CN102451117B - Cleansing composition - Google Patents
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- CN102451117B CN102451117B CN201010516314.9A CN201010516314A CN102451117B CN 102451117 B CN102451117 B CN 102451117B CN 201010516314 A CN201010516314 A CN 201010516314A CN 102451117 B CN102451117 B CN 102451117B
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Abstract
The invention provides a kind of cleansing composition, it has than the better cleaning strength of prior art and foaming characteristic.Cleansing composition of the present invention contains: (A) anion surfactant; (B) Fructus oleae europaeae fruit oil; Wherein, described composition (A) is 1000/1 ~ 100/1 with the weight ratio of described composition (B).
Description
Technical field
The present invention relates to and there is excellent foaming characteristic and the cleansing composition of cleaning strength.
Background technology
At present, during in order to suppress to clean, hair withered after the friction of hair and drying, has coordinated various hair care ingredient in the hair shampoo composition containing various surfactant.But when with the use of hair care ingredient, the bubble performance of foaming power, alveolar substance, bubble stability etc. can be deteriorated sometimes.
And, similarly, in the abluent except hair cleansing composition, in order to improve its use sense on skin, the nursing composition of oil preparation etc. can be coordinated wherein.But now, as described above, also have the problem that foaming power, alveolar substance etc. decline.
Such as, in order to improve foaming characteristic, propose at present to coordinate and there is the cleansing composition (Japanese Patent No. 3403367 publication, Japanese Patent No. 423759 publication, Japanese Patent No. 3371098 publication) that carbon number is single glycerin ether of the alkyl of the straight or branched of 4 ~ 9.
But in these techniques, the raising effect of foaming characteristic not enough.
On the other hand, known oil preparation has the effect of control foaming usually, and thus people never expected being coupled in cleansing composition by the oil preparation as nursing composition to improve foaming characteristic so far.
Summary of the invention
Therefore, the present invention makes in view of technical problem as above, and object is to provide a kind of cleansing composition, and it not only has nursing efficacy but also has better foaming characteristic than prior art.
The present inventor finds: by using anion surfactant and the such nursing oil of Fructus oleae europaeae fruit oil with specific ratio combine, thus while giving nursing efficacy to cleansing composition, can also give excellent cleaning strength and foaming characteristic.
That is, the invention provides a kind of cleansing composition, it contains following composition (A) and (B):
(A) anion surfactant,
(B) Fructus oleae europaeae fruit oil,
Wherein, described composition (A) is 1000/1 ~ 100/1 with the weight ratio of described composition (B).
Detailed description of the invention
composition (A)
As the anion surfactant of the composition used in the present invention (A), can enumerate: alkyl sulfate, polyoxyalkylene alkyl sulfate, 2-Sulfosuccinic acid alkanol ester salt (alkylsulfosuccinates), polyoxyalkylene 2-Sulfosuccinic acid alkanol ester salt, polyoxyalkylene alkyl phenyl ether sulfate, higher fatty acid salt and their mixture etc. there is the anion surfactant that carbon number is the alkyl of 8 ~ 18.As above-mentioned salt, sodium salt, potassium salt, calcium salt, magnesium salt, alkanolamine, ammonium salt, alkylamine salt etc. can be enumerated.
From the view point of improve composition (A) and the compatibility of composition (B) and plays by these compositions and use the viewpoint of the cooperative effect obtained and, improve cleaning strength and the foaming characteristic of cleansing composition, as composition of the present invention (A), be preferably the alkyl sulfate or polyoxyethylene (E.O.) alkyl ether sulfate that represent with following general formula (1).
RO(CH
2CH
2O)
aSO
3M(1)
(in formula, R represents that carbon number is 8 ~ 18, is preferably the alkyl or alkenyl of the straight or branched of 10 ~ 16, and a represents the integer in 0 ~ 5, and M represents alkali metal, alkaline-earth metal, ammonium, alkanolamine, alkylamine etc.).
Specifically, as the alkyl sulfate that above-mentioned general formula (1) represents, can enumerate: octyl sulfate (C8), decyl sulfate (C10), lauryl sulfate (C12), myristyl sulfate (C14), cetyl sulfate (C16), stearin-based sulfate (C18), oleyl sulfate (C18) etc.
As the polyoxyethylene alkyl ether sulfate salt that above-mentioned general formula (1) represents, sodium laureth sulfate, polyoxyethylene myristyl ether sodium sulfate, Polyoxyethylene cetyl ether sodium sulfate, polyoxyethylene stearyl base ether sodium sulfate, polyoxyethylene oleyl ether sodium sulfate, polyoxyethylene decyl ethers sodium sulfate, potassium laureth sulfate, polyoxyethylene lauryl ether ammonium sulfate, polyoxyethylene lauryl ether sulphuric acid triethanol ammonium etc. can be enumerated.
As composition of the present invention (A), also can use following sulfuric acid based anion surfactant: wherein containing represented by above-mentioned general formula (1) respectively, the a=0 of 30 ~ 45 % by weight time sulfate, 18 ~ 27 % by weight a=1 time sulfate, 10 ~ 20 % by weight a=2 time sulfate and more than the a=3 of surplus time sulfate, and the content of sulfate during a=0 ~ 2 is wherein more than 70 % by weight.
As composition (A), two or more above-mentioned anion surfactants can be combinationally used.From the view point of the viewpoint of the cleaning strength and foaming characteristic of improving cleansing composition and, the compatibility of composition (A) and composition (B), composition (A) content in cleansing composition of the present invention is preferably 5 ~ 50 % by weight, be more preferably 8 ~ 30 % by weight, be particularly preferably 10 ~ 22 % by weight.
composition (B)
From the view point of cleaning strength and the foaming characteristic of improving cleansing composition, cleansing composition of the present invention contains composition (B) Fructus oleae europaeae fruit oil (INCI name: OleaEuropaea (Olive) FruitOil, CASRN:8001-25-0).
Known oil preparation is usually used as nursing composition and be engaged in abluent, and known its has the effect of control foaming usually.But, the present inventor by experiment (such as, RossMilesTest) find: composition of the present invention (B) be generally used for giving compared with the GE-ID (isodecyl glyceryl ether) of foaming characteristic to cleansing composition, can to the more excellent foaming characteristic of cleansing composition imparting.
The olive oil fatty glyceride that composition of the present invention (B) represents containing following general formula (2) is as constituent.
[in formula, R
1, R
2, R
3represent that carbon number is the olive oil fatty acid alkyl of 15 ~ 19 respectively.]
As the fatty acid forming the olive oil fatty glyceride that above-mentioned general formula (2) represents, Palmic acid, palmitic olefinic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, arachidic acid etc. can be listed.
As the example of composition of the present invention (B), CropureOL (CrodaJapanKK) can be enumerated, CropureOlive (Croda, Inc.), CrodaOlive (CrodaChemicals), OliveFruitExtract (Nanjing Kang Manlin chemical industry Industrial Co., Ltd. (NanjingChemlinChemicalIndustryCo., Ltd.)), OliveOil (Aldiva), OliveOil (InternationalCosmeticScienceCentre), OliveOil (Provital), OliveOil-ECO (Provital) etc.Wherein preferred CropureOL (CrodaJapanKK) and CropureOlive (Croda, Inc.).
In addition, such as, can by carrying out taking from the fruit (oil content 40 ~ 60%) of Chinese olive tree and utilizing common extracting method to carry out extracting and refine and obtain the method etc. of Fructus oleae europaeae fruit oil, manufacture obtains composition of the present invention (B).The color of Fructus oleae europaeae fruit oil is viridescent faint yellow for being with, and it has special fragrance, can provide edible without refining (taste removal).And as cosmetic material, due in the crude oil adopted containing colloid, pigment, trace meter, odour component and other impurity, in storage or use procedure, their can accelerating oxidation and rotten, is thus necessary they fully refining removings.Therefore, can comprise in the refining step of the manufacture method of composition of the present invention (B) come unstuck, alkali refining, decolouring, deodorization etc. operation (list of references: new edition " oil product knowledge (good fortune study) " etc.).
From the view point of the viewpoint of the cleaning strength and foaming characteristic of improving cleansing composition and, the compatibility of composition (A) and composition (B), the content of composition (B) the Fructus oleae europaeae fruit oil in cleansing composition of the present invention is preferably 0.005 ~ 0.5 % by weight, be more preferably 0.008 ~ 0.3 % by weight, be particularly preferably 0.01 ~ 0.22 % by weight.
Further, composition of the present invention (A) is 1000/1 ~ 100/1 with the weight ratio (A/B) of composition (B), is preferably 900/1 ~ 100/1, is more preferably 200/1 ~ 100/1.When weight ratio (A/B) is in 1000/1 ~ 100/1 scope, the foam number that method described in aftermentioned embodiment measures the cleansing composition obtained can reach more than 170mL, thus can obtain the cleansing composition with excellent foaming characteristic.
From the view point of cleaning strength and the foaming characteristic of improving cleansing composition further, cleansing composition of the present invention is preferably: containing following composition (A) and (B):
(A) anion surfactant, 5 ~ 50 % by weight
(B) Fructus oleae europaeae fruit oil, 0.005 ~ 0.5 % by weight
Wherein, described composition (A) is 1000/1 ~ 100/1 with the weight ratio of described composition (B).
Cleansing composition of the present invention is more preferably: containing following composition (A) and (B):
(A) anion surfactant, 8 ~ 30 % by weight
(B) Fructus oleae europaeae fruit oil, 0.008 ~ 0.3 % by weight
Wherein, described composition (A) is 1000/1 ~ 100/1 with the weight ratio of described composition (B).
Cleansing composition of the present invention is particularly preferably: containing following composition (A) and (B):
(A) anion surfactant, 10 ~ 22 % by weight
(B) Fructus oleae europaeae fruit oil, 0.01 ~ 0.22 % by weight
Wherein, described composition (A) is 1000/1 ~ 100/1 with the weight ratio of described composition (B).
composition (C)
In cleansing composition of the present invention, composition (C) can also be contained further and be selected from least one organic acid in hydroxy carboxylic acid and dicarboxylic acids.In the organic acid of composition (C), as dicarboxylic acids, malonic acid, succinic acid, 1,3-propanedicarboxylic acid, adipic acid, maleic acid, fumaric acid, phthalic acid, oxalic acid etc. can be enumerated; As hydroxy carboxylic acid, glycolic, lactic acid, hydroxy acrylic acid, hydroxybutyric acid, glyceric acid, malic acid, tartaric acid, citric acid, hydroxyacetic acid etc. can be enumerated.
In these organic acid, from the view point of cleaning strength and the foaming characteristic of improving cleansing composition, preferred malonic acid, succinic acid, 1,3-propanedicarboxylic acid, adipic acid, maleic acid, fumaric acid, phthalic acid, oxalic acid, malic acid, tartaric acid, glycolic, lactic acid, hydroxy acrylic acid, hydroxyacetic acid, glyceric acid, more preferably maleic acid, malic acid, lactic acid, glycolic, particularly preferably malic acid.
As composition (C), two or more above-mentioned organic acid can be combinationally used.From the view point of the viewpoint of the cleaning strength and foaming characteristic of improving cleansing composition further and, the stability of cleansing composition, relative to the total amount of cleansing composition of the present invention, the content of composition (C) is preferably 0.1 ~ 5 % by weight, be preferably 0.1 ~ 3 % by weight, be more preferably 0.1 ~ 0.75 % by weight.
other composition
(1) aromatic alcohols
From the view point of improving sense of touch, cleansing composition of the present invention is preferably also containing aromatic alcohols.As aromatic alcohols, benzyl alcohol, benzyl oxyethanol and phenyl phenol etc. can be enumerated, particularly preferably benzyl alcohol and benzyl oxyethanol.
Two or more aromatic alcohols can be combinationally used.The content of aromatic alcohols in cleansing composition of the present invention is preferably 0.01 ~ 20 % by weight, is more preferably 0.01 ~ 10 % by weight, is particularly preferably 0.5 ~ 5 % by weight.
(2) other surfactant
In order to improve foam performance further, in cleansing composition of the present invention, also containing the surfactant except composition (A), such as, can be selected from the surfactant in non-ionic surface active agent and amphoteric surfactant.
As non-ionic surface active agent, polyoxyalkene sorbitan fatty acid ester, polyoxyalkylene sorbitan polyol fatty acid esters, polyoxyalkylene glycerine fatty acid esters, polyoxyalkylene fatty acid ester class, polyoxyalkylene alkyl class, polyoxyalkylene alkyl phenyl ethers, polyoxyalkylene (sclerosis) Semen Ricini oils, sucrose-fatty esters, poly-alkyl glycerol ethers, polyglycerol fatty acid glyceride type, fatty acid alkanol amides, alkyl glucosides glycoside etc. can be enumerated.Wherein, alkyl glucosides glycoside, polyoxyalkylene (C is preferably
8~ C
20) fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene hardened castor oil, fatty acid alkanol amides.As fatty acid alkanol amides, preferably have carbon number be 8 ~ 18, particularly preferably carbon number be the fatty acid alkanol amides of the acyl group of 10 ~ 16.As fatty acid alkanol amides, both can be monoalkylol amide, also can be di alkanolamide; The fatty acid alkanol amides of the hydroxyalkyl preferably containing 2 ~ 3 carbon atoms, such as, oleic acid diethyl amide, palm kernel oil fatty diglycollic amide, cocoanut fatty acid diethanolamide, lauric acid diethyl amide, polyoxyethylene coconut fatty acid oil single ethanol amide, coconut oil fatty acid monoethanolamide, lauric isopropropanolamide, lauric monoethanolamide etc. can be enumerated.
As amphoteric surfactant, betaine type amphoteric surfactant etc. can be enumerated.In these betaine type amphoteric surfactants, the more preferably betaine type amphoteric surfactant of alkyl dimethyl oxyneurine, fatty acid amide propyl betanin etc., particularly preferably fatty acid amide propyl betanin.Fatty acid amide propyl betanin is preferably and is 8 ~ 18 containing carbon number, is particularly preferably the fatty acid amide propyl betanin of the acyl group of 10 ~ 16; Particularly preferably lauric amide CAB, palm kernel oil fatty acid amide propyl betanin, coco-nut oil fatty acid amido propyl betaine, lauryl hydroxyl sulfo betaine etc.
These surfactants except composition (A) can be coupled in cleansing composition of the present invention as required.When cleansing composition of the present invention is formulated into the form of waterborne liquid shape abluent, it is particularly preferred for fatty acid amide propyl betanin or fatty acid alkanol amides being combinationally used together with composition (A), because this not only can improve foaming capacity further, also can obtain suitable characteristics of liquids simultaneously.
When as mentioned above containing fatty acid amide propyl betanin or fatty acid alkanol amides, its content in cleansing composition of the present invention is preferably 0.1 ~ 10 % by weight, be more preferably 1 ~ 8 % by weight, be particularly preferably 2 ~ 6 % by weight, because good foam enhancing effect can be obtained like this.
(3) silicone
In order to obtain high nursing efficacy, silicone can also be coordinated in cleansing composition of the present invention.As silicone, can following substances be enumerated:
(a) dimethyl polysiloxane
Include, for example the dimethyl polysiloxane shown in following general formula:
(Me)
3Si-[(Me)
2SiO]
d-Si(Me)
3
[in formula, Me represents methyl, and d represents the numeral between 3 ~ 20000].
(b) amino modified silicone
Various amino modified silicone can be used, but the particularly preferably amino modified silicone in CTFA dictionary (" cosmetic ingredient dictionary " (CosmeticIngredientDictionary), the U.S.) third edition with " amino dimethicone (Amodimethicone) " named of mean molecule quantity between about 3000 ~ 100000.This amino modified silicone preferably uses with the form of water-based emulsion, its commercially available product can enumerate SM8704C (DowCorningToraySiliconeCo., Ltd. make) and DC929 (DowCorningToraySiliconeCo., Ltd. system) etc.
(c) other silicone
In addition to the foregoing, polyether modified silicone, methyl phenyl silicone, fatty acid modified silicone, alcohol modified silicone, alkoxy-modified silicone, epoxide modified silicone, fluorine richness silicone, cyclic silicone, alkyl-modified silicone etc. can also be enumerated.
Two or more above-mentioned silicones can be combinationally used.Their content is preferably in cleansing composition of the present invention 0.01 ~ 20 % by weight, is more preferably 0.1 ~ 10 % by weight, is particularly preferably 0.1 ~ 5 % by weight.
(4) aliphatic higher alcohol
In order to improve stability, foam slickness and modify sense, also can contain aliphatic higher alcohol further in cleansing composition of the present invention.As aliphatic higher alcohol, preferably containing straight or branched, be particularly preferably straight chain, carbon number is 12 ~ 22, is particularly preferably the aliphatic higher alcohol of the alkyl of 12 ~ 18.More specifically, lauryl alcohol, myristyl alcohol and spermol, stearyl alcohol can be enumerated, particularly preferably stearyl alcohol.
Two or more above-mentioned aliphatic higher alcohols can be combinationally used.The content of aliphatic higher alcohol in cleansing composition of the present invention is preferably 0.05 ~ 5 % by weight, is more preferably 0.1 ~ 3 % by weight, is particularly preferably 0.5 ~ 2 % by weight.
(5) other composition
In cleansing composition of the present invention, except mentioned component, according to application target, can also suitably coordinate the composition used in common cleansing composition.As such composition, can enumerate, such as: dandruff removing agent; Vitamin; Antibacterial; Antiinflammatory; Antiseptic; Chelating agen; The wetting agent of propylene glycol, glycerol, TC, sorbitol and panthenol etc.; The coloring agent of dyestuff and pigment etc.; The viscosity modifier of hydroxyethyl-cellulose, methylcellulose, Polyethylene Glycol, ethanol and clay mineral etc.; The pH adjusting agent of sodium hydroxide etc.; Plant extract class; Pearling agent; Spice; Color element; UV absorbent; Antioxidant; And other " shampoo composition encyclopedia (ENCYCLOPEDIAOFSHAMPOOINGREDIENTS)) composition of describing in (MICELLE publishing house).
cleansing composition
From the view point of viewpoint and the suppression stimulation of the foaming characteristic and stability of improving cleansing composition, cleansing composition of the present invention be diluted with water to 20 times of weight time pH value (25 DEG C) be 1 ~ 4, be preferably pH2 ~ 4, be especially preferably pH3 ~ 4.
When measuring by the method recorded in embodiment described later, the foam number being diluted to the solution of 20 times of weight of every 100mL of cleansing composition of the present invention is more than 170mL, is particularly preferably more than 190mL.
The form of cleansing composition of the present invention suitably can be selected from aqueous, Powdered, gel, graininess etc., and preferably uses water or lower alcohol as the aqueous form of solvent, is particularly preferably the aqueous form using water.
Cleansing composition of the present invention according to usual method manufacture, such as, can be suitable as the hair abluent and health abluent etc. of shampoo, body detergent, facial agent, hand lotion etc.
Embodiment
Embodiment 1 ~ 22 and comparative example 1 ~ 5
There is according to usual method preparation the cleansing composition of the composition shown in table 1 and pH value, and their foaming characteristic is evaluated.Result represents in Table 1 in the lump.The each composition of numeric representation of the content of each composition shown in table 1 is relative to the weight percentage (% by weight) of the total amount of cleansing composition.
(evaluation methodology)
Foaming characteristic
Prepare the aqueous solution of the dilution 20 times of cleansing composition, this solution 100mL (liquid temperature 40 DEG C) is injected the graduated cylinder of 1000mL.Then, 4 pieces of agitators are set in this solution, after stirring 30 seconds with 1000r/min, measure the foam long-pending (mL) generated and be used as foam number, evaluate according to following standard.Reversion in an every 5 seconds agitator.
I: foam number is more than 200mL
II: foam number is more than 190mL and is less than 200mL
III: foam number is more than 170mL and is less than 190mL
IV: foam number is more than 150mL and is less than 170mL
V: foam number is less than 150mL
The cleansing composition of above-described embodiment 1 ~ 22 all has excellent foaming characteristic (foam number is more than 170mL).Corresponding thereto, do not coordinate the comparative example 1 ~ 3 of Fructus oleae europaeae fruit oil, its foaming characteristic all poor (foam number is less than 150mL).Further, the weight ratio of A/B is that the comparative example 4 of 20/1 (outside the scope of A/B of the present invention) also show poor foaming characteristic (foam number is less than 150mL).Further, the weight ratio of A/B is that the comparative example 5 of 2000/1 (outside the scope of A/B of the present invention) also show poor foaming characteristic (foam number is less than 150mL).
the effect of invention
Cleansing composition of the present invention not only has nursing efficacy but also has excellent cleaning strength and foaming characteristic.
Claims (26)
1. a cleansing composition, is characterized in that:
Containing following composition (A), (B) and (C):
(A) anion surfactant,
(B) Fructus oleae europaeae fruit oil,
(C) organic acid of at least one in malonic acid, succinic acid, 1,3-propanedicarboxylic acid, adipic acid, maleic acid, fumaric acid, phthalic acid, oxalic acid, malic acid, tartaric acid, glycolic, lactic acid and glyceric acid is selected from,
Wherein, described composition (A) is 1000/1 ~ 100/1 with the weight ratio of described composition (B).
2. cleansing composition as claimed in claim 1, is characterized in that:
Described composition (A) is selected from least one in alkyl sulfate, polyoxyalkylene alkyl sulfate, 2-Sulfosuccinic acid alkanol ester salt, polyoxyalkylene 2-Sulfosuccinic acid alkanol ester salt, polyoxyalkylene alkyl phenyl ether sulfate and higher fatty acid salt.
3. cleansing composition as claimed in claim 1, is characterized in that:
Relative to the total amount of described cleansing composition, the content of described composition (A) is 5 ~ 50 % by weight.
4. cleansing composition as claimed in claim 1, is characterized in that:
Relative to the total amount of described cleansing composition, the content of described composition (A) is 8 ~ 30 % by weight.
5. cleansing composition as claimed in claim 1, is characterized in that:
Relative to the total amount of described cleansing composition, the content of described composition (A) is 10 ~ 22 % by weight.
6. cleansing composition as claimed in claim 1, is characterized in that:
Relative to the total amount of described cleansing composition, the content of described composition (B) is 0.005 ~ 0.5 % by weight.
7. cleansing composition as claimed in claim 1, is characterized in that:
Relative to the total amount of described cleansing composition, the content of described composition (B) is 0.008 ~ 0.3 % by weight.
8. cleansing composition as claimed in claim 1, is characterized in that:
Relative to the total amount of described cleansing composition, the content of described composition (B) is 0.01 ~ 0.22 % by weight.
9. cleansing composition as claimed in claim 1, is characterized in that:
Relative to the total amount of described cleansing composition, the content of described composition (C) is 0.1 ~ 5 % by weight.
10. cleansing composition as claimed in claim 1, is characterized in that:
Relative to the total amount of described cleansing composition, the content of described composition (C) is 0.1 ~ 3 % by weight.
11. cleansing compositions as claimed in claim 1, is characterized in that:
Relative to the total amount of described cleansing composition, the content of described composition (C) is 0.1 ~ 0.75 % by weight.
12. cleansing compositions as claimed in claim 1, is characterized in that:
Described composition (A) is 900/1 ~ 100/1 with the weight ratio of described composition (B).
13. cleansing compositions as claimed in claim 1, is characterized in that:
Described composition (A) is 200/1 ~ 100/1 with the weight ratio of described composition (B).
14. cleansing compositions as claimed in claim 1, is characterized in that:
Described composition (A) is 1000/1 ~ 900/1 with the weight ratio of described composition (B).
15. cleansing compositions as claimed in claim 1, is characterized in that:
When being diluted with water to 20 times of weight, the pH value of described cleansing composition at 25 DEG C is 1 ~ 4.
16. cleansing compositions as claimed in claim 1, is characterized in that:
When being diluted with water to 20 times of weight, the pH value of described cleansing composition at 25 DEG C is 2 ~ 4.
17. cleansing compositions as claimed in claim 1, is characterized in that:
When being diluted with water to 20 times of weight, the pH value of described cleansing composition at 25 DEG C is 3 ~ 4.
18. cleansing compositions as claimed in claim 1, is characterized in that:
When described cleansing composition is diluted to the solution of 20 times of weight, the foam number of every this solution of 100mL is more than 170mL.
19. Fructus oleae europaeae fruit oil for improving the purposes of the foaming characteristic of cleansing composition, wherein:
Described cleansing composition contains following composition (A), (B) and (C):
(A) anion surfactant,
(B) Fructus oleae europaeae fruit oil,
(C) organic acid of at least one in malonic acid, succinic acid, 1,3-propanedicarboxylic acid, adipic acid, maleic acid, fumaric acid, phthalic acid, oxalic acid, malic acid, tartaric acid, glycolic, lactic acid and glyceric acid is selected from,
Wherein, described composition (A) is 1000/1 ~ 100/1 with the weight ratio of described composition (B).
20. Fructus oleae europaeae fruit oil for improving the purposes of the foaming characteristic of cleansing composition, wherein:
Described cleansing composition contains following composition (A), (B) and (C):
(A) anion surfactant,
(B) Fructus oleae europaeae fruit oil,
(C) organic acid of at least one in malonic acid, succinic acid, 1,3-propanedicarboxylic acid, adipic acid, maleic acid, fumaric acid, phthalic acid, oxalic acid, malic acid, tartaric acid, glycolic, lactic acid and glyceric acid is selected from,
Wherein, described composition (A) is 900/1 ~ 100/1 with the weight ratio of described composition (B).
21. Fructus oleae europaeae fruit oil for improving the purposes of the foaming characteristic of cleansing composition, wherein:
Described cleansing composition contains following composition (A), (B) and (C):
(A) anion surfactant,
(B) Fructus oleae europaeae fruit oil,
(C) organic acid of at least one in malonic acid, succinic acid, 1,3-propanedicarboxylic acid, adipic acid, maleic acid, fumaric acid, phthalic acid, oxalic acid, malic acid, tartaric acid, glycolic, lactic acid and glyceric acid is selected from,
Wherein, described composition (A) is 200/1 ~ 100/1 with the weight ratio of described composition (B).
22. Fructus oleae europaeae fruit oil for improving the purposes of the foaming characteristic of cleansing composition, wherein:
Described cleansing composition contains following composition (A), (B) and (C):
(A) anion surfactant,
(B) Fructus oleae europaeae fruit oil,
(C) organic acid of at least one in malonic acid, succinic acid, 1,3-propanedicarboxylic acid, adipic acid, maleic acid, fumaric acid, phthalic acid, oxalic acid, malic acid, tartaric acid, glycolic, lactic acid and glyceric acid is selected from,
Wherein, described composition (A) is 1000/1 ~ 900/1 with the weight ratio of described composition (B).
23. 1 kinds of compositionss as the purposes of hair abluent, wherein:
Described compositions contains following composition (A), (B), (C) and water:
(A) anion surfactant,
(B) Fructus oleae europaeae fruit oil,
(C) organic acid of at least one in malonic acid, succinic acid, 1,3-propanedicarboxylic acid, adipic acid, maleic acid, fumaric acid, phthalic acid, oxalic acid, malic acid, tartaric acid, glycolic, lactic acid and glyceric acid is selected from,
Wherein, described composition (A) is 1000/1 ~ 100/1 with the weight ratio of described composition (B).
24. 1 kinds of compositionss as the purposes of health abluent, wherein:
Described compositions contains following composition (A), (B), (C) and water:
(A) anion surfactant,
(B) Fructus oleae europaeae fruit oil,
(C) organic acid of at least one in malonic acid, succinic acid, 1,3-propanedicarboxylic acid, adipic acid, maleic acid, fumaric acid, phthalic acid, oxalic acid, malic acid, tartaric acid, glycolic, lactic acid and glyceric acid is selected from,
Wherein, described composition (A) is 1000/1 ~ 100/1 with the weight ratio of described composition (B).
25. 1 kinds of compositionss as the purposes of hair abluent, wherein:
Described compositions contains following composition (A), (B), (C) and water:
(A) anion surfactant,
(B) Fructus oleae europaeae fruit oil,
(C) organic acid of at least one in malonic acid, succinic acid, 1,3-propanedicarboxylic acid, adipic acid, maleic acid, fumaric acid, phthalic acid, oxalic acid, malic acid, tartaric acid, glycolic, lactic acid and glyceric acid is selected from,
Wherein, described composition (A) is 1000/1 ~ 100/1 with the weight ratio of described composition (B), and when being diluted with water to 20 times of weight, the pH value of described compositions at 25 DEG C is 1 ~ 4.
26. 1 kinds of compositionss as the purposes of health abluent, wherein:
Described compositions contains following composition (A), (B), (C) and water:
(A) anion surfactant,
(B) Fructus oleae europaeae fruit oil,
(C) organic acid of at least one in malonic acid, succinic acid, 1,3-propanedicarboxylic acid, adipic acid, maleic acid, fumaric acid, phthalic acid, oxalic acid, malic acid, tartaric acid, glycolic, lactic acid and glyceric acid is selected from,
Wherein, described composition (A) is 1000/1 ~ 100/1 with the weight ratio of described composition (B), and when being diluted with water to 20 times of weight, the pH value of described compositions at 25 DEG C is 1 ~ 4.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010516314.9A CN102451117B (en) | 2010-10-19 | 2010-10-19 | Cleansing composition |
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| CN201010516314.9A CN102451117B (en) | 2010-10-19 | 2010-10-19 | Cleansing composition |
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| CN102451117B true CN102451117B (en) | 2016-04-06 |
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| KR20210082277A (en) | 2015-05-01 | 2021-07-02 | 로레알 | Use of active agents during chemical treatments |
| WO2017091796A1 (en) | 2015-11-24 | 2017-06-01 | L'oreal | Compositions for treating the hair |
| KR20210084681A (en) | 2015-11-24 | 2021-07-07 | 로레알 | Compositions for treating the hair |
| BR112018010381B1 (en) | 2015-11-24 | 2021-08-17 | L'oreal | HAIR TREATMENT COMPOSITION, HAIR TREATMENT SYSTEM, HAIR TREATMENT AND HAIR COLOR CHANGE METHODS, AND MULTI-COMPARTMENT KIT FOR HAIR COLOR OR SHAPE CHANGE |
| US11135150B2 (en) | 2016-11-21 | 2021-10-05 | L'oreal | Compositions and methods for improving the quality of chemically treated hair |
| US9974725B1 (en) | 2017-05-24 | 2018-05-22 | L'oreal | Methods for treating chemically relaxed hair |
| ES2914404T3 (en) | 2017-12-29 | 2022-06-10 | Oreal | Compositions for altering hair color |
| US11090249B2 (en) | 2018-10-31 | 2021-08-17 | L'oreal | Hair treatment compositions, methods, and kits for treating hair |
| US11419809B2 (en) | 2019-06-27 | 2022-08-23 | L'oreal | Hair treatment compositions and methods for treating hair |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1433748A (en) * | 2002-01-21 | 2003-08-06 | 花王株式会社 | Hair cleansing compositions |
| CN101578414A (en) * | 2007-01-04 | 2009-11-11 | 考格尼斯知识产权管理有限责任公司 | Use of aqueous emulsions in the form of foam for the reloading of textiles |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| DE102005010142A1 (en) * | 2005-03-02 | 2005-11-03 | Dr. Kurt Wolff Gmbh & Co. Kg | Composition for activating hair roots, especially to combat androgenetic alopecia, containing synergistic combination of caffeine and plant extract with phyto-estrogenic action |
| EP1975224A1 (en) * | 2007-03-30 | 2008-10-01 | Johnson & Johnson Consumer France SAS | Mild, foaming cleansing composition |
| US20080267899A1 (en) * | 2007-04-30 | 2008-10-30 | Mr. Hamit Leskaj | Plant extract composition for hair growth |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1433748A (en) * | 2002-01-21 | 2003-08-06 | 花王株式会社 | Hair cleansing compositions |
| CN101578414A (en) * | 2007-01-04 | 2009-11-11 | 考格尼斯知识产权管理有限责任公司 | Use of aqueous emulsions in the form of foam for the reloading of textiles |
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| CN102451117A (en) | 2012-05-16 |
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