CN102432286B - Preparation method of aluminum titanate powder by taking metal aluminum as aluminum source through non-hydrolytic sol-gel process at low temperature - Google Patents
Preparation method of aluminum titanate powder by taking metal aluminum as aluminum source through non-hydrolytic sol-gel process at low temperature Download PDFInfo
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 105
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 102
- 239000000843 powder Substances 0.000 title claims abstract description 54
- 230000003301 hydrolyzing effect Effects 0.000 title claims abstract description 14
- 238000003980 solgel method Methods 0.000 title claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 title abstract description 7
- 239000002184 metal Substances 0.000 title abstract description 7
- 229910000505 Al2TiO5 Inorganic materials 0.000 title abstract description 5
- AABBHSMFGKYLKE-SNAWJCMRSA-N propan-2-yl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(C)C AABBHSMFGKYLKE-SNAWJCMRSA-N 0.000 title abstract description 5
- 238000002360 preparation method Methods 0.000 title abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 14
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 12
- 239000002243 precursor Substances 0.000 claims abstract description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 3
- 239000001301 oxygen Substances 0.000 claims abstract description 3
- 239000004411 aluminium Substances 0.000 claims description 94
- 239000000499 gel Substances 0.000 claims description 17
- 238000010992 reflux Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 7
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 5
- 239000011630 iodine Substances 0.000 claims description 5
- 229910052740 iodine Inorganic materials 0.000 claims description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- 229940055858 aluminum chloride anhydrous Drugs 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 4
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 150000001805 chlorine compounds Chemical class 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 2
- 229940073589 magnesium chloride anhydrous Drugs 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 2
- 239000011240 wet gel Substances 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 6
- 238000003786 synthesis reaction Methods 0.000 abstract description 6
- 239000002994 raw material Substances 0.000 abstract description 5
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 1
- -1 aluminum alkoxide Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 10
- 238000005303 weighing Methods 0.000 description 9
- 238000007603 infrared drying Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 238000009413 insulation Methods 0.000 description 6
- 238000007669 thermal treatment Methods 0.000 description 6
- 229940063656 aluminum chloride Drugs 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- 238000009841 combustion method Methods 0.000 description 2
- 229910017053 inorganic salt Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 238000010532 solid phase synthesis reaction Methods 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000156 glass melt Substances 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 229910001387 inorganic aluminate Inorganic materials 0.000 description 1
- 229960002337 magnesium chloride Drugs 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
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Abstract
The invention discloses aluminum titanate powder prepared by taking metal aluminum as an aluminum source through a non-hydrolytic sol-gel process at a low temperature and a preparation method thereof. The metal aluminum and titanium tetrachloride are used as precursor raw materials, anhydrous low-carbon alcohol is used as an oxygen donor, and a proper catalyst is selected to prepare the aluminum titanate powder at the low temperature of 750 DEG C. According to the invention, the metal aluminum is utilized to replace aluminum alkoxide and inorganic aluminum salt as the aluminum source, so the preparation method disclosed by the invention has the outstanding advantages of cheap reaction raw material, simple process, low synthesis temperature and the like, and is suitable for industrial mass production.
Description
Technical field
The present invention relates to the ceramic powder preparing technical field, being specifically related to a kind of is that the non-hydrolytic sol-gel process low temperature in aluminium source prepares the method for aluminium titanates powder with the metallic aluminium.
Background technology
Aluminium titanates integrates low bulk and high temperature resistant premium properties, also have the fusing point height simultaneously, thermal conductivity is low, the coefficient of expansion is little, good thermal shock, erosion resistance be by force and to characteristics such as multiple metal and glass melt do not soak into, have a extensive future in fields such as iron and steel, non-ferrous metal, glass, chemical industry, automobile, war industrys.The aluminium titanates powder is the important starting material of preparation aluminum titanate ceramic material.Selecting cheap reaction raw materials for use, reduce the synthesis temperature of aluminium titanates powder, thereby reach the purpose that reduces production costs, is that aluminum titanate ceramic material can realize industrialization and the key of being used widely.The method for preparing at present the aluminium titanates powder mainly contains solid phase method, combustion method, coprecipitation method, hydrolytic sol-gel process, non-hydrolytic sol-gel process etc.It is raw material that solid phase method directly adopts solid alumina and titanium oxide, generally needs after the mechanically mixing could synthesize the aluminium titanates powder through 1400～1500 ℃ of calcinings; Combustion method need add a large amount of fuel and synthesize aluminium titanates institute energy requirement to provide, and synthesis temperature is more than 1300 ℃; Coprecipitation method need make aluminium, titanium ion precipitation from homogeneous solution by regulating pH value, and control technology is complexity, and synthesis temperature is about 1300 ℃ (see Y. X. Huang, Materials Research Bulletin, 2002, Vol. 37, P99～111) generally; It is tiny that sol-gel method has a particle, be uniformly dispersed, advantages such as stoichiometry is easy to control, but its used precursor material mostly is expensive metal alkoxide greatly, for this reason, it is the method that the synthetic aluminium titanates of hydrolyzed collosol-gelatin technology is used in the aluminium source with the inorganic salt aluminum nitrate that this seminar discloses a kind of in ZL200610005317.X, and it compares to uses aluminium-alcohol salt to do the aluminium source, raw materials cost obviously reduces, but synthesis temperature is up to 1350 ℃; It is the non-hydrolytic sol-gel process of precursor material with inorganic salt aluminum chloride and titanium tetrachloride that this seminar discloses a kind of in ZL200610005316.5, make the synthesis temperature of aluminium titanates be reduced to 750 ℃, but must use Aluminum chloride anhydrous as the aluminium source, and Aluminum chloride anhydrous suction easily itself, it both had been difficult for preservation and also had been not easy to weighing.The present invention directly utilizes metallic aluminium to do the aluminium source, causes non-hydrolytic sol-gel reaction by adding catalyzer, prepares the aluminium titanates powder at 750 ℃ of low temperature, and this is an innovation research achievement of not seeing domestic and international any bibliographical information so far.
Summary of the invention
It is that the non-hydrolytic sol-gel process low temperature in aluminium source prepares the method for aluminium titanates powder with the metallic aluminium that the technical problem to be solved in the present invention provides a kind of.
For solving above technical problem, technical scheme of the present invention is: a kind of is that the non-hydrolytic sol-gel process low temperature in aluminium source prepares the method for aluminium titanates powder with the metallic aluminium, be presoma with metallic aluminium and titanium tetrachloride, be oxygen donor with the anhydrous low-carbon alcohol, with Anhydrous Ferric Chloride, Aluminum chloride anhydrous, the anhydrous chlorides of rase zirconium, in Magnesium Chloride Anhydrous and the iodine one or more are catalyzer, described metallic aluminium, titanium tetrachloride, low-carbon alcohol and catalyzer, by mole per-cent 2:1:(8～38): (0.01～0.25), adopt the synthetic aluminium titanates powder that obtains of non-hydrolytic sol-gel process low temperature;
May further comprise the steps:
(1) in stink cupboard, measure a certain amount of low-carbon alcohol and put into dry wide-necked bottle, wide-necked bottle is placed cooling bath, add amount of metallic aluminum then therein;
(2) measure a certain amount of titanium tetrachloride by the stoichiometric ratio of aluminium titanates with transfer pipet, slowly it is splashed in the wide-necked bottle that fills low-carbon alcohol and metallic aluminium, the back that stirs adds a certain amount of catalyzer, finally forms the presoma mixed solution;
(3) precursor mixed solution backflow certain hour under the condition of oil bath heating is formed wet gel, after super-dry, obtain xerogel;
(4) the aluminium titanates xerogel obtains the aluminium titanates powder through grinding, calcining;
The preferred dehydrated alcohol of described low-carbon alcohol, propyl carbinol or Virahol.
Described metallic aluminium is aluminium powder, aluminium bits or aluminium flake.
Described reflux temperature is 70～130 ℃, and return time is 7～24 hours.
The calcining temperature of described dry gel powder is 750 ℃, is incubated 30 ~ 60 minutes.
The present invention adopts metallic aluminium as the aluminium source in the world first, ingenious hydrogen chloride emission and the catalyzer that utilizes titanium tetrachloride and low-carbon alcohol reaction to form, impel the activation of metallic aluminium, make it be converted into aluminum chloride, successfully prepare the aluminium titanates powder by non-hydrolytic sol-gel process at 750 ℃.Compare with using aluminium-alcohol salt or inorganic aluminate, the metallic aluminium cost is lower, and easier preservation and weighing, improves the synthetic effect of aluminium titanates.
Description of drawings
Fig. 1 is process flow sheet of the present invention.
Embodiment
The present invention is further detailed explanation below in conjunction with accompanying drawing 1 and embodiment.
Embodiment 1
Take by weighing the 1.9683g aluminium powder and put into the dry Erlenmeyer flask that the 22ml dehydrated alcohol is housed, measure the 4ml titanium tetrachloride with transfer pipet by the stoichiometric ratio of aluminium titanates and slowly splash into this Erlenmeyer flask, add 0.59g iron(ic) chloride again, after the vigorous stirring this Erlenmeyer flask put into 80 ℃ of oil baths, condensing reflux 7h, obtain the aluminium titanates precursor mixture, obtain the aluminium titanates dry gel powder through 3 hours infrared dryings.Dry gel powder is ground, through 750 ℃ of insulations thermal treatment in 30 minutes, namely obtain aluminium titanates powder of the present invention.
Embodiment 2
Take by weighing the 1.9683g aluminium powder and put into the dry Erlenmeyer flask that the 22ml dehydrated alcohol is housed, measure the 4ml titanium tetrachloride with transfer pipet by the stoichiometric ratio of aluminium titanates and slowly splash into this Erlenmeyer flask, add 0.95g aluminum chloride again, after the vigorous stirring this Erlenmeyer flask put into 110 ℃ of oil baths, condensing reflux 15h, obtain the aluminium titanates precursor mixture, obtain the aluminium titanates dry gel powder through 3 hours infrared dryings.Dry gel powder is ground, through 750 ℃ of insulations thermal treatment in 60 minutes, namely obtain aluminium titanates powder of the present invention.
Embodiment 3
Take by weighing the 1.9683g aluminium powder and put into the dry Erlenmeyer flask that the 24ml anhydrous isopropyl alcohol is housed, measure the 4ml titanium tetrachloride with transfer pipet by the stoichiometric ratio of aluminium titanates and slowly splash into this Erlenmeyer flask, add 0.1g iodine again, after the vigorous stirring this Erlenmeyer flask put into 130 ℃ of oil baths, condensing reflux 24h, obtain the aluminium titanates precursor mixture, obtain the aluminium titanates dry gel powder through 3 hours infrared dryings.Dry gel powder is ground, through 750 ℃ of insulations thermal treatment in 60 minutes, namely obtain aluminium titanates powder of the present invention.
Embodiment 4
Take by weighing the 2.948g aluminium powder and put into the dry Erlenmeyer flask that the 40ml dehydrated alcohol is housed, measure the 6ml titanium tetrachloride with transfer pipet by the stoichiometric ratio of aluminium titanates and slowly splash into this Erlenmeyer flask, add 1.2g aluminum chloride again, after the vigorous stirring this Erlenmeyer flask put into 80 ℃ of oil baths, condensing reflux 15h, obtain the aluminium titanates precursor mixture, obtain the aluminium titanates dry gel powder through 3 hours infrared dryings.Dry gel powder is ground, namely obtain aluminium titanates powder of the present invention.
Embodiment 5
Take by weighing the 2.948g aluminium powder and put into the dry Erlenmeyer flask that the 80ml propyl carbinol is housed, measure the 6ml titanium tetrachloride with transfer pipet by the stoichiometric ratio of aluminium titanates and slowly splash into this Erlenmeyer flask, add 0.18g iodine again, after the vigorous stirring this Erlenmeyer flask put into 80 ℃ of oil baths, condensing reflux 15h, obtain the aluminium titanates precursor mixture, obtain the aluminium titanates dry gel powder through 3 hours infrared dryings.Dry gel powder is ground, through 750 ℃ of insulations thermal treatment in 30 minutes, namely obtain aluminium titanates powder of the present invention.
Embodiment 6
Take by weighing the 2.948g aluminium powder and put into the dry Erlenmeyer flask that the 80ml dehydrated alcohol is housed, measure the 6ml titanium tetrachloride with transfer pipet by the stoichiometric ratio of aluminium titanates and slowly splash into this Erlenmeyer flask, add 0.3g iodine and 0.4g zirconium chloride again, after the vigorous stirring this Erlenmeyer flask put into 110 ℃ of oil baths, condensing reflux 15h, obtain the aluminium titanates precursor mixture, obtain the aluminium titanates dry gel powder through 3 hours infrared dryings.Dry gel powder is ground, through 750 ℃ of insulations thermal treatment in 30 minutes, namely obtain aluminium titanates powder of the present invention.
Embodiment 7
Take by weighing the 2.948g aluminium powder and put into the dry Erlenmeyer flask that the 80ml dehydrated alcohol is housed, measure the 6ml titanium tetrachloride with transfer pipet by the stoichiometric ratio of aluminium titanates and slowly splash into this Erlenmeyer flask, add 1.7g aluminum chloride and 0.65g magnesium chloride again, after the vigorous stirring this Erlenmeyer flask put into 80 ℃ of oil baths, condensing reflux 15h, obtain the aluminium titanates precursor mixture, obtain the aluminium titanates dry gel powder through 3 hours infrared dryings.Dry gel powder is ground, through 750 ℃ of insulations thermal treatment in 30 minutes, namely obtain aluminium titanates powder of the present invention.
Claims (2)
1. one kind is that the non-hydrolytic sol-gel process low temperature in aluminium source prepares the method for aluminium titanates powder with the metallic aluminium, it is characterized in that: be presoma with metallic aluminium and titanium tetrachloride, anhydrous low-carbon alcohol is oxygen donor, in Anhydrous Ferric Chloride, Aluminum chloride anhydrous, anhydrous chlorides of rase zirconium, Magnesium Chloride Anhydrous and the iodine one or more are catalyzer, described metallic aluminium, titanium tetrachloride, low-carbon alcohol and catalyzer, by mole per-cent 2:1:8～38:0.01～0.25, adopt the synthetic aluminium titanates powder that obtains of non-hydrolytic sol-gel process low temperature;
May further comprise the steps:
(1) in stink cupboard, measure a certain amount of low-carbon alcohol and put into dry wide-necked bottle, wide-necked bottle is placed cooling bath, add amount of metallic aluminum then therein;
(2) measure a certain amount of titanium tetrachloride by the stoichiometric ratio of aluminium titanates with transfer pipet, slowly it is splashed in the wide-necked bottle that fills low-carbon alcohol and metallic aluminium, the back that stirs adds a certain amount of catalyzer, finally forms the presoma mixed solution;
(3) precursor mixed solution backflow certain hour under the condition of oil bath heating is formed wet gel, after super-dry, obtain xerogel;
(4) the aluminium titanates xerogel obtains the aluminium titanates powder through grinding, calcining;
The preferred dehydrated alcohol of described low-carbon alcohol, propyl carbinol or Virahol.
2. the method for preparing the aluminium titanates powder according to claim 1 is characterized in that: described metallic aluminium is aluminium powder, aluminium bits or aluminium flake.
3, the method for preparing the aluminium titanates powder according to claim 1 is characterized in that: described reflux temperature is 70～130 ℃, and return time is 7～24 hours.
4, the method for preparing the aluminium titanates powder according to claim 1 is characterized in that: the calcining temperature of described dry gel powder is 750 ℃, is incubated 30 ~ 60 minutes.
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| CN104556216B (en) * | 2014-12-29 | 2016-05-04 | 景德镇陶瓷学院 | A kind of method that adopts non-hydrolytic sol-gel process to prepare Barium Titanate nano-powder |
| CN105271337B (en) * | 2015-10-21 | 2017-03-08 | 景德镇陶瓷大学 | A kind of method that alumina ultrafine powder body is prepared using non-aqueous depositing technology |
| CN106045523B (en) * | 2016-07-29 | 2018-07-06 | 张宁 | A kind of method based on Bayer process production aluminum nitride ceramic powder |
| CN115231904B (en) * | 2022-08-03 | 2023-11-17 | 景德镇陶瓷大学 | Method for preparing ceramic powder by non-solvent replacement non-aqueous precipitation process |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1803718A (en) * | 2006-01-12 | 2006-07-19 | 景德镇陶瓷学院 | Method for synthesizing composite oxide powder by non-hydrolytic sol-gel process with alcohol as oxygen donor |
| CN101696030A (en) * | 2009-08-18 | 2010-04-21 | 景德镇陶瓷学院 | Method for preparing stabilizing aluminum titanate at low temperature by non-hydrolytic sol-gel process |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1803718A (en) * | 2006-01-12 | 2006-07-19 | 景德镇陶瓷学院 | Method for synthesizing composite oxide powder by non-hydrolytic sol-gel process with alcohol as oxygen donor |
| CN101696030A (en) * | 2009-08-18 | 2010-04-21 | 景德镇陶瓷学院 | Method for preparing stabilizing aluminum titanate at low temperature by non-hydrolytic sol-gel process |
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| Title |
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| 江伟辉等.非水解溶胶-凝胶法低温制备铁稳定钛酸铝粉体.《人工晶体学报》.2011,第40卷(第2期),455-469. |
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