CN102453099A - Preparation method of corn starch - Google Patents
Preparation method of corn starch Download PDFInfo
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- CN102453099A CN102453099A CN2010105176651A CN201010517665A CN102453099A CN 102453099 A CN102453099 A CN 102453099A CN 2010105176651 A CN2010105176651 A CN 2010105176651A CN 201010517665 A CN201010517665 A CN 201010517665A CN 102453099 A CN102453099 A CN 102453099A
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Abstract
The invention relates to a preparation method of corn starch. The method comprises: smashing immersed niblets so as to separate germs, subjecting degermed corn-bran and endosperm-containing niblet tissues to grinding so as to separate fiber, separating the obtained crude starch milk so as to obtain gluten water and starch milk, and washing the starch milk. Specifically, the gluten water is then concentrated to obtain a concentrate and process water containing insoluble protein. The process water is then mixed with a flocculating agent solution for floatation separation. The flocculating agent involved is a material able to make insoluble protein in the process water flocculate and/or subside. The method of the invention can make the insoluble protein and water in the process water effectively separated, thus substantially enhancing the yield of gluten protein powder. In addition, the protein flocculated process water can be reused to immerse corn and wash germs and fiber cyclically, basically can reach the immersion and washing effects of fresh water, and substantially improves the quality of refined starch milk.
Description
Technical field
The present invention relates to a kind of preparation method of W-Gum.
Background technology
The leaching process of starch is the chief component separating process of corn grain, and the separation of each integral part of corn grain has two kinds of dry method and wet methods, and lock out operation main be to grind, therefore, the branch of dry grinding and wet-milling is arranged.Wet-milling is the general technology of current corn starch industry, is mainly the corn process fragmentation of process dipping back, takes off embryo, correct grinding and screening, to tell plumule, fibrous residue, makes the process of rough milk of starch.After starch wearable riddler preface was extracted, the gained milk of starch still was a coarse starch milk, still contains a large amount of insoluble proteins and soluble substance; And the concentration of powder slurry is also rarer, need make with extra care and concentrate, for processing and deep processing at last provides purified smart milk of starch; The purified method is to utilize the spinning principle, and coarse starch milk is separated, and tells the water that gently contains insoluble protein mutually; Be seitan water; Heavy phase is a milk of starch, removes soluble substance remaining in the milk of starch with the pure water washing again, promptly gets smart milk of starch.And isolated seitan water utilizes the method for spinning to concentrate once more; Obtain enriched material and process water, after enriched material is dehydrated, promptly get the gluten protein powder; Separate the process water that obtains, directly cyclically utilizing is in the washing process of technique for soaking corn or milk of starch.On the one hand; Adopt the preparation method of the W-Gum of prior art to utilize the method for spinning to carry out spissated technology deficiency so that the insoluble protein in the seitan water is fully separated once more to seitan water, separation efficiency is lower, and causes the productive rate of gluten protein powder not high; On the other hand; After the direct cyclically utilizing of process water is in technique for soaking corn and the milk of starch washing process, the remarkable variation of washing effect of the immersion effect of corn and milk of starch, and influence the quality of smart milk of starch.
Summary of the invention
It is high and directly with after the direct cyclically utilizing of process water is in technique for soaking corn and plumule, the fibre washing technique to the objective of the invention is to overcome the productive rate of existing W-Gum preparation technology gluten protein powder; The immersion effect of corn and the remarkable variation of quality product; And influence the defective of the quality of smart milk of starch; Provide a kind of and can either improve gluten protein powder productive rate and improve corn soaking effect and cyclically utilizing to the plumule of process water cyclically utilizing to technique for soaking corn, the starch washing effect of fibre washing technique, improve the preparation method of W-Gum of the quality of smart milk of starch.
Contriver of the present invention finds; Also contain a large amount of insoluble proteins in the process water that obtains after adopting existing W-Gum preparation technology to utilize the method for spinning to concentrate once more to seitan water; If directly with the direct cyclically utilizing of process water to technique for soaking corn; Because the protein content in the process water is high, therefore can't fully the soluble protein in the corn be soaked out and incorporate in the water, and influence follow-up separating technology; Equally; The direct cyclically utilizing of the process water that prior art obtains in plumule, the fibre washing technique after, also can't fully the soluble substance thorough washing in plumule, the fiber be come out, and quality that can the smart milk of starch of remarkably influenced.
The invention provides a kind of preparation method of W-Gum, this method comprises soaks corn grain, and the corn grain that will pass through immersion carries out fragmentation; Isolate plumule, the corn grain tissue that contains maize peel and endosperm that will take off behind the embryo grinds, and isolates fiber; The coarse starch milk that obtains separated obtaining seitan water and milk of starch, and milk of starch is washed, wherein; The treatment process of said seitan water comprises seitan water concentrated, obtains enriched material and process water, contains insoluble protein in the said process water; Process water is mixed with flocculant solution, and the promoting the circulation of qi of going forward side by side is floating to be separated; Said flocculation agent is for making insoluble protein flocculation and/or the settled material in the process water.
Method of the present invention is through concentrating seitan water; Obtain enriched material and process water; And insoluble protein contained in the said process water flocculated, and making said insoluble protein natural subsidence and/or flocculation, the promoting the circulation of qi of going forward side by side is floating to be separated; Thereby reaching the insoluble protein that makes in the said process water effectively separates with water; With the albumen that obtains dewater, dry back and obtain gluten protein powder feed, thereby the insoluble protein in the process water after seitan water concentrated once more reclaims, and has improved the productive rate of gluten protein powder thus greatly.In addition, with make after the albumen flocculation process water once more the reuse circulation corn is soaked and plumule, fiber is washed, can reach basically and soak with fresh water and the effect of washing, and significantly improve the quality of smart milk of starch.The deficiency of the technology that the method that has remedied prior art is handled seitan water so that insoluble protein can fully separate.In addition, flocculation agent used among the present invention can not bring any toxicity to finished product, guarantees for food safety provides well yet.
Embodiment
According to the present invention, the preparation method of said W-Gum comprises corn grain is soaked that the corn grain that will pass through immersion carries out fragmentation; Isolate plumule, the corn grain tissue that contains maize peel and endosperm that will take off behind the embryo grinds, and isolates fiber; The coarse starch milk that obtains separated obtaining seitan water and milk of starch, and milk of starch is washed, wherein; The treatment process of said seitan water comprises seitan water concentrated, obtains enriched material and process water, contains insoluble protein in the said process water; Process water is mixed with flocculant solution, and the promoting the circulation of qi of going forward side by side is floating to be separated; Said flocculation agent is for making insoluble protein flocculation and/or the settled material in the process water.
Contriver of the present invention finds, flocculation agent is mixed with process water with the form of flocculant solution, can make it more even with the process water blended, makes insoluble protein flocculation in this process water and/or settled more abundant, complete.
According to the present invention, the solvent in the said flocculant solution can be the various solvents that can form solution with flocculation agent, and generally, the solvent in the said flocculant solution is a water.Said flocculation agent can be various can be with the insoluble protein in process water flocculation, sedimentation, and make its effective isolating flocculation agent from process water, under the preferable case, said flocculation agent can be ROHM and/or ZX-I and Poly aluminum Chloride (PAC).
More preferably under the situation, said polyacrylic number-average molecular weight can be 6,000,000-1,000 ten thousand dalton, and the number-average molecular weight of said ZX-I can be 6,000,000-1,000 ten thousand dalton.Said Poly aluminum Chloride (PAC) is a kind of inorganic flocculating agent, and its molecular formula is [Al
2(OH)
nCl
6-n]
m, wherein, n is 1-5, m≤10, basicity B=n/6 * 100%.
Contriver of the present invention finds; Poly aluminum Chloride (PAC) makes the fine particle thing in the said process water accumulate in the suspended substance that it forms larger particles on every side more easily; And ROHM and/or ZX-I make the suspended substance sedimentation of larger particles more easily, therefore, and in the ban after the aqueous solution with process water and Poly aluminum Chloride (PAC); With the aqueous solution of ROHM and/or ZX-I, can play better separating effect again.In addition; Contriver of the present invention also finds, the weight ratio of Poly aluminum Chloride (PAC) and ROHM and/or ZX-I is controlled at 2-5 in this flocculant solution, in the time of more preferably in the scope of 3-4.5; The layering of insoluble protein and water is more clear, and promptly separating effect is better.
Under the preferable case; After aqueous solution, before the aqueous solution of ROHM and/or ZX-I, also comprise the step of stirring with process water and Poly aluminum Chloride (PAC); Gathering fully to make the fine particle thing in Poly aluminum Chloride (PAC) and the process water is more thorough; Destroy in order to be beneficial to the Poly aluminum Chloride (PAC) fine particle thing that fully flocculates, can not destroy again simultaneously the PM for particulate matter that has flocculated, the time of said stirring is preferably 0.5-5 minute.
In the present invention, the solubleness of flocculation agent in water is moderate, therefore; The adjustable extent broad of the mass and size concentration of said flocculant solution; As, can be 0.1-5% (m/v), from taking all factors into consideration of cost and effect; The mass and size concentration of said ROHM and ZX-I flocculant solution is preferably 0.1-0.5% (m/v), and the mass and size concentration of said flocculant of polymeric aluminium chloride solution is preferably 1-5% (m/v).
According to method of the present invention; The adjustable extent broad of the consumption of said flocculant solution; For example, can be according to the consumption of how much regulating flocculant solution of the amount of insoluble protein in the process water, under the preferable case; The consumption of said flocculant solution makes that the amount of flocculation agent in said process water is 20-1000ppm; More preferably under the situation, the consumption of said flocculant solution makes that ROHM and the amount of ZX-I flocculation agent in said process water are 20-100ppm, makes that the amount of flocculant of polymeric aluminium chloride in said process water is 200-1000ppm.
The mass and size concentration of insoluble protein generally can be 1.5-1.9% (m/v) in the said process water.
Above-mentioned m/v refers to mass and size concentration, and concrete implication comprises the quality (gram) of insoluble protein in quality (gram) or the every liter of process water that obtains after seitan water is concentrated of flocculation agent in every liter of flocculant solution.
Ppm representes the weight of contained solute in the solution of 1,000,000 parts of weight.The weight of the weight/solution of ppm=solute * 10
6Promptly contain 1 kilogram of (liter) solute in the solution of 100 kilograms (liter) like 1ppm.In the present invention, the concrete implication of ppm is that the consumption of flocculant solution in the said process water of 100 kilograms (liter) makes that the amount of flocculation agent is 5-100 kilogram (liter).
According to the present invention, process water and flocculant solution blended condition can be comprised blended time and blended temperature, for example, the said blended time can be 1-10 minute, more preferably 1-5 minute; Said blended temperature can be 30-70 ℃, more preferably 40-60 ℃.In order to make process water and flocculant solution blended more even, said process water and mixing preferably of flocculant solution are under agitation carried out.
According to the present invention, do not limit process water and flocculant solution blended mode are special, for example, can be static mixing, also can be dynamic mixing, also or the combination of two kinds of hybrid modes.Wherein, said static mixing can for: process water and flocculant solution at container, as are left standstill and mix in the equipment and leave standstill; Said dynamic mixing can for: will in another transport pipe, converge with being incorporated in the flow process from the process water of different transport pipes and flocculant solution and mix; Process water and flocculant solution are mixed through line mixer, and this mixture is delivered in the equipment of leaving standstill leaves standstill.
According to the present invention, with process water mix with flocculant solution and will by the flocculation and/or the isolating method of settled insoluble protein be the method for dissolved air flotation.To be the micro-bubble that utilizes high dispersing go in the adhesion process water by flocculation and/or settled seitan particle as carrier the method for said dissolved air flotation, makes its density float to the water surface on less than water, realizes process of solid-liquid separation.According to the present invention, the method for said dissolved air flotation comprises with process water and flocculant solution blended simultaneously or afterwards, in mixture, blasts air, makes the bubble adhesion that is formed by flocculation and/or settled seitan particle and with bubble floating.Wherein, As long as in mixture, blast conditions of air can with by flocculation and/or settled seitan particle by the bubble adhesion that forms by the air that feeds and with bubble floating; Forming the air supporting layer gets final product; Under the preferable case, the pressure of bubbling air can be the 0.2-0.4 MPa, and the size of bubble can be the 15-30 micron usually.The air supporting time can be 1-10 minute, is preferably 4-7 minute.
According to the present invention, can adopt various existing airfloat equipments to realize solid-liquid separation, will be for example, can utilize air flotation slot to carry out dissolved air flotation, the principle of promptly utilizing different suspensions of material and absorption bubble (gas molecule) is with seitan particle and water sepn.For example; The mixture of process water and the flocculant solution feed end by air flotation slot is got into, and aeration pump input gas electricity gets into the feed end of air flotation slot, and the gas that gets into air flotation slot is formed in the bubble diffusion bullet liquid by aeration head; Throw out and/or sediment that these bubbles will get into air flotation zone adhere to; And upwards floating along with flowing, and can not with the starch granules of bubble incorporation along with flowing gradually to settle, water obtains clarification gradually.The seitan particle that swims in the upper strata in a large number gathers and is called the higher liquid of concentration; Peeled by stripper plate from the air flotation slot discharge end then; And can filter; Downward gradually sedimentary starch granules is drawn when reaching finite concentration flows back to other operation, the air flotation slot middle part be clarifying process water, the dry matter content of the process water after the processing is below 1.3%.
According to the present invention, this method can also comprise the step that isolated insoluble protein is dehydrated.Said method that dehydrates and condition all can adopt method well known in the art and condition to carry out.For example, the exsiccant mode can be seasoning, forced air drying, the drying mode of various routines such as vacuum-drying.Said exsiccant condition can comprise that the exsiccant temperature is 80-100 ℃, and the exsiccant time can be 1-5 hour.
According to the present invention, the spissated method of seitan water can for example, be utilized the principle of spinning for various concentrated modes well known in the art, adopt disc separator that seitan water is concentrated, enriched material flows out from underflow, and stream flows out process water from the top.The solid content of the insoluble protein in the enriched material is generally 8-12 weight %.
In the present invention, the light water that contains insoluble protein mutually that obtains after referring to the corn coarse starch milk separated of said seitan water.
According to the present invention, the method that corn grain is soaked can adopt the method for well known to a person skilled in the art, for example, under 50-55 ℃, is that the sulfurous acid aqueous solution of 0.1-0.5 weight % contacts 48-52 hour with corn particle and concentration.Can make its each integral part loose with sulfurous acid soaking corn grain; Weaken mutual contact; Sulfurous acid can also destroy the protein net, makes the semipermeable partition of corn grain epidermis become permeable membrane, quickens and promote to permeate and diffusion; Make a large amount of water absorption and swellings of corn grain, softening, the great amount of soluble protein dissolution can further be processed into steeping water in soak solution.
According to the present invention, the corn grain that will pass through immersion takes off embryo, and the method for isolating plumule also can be carried out according to the method for well known to a person skilled in the art; For example, utilize corn degerming mill (TCM920), make the corn grain that gets into degerming mill under action of centrifugal force, get into the moving of band double wedge and decide between tooth plate; Because two dishes are done rotation relatively; And close outside dredging in recessed tooth is on dish, maize germ, scurf and endosperm are because of the fragmentation in various degree of the different quilts of physical property, and be separated from one another.Because the specific density of plumule and rest part is different, under action of centrifugal force, the free plumule is separated.
According to the present invention; The corn grain tissue that contains maize peel and endosperm that will take off behind the embryo grinds; Isolate the method for fiber and also can carry out, for example, utilize the impact grinding of pin type to grind according to the method for well known to a person skilled in the art; At moving pin that receives high speed rotating and the fixed strong bump in repeated multiple times ground of deciding pin, most starch and fiber get loose and dissociate out.The thickness slag ratio generally can be 2.5-3: 1.Though the starch through after grinding has been unbound state, but still mixes with fibrous residue, owing to varying in size of several kinds of material particles; The screening plant that therefore, can utilize different apertures with fiber by separating in the farinaceous size, in said farinaceous size; The size of starch granules is generally the 3-30 micron; The particle size of fine-fibered is generally more than 65 microns in the fibrous residue, and the robust fibre slag becomes big sheet, and the seitan particle size is generally the 1-2 micron.Said screening plant can be various screening plants, for example, and trommel, oscillating flat sieve, centrifugal screen etc.
According to the present invention, the coarse starch milk that obtains separated obtaining seitan water and milk of starch, and the method that milk of starch washs can be carried out for method well known in the art.For example, milk of starch and the isolating principle of seitan mainly utilize specific density and the particle size of these two kinds of materials different and separate, and for example, can adopt settling process or centrifuging to separate.
To further describe in detail the present invention through specific embodiment below, following examples only are used to explain the present invention, but are not used for limiting scope of the present invention.
The model of air flotation slot is FXP300 * 600, so self-control preferably provides available from institute of Wuhan grain section.
Adopt disc separator that seitan water is concentrated among the following embodiment, enriched material flows out from underflow, and stream flows out process water from the top; The model of used disc-type separating centrifuge is DPF520.
The measuring method of the concentration of insoluble protein is an Oven Method in the process water that obtains after seitan water is concentrated.
Adopt GB/T 5009.5-1985 to measure with the protein content in the feed that obtains behind the filtration cakes torrefaction (butt with feed is a benchmark).
ROHM flocculation agent, ZX-I flocculation agent and flocculant of polymeric aluminium chloride used among the following embodiment are respectively available from Shanghai sounds of nature bio tech ltd and Gongyi City's material for water treatment factory.
Embodiment 1
Present embodiment is used to explain the preparation method of W-Gum provided by the invention.
(1) raw materials pretreatment
Maize raw material (water cut 14 weight %) through chapelet carry get into successively receiving sieve, tramp iron separator, plane rotation cleaning screen, except that cleaning sections such as stone, magnetic separation;
(2) soak
To purify and remove infusion system with the waterpower conveying after the back corn measures, and carry out adverse current with the sulfurous acid aqueous solution and soak.Soaking filling is 10, in 10 steeping tanks, adds 50 tons of maize raw materials after the above-mentioned purification respectively, and the time of immersion is 48 hours, and the temperature of immersion is 50 ± 2 ℃;
(3) take off embryo
Corn after soaking is got into the wet corn hopper by the wet corn transferpump through rockover remover; Get into the one-level degerming mill again; Corn is broken into the 4-6 lobe; Contain shaping corn amount and be no more than 1 weight %, and tell the plumule of the 75-89 weight % of plumule total amount, discharge the starch of the 20-25 weight % of total starch content simultaneously;
Corn after the fragmentation is pumped to the plumule primary cyclone with plumule, and the effusive plumule in separator top removes washing system, and the underflow thing gets into the secondary degerming mill; Corn is broken for the 10-12 lobe; In this slurry, do not contain whole kernel corn, the plumule that is in bonding state is no more than 0.3 weight %, and the slurry of process secondary breaking is pumped into secondary plumule cyclone separator through plumule; Top stream thing gets into one-level germ separation device again, and underflow slurry is gone into the fine grinding operation;
(4) grind
The underflow grout that process secondary cyclone separator is isolated behind the plumule passes through pressure curved sieve, and screen underflow is a coarse starch milk; Screen overflow gets into impact grinding (or pin mill) and carries out fine grinding, dissociates out with the free starch that itself and fiber are connect, and in the feasible slurry after grinding of the condition of pin mill, connects starch and is not more than 10 weight %;
Slurry after the fine grinding gets into the fiber wash groove, delivers to first step pressure curved sieve at these washing water with later washing the fibre.Screen underflow is isolated coarse starch milk, and through the countercurrent washing of the bent sieve of 6 stage pressures, washing process water adds before the last step sieve screen overflow again; Through compass screen surface, carrying the free starch that washs and moving forward step by step, before first step sieve in the rinse bath; Merge with the slurry after the fine grinding, get into first step pressure curved sieve jointly, tell coarse starch milk; The screen underflow coarse starch milk that this milk of starch and fine grinding fore worker are told converges, and gets into the starch separation circuit.Fiber on the compass screen surface, skin slag and washing water are gone against the stream, and,, after washing screening several times, discharge from the bent sieve of last step to each sieve is mobile later on from first sieve, dewater through screw extrusion press then;
(5) milk of starch is refining
The bent screening from the thick starch that obtains after sand separator, revolving filter are removed impurity from the fine grinding front and back; Get into primary separation machine (disc separator); The overflow substance that top stream is discharged is rare seitan water; Should carry out concentration in rare seitan entering seitan separation thickner, obtaining solid content is enriched material and the process water of 9-12 weight %, enriched material is dried down through the vacuum filter dehydration and at 95 ℃ obtain feed (10 weight % moisture); Process water is carried out following processing:
(1) process water [insoluble protein concentration is 1.85% (m/v)] that obtains after seitan water being concentrated 1000L places reaction kettle.
(2) be that 6,000,000 ZX-I flocculation agent is soluble in water with number-average molecular weight, make the mass and size specific concentration and be 0.05% solution; Poly aluminum Chloride (PAC) (n is 1-5, m≤10, basicity B=n/6 * 100%) is soluble in water, make the mass and size specific concentration and be 5% polymeric aluminum chlorides solution.And under 50 ℃; In the above-mentioned process water that obtains after seitan water is concentrated, add above-mentioned two kinds of flocculant aqueous solutions; The consumption of said ZX-I flocculant aqueous solution (25L) makes that the amount of ZX-I flocculation agent in process water is 12.5ppm; The consumption of the said flocculant of polymeric aluminium chloride aqueous solution (1L) makes that the amount of flocculant of polymeric aluminium chloride in process water is 50ppm, mixes 0.5 minute.
(3) mixed solution that step (2) is obtained is inserted and is carried out dissolved air flotation (pressure of bubbling air is 0.3 MPa, and the air supporting time can be 5 minutes) in the air flotation slot, and the dry matter content of the process water that obtains is 1.35 weight %, and separation upper strata seitan particle also filters.
(4) the seitan cake of particles that step (3) is obtained is dried down at 95 ℃ and is obtained feed (10 weight % moisture), and the protein content that gets in the feed with the butt instrumentation is 60% (m/m).
The starch concentration that obtains from elementary separating centrifuge underflow is 19-20 ° of Be '; And the moisture about 60 weight % of purified starch breast after 12 grades of swirler-washings; Protein contnt is less than 0.35 weight %; Smart milk of starch obtains the wet starch of moisture 38-40 weight % after dehydration, wet starch is sent into pneumatic drier and is dried to the commodity starch finished product.
Embodiment 2
Present embodiment is used to explain the preparation method of W-Gum provided by the invention.
Method according to embodiment 1 prepares W-Gum, and different is, in the milk of starch treating process:
(1) process water [insoluble protein concentration is 1.96% (m/v)] that obtains after seitan water being concentrated 1000L places reaction kettle.
(2) be that 8,000,000 ROHM flocculation agent is soluble in water with number-average molecular weight, make the mass and size specific concentration and be 0.05% solution; Poly aluminum Chloride (PAC) (n is 1-5, m≤10, basicity B=n/6 * 100%) is soluble in water, make the mass and size specific concentration and be 5% polymeric aluminum chlorides solution.And under 40 ℃; In the above-mentioned process water that obtains after seitan water is concentrated, add above-mentioned two kinds of flocculant aqueous solutions; The consumption of said ROHM flocculant aqueous solution (25L) makes that the amount of ROHM flocculation agent in process water is 12.5ppm; The consumption of the said flocculant of polymeric aluminium chloride aqueous solution (1L) makes that the amount of flocculant of polymeric aluminium chloride in process water is 50ppm, mixes 3 minutes.
(3) mixed solution that step (2) is obtained is inserted and is carried out dissolved air flotation (pressure of bubbling air is 0.4 MPa, and the air supporting time can be 8 minutes) in the air flotation slot, and the dry matter content of the process water that obtains is 1.29 weight %, and separation upper strata seitan particle also filters.
(4) the seitan cake of particles that step (3) is obtained is dried down at 95 ℃ and is obtained feed (10 weight % moisture), and the protein content that gets in the feed with the butt instrumentation is 58% (m/m).
Embodiment 3
Present embodiment is used to explain the preparation method of W-Gum provided by the invention.
Method according to embodiment 1 prepares W-Gum; Different is; When the process water that obtains after seitan water is concentrated is carried out albumen sepn; The consumption of said ZX-I flocculant aqueous solution (30L) makes that the amount of ZX-I flocculation agent in process water is 15ppm, and the consumption (0.9L) of the said flocculant of polymeric aluminium chloride aqueous solution in process water makes that the amount of flocculant of polymeric aluminium chloride is 45ppm, and the dry matter content of the water that obtains after the filtration is 1.32 weight %.Filter cake is obtained the protein content 61% (m/m) in the feed 90 ℃ of following dryings.
Embodiment 4
Present embodiment is used to explain the preparation method of W-Gum provided by the invention.
Method according to embodiment 2 prepares W-Gum; Different is; When the process water that obtains after seitan water is concentrated is carried out albumen sepn, with flocculant aqueous solution with seitan water is concentrated after the process water blended mode that obtains be the aqueous solution of adding Poly aluminum Chloride (PAC) earlier, and mixed 2 minutes; And then add the polyacrylic aqueous solution, mixed 1 minute.The dry matter content of the process water that obtains is 1.23 weight %, and separation upper strata seitan also filters, and is 62% (m/m) with filter cake at the protein content that 90 ℃ of following dryings obtain in the feed.
Embodiment 5
Present embodiment is used to explain the preparation method of W-Gum provided by the invention.
Method according to embodiment 2 prepares W-Gum; Different is; When the process water that obtains after seitan water is concentrated is carried out albumen sepn, with flocculant aqueous solution with seitan water is concentrated after the process water blended mode that obtains be the aqueous solution of adding Poly aluminum Chloride (PAC) earlier, and mixed 2 minutes; And then add the polyacrylic aqueous solution, mixed 1 minute; The consumption (4L) of the aqueous solution of said Poly aluminum Chloride (PAC) (the mass and size specific concentration of Poly aluminum Chloride (PAC) is 2%) makes that the amount of flocculation agent in process water is 80ppm, and the consumption (20L) of the aqueous solution of said ROHM (polyacrylic mass and size specific concentration is 0.2%) makes that the amount of flocculation agent in process water is 40ppm.The dry matter content of the process water that obtains is 1.25 weight %, and separation upper strata seitan also filters, and is 60% (m/m) with filter cake at the protein content that 90 ℃ of following dryings obtain in the feed.
Embodiment 6
Present embodiment is used to explain the preparation method of W-Gum provided by the invention.
Method according to embodiment 2 prepares W-Gum; Different is; When the process water that obtains after seitan water is concentrated is carried out albumen sepn, with flocculant aqueous solution with seitan water is concentrated after the process water blended mode that obtains be the aqueous solution of adding Poly aluminum Chloride (PAC) earlier, and mixed 2 minutes; And then add the polyacrylic aqueous solution, mixed 1 minute; The consumption (3L) of the aqueous solution of said Poly aluminum Chloride (PAC) (the mass and size specific concentration of Poly aluminum Chloride (PAC) is 1%) makes that the amount of flocculation agent in process water is 30ppm, and the consumption (15L) of the said polyacrylic aqueous solution (polyacrylic mass and size specific concentration is 0.1%) makes that the amount of flocculation agent in process water is 15ppm.The dry matter content of the process water that obtains is 1.27 weight %, and separation upper strata seitan also filters, and is 59% (m/m) with filter cake at the protein content that 90 ℃ of following dryings obtain in the feed.
Embodiment 7
Present embodiment is used to explain the preparation method of W-Gum provided by the invention.
Method according to embodiment 2 prepares W-Gum; Different is; When the process water that obtains after seitan water is concentrated is carried out albumen sepn; The consumption (0.8L) of the aqueous solution of said Poly aluminum Chloride (PAC) (the mass and size specific concentration of Poly aluminum Chloride (PAC) is 5%) makes that the amount of flocculation agent in process water is 40ppm, and the consumption (80L) of the said polyacrylic aqueous solution (polyacrylic mass and size specific concentration is 0.05%) makes that the amount of flocculation agent in process water is 40ppm.The dry matter content of the process water that obtains is 1.38 weight %.Is 60% (m/m) with filter cake at the protein content that 90 ℃ of following dryings obtain in the feed.
Can find out by the foregoing description; Insoluble protein in the process water that obtains after adopting method of the present invention effectively to separate seitan water concentrated; Simultaneously can improve filtration velocity; And the quality of the fodder that obtains is better, with make after the albumen flocculation process water once more the reuse circulation corn is soaked and plumule, fiber is washed, can reach basically and soak with fresh water and the effect of washing.
Claims (13)
1. the preparation method of a W-Gum, this method comprises soaks corn grain, and the corn grain that will pass through immersion carries out fragmentation; Isolate plumule, the corn grain tissue that contains maize peel and endosperm that will take off behind the embryo grinds, and isolates fiber; The coarse starch milk that obtains separated obtaining seitan water and milk of starch, and milk of starch is washed, it is characterized in that; The treatment process of said seitan water comprises seitan water concentrated, obtains enriched material and process water, contains insoluble protein in the said process water; Process water is mixed with flocculant solution, and the promoting the circulation of qi of going forward side by side is floating to be separated; Said flocculation agent is for making insoluble protein flocculation and/or the settled material in the process water.
2. method according to claim 1, wherein, said flocculant solution is the aqueous solution of flocculation agent, said flocculation agent is ROHM and/or ZX-I and Poly aluminum Chloride (PAC).
3. method according to claim 2, wherein, said polyacrylic number-average molecular weight is 6,000,000-1,000 ten thousand dalton, the number-average molecular weight of said ZX-I is 6,000,000-1,000 ten thousand dalton; The molecular formula of said Poly aluminum Chloride (PAC) is [Al
2(OH)
nCl
6-n]
m, wherein, n is 1-5, m≤10, basicity B=n/6 * 100%.
4. method according to claim 2 wherein, comprises earlier the aqueous solution with said process water and Poly aluminum Chloride (PAC) with process water and flocculant solution method of mixing, again with the aqueous solution of ROHM and/or ZX-I; The mass ratio of Poly aluminum Chloride (PAC) and ROHM and/or ZX-I is 2-5.
5. method according to claim 4 wherein, after the aqueous solution with process water and Poly aluminum Chloride (PAC), before the aqueous solution of ROHM and/or ZX-I, also comprises the step of stirring, and the time of said stirring is 1-5 minute.
6. method according to claim 4; Wherein, The mass and size concentration of insoluble protein is 1.5-1.9% in the said process water; The consumption of said flocculant solution makes that ROHM and the amount of ZX-I flocculation agent in said process water are 5-50ppm, makes that the amount of flocculant of polymeric aluminium chloride in said process water is 20-100ppm.
7. method according to claim 6, wherein, the mass and size concentration of ROHM and ZX-I flocculant solution is 0.1-0.5%, the mass and size concentration of flocculant of polymeric aluminium chloride solution is 1-5%.
8. according to claim 1 or 4 described methods, wherein, said process water and mixing under agitation of flocculant solution to be carried out, the blended temperature is 30-70 ℃, the blended time is 1-10 minute.
9. method according to claim 1; Wherein, The method of said dissolved air flotation comprises with process water and flocculant solution blended simultaneously or afterwards, in mixture, blasts air, makes the bubble adhesion that is formed by flocculation and/or settled seitan particle and with bubble floating.
10. method according to claim 9, wherein, the pressure of bubbling air is the 0.2-0.4 MPa, the air supporting time is 1-10 minute.
11. method according to claim 1, wherein, this method also comprises the step that isolated insoluble protein is dehydrated.
12. method according to claim 1, wherein, the light water that contains insoluble protein mutually that said seitan water obtains after referring to the corn coarse starch milk separated.
13. method according to claim 1, wherein, the method that corn grain is soaked is included under 50-55 ℃, is that the sulfurous acid aqueous solution of 0.1-0.5 weight % contacts 48-52 hour with corn particle and concentration.
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| CN104151447A (en) * | 2014-08-26 | 2014-11-19 | 淮安麦德森制药有限公司 | Method for removing impurities from chondroitin sulfate enzymatic hydrolysate |
| CN104672299A (en) * | 2013-11-28 | 2015-06-03 | 中粮营养健康研究院有限公司 | Corn starch process water protein recovery technique |
| CN106905439A (en) * | 2017-04-13 | 2017-06-30 | 潍坊盛泰药业有限公司 | A kind of protein treatment process in Starch Production |
| CN107501419A (en) * | 2017-08-25 | 2017-12-22 | 山东西王糖业有限公司 | A kind of production technology and process units of refined corn starch milk |
| CN109384853A (en) * | 2018-09-29 | 2019-02-26 | 高雯友 | A kind of preparation method of buckwheat starch |
| CN109651516A (en) * | 2018-12-21 | 2019-04-19 | 北安象屿金谷生化科技有限公司 | A kind of dolantin Asia raw material cornstarch processing technology |
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