CN102392361B - Method for preparing uncovering agent for unearthed silk fabrics - Google Patents
Method for preparing uncovering agent for unearthed silk fabrics Download PDFInfo
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- CN102392361B CN102392361B CN 201110237932 CN201110237932A CN102392361B CN 102392361 B CN102392361 B CN 102392361B CN 201110237932 CN201110237932 CN 201110237932 CN 201110237932 A CN201110237932 A CN 201110237932A CN 102392361 B CN102392361 B CN 102392361B
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- China
- Prior art keywords
- parts
- silk fabrics
- container
- unearthed
- uncovering
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004744 fabric Substances 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 12
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003921 oil Substances 0.000 claims description 15
- -1 amido silicon Chemical compound 0.000 claims description 14
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- 239000010703 silicon Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- OBFQBDOLCADBTP-UHFFFAOYSA-N aminosilicon Chemical class [Si]N OBFQBDOLCADBTP-UHFFFAOYSA-N 0.000 claims description 5
- UDHMTPILEWBIQI-UHFFFAOYSA-N butyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCCCC)=CC=CC2=C1 UDHMTPILEWBIQI-UHFFFAOYSA-N 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003344 environmental pollutant Substances 0.000 abstract description 4
- 231100000719 pollutant Toxicity 0.000 abstract description 4
- WZGREKNBSLUCPW-UHFFFAOYSA-N 1-butylnaphthalene;sodium Chemical compound [Na].C1=CC=C2C(CCCC)=CC=CC2=C1 WZGREKNBSLUCPW-UHFFFAOYSA-N 0.000 abstract 1
- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 abstract 1
- 229920013822 aminosilicone Polymers 0.000 abstract 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 abstract 1
- 229960001484 edetic acid Drugs 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000002689 soil Substances 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 239000010433 feldspar Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229910052622 kaolinite Inorganic materials 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention relates to a method for preparing an uncovering agent for unearthed silk fabrics. The method is characterized by comprising the following steps of: A) putting 1 part of citric acid powder and 0.5 to 1.5 parts of sodium dodecyl benzene sulfonate into a container, and mixing uniformly; B) adding 1 part of nekal, 2.5 parts of 60 percent butyl naphthalene sodium sulfonate solution, 3 parts of 3 percent ethylene diamine tetraacetic acid solution, 3 parts of 98 percent amino silicone oil and 10 parts of 99 percent ethanol into the container sequentially with stirring; and C) adding deionized water into the container, stirring, and regulating the pH value of the solution to be 6.2 to obtain the uncovering agent for the unearthed silk fabrics. Compared with the prior art, the method has the advantages that: 1) the original structure and performance of the silk fabrics cannot be damaged; 2) the uncovering effect on the silk fabrics with various pollutants is good; and 3) the breaking strength of rotten silk fabrics can be improved, so that the silk fabrics are easy to store.
Description
Technical field
What the present invention relates to is a kind of guard method of silk relics, particularly a kind of preparation method of uncovering agent for unearthed silk fabrics.
Background technology
China is the silk ancient civilized country, and in very long historical long river, the Chinese people of industry and intelligence can give human so bright and colourful silk of creating to own ancestors, always as being extolled as the epic.But for the silk goods that are unearthed ancient times, because the organic material of itself uniqueness is added the impact that is subjected to buring environment, so that silk goods have suffered huge destruction and loss.
The whole silk goods of putting and being bundled together that pile up, for a long time by buried in underground, be subject to the extruding of earthquake, body of wall equal pressure and earth, the impact of the various conditions such as erosion of humiture, soil salinity and alkalinity, mould and microorganism, as time goes by, these silk goods may the company of sticking, be consolidated, and the archeologist describes its picture one by one " cow dung heap ", for these valuable historical relics are emerged, just must first it be taken off and launch.About the research of taking off spreader also seldom, abroad be blank out in this respect both at home and abroad; Domestic have several museums to do in this respect research, but because the cohering of the silk goods that are unearthed, fixed situation, fixed thing are different, the research of therefore taking off spreader has very strong specific aim.
Summary of the invention
The object of the present invention is to provide a kind of preparation method of uncovering agent for unearthed silk fabrics, preparation method for the uncovering agent for unearthed silk fabrics that is consolidated with pollutant, employing has surfactant and the chemical reagent of fine infiltration, wettability and soft effect, fixed silk goods well can be taken off in certain temperature, humidity and process regular hour and be launched, and the various performances of silk goods are not affected.Be used for being consolidated with kaolinite, imvite, quartz, calcium carbonate, feldspar, silicoglaserite, common soil constituent and the iron rust such as potassium chloride class salt, saturated fatty acid calcium salt, the wax-like residue of silk cocoon, the exhibition of taking off of vulcanized lead and the pollutant silk goods such as spices that silk goods wrap up.
A kind of preparation method of uncovering agent for unearthed silk fabrics is characterized in that adopting following steps:
A) get 1 part in citric acid powder by mass fraction, 0.5～1.5 part of neopelex is put into container and is mixed;
B) according to steps A) metering of identical mass fraction gets and pulls open 1 part in powder, mass percentage concentration is 2.5 parts of 60% sodium butylnaphthalenesulfonate solution, mass percentage concentration is 3 parts of 3% edta solutions, mass percentage concentration is 3 parts of 98% amido silicon oils, mass percentage concentration is 10 parts of 99% ethanol, join successively in the container, stir while adding, described amido silicon oil is hydrophilic epoxidized polyether modified amino silicon oil;
C) deionized water is joined in the container, the pH value of stirring and regulator solution is 6.2, obtains uncovering agent for unearthed silk fabrics.
Compared with prior art, advantage of the present invention has: 1) can not damage effect to original structure, the performance of silk goods; 2) pointed, for being consolidated with kaolinite, imvite, quartz, calcium carbonate, feldspar, silicoglaserite, common soil constituent and the iron rust such as potassium chloride class salt, saturated fatty acid calcium salt, the wax-like residue of silk cocoon, the silk goods of the pollutants such as spices that vulcanized lead and silk goods wrap up have well takes off the exhibition effect; 3) for the rotten silk goods of grain, take off exhibition after its ultimate strength can increase, thereby be conducive to the preservation of silk goods.
The specific embodiment
Embodiment 1:
A kind of preparation method of uncovering agent for unearthed silk fabrics is characterized in that adopting following steps:
A) get 1 part in citric acid powder by mass fraction, 0.5 part of neopelex is put into container and is mixed;
B) according to steps A) metering of identical mass fraction gets and pulls open 1 part in powder, mass percentage concentration is 2.5 parts of 60% sodium butylnaphthalenesulfonate solution, mass percentage concentration is 3 parts of 3% edta solutions, mass percentage concentration is 3 parts of 98% amido silicon oils, mass percentage concentration is 10 parts of 99% ethanol, join successively in the container, stir while adding, described amido silicon oil is hydrophilic epoxidized polyether modified amino silicon oil;
C) deionized water is joined in the container, the pH value of stirring and regulator solution is 6.2, obtains uncovering agent for unearthed silk fabrics.
Embodiment 2:
A kind of preparation method of uncovering agent for unearthed silk fabrics is characterized in that adopting following steps:
A) get 1 part in citric acid powder by mass fraction, 1.5 parts of neopelexes are put into container and are mixed;
B) according to steps A) metering of identical mass fraction gets and pulls open 1 part in powder, mass percentage concentration is 2.5 parts of 60% sodium butylnaphthalenesulfonate solution, mass percentage concentration is 3 parts of 3% edta solutions, mass percentage concentration is 3 parts of 98% amido silicon oils, mass percentage concentration is 10 parts of 99% ethanol, join successively in the container, stir while adding, described amido silicon oil is hydrophilic epoxidized polyether modified amino silicon oil;
C) deionized water is joined in the container, the pH value of stirring and regulator solution is 6.2, obtains uncovering agent for unearthed silk fabrics.
Embodiment 3:
A kind of preparation method of uncovering agent for unearthed silk fabrics is characterized in that adopting following steps:
A) get 1 part in citric acid powder by mass fraction, 1 part of neopelex is put into container and is mixed;
B) according to steps A) metering of identical mass fraction gets and pulls open 1 part in powder, mass percentage concentration is 2.5 parts of 60% sodium butylnaphthalenesulfonate solution, mass percentage concentration is 3 parts of 3% edta solutions, mass percentage concentration is 3 parts of 98% amido silicon oils, mass percentage concentration is 10 parts of 99% ethanol, join successively in the container, stir while adding, described amido silicon oil is hydrophilic epoxidized polyether modified amino silicon oil;
C) deionized water is joined in the container, the pH value of stirring and regulator solution is 6.2, obtains uncovering agent for unearthed silk fabrics.
Claims (1)
1. the preparation method of a uncovering agent for unearthed silk fabrics is characterized in that adopting following steps:
A) get 1 part in citric acid powder by mass fraction, 0.5～1.5 part of neopelex is put into container and is mixed;
B) according to steps A) metering of identical mass fraction gets and pulls open 1 part in powder, mass percentage concentration is 2.5 parts of 60% sodium butylnaphthalenesulfonate solution, mass percentage concentration is 3 parts of 3% edta solutions, mass percentage concentration is 3 parts of 98% amido silicon oils, mass percentage concentration is 10 parts of 99% ethanol, join successively in the container, stir while adding, described amido silicon oil is hydrophilic epoxidized polyether modified amino silicon oil;
C) deionized water is joined in the container, the pH value of stirring and regulator solution is 6.2, obtains uncovering agent for unearthed silk fabrics.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110237932 CN102392361B (en) | 2011-08-18 | 2011-08-18 | Method for preparing uncovering agent for unearthed silk fabrics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110237932 CN102392361B (en) | 2011-08-18 | 2011-08-18 | Method for preparing uncovering agent for unearthed silk fabrics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102392361A CN102392361A (en) | 2012-03-28 |
| CN102392361B true CN102392361B (en) | 2013-04-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110237932 Expired - Fee Related CN102392361B (en) | 2011-08-18 | 2011-08-18 | Method for preparing uncovering agent for unearthed silk fabrics |
Country Status (1)
| Country | Link |
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| CN (1) | CN102392361B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3479128A (en) * | 1965-12-27 | 1969-11-18 | Miles Lab | Process for improving the strength of wool or silk fibers and products thereof |
| CN1560354A (en) * | 2004-02-20 | 2005-01-05 | 湖北省博物馆 | Microorganism reinforced method of non-strength silk |
| CN101407711A (en) * | 2008-12-01 | 2009-04-15 | 荆州文物保护中心 | Method for separating and stripping highly water-bearing low-intensity cultural relics silk |
-
2011
- 2011-08-18 CN CN 201110237932 patent/CN102392361B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3479128A (en) * | 1965-12-27 | 1969-11-18 | Miles Lab | Process for improving the strength of wool or silk fibers and products thereof |
| CN1560354A (en) * | 2004-02-20 | 2005-01-05 | 湖北省博物馆 | Microorganism reinforced method of non-strength silk |
| CN101407711A (en) * | 2008-12-01 | 2009-04-15 | 荆州文物保护中心 | Method for separating and stripping highly water-bearing low-intensity cultural relics silk |
Non-Patent Citations (5)
| Title |
|---|
| "丝织品揭展剂对纺织品类文物性能影响研究";孙丽娟等;《中国文物保护技术协会第四次学术年会论文集》;20051101;341-349 * |
| "出土丝织品揭展剂在出土宋代丝绸上的应用";杨建洲等;《考古与文物》;20040730(第4期);90-93 * |
| 奚三彩等."古代丝织品的病害及其防治研究".《古代丝织品的病害及其防治研究》.河海大学出版社,2008,(第1版),183-184. |
| 孙丽娟等."丝织品揭展剂对纺织品类文物性能影响研究".《中国文物保护技术协会第四次学术年会论文集》.2005,341-349. |
| 杨建洲等."出土丝织品揭展剂在出土宋代丝绸上的应用".《考古与文物》.2004,(第4期),90-93. |
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| Publication number | Publication date |
|---|---|
| CN102392361A (en) | 2012-03-28 |
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Granted publication date: 20130417 Termination date: 20130818 |