table 2.
[comparative example 4]
Be polyester/process nonwoven pulp fabric, have the commercially available band that perforation is bored a hole that the composition of non-woven fabrics and the shape of perforation are shown in table 1 for supporter, result of the test is shown in table 2.
[comparative example 5]
Be polyester/staple fibre non-woven fabrics, have the commercially available band that perforation is bored a hole that the composition of non-woven fabrics and the shape of perforation are shown in table 1 for supporter, result of the test is shown in table 2.
[table 1]
Figure BDA0000118724420000131
(footnote)
(* 1) " ス キ Na ゲ one ト メ Star シ ユ " (ニ チ バ Application Co., Ltd. system, registered trade mark)
(* 2) " ST-21N " (ニ チ バ Application Co., Ltd. system)
(* 3) "excellent muscle
Figure BDA0000118724420000141
GS "(Nitto Denko)
(* 4) " ト ラ Application ス Port ア ホ ワ イ ト " (ス リ one エ system ヘ Le ス ケ ア Co., Ltd. system, registered trade mark)
(* 5) are owing to the perforation state with non-woven fabrics does not have direct relation and undetermined.
[table 2]
Figure BDA0000118724420000142
Result by shown in the table 1 and 2 can be clear and definite, and web-like medical adhesive tape of the present invention (embodiment 1~4) tearing property of hands, smooth tearing property are good.Particularly not only tearing property of hands, smooth tearing property are excellent for embodiment 1 and 4 adhesive tape, and tensile strength is also good.In addition, web-like medical adhesive tape of the present invention (embodiment 1~4) does not need over-drastic power when tear-open strip, therefore can easily peel off this adhesive tape from glove.
Relative therewith, though the fibers melt of the adhesive tape of comparative example 1 through non-woven fabrics formed dark depressed part, because fiber does not have appropriateness to be cut off, thereby tearing property of hands is poor, smooth tearing property is also poor.In addition, comparative example 2~5 commercially available is that the volume rubber plaster of supporter needs strength when not only hands tears with the non-woven fabrics, and smooth tearing property as shown in Figure 3 is also poor.The adhesive tape of comparative example 1~5 is owing to need strength when tear-open strip, thereby excessively attached on the glove, is difficult to peel off band from glove.
The industry utilizability
Web-like medical adhesive tape of the present invention can be used for protection, gauze, conduit, puncture needle etc. fixing etc. of skin affected part at medical field.
Even web-like medical adhesive tape of the present invention is because tearing property of hands is good, can straightly to tear when wearing glove operability also good, thereby can help to improve on-the-spot, the operability in the operative site particularly of medical treatment, help to improve the treatment of disease, damage.In addition, because can utilize the hot padding roller to form depressed part, so can make the good web-like medical adhesive tape of tearing property of hands at an easy rate through hot piercing.Therefore, web-like medical adhesive tape of the present invention can help the improvement of patient burden and medical treatment finance.
Description of reference numerals
1,1 ': the stickup position of OPP film
2,2 ': the retained part in tearing property of the hands virtual test
3: wooden stand
4: glass plate
5: test film.

Claims (13)

1. web-like medical adhesive tape is that one side at supporter is formed with adhesive phase and is wound into the web-like medical adhesive tape of web-like, wherein,
(1) supporter comprises the non-woven fabrics that the synthetic resin fiber by the long 1~20mm of fiber forms,
(2) at the back side of supporter be the opposition side of adhesive phase, having formed on respect to the vertical width of coiling direction of band through hot piercing is depressed part linearity, that do not connect non-woven fabrics,
(3) degree of depth of this depressed part is 5~60% the degree of depth with respect to the thickness of supporter, this depressed part be spaced apart 0.5~1.5mm, and,
(4) mode that contacts with the back side of supporter with adhesive phase of adhesive tape is rolled-up and form web-like.
2. web-like medical adhesive tape according to claim 1; Wherein, In tearing property of the hands virtual test that utilizes the disclosed assay method of this part description to carry out, the end check resistance of tearing of width is 2.0~5.0N, and the tear propogation resistance is 0.5~2.5N/25mm.
3. web-like medical adhesive tape according to claim 1, wherein, the tensile strength of the coiling direction of the band that records through the disclosed assay method of this part description is 5.0~50.0N/25mm.
4. web-like medical adhesive tape according to claim 1, wherein, the smooth tearing property that records through the disclosed assay method of this part description is more than 80%.
5. web-like medical adhesive tape according to claim 1, wherein, what record through the disclosed assay method of this part description is below the 1.0N to the glove bonding force.
6. web-like medical adhesive tape according to claim 1, wherein, the thickness of this non-woven fabrics is 50~200 μ m.
7. web-like medical adhesive tape according to claim 1, wherein, the weight per unit area of this non-woven fabrics is 20~60g/m 2
8. web-like medical adhesive tape according to claim 1, wherein, the material of this non-woven fabrics is polyolefin, polyester, nylon or polyurethane.
9. web-like medical adhesive tape according to claim 1, wherein, this non-woven fabrics is through the air lay manufactured.
10. web-like medical adhesive tape according to claim 1, wherein, this binding agent is an acrylic adhesive.
11. web-like medical adhesive tape according to claim 1, wherein, the adhesive tape of the width 25mm that records according to the JIS Z of Japanese Industrial Standards 0237 is 0.4~3.0N/cm with respect to the bonding force of phenolic resins plate.
12. web-like medical adhesive tape according to claim 1, the assay method of putting down in writing through description is respectively measured, and the tensile strength of coiling direction (A) is greater than uncoiling power (B) as a result.
13. the manufacturing approach of the described web-like medical adhesive tape of claim 1 comprises following operation: utilize the hot padding roller to carry out hot piercing, thereby form the depressed part that does not connect non-woven fabrics.
CN201080025970.7A 2009-06-12 2010-06-09 Roll-shaped medical adhesive tape and manufacturing method therefor Expired - Fee Related CN102458326B (en)

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CN107805465A (en) * 2017-10-23 2018-03-16 江阴通利光电科技有限公司 One kind can heavy industry non-woven fabrics non-flammable adhesive tape

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CN103450823A (en) * 2012-06-04 2013-12-18 亚化科技(东莞)胶粘制品有限公司 Environment-friendly cut-free adhesive tape
CN107805465A (en) * 2017-10-23 2018-03-16 江阴通利光电科技有限公司 One kind can heavy industry non-woven fabrics non-flammable adhesive tape

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JP5632373B2 (en) 2014-11-26
CN102458326B (en) 2014-09-24

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