CN102408208A - Autoclaved/steam cured brick prepared from industrial waste and preparation process thereof - Google Patents

Autoclaved/steam cured brick prepared from industrial waste and preparation process thereof Download PDF

Info

Publication number
CN102408208A
CN102408208A CN2011102313100A CN201110231310A CN102408208A CN 102408208 A CN102408208 A CN 102408208A CN 2011102313100 A CN2011102313100 A CN 2011102313100A CN 201110231310 A CN201110231310 A CN 201110231310A CN 102408208 A CN102408208 A CN 102408208A
Authority
CN
China
Prior art keywords
slag
brick
discarded
grout
exciting agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2011102313100A
Other languages
Chinese (zh)
Other versions
CN102408208B (en
Inventor
徐志平
陈诚
陈承岭
刘诚
王来水
叶正茂
常钧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANDONG PINGAN CONSTRUCTION GROUP CO Ltd
Original Assignee
SHANDONG PINGAN CONSTRUCTION GROUP CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANDONG PINGAN CONSTRUCTION GROUP CO Ltd filed Critical SHANDONG PINGAN CONSTRUCTION GROUP CO Ltd
Priority to CN2011102313100A priority Critical patent/CN102408208B/en
Publication of CN102408208A publication Critical patent/CN102408208A/en
Application granted granted Critical
Publication of CN102408208B publication Critical patent/CN102408208B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Processing Of Solid Wastes (AREA)

Abstract

The invention relates to an autoclaved/steam cured brick prepared from industrial waste, which relates to the technical field of recovery and utilization of industrial waste. Raw materials for the brick comprises, by weight, 15 to 25% of waste cement mortar, 40 to 60% of slag, 10 to 30% of medium sand and 5 to 20% of broken stone, wherein, the slag contains 0.2 to 0.5 wt % of an exciting agent, in which the weight ratio of sodium silicate to sodium sulfate to sodium formate is 1:1:0.5. A preparation process comprises the following steps: stirring of the raw materials; pressing and molding, wherein, pressure for molding is 8 to 10 MPa, and time for molding is 25 to 30 s; maintaining with steam. The invention has the following advantages: the preparation process is simple, a production period is short, treatment cost is saved, pollution of waste to environment is avoided, and cost for making bricks is reduced; the exciting agent is added, a formula for the exciting agent is simple, the exciting agent can play a role in excitation and gelatinization and has no specific requirements for density and fluidity of waste cement mortar, process procedures are reduced, and all the properties of the prepared autoclaved/steam cured brick are excellent.

Description

Utilize the steaming pressure/steamed brick and the preparation technology thereof of trade waste preparation
Technical field
The present invention relates to trade waste recovery and utilization technology field, particularly a kind of steaming pressure/steamed brick that utilizes trade waste preparation also relates to the preparation technology of said steaming pressure/steamed brick.
Background technology
Along with the develop rapidly of urbanization process, industry and covil construction increase day by day, and the clay common brick need consume a large amount of clays, is prohibited employing by country at present.Each is made brick enterprise and adopts diverse ways to produce fragment of brick one after another.Wherein more representational non-burning brick be coagulating cement cob brick and the steam-cured brick of flyash, the brick of these kinds adopts cement, flyash, sandstone, lime and part admixture to add the compression moulding of water method of mixing.Yet along with non-burning brick applying, manufacturing enterprise and quantity constantly increase, dog-eat-dog.Simultaneously, because raw-material prices such as cement rise steadily, make coagulating cement cob brick cost increase.
Prestressed concrete pipe pile is a kind of precast concrete pile that embodies contemporary concrete technology progress and the high-new state of the art of concrete product; Because bearing capacity of single pile is high, the design Selection scope is wide, strong to geographical conditions flexibility, pile extension fast reaches advantages such as inexpensive, prestressed concrete pipe pile has obtained fast development.But when producing prestressed concrete pipe pile, can produce a large amount of wastes; In the high speed centrifugation moulding process, can throw away a large amount of discarded liquid on the one hand; The alkaline water mud that promptly mainly contains cement and water reducer, this grout will hydration and hardening as not utilizing fast at short notice.The method of usually conduct is to treat its coagulation forming now, stacks landfill after the hand breaking, the higher and contaminate environment of this method cost.On the other hand, for providing the prestressed concrete pipe pile maintenance required autoclaved condition, need to consume a large amount of coals, this just certainly will produce a large amount of slags, and the stacking of slag is contaminate environment not only, and is a kind of waste to resource.
As far back as the nineties in last century, the manufacturing that cinder and cement is used for brick is just arranged, be 92104144.6 Chinese invention patent application like application number, a kind of hollow brick that uses slag, cement, unslaked lime to make is just disclosed.
The Chinese invention patent of application number 201010152472.0 discloses a kind of method of utilizing residual slurry of tubular pile to produce concrete brick; But the mode of nature or water curing is taked in the preparation of brick; Production cycle is long; The brick performance has just reached general request for utilization, and described residual slurry of tubular pile need measure density and degree of mobilization in use, has caused the puzzlement that the manufacturing cycle is long, increase cost to production.
The patent No. is that 00113848.0 Chinese invention patent discloses a kind of compound activator that is mixed by lightweight water glass, plaster of Paris, calcined lime and Sodium sulfate anhydrous.min(99); Can improve the add-on of industrial residue in the cement production process; Enhance competitiveness; But the prescription of compound activator is complicated, and the mechanism of action is complicated, uses limitation bigger.
The patent No. is 98125624.4 Chinese invention patent application, discloses a kind of lightweight non-sintered bricks made from coal cinders that contains cement, slag, quicklime, calcium sulfate, sodium sulfate, water glass, Sodium Silicofluoride 98min, and additive types is complicated, is unfavorable for producing.
Therefore, comprehensive utilization pile tube factory waste produces various aspects of performance all than more excellent and cost is low, with short production cycle, the simple brick of technology is a problem that needs to be resolved hurrily.
Summary of the invention
In order to address the above problem, the invention provides a kind of various aspects of performance of utilizing discarded grout of pile tube and slag all than steaming pressure/steamed brick more excellent and that cost is low, with short production cycle.
The present invention also provides the preparatory technology of said steaming pressure/steamed brick.
The present invention realizes through following measure:
A kind of steaming pressure/steamed brick that utilizes the trade waste preparation, raw materials used weight percent is following:
Discarded grout 15-25%, slag 40-60%, medium sand 10-30%, rubble 5-20%,
Wherein discarded grout is the discarded liquid that when producing prestressed concrete pipe pile, throws away in the centrifugal forming process;
Slag is the solid residue of coal combustion, and particle diameter is 1-5mm, wherein contains the exciting agent of 0.2-0.5wt%, and exciting agent is that water glass, sodium sulfate mix with weight ratio 1:1:0.5 with calcium formiate and obtains.
Said medium sand is that fineness modulus is the sand of 2.3-3.0.
Said ballast grain sizes is not more than 15mm.
The described preparation technology who utilizes the steaming pressure/steamed brick of trade waste preparation may further comprise the steps:
(1) batching: the order of raw material according to slag, medium sand and rubble added, stir the back and add discarded grout, stir;
(2) moulding: the starting material that mix are utilized press-forming machine compression moulding, and forming pressure maintains 8-10MPa, and molding time is controlled at 25-30s, wherein pressurize 10-15s;
(3) vapor cure: with formed green brick maintenance 4-8h, curing condition is 20 ± 5 ℃, relative humidity >=65%.
Also comprise step (4) steam press maintenance: the time is 4-8 h, and water vapour pressure is 0.5-1.0 MPa, and temperature is 210-230 ℃.
With after slag, medium sand and the rubble adding, 140r/min stirs 20-30s in the step (1), and middling speed 285r/min stirs 90-140s behind the discarded grout of adding.
Beneficial effect of the present invention:
1, the preparation technology of steaming pressure/steamed brick of the present invention fully utilizes the discarded grout and the slag of pile tube factory; Production technique is simple; With short production cycle, not only saved of the processing costs of pile tube manufacturing enterprise to discarded grout and slag, avoided the pollution of waste to environment; And utilize discarded grout and slag as gelling material and aggregate, reduced the cost of brickmaking;
2, owing in the preparation process, added exciting agent, the exciting agent prescription is simple, can play to excite and the agglomerative effect; So density and mobile no specific requirement to discarded grout; Reduced process procedure, the steaming pressure/steamed brick of preparation, each item excellent performance.
Embodiment
For a better understanding of the present invention, further specify below in conjunction with specific embodiment.
Embodiment 1
A kind of steaming pressure/steamed brick that utilizes the trade waste preparation, raw materials used weight proportion is following:
Discarded grout 15%, slag 35%, medium sand 30%, rubble 20%,
Collect discarded grout and slag respectively from pile tube production plant and boiler house and be transported to the steamed brick production plant; Wherein discarded grout is the discarded liquid that when producing prestressed concrete pipe pile, throws away in the high speed centrifugation moulding process, and slag is the solid residue of coal combustion, after slag is handled through airing; Be crushed to particle diameter 1-5 mm; The exciting agent that adds 0.2wt%, exciting agent are that water glass, sodium sulfate mix with weight ratio 1:1:0.5 with calcium formiate and obtains
Medium sand is that fineness modulus is the sand of 2.3-3.0;
The maximum particle diameter of rubble is not more than 10mm.
Utilize the preparation technology of the steaming pressure/steamed brick of trade waste preparation, may further comprise the steps:
(1) batching: raw material is added according to the order of slag, medium sand and rubble, add discarded grout after stirring 30s at a slow speed with 140r/min, middling speed 285r/min stirs 140s;
(2) moulding: the starting material that mix are utilized press-forming machine compression moulding, and forming pressure maintains 8MPa, and molding time is controlled at 25s, wherein pressurize 10s;
(3) vapor cure: with formed green brick maintenance 4h, curing condition is 25 ℃, relative humidity 65%.
Embodiment 2
A kind of steaming pressure/steamed brick that utilizes the trade waste preparation is characterized in that raw materials used weight proportion is following:
Discarded grout 25%, slag 60%, medium sand 10%, rubble 5%,
Collect discarded grout respectively from pile tube production plant and boiler house and be transported to the steamed brick production plant with slag, slag through the airing processing after, be crushed to particle diameter 1-5 mm.Sand adopts medium sand, and stone adopts rubble, and the maximum particle diameter of rubble is not more than 15 mm.Wherein discarded grout is the discarded liquid that when producing prestressed concrete pipe pile, throws away in the high speed centrifugation moulding process;
Slag is the solid residue of coal combustion, and particle diameter is 1-5mm, wherein contains the exciting agent of 0.5wt%, and exciting agent is that water glass, sodium sulfate mix with weight ratio 1:1:0.5 with calcium formiate and obtains; Medium sand is that fineness modulus is the sand of 2.3-3.0;
Ballast grain sizes is not more than 15mm.
Utilize the preparation technology of the steaming pressure/steamed brick of trade waste preparation, may further comprise the steps:
(1) batching: raw material added according to the order of slag, medium sand and rubble add discarded grout after 140r/min stirs 20-s at a slow speed, middling speed 285r/min stirs 90s;
(2) moulding: the starting material that mix are utilized press-forming machine compression moulding, and forming pressure maintains 10MPa, and molding time is controlled at 30s, wherein pressurize 15s;
(3) vapor cure: with formed green brick maintenance 8h, curing condition is 15 ℃, relative humidity 70%.
(4) steam press maintenance: the time is 4 h, and water vapour pressure is 1.0 MPa, and temperature is 230 ℃.
The comparative example 1
Control Example 1 does not add exciting agent in the slag, other raw material selections are with the product of 1 same batch of embodiment, and consumption and preparation technology are identical with embodiment 1.
The comparative example 2
Control Example 2 does not add exciting agent in the slag, other raw material selections are with the product of 2 same batches of embodiment, and consumption and preparation technology are identical with embodiment 2.
Performance Detection
Steaming pressure/steamed brick Performance Detection the index that embodiment 1,2 and comparative example 1,2 prepare sees the following form 1.
Steaming pressure/steamed brick performance comparison the table that table 1 embodiment 1,2 and comparative example 1,2 prepare
Above-mentioned test item all detects according to the test item of GB/T21144-2007 concrete solid brick.
Can know by table 1; Steaming pressure/the steamed brick of embodiment 1 and embodiment 2 preparations; Comparison is all to improve a lot from maximum water-intake rate, ultimate compression strength or frost resistance quality or loss of strength aspect than embodiment 1 and comparative example's 2 performance; It is thus clear that exciting agent of the present invention is fine to the improved performance effect of steaming pressure/steamed brick.

Claims (6)

1. steaming pressure/steamed brick that utilizes trade waste preparation is characterized in that raw materials used weight percent is following:
Discarded grout 15-25%, slag 40-60%, medium sand 10-30%, rubble 5-20%,
Wherein discarded grout is the discarded liquid that when producing prestressed concrete pipe pile, throws away in the centrifugal forming process;
Slag is the solid residue of coal combustion, and particle diameter is 1-5mm, wherein contains the exciting agent of 0.2-0.5wt%, and exciting agent is that water glass, sodium sulfate mix with weight ratio 1:1:0.5 with calcium formiate and obtains.
2. steaming pressure/steamed brick according to claim 1 is characterized in that said medium sand is that fineness modulus is the sand of 2.3-3.0.
3. steaming pressure/steamed brick according to claim 1 is characterized in that said ballast grain sizes is not more than 15mm.
4. each described preparation technology who utilizes the steaming pressure/steamed brick of trade waste preparation of a claim 1-3 is characterized in that may further comprise the steps:
(1) batching: the order of raw material according to slag, medium sand and rubble added, stir the back and add discarded grout, stir;
(2) moulding: the starting material that mix are utilized press-forming machine compression moulding, and forming pressure maintains 8-10MPa, and molding time is controlled at 25-30s, wherein pressurize 10-15s;
(3) vapor cure: with formed green brick maintenance 4-8h, curing condition is 20 ± 5 ℃, relative humidity >=65%.
5. preparation technology according to claim 4, it is characterized in that also comprising step (4) steam press maintenance: the time is 4-8 h, and water vapour pressure is 0.5-1.0 MPa, and temperature is 210-230 ℃.
6. preparation technology according to claim 4, after it is characterized in that in the step (1) slag, medium sand and rubble added, 140r/min stirs 20-30s, adds middling speed 285r/min stirring 90-140s behind the discarded grout.
CN2011102313100A 2011-08-12 2011-08-12 Autoclaved/steam cured brick prepared from industrial waste and preparation process thereof Expired - Fee Related CN102408208B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011102313100A CN102408208B (en) 2011-08-12 2011-08-12 Autoclaved/steam cured brick prepared from industrial waste and preparation process thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011102313100A CN102408208B (en) 2011-08-12 2011-08-12 Autoclaved/steam cured brick prepared from industrial waste and preparation process thereof

Publications (2)

Publication Number Publication Date
CN102408208A true CN102408208A (en) 2012-04-11
CN102408208B CN102408208B (en) 2013-08-14

Family

ID=45910605

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2011102313100A Expired - Fee Related CN102408208B (en) 2011-08-12 2011-08-12 Autoclaved/steam cured brick prepared from industrial waste and preparation process thereof

Country Status (1)

Country Link
CN (1) CN102408208B (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104355660A (en) * 2014-10-13 2015-02-18 合肥庭索环保材料有限公司 Preparation method of insulation board doped with blast furnace slag
CN105235061A (en) * 2015-08-20 2016-01-13 洛阳佳一机电设备有限公司 Production system and process method for preparing aerated bricks through waste slurry
CN107522461A (en) * 2017-07-31 2017-12-29 铜陵丰泽建材科技有限公司 A kind of preparation method of resistance to cracking fly ash autoclaved brick
CN108751823A (en) * 2018-08-13 2018-11-06 成都尚威耐火材料有限公司 A kind of solid waste material is non-burning brick and preparation method thereof
CN108911608A (en) * 2018-08-24 2018-11-30 肇庆市珈旺环境技术研究院 A kind of autoclaved lime-sand brick and preparation method thereof
CN109231901A (en) * 2018-10-11 2019-01-18 十九冶成都建设有限公司 High-titanium blast furnace slag concrete laitance recoverying and utilizing method
CN117700191A (en) * 2023-12-13 2024-03-15 河海大学 Baking-free brick of full solid waste system based on waste slurry and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101486550A (en) * 2008-01-16 2009-07-22 新立基(北京)建材有限公司 Domestic garbage prefabricated part and method of manufacturing the same
CN101875211A (en) * 2010-04-21 2010-11-03 宁波市镇海永恒建材厂 Method for producing concrete brick by using residual slurry of tubular pile

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101486550A (en) * 2008-01-16 2009-07-22 新立基(北京)建材有限公司 Domestic garbage prefabricated part and method of manufacturing the same
CN101875211A (en) * 2010-04-21 2010-11-03 宁波市镇海永恒建材厂 Method for producing concrete brick by using residual slurry of tubular pile

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
王新民等: "《深井矿山充填理论与技术》", 30 April 2005, article "早强剂", pages: 109 *
闫振甲等: "《免烧砖生产实用技术》", 30 April 2009, article "免烧砖", pages: 4-88 *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104355660A (en) * 2014-10-13 2015-02-18 合肥庭索环保材料有限公司 Preparation method of insulation board doped with blast furnace slag
CN105235061A (en) * 2015-08-20 2016-01-13 洛阳佳一机电设备有限公司 Production system and process method for preparing aerated bricks through waste slurry
CN107522461A (en) * 2017-07-31 2017-12-29 铜陵丰泽建材科技有限公司 A kind of preparation method of resistance to cracking fly ash autoclaved brick
CN108751823A (en) * 2018-08-13 2018-11-06 成都尚威耐火材料有限公司 A kind of solid waste material is non-burning brick and preparation method thereof
CN108911608A (en) * 2018-08-24 2018-11-30 肇庆市珈旺环境技术研究院 A kind of autoclaved lime-sand brick and preparation method thereof
CN108911608B (en) * 2018-08-24 2020-09-29 路德环境科技股份有限公司 Autoclaved sand-lime brick and preparation method thereof
CN109231901A (en) * 2018-10-11 2019-01-18 十九冶成都建设有限公司 High-titanium blast furnace slag concrete laitance recoverying and utilizing method
CN109231901B (en) * 2018-10-11 2021-03-19 十九冶成都建设有限公司 High titanium type blast furnace slag concrete floating slurry recycling method
CN117700191A (en) * 2023-12-13 2024-03-15 河海大学 Baking-free brick of full solid waste system based on waste slurry and preparation method thereof

Also Published As

Publication number Publication date
CN102408208B (en) 2013-08-14

Similar Documents

Publication Publication Date Title
Part et al. An overview on the influence of various factors on the properties of geopolymer concrete derived from industrial by-products
CN102408208B (en) Autoclaved/steam cured brick prepared from industrial waste and preparation process thereof
CN107935555B (en) Nickel iron slag ceramic and preparation method thereof
Gupta et al. A state of the art review to enhance the industrial scale waste utilization in sustainable unfired bricks
CN108516765A (en) A kind of riverway sludge is non-burning brick and preparation method thereof
CN101734895B (en) Process for producing regenerated building waste autoclaved brick
CN105801053A (en) Self-compacting concrete with high content of fly ash C40
CN110606720B (en) Preparation method of high-content fly ash-based water permeable brick
CN106587788A (en) Low-cement-content self-compacting concrete and preparation method thereof
CN112250355A (en) Alkali-activated fly ash/slag recycled concrete and preparation method thereof
CN101531029A (en) Partition brick with high fire resistance and manufacturing method thereof
CN101519896B (en) Vapor-pressing plaster brick and preparation method thereof
CN108249871A (en) A kind of preparation method of novel water permeable product
CN101255037A (en) Method for manufacturing silicate product by ceramic waste hydrothermal process
CN108191321B (en) Preparation method of pervious concrete
CN102126866A (en) High-purity silica refractory material and production process thereof
CN107311559A (en) Waste ceramic fine concrete and preparation method thereof
CN104140229A (en) Shrinkage-compensating recycled concrete and preparation method thereof
CN112500084A (en) Ecological concrete water permeable brick based on fly ash lightweight aggregate and preparation method thereof
Burciaga-Díaz et al. Mortars of alkali-activated blast furnace slag with high aggregate: binder ratios
CN102659376A (en) Water proof baking-free brick with ardealite serving as main material and manufacturing method thereof
CN103539417A (en) Method for manufacturing steam-pressing bricks by using iron tailings and steel slag
CN115215597A (en) Shield slag slurry alkali-activated regenerated mortar and preparation method and application thereof
CN108341618A (en) A kind of non-steamed reactive powder concrete admixture and production method
CN111253139A (en) Preparation method of high-performance structural material based on carbonation

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20130814