CN102453582A - Production method of pollution-free garbage treatment and garbage conversion into cycling clean energy - Google Patents
Production method of pollution-free garbage treatment and garbage conversion into cycling clean energy Download PDFInfo
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- CN102453582A CN102453582A CN201010509885XA CN201010509885A CN102453582A CN 102453582 A CN102453582 A CN 102453582A CN 201010509885X A CN201010509885X A CN 201010509885XA CN 201010509885 A CN201010509885 A CN 201010509885A CN 102453582 A CN102453582 A CN 102453582A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/20—Waste processing or separation
Abstract
A production method of pollution-free garbage treatment and garbage conversion into cycling clean energy. Garbage resource is treated with cleaning treatment into combustible coalification base-material, which is then treated with energy conversion, substance recombination and optimization to be synthesized into clean energy superior to original coal. The method can increase an original coal saving rate to 65-85%, effectively reduce emission of harmful substance and harmful gas to 65-85% and increase utilization rate of life garbage and industrial garbage to 95-99%; quantity of heat of garbage can be increased from 1500-3500 kilocalorie to an industrial coal standard of 4200-6200 kilocalorie, which completely satisfies requirements of usage of various boilers, industrial generating, industrial chemistry and industrial smelting and civil usage. Pollution-free garbage treatment and effective integral utilization of garbage are great contributions to human kind and have imperative significance for protection of original coal resource, increase of original coal utilization rate, original coal reservation and environmental protection.
Description
Technical field
The present invention relates to a kind of domestic garbage resources that utilizes and change into the cyclic regeneration clear energy sources; In particular; Be a kind ofly especially to be fit to utilize various domestic garbage resources to carry out permanent nuisancelessization to be treated as flammable coalification base-material; And carry out material reorganization and Conversion of energy and optimize synthesizing the extremely strong of non-harmful, ultra energy-conservation, ultra clean environmental protection with reproducibility; Use is smelted in suitable fully various boilers, industrial generation, industrial chemical industry, industry, and clear energy sources civilian use and that be superior to original coal.The invention still further relates to the processing of nuisancelessization of rubbish and change into the working method of cyclic regeneration clear energy sources.
Background technology
At present, known existing various fossil coals do not have recyclability, and it is very urgent with coal utilizaton rate therefore to improve the coal deposit; And existing refuse treatment and burning disposal have also all become the pollution disaster of chronicity; Therefore seeking a kind of permanent nuisancelessization technology of garbage disposal, become a human major issue of optimizing in the living environment, also is simultaneously that national governments need a urgent significant problem that solves.Be processed into flammable coalification base-material if can domestic garbage resources be carried out permanent nuisancelessization with complete cleaningization; And carry out the reorganization of Conversion of energy and material and synthesize the cyclic regeneration clear energy sources with optimization; To and improve original coal utilizaton rate to the saving of original coal so, and all will play an important role the nuisancelessization processing of rubbish.Because domestic garbage resources is persistence circulating resources and powerful reproducibility, so development prospect is boundless, domestic garbage resources will become the resource energy of human permanent loops.With the nuisancelessization processing of domestic refuse with effectively utilize, be a contribution greatly to the universe.It is thus clear that existing various fossil coals and domestic rubbish disposal all exist disadvantage and weak point:
1, various original coals: various fossil coals are not only non-renewable, and resource is very poor, if do not improve coal deposit and coal utilizaton rate, century-old back coal resources will remain little, and it is very urgent with coal utilizaton rate therefore to improve the coal deposit; Optimization and reorganization coal and regeneration techniques have arrived critical moment, and it is vital improving the coal added value.The at present human importance of having known very well the coal energy has become inevitable to the comprehensive utilization and the comprehensive exploitation of coal.In recent years, the Shanxi Province of the big province of Chinese producing coal has carried out large-scale coal and has integrated, and closes little colliery and reaches ten thousand, and the coal energy reserves is played an important role; But comprehensive utilization and comprehensive exploitation to coal also very lack; And Chinese Government is in order further to improve coal utilizaton rate and environment effectively to be protected; National regulation forbids directly burning raw coal; And carry out the processing and utilization of clean coal; This is to the protection of original coal resources and improve original coal utilizaton rate and original coal deposit has played significant role again, and these all embody Chinese Government the mankind's contribution has been taken essential step.This also is processing of nuisancelessization of domestic refuse and the important meaning that changes into clear energy sources place, and it can improve the utilization ratio and the energy reserves that prolongs original coal of original coal to a great extent.The original coal energy of today should be walked biochemical again Conversion of energy and material reorganization and the multiplication of optimization synthetic, circulation and regeneration road.
2, waste incineration and generating: after the consumer waste incineration method has been passed through the practice of last a century, also fail to be accepted by the numerous common people, its all disadvantage outstanding behaviours is even more serious in the pollution of hiding; And facility investment and expensive all extremely expensive, complicated operating process is because domestic refuse mainly is rubbish from cooking, pericarp and leftover etc.; Water cut is bigger, even after the drying, its combustion heat value also is extremely low; Be difficult to reach the generating requirement, therefore in burning process, also be difficult to reach ideal high temperature, so generated energy is low; Want to reach the ideal temperature, thus can only directly give ability (as: direct injection or interpolation fuel raw coal) ability combustion-supporting by the external world, owing to directly utilize fuel oil and raw coal; Dustiness increases, serious waste of resources; Owing to include plastics such as a large amount of waste plastic packings and disposable lunch-box, in the burning process of rubbish, more be prone to produce " Dioxins " toxicant again; Yet the temperature that does not produce " Dioxins " but requires about 850 degree, so incineration temperature is difficult to control.It is low to add generated energy, and cost of electricity-generating is high, so waste incineration is a lot of with the generating unfavorable factor, so very difficultly accepted by people.Analyze from the science angle, in fact waste incineration is exactly the solid-state gaseous state that become, solid decrement on the surface; But increased from contaminated area; Can be transformed into the gas of 4000-7000 cubic meter after one ton of waste incineration, only some can aloft degrade these gases, also has quite a few (comprising " Dioxins " and tens kinds of obnoxious flavoures) to degrade; In fact incinerator is exactly a malicious stove of refining; It is transformed into invisible severe toxicity and gas with the nontoxic and gr rubbish of script, and half the lime-ash, and those harmful and noxious substances that are released in the environment (comprise strong carcinogens such as Dioxins; And various heavy such as lead, cadmium, tin, zinc), natural hazard is very big.
In objectionable impurities, topmost composition is exactly " Dioxins ", and Dioxins is internationally recognized one-level carcinogens; Be called as " the strongest poisonous substance of toxicity on the earth ", exist hardly, have only through pyrochemistry is synthetic and could produce at occurring in nature; Toxicity is 100 times of Repone K, 900 times of arsenic, and its transformation period is longer; Be 14-273, and can constantly accumulation in human body.The demonstration that result of study is clear and definite incinerator be very serious to the infringement of human health, chlorinated naphthalene, lead, mercury and arsenic content increase in incineration plant workman body.Near the residents ' health influence incineration plant is summed up: thioether content is high in children's urine; The soft tissue malignant neoplasm has increased by 44%; Lymphoma has increased by 27%; Lung cancer mortality has increased by 6.7 times; The PLC mortality rate surpasses normal value 37%; Children's cancer mortality has increased by 2 times; The respiratory system disease symptom increases (than normally exceeding) 9 times; Congenital abnormality increases; Harelip disease, spina bifida, bifid urethra and reproductive system disease and the how pregnant disease of women etc. increased.
Another distinct issues of consumer waste incineration are: can't solve a lime-ash difficult problem, lime-ash contains severe toxicity, must be embedded in the landfill site special-purpose and antiseep of monitoring of costing costliness, otherwise can cause bigger soil and groundwater pollution.This huge investment also causes heavy financial burden, no matter is negative influence, and still positive influence has been turned from side to side after some, still will remove to bury lime-ash.Because all drawbacks of waste incineration today, by some developed countries' cancellations with ban use of.Therefore we must adhere to four principles to waste incineration, if because the rubbish crisis is had to and the waste incineration and generating electricity coexistence, just must put halter to waste incineration and generating electricity as mewing power.Precisely because so, could the environmental exposure of burning be controlled at minimum extent.Hold with to greatest extent scrupulous to waste incineration and generating electricity.Waste incineration; The task of top priority can only be based on the sociology visual field; Based on modern development and special national conditions; Promptly should under what kind of social condition, burn, whether these conditions and environment we fully possess, and this attitude is only really responsible to life, responsible, responsible to universe's living environment to history attitude.
Below four, be the basic and social complementary conditions of domestic garbage burning electricity generation:
(1), do not sort to put in place and do not burn:
Sound refuse classification is the precondition of waste incineration and generating electricity, is the historical stage of No overtaking, and this early is exactly a social consensus.Present problem is that categorized consumer waste needs powerful Infrastructure, has only government just to have the ability to provide refuse classification needed powerful Infrastructure.No matter how strong the public's classification impulsion is, if the powerful Infrastructure that does not have government to provide cooperates, the possibility that just exhausted nothing is landed.
(2), not financially fully do not burn:
Huge environmental exposure is destined to this high risk industry of a domestic garbage burning electricity generation and gives market, gives enterprise and go to dominate, and consequence is extremely serious.If the municipal wastes crisis is really serious in must burning, and is so this concerning the high risk industry that is tied to public safety, just belong to the category of Public services fully, just should mainly check by urban government, should belong to the public good industry of finance guarantee in full.Only finance is in full ensures, disregards cost, just possibly stop jerry industry black hole.
(3), not underground transparently do not burn:
Can accomplish that consumer waste incineration whole process is open and clear, also should be the important indicator whether the decision waste incineration and generating electricity starts.Waste incineration and generating electricity must accomplish to entire society, especially opens up comprehensively to the resident as potential victim's place community, accepts entire society and especially belongs to the omnibearing supervision of community resident, could really win the people's confidence, and really lets the people relieved.
(4), unfair compensation is not burned:
The inevitable environmental exposure of waste incineration and generating electricity obviously will be brought certain loss to peripheral resident's property, and existing loss should be compensated.Interests can only be replaced, and can not be sacrificed, and no matter working as thing is majority or a few peoples.This principle must be an inflexible, otherwise, borrowing so-called overall interests, majority's interests, that sacrificed today possibly be him, but just possibly be you tomorrow.
The principle of waste incineration is exactly the social responsibility method, can not be broken by any interests, can not be broken with temptation with high investment by anyone, any group, any enterprise; More can not be broken by state power, local power, group's setting a precedent property of power.
Yet, the nearly 1,000,000,000 tons of rubbish of the annual generation of China, wherein the domestic refuse generation reaches 400,000,000 tons, can't carry out permanent nuisancelessization and cleaningization processing fully at present; In face of harm so greatly, China still has the part city can only in panic, build waste incineration and power station, and invests huge.
And annual speed with about 10% increases.But the processing rate of China's domestic waste is not high, and the ratio that really reaches harmless treatment and recycling is lower, and the domestic refuse that grows with each passing day has become the significant problem of puzzlement Economic development and environmental improvement.Refuse treatment is improper, can cause significant damage to environment, comprises land occupation, contaminated soil, and the polluted underground water resource influences Air quality, and atmosphere pollution spreads disease etc.Therefore, how harmless treatment domestic refuse and how rubbish effectively being utilized has become the outstanding problem that each state of the world needs to be resolved hurrily.
Garbage problem becomes the significant challenge that faces in each urban development just day by day, becomes a major issue that presses for solution in the sustainable development of socio-economy.In recent years; Each state government of the world all pays much attention to the work of treatment of domestic waste; The substantial contribution of having thrown the people, but still what adopt is modes such as primary sanitary landfill, During High-Temperature Composting, burning, simple classification, can not fundamentally solve the pollution problem and the recycling problem of rubbish.
" processing of nuisancelessization of rubbish and change into cyclic regeneration clear energy sources and working method " adopted in present technique invention; Be a kind of nuisancelessization comparatively completely and resource cleaningization processing mode; Reach the requirement of aseptic, energy-saving and environmental protection, low-carbon (LC), created a kind of waste disposal method " cleaningization and energy-conservationization pattern " that meets.
Consumer waste incineration and generation technology, be in fact human, treatment process incomplete from a kind of trouble of making and one improperly, the halfway individual of purification rate, group, enterprise, country, place and group's interests type, the temptation type, the black hole type, the problem type, conceal low value project type, resting form of covering.The present invention is significant.
3, industrial refuse and construction waste: the industrial refuse that China the is annual and construction waste generation reaches 600,000,000 tons of present industrial refuses and the construction waste utilization ratio is not high; Do not carry out the high benefit exploitation yet; The main product of China's industrial refuse and construction waste exploitation is exactly the wall floor tile; Its economic benefit is extremely low, and is to be difficult to utilize.The important meaning place that the present invention that Here it is produces.Here it is, and important meaning of the present invention belongs to.More than many shortcoming and defect parts, demand urgently improving.
Summary of the invention:
The objective of the invention is to provide a kind of utilizes various domestic garbage resources to carry out permanent nuisancelessization to be treated as flammable coalification base-material; And carry out material reorganization and Conversion of energy and optimize synthesizing the extremely strong of non-harmful, ultra energy-conservation, ultra clean environmental protection with reproducibility; Use is smelted in suitable fully various boilers, industrial generation, industrial chemical industry, industry, and cyclic regeneration clear energy sources civilian use and that be superior to original coal.
It is waste resources to be carried out cleaning be processed into flammable coalification base-material; Carry out the reorganization of Conversion of energy and material again and synthesize the clear energy sources that is superior to original coal with optimization; It can make original coal saving rate improve to reach 65-85%, and can reduce the discharging that objectionable impurities and obnoxious flavour reach 65-85% effectively; Simultaneously, can make the rate of utilization of domestic refuse, industrial refuse and construction waste bring up to 95-99%; This is to the protection of original coal resources and improve original coal utilizaton rate and original coal deposit plays major contribution, and protection plays an important role to existent environment of people.
The present invention can bring up to industrial coal standard with the 1500-3500 kilocalorie of rubbish self heat, and heat can be brought up to the 4200-6200 kilocalorie, and meet various boilers, industrial generation, industrial chemical industry, industry fully and smelt and use, and the requirement of civilian use.Because domestic garbage resources is persistence circulating resources and powerful reproducibility, so development prospect is boundless, domestic garbage resources will become the resource energy of human permanent loops.With the nuisancelessization processing of domestic refuse and utilization effectively synthetically, be a contribution greatly to the universe.
The technical scheme that the present invention adopted is: a kind of nuisancelessization of rubbish processing and change into the cyclic regeneration clear energy sources; It is to be regenerated after flammable coalification base-material and synthetic energy evolution agent stir in the lump by the domestic refuse charing, promptly gets cyclic regeneration clear energy sources finished product.Its prescription is: domestic refuse charing regeneration coalification base-material 85-97% (weight part), synthetic energy evolution agent 15-3% (weight part), interpolation tackiness agent 5-10% weight part (in prescription, can disregard weight).
Nuisancelessization of rubbish processing and change into the working method of cyclic regeneration clear energy sources:
At first life industrial refuse (rubbish from cooking, pericarp and leftover and other rubbish) is carried out metal go-no-go, high pressure deodoring and disinfecting, dehydration, drying (moisture is at 8-15%), Rapid Cycle charing; And after being ground into (35-50 purpose) garbage regeneration reorganization component, store for future use; Again plant charcoal material (with various plant carbonated processing) and a certain amount of raw coal (various standard coal equivalent) are crushed to the 40-60 order jointly, and synthesize regeneration optimization material; After stirring with garbage regeneration reorganization component again, can obtain flammable coalification base-material, store for future use at normal temperatures; Again after crushed, carry out secondary with flammable coalification base-material and synthesize, and after mixing, promptly get the cyclic regeneration clear energy sources synthetic energy evolution agent; The sulphur content of this cyclic regeneration clear energy sources shows about sulphur content 0.25-0.8 through national examining report result that all below 0.9 the Lin Geman flue gas concentration is 15-40%, than general raw coal decline 85-60%, is pure clean cyclic regeneration clear energy sources; The present invention can bring up to industrial coal and civilian coal standard with the 1500-3500 kilocalorie of rubbish self heat; Heat can be brought up to the 4200-6200 kilocalorie; Meet various boilers, industrial generation, industrial chemical industry fully, industry is smelted and is used, and civilian use use the coal standard, ten minutes is perfect.Its synthetic energy evolution agent is by strong oxidizer (potassium perchlorate, saltpetre); Powerful catalyst (Manganse Dioxide); Scale remover (quicklime or lime carbonate); Smoke suppressor (yellow soda ash, light Natural manganese dioxide); Sweetening agent (aluminium sesquioxide) and magnesium nitrate are formed.
The transportation and the side of depositing for ease of the cyclic regeneration clear energy sources; In the cyclic regeneration clear energy sources, adding a certain amount of tackiness agent (after 100 ℃ of boiling water dissolve) again joins in the cyclic regeneration clear energy sources and stirs; Press fast and pressure ball moulding by forming machine again; Also can be made into honeycomb briquette, coal briquette, coal cinder, coal rod, coal grain, can do various boilers, industrial generation, industrial chemical industry, industry smelting use, and the civilian coal of using.
Embodiment
According to production operation embodiment; A kind of cyclic regeneration clear energy sources; It is (35-50 purpose) garbage regeneration reorganization component 60-100% (weight part) to be optimized material 37-80% (weight part) with the regeneration of (40-60 order) stir; Can obtain flammable coalification base-material 97-180% (weight part), store for future use at normal temperatures; Again after crushed, carry out secondary with flammable coalification base-material 97-180% (weight part) and synthesize, and after mixing, promptly get cyclic regeneration clear energy sources 100-195% (weight part) synthetic energy evolution agent 3-15% (weight part).Its synthetic energy evolution agent is by strong oxidizer 1% weight part (potassium perchlorate 0.5%, saltpetre 0.5%); Powerful catalyst 0.5% weight part (Manganse Dioxide 0.5%); Scale remover 0.5% weight part (quicklime 0.5% or lime carbonate 0.5%); Smoke suppressor 0.5% weight part (yellow soda ash 0.3%, light Natural manganese dioxide 0.2%); Sweetening agent 0.5% weight part (aluminium sesquioxide 0.5%) and magnesium nitrate 0-0.5% (weight part) form; Can add and adjust the dosage of synthetic energy evolution agent according to flammable coalification base-material situation, floating downward to be less than 2%, and rising can not be higher than 10%.
The sulphur content of this renewable environment-protecting industrial coal shows about sulphur content 0.25-0.8 through national examining report result that all below 0.9 the Lin Geman flue gas concentration is 15-40%, than general raw coal decline 85-60%, is pure clean cyclic regeneration clear energy sources; The present invention can bring up to industrial coal standard with the 1500-3500 kilocalorie of rubbish self heat; Heat can be brought up to the 4200-6200 kilocalorie; Meet various boilers, industrial generation, industrial chemical industry, industry smelting use fully, and the civilian coal standard of using, very perfect.The transportation and the side of depositing for ease of the cyclic regeneration clear energy sources; In cyclic regeneration clear energy sources 100-195% (weight part), adding a certain amount of tackiness agent 5-10% (weight part) (after 100 ℃ of boiling water dissolve) again joins in the cyclic regeneration clear energy sources and stirs; Press fast and pressure ball moulding by forming machine again; Also can be made into honeycomb briquette, coal briquette, coal cinder, coal rod, coal grain, can do various boilers, industrial generation, industrial chemical industry, industry smelting use, and the civilian coal of using.
Claims (1)
1. a waste resources changes into cyclic regeneration clear energy sources and working method; It is characterized in that: it is that (35-50 purpose) garbage regeneration reorganization component 60-100% (weight part) is optimized material 37-80% (weight part) through stirring with the regeneration of (40-60 order), can obtain flammable coalification base-material 97-180% (weight part); Again after crushed, carry out secondary with flammable coalification base-material 97-180% (weight part) and synthesize, promptly get cyclic regeneration clear energy sources 100-200% (weight part) synthetic energy evolution agent 3-15% (weight part).
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Cited By (1)
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Effective date of registration: 20140528 Address after: 239300 hi tech center of Tianchang Economic Development Zone, Anhui, A205 Applicant after: Tianchang Zhongneng Guotai Energy Technology Co., Ltd. Address before: 100070 Beijing Fengtai District Branch Road No. 9 two 201 floor office Applicant before: ZHONGYANGWEIYE (BEIJING) ENERGY TECHNOLOGY INDUSTRY CO., LTD. |
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