CN102392083B - Method for manufacturing high temperature-resistant wool sheepskin for shoes and boots - Google Patents
Method for manufacturing high temperature-resistant wool sheepskin for shoes and boots Download PDFInfo
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- CN102392083B CN102392083B CN2011103060496A CN201110306049A CN102392083B CN 102392083 B CN102392083 B CN 102392083B CN 2011103060496 A CN2011103060496 A CN 2011103060496A CN 201110306049 A CN201110306049 A CN 201110306049A CN 102392083 B CN102392083 B CN 102392083B
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Abstract
The invention relates to a manufacturing method for improving the heat-resistant performance of leatherboard in the wool sheepskin industry, in particular to a method for manufacturing high temperature-resistant wool sheepskin for shoes and boots. In the high temperature-resistant wool sheepskin, the leatherboard can resist high temperature of 150 DEG C. The method comprises the steps of: preparing blank skin before weighing and processing the blank skin after degreasing; and the method is characterized in that: a process between the weighing process and the degreasing process comprises the steps of retanning, standing, pickling and rinsing, wherein in the retanning step, a fatliquor GLH which is diluted by adding hot water, diluted formic acid, chromium powder, Bayer zirconium ZB33 and sodium bicarbonate are added to extract alkali. In the key technology, a method for combining a chrome tanning agent and a zirconium tanning agent is adopted in the retanning process; and the leatherboard of products produced under the condition that the using amount of the chrome tanning agent and the zirconium tanning agent is adjusted to a reasonable ratio meets the requirement of resisting temperature of 150 DEG C completely, fibers of the leatherboard are compact, and the dyed leatherboard is bright and strong in colors. The products are suitable for fields of manufacturing the shoes and boots, the high temperature-resistant wool sheepskin and the like.
Description
Technical fieldThe present invention relates to the making that shearling industry dermatotome resistance toheat improves, especially relate to the high temperature resistant footwear boots shearling making method that the dermatotome heatproof will reach 150 ℃.
Background technologyCompany obtains client's information at the beginning of 2010, and a kind of product that a domestic foreign trade corporation makes is badly in need of wanting a kind of heatproof to reach 150 ℃ high temperature resistant footwear boots shearling.All about 95 ℃, the shearling that can reach anti-150 ℃ of high-temperatures still belongs to blank at home, outward to shearling product heatproof degree generally speaking.
Retanning occupies critical role in fur industry, it is that the good skin base of tanning is carried out another tanning, can replenish the deficiency of just tanning, improve the stability of skin base chemically-resistant effect, be conducive to follow-up housekeeping operation, improve use properties, increase to greatest extent value-added content of product, the needs of applicable various uses.
At present, chrome tanning agent retanning, aldehyde tanning agent retanning, aluminum tanning agent retanning or synthetic tanning agent, vegetable tanning agent, resene tanning agent retanning several different methods are generally taked in the fur retanning, the effect that different retanning methods reaches and excellent, shortcoming is different.The advantage of chrome tanning agent retanning is to improve the shrinkage temperature of dermatotome, and the stability of the fullness of increase dermatotome, elasticity, flexibility, chemical-resistant reagent and anionic dyestuff are to the colourability of dermatotome; Along with the fur industrial expansion, higher, Secretary has more been proposed for fur and goods thereof both at home and abroad, impel fur manufacturing technique constantly to be improved.How to improve anti-shrinkage temperature, reach customer requirement, become fur retanning procedures problem in the urgent need to address.
Product development for the shearling of finishing anti-150 ℃ of high-temperatures, I engineering technical personnel of company mainly start with from tests such as screening material, change processing condition, be combined retanning with chromium with different Retanning Materials, by to the simultaneous test of several Retanning Materials with to the test of many times contrast of retanning method, the retanning process that development makes new advances, after the sample piece is manufactured experimently out, under 150 ° of C conditions, test, do not shrink in 2 minutes; The color of footwear boots skin by draw a design, setting-out reaches customer requirement, makes product dermatotome heatproof and the hair color produced reach customer requirement.
Summary of the inventionThe object of the present invention is to provide a kind of high temperature resistant footwear boots shearling making method, the shearling that the method is made, heatproof can reach 150 ℃.
The present invention realizes that the technical scheme that above-mentioned purpose takes is as follows: a kind of high temperature resistant footwear boots shearling making method, comprise base skin before weighing prepare with degreasing after the base skin process, it is characterized in that weighing and degreasing between process flow be: retanning, leave standstill, pickling, rinsing; Concrete technical matters step is as follows:
Steps A, base skin are prepared
Undertaken by existing following common process step: footwear boots base skin, cropping, swabbing, boiling hot hair, cropping, secondary swabbing are scalded hair, carding, cropping, brush formic acid liquid, scald hair, cropping, are checked, weigh, and described weighing is accurately to weigh 132 kg/ grooves as following operation materials foundation;
Step B, retanning
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 45～48 ℃,
Material: GLH fatting agent 1.0g/l 60 minutes
It is 2.9～3.2 that formic acid 1g/l surveyed PH in 30 minutes
Chromium powder 20g/l
Bayer zirconium ZB33 5g/l stops after 60 minutes to draw, and per 2 hours intermittences, paddling was 20 minutes, early carried alkali next day
Sodium bicarbonate (1) 1.0g/l 120 minutes
Sodium bicarbonate (2) 1.0g/l 120 minutes
Sodium bicarbonate (3) 1.0g/l 120 minutes
Sodium bicarbonate (4) 1.0g/l 120 minutes
Sodium bicarbonate (5) 1.0g/l 120 minutes, surveying pH value is 3.9～4.2
Sodium bicarbonate (6) 0.5～1.0g/l for subsequent use 30 minutes, surveying pH value is 3.9～4.2; Spend the night, early go out skin next day;
Working method: the temperature adjustment to 45 that discharges water～48 ℃ hypodermis; Add with 1 times of continuous paddling of the water-reducible fatting agent GLH of 60～65 ℃ of heat 60 minutes; Add again and diluted good formic acid and continued paddling 30 minutes, after surveying PH and reaching 2.9～3.2 requirement, added chromium powder and the continuous paddling of Bayer zirconium ZB33 60 minutes, stop drawing; Paddling was 20 minutes in per 2 hours later on, stopped night to draw, and early carried alkali next day; Order adds sodium bicarbonate (1) to (5) five parts in sodium bicarbonate, and the continuous paddling of a sodium bicarbonate of every adding stopped to draw 90 minutes in 30 minutes, and after the continuous paddling of adding sodium bicarbonate (5) stopped to draw 90 minutes in 30 minutes, surveying pH value was 3.9～4.2; Added sodium bicarbonate for subsequent use (6) and paddling 30 minutes as pH value is improper, being adjusted to pH value suitable is that pH value is 3.9～4.2, can stop to draw, and spends the night again; Next day, early continuous paddling went out skin in 30 minutes;
Specification of quality and precaution: a, material must be sequentially added into, pH value must be controlled at every turn and can continue in the claimed range down to carry out, b, sodium bicarbonate are opened with 5～10 times of 30 ℃ of aquations, formic acid with 10 times of normal-temperature water dilutions evenly, after c, various material add, want continuous paddling, guarantee that the leather suction is even;
Step C, leave standstill
The base skin that retanning goes out behind the skin left standstill 1～2 day;
Step D, pickling
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 34～36 ℃;
Material: formic acid 1.0～1.2g/l, paddling 30 minutes is surveyed PH:3.6～3.8
Working method: the temperature adjustment to 34 that discharges water～36 ℃ hypodermis, add and diluted the continuous paddling of uniform formic acid 30 minutes with 10 times of normal-temperature water, after reaching 3.6～3.8, the survey pH value goes out skin;
Step e, rinsing
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 20～25 ℃, the time: 15 minutes
Working method: the temperature adjustment to 20 that discharges water～25 ℃ hypodermis, paddling went out skin after 15 minutes continuously;
Step F, base skin are processed
By existing following common process step with rinsing after the base skin process: degreasing, flushing, dyeing, flushing, water dumping, brush stuffing, drying, moisture regain, stretching, extension, toggling, placement, swabbing, scald hair, brush formic acid liquid two times, scald hair two times, cropping, do and scald hair, cropping, inspection after construction, gage friendship storehouse.
Most critical technology of the present invention is the method for taking chromium, zirconium tanning agent to combine at retanning procedures, adjust at the consumption of chrome tanning agent, zirconium tanning agent in the situation of rational proportioning, its dermatotome of the product of producing not only heatproof can reach 150 ℃ requirement fully, and the dermatotome fiber is tightr, and dermatotome is bright in colour, dense, bright after the dyeing.The footwear boots shearling of manufacturing according to the present invention obtains foreign trader's favorable comment, for a new route has been broken in company's trade.Through research and experiment, high temperature resistant footwear boots shearling making method is fit to make domestic three generations above improvement fine furs and Australian shearling, its product is applicable to make the fields such as footwear boots and high temperature resistant shearling, technique innovation has been established good basis for company opens up foreign trade market, and is of far-reaching significance and will bring good economic benefit.
Embodiment
Embodiment 1
1, the base skin is prepared
Undertaken by existing common process step: footwear boots base skin, cropping, swabbing, boiling hot hair, cropping, secondary swabbing are scalded hair, carding, cropping, brush formic acid liquid, are scalded hair, cropping, check, the 132 kg/ groove base skins of then accurately weighing, and as following operation materials foundation.
2, retanning:
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 47 ℃
Material: GLH fatting agent 1.0g/l * 3800=3800 g
Formic acid 1g/l * 3800=3800 g
Chromium powder 20g/l * 3800=76000 g
Bayer zirconium ZB33 5g/l * 3800=19000 g
Sodium bicarbonate (1) 1.0g/l * 3800=3800 g
Sodium bicarbonate (2) 1.0g/l * 3800=3800 g
Sodium bicarbonate (3) 1.0g/l * 3800=3800 g
Sodium bicarbonate (4) 1.0g/l * 3800=3800 g
Sodium bicarbonate (5) 1.0g/l * 3800=3800 g
Sodium bicarbonate for subsequent use (6) 0.6g/l * 3800=2280 g
65 ℃ of hot water with 7600g are evenly for subsequent use with the dilution of GLH fatting agent; With the 38kg normal-temperature water that the formic acid dilution is evenly for subsequent use; Open for subsequent use with 30 ℃ of aquations of 6 times of its weight sodium bicarbonate (1) to sodium bicarbonate (6) respectively.
Working method: temperature adjustment to 47 ℃ hypodermis discharges water, add and diluted the continuous paddling of uniform fatting agent GLH 60 minutes, add again and diluted good formic acid continuation paddling 30 minutes, surveying PH is 3.0, added chromium powder and the continuous paddling of Bayer zirconium ZB33 60 minutes, and stopped drawing, paddling was 20 minutes in later per 2 hours, stop night to draw, early carry alkali next day; The sodium bicarbonate that addingization is good (1), paddling stopped to draw 90 minutes in 30 minutes continuously; The sodium bicarbonate (2) that addingization is good again, paddling stopped to draw 90 minutes in 30 minutes continuously ..., until the good sodium bicarbonate (5) of addingization, paddling stopped to draw 90 minutes in 30 minutes continuously; Survey PH3.7, because pH value is improper, the sodium bicarbonate for subsequent use (6) that adding is good again, paddling is 30 minutes continuously, surveys pH value 4.2, and suitable the stopping of pH value drawn, and spends the night; Next day, early continuous paddling went out skin in 30 minutes.
3, left standstill 2 days after leaving standstill out skin.
4, pickling
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 35 ℃
Material: formic acid: 1.1g/l * 3800=4180 g surveys PH:3.6
Working method: temperature adjustment to the 35 ℃ hypodermis that discharges water, add and diluted the continuous paddling of uniform formic acid 30 minutes with 10 times of normal-temperature water, the survey pH value reaches will obtain skin.
5, rinsing
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 24 ℃, the time: 15 minutes
Working method: the temperature adjustment that discharges water is to the regulation hypodermis, and paddling went out skin after 15 minutes continuously.
6, the base skin is processed
By existing following common process step with rinsing after the base skin process: degreasing, flushing, dyeing, flushing, water dumping, brush stuffing, drying, moisture regain, stretching, extension, toggling, placement, swabbing, scald hair, brush formic acid liquid two times, scald hair two times, cropping, do and scald hair, cropping, inspection after construction, gage friendship storehouse.
Embodiment 2
1, the base skin is prepared identical with embodiment 1.
2, retanning
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 45 ℃
Material: do not need sodium bicarbonate for subsequent use (6), sodium bicarbonate (1) to sodium bicarbonate (5) is opened respectively for subsequent use with 30 ℃ of aquations of 10 times of its weight, all the other are identical with embodiment 1;
Survey PH:3.0 after adding formic acid, add continuously paddling 30 minutes of sodium bicarbonate (5), stop drawing that to survey PH after 90 minutes be 3.9: all the other are identical with embodiment 1.
3, left standstill 1 day after leaving standstill out skin.
4, pickling temperature: 36 ℃, survey PH:3.7; All the other are identical with embodiment 1.
5, rinsing temperature: 23 ℃; All the other are identical with embodiment 1.
Embodiment 3
1, the base skin is prepared identical with embodiment 1.
2, retanning
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 48 ℃;
Material: sodium bicarbonate for subsequent use (6) 1g/l * 3800=3800 g, sodium bicarbonate (1) to sodium bicarbonate (6) to be opened respectively for subsequent use with 30 ℃ of aquations of 8 times of its weight, all the other are identical with embodiment 1;
Survey PH:3.1 after adding formic acid, add continuously paddling 30 minutes of sodium bicarbonate (5), stop drawing that to survey PH after 90 minutes be 3.6, survey PH:4.1 after adding sodium bicarbonate for subsequent use (6); All the other are identical with embodiment 1.
3, left standstill 2 days after leaving standstill out skin.
4, pickling temperature: 34 ℃, survey PH:3.8; All the other are identical with embodiment 1.
5, rinsing temperature: 25 ℃; All the other are identical with embodiment 1.
Claims (3)
1. high temperature resistant footwear boots shearling making method, comprise base skin before weighing prepare with degreasing after the base skin process, it is characterized in that: weigh and degreasing between process flow be: retanning, leave standstill, pickling, rinsing; Concrete technical matters step is as follows:
Steps A, base skin are prepared
Step B, retanning
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 45～48 ℃,
Material: GLH fatting agent 1.0g/L 60 minutes
It is 2.9～3.2 that formic acid 1g/L surveyed pH in 30 minutes
Chromium powder 20g/L
Bayer zirconium ZB33 5g/L stops after 60 minutes to draw, and per 2 hours intermittences, paddling was 20 minutes, early carried alkali next day
Sodium bicarbonate (1) 1.0g/L120 minute
Sodium bicarbonate (2) 1.0g/L 120 minutes
Sodium bicarbonate (3) 1.0g/L 120 minutes
Sodium bicarbonate (4) 1.0g/L 120 minutes
Sodium bicarbonate (5) 1.0g/L 120 minutes, surveying the pH value is 3.9～4.2
Sodium bicarbonate (6) 0.5～1.0g/L for subsequent use 30 minutes, surveying the pH value is 3.9～4.2; Spend the night, early go out skin next day;
Working method: the temperature adjustment to 45 that discharges water～48 ℃ hypodermis; Add with 1 times of continuous paddling of the water-reducible fatting agent GLH of 60～65 ℃ of heat 60 minutes; Add again and diluted good formic acid and continued paddling 30 minutes, after surveying pH and reaching 2.9～3.2 requirement, added chromium powder and the continuous paddling of Bayer zirconium ZB33 60 minutes, stop drawing; Paddling was 20 minutes in per 2 hours later on, stopped night to draw, and early carried alkali next day; Order adds sodium bicarbonate (1) to (5) five parts in sodium bicarbonate, and the continuous paddling of a sodium bicarbonate of every adding stopped to draw 90 minutes in 30 minutes, and after the continuous paddling of adding sodium bicarbonate (5) stopped to draw 90 minutes in 30 minutes, surveying the pH value was 3.9～4.2; Added sodium bicarbonate for subsequent use (6) and paddling 30 minutes as the pH value is improper, being adjusted to the suitable pH of the being value of pH value is 3.9～4.2, can stop to draw, and spends the night again; Next day, early continuous paddling went out skin in 30 minutes;
Step C, leave standstill
The base skin that retanning goes out behind the skin left standstill 1～2 day;
Step D, pickling
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 34～36 ℃;
Material: formic acid 1.0～1.2g/L, paddling 30 minutes is surveyed pH:3.6～3.8
Working method: the temperature adjustment to 34 that discharges water～36 ℃ hypodermis, add and diluted the continuous paddling of uniform formic acid 30 minutes with 10 times of normal-temperature water, after reaching 3.6～3.8, survey pH value goes out skin;
Step e, rinsing
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 20～25 ℃, the time: 15 minutes
Working method: the temperature adjustment to 20 that discharges water～25 ℃ hypodermis, paddling went out skin after 15 minutes continuously;
Step F, base skin are processed.
2. a kind of high temperature resistant footwear boots shearling making method as claimed in claim 1 is characterized in that: the described working method of step B retanning, and material must be sequentially added into, and the pH value must be controlled at every turn and can continue in the claimed range down to carry out; Sodium bicarbonate is opened with 5～10 times of 30 ℃ of aquations, and formic acid with 10 times of normal-temperature water dilutions evenly after various materials add, continuous paddling, guarantees that the leather suction is even.
3. a kind of high temperature resistant footwear boots shearling making method as claimed in claim 1, it is characterized in that: it is to be undertaken by existing following common process step that described steps A base skin is prepared: footwear boots base skin, cropping, swabbing, boiling hot hair, cropping, secondary swabbing are scalded hair, carding, cropping, brush formic acid liquid, scald hair, cropping, are checked, weigh, and described weighing is accurately to weigh 132 kg/ grooves as subsequent handling materials foundation; It is that the base skin after the step e rinsing is undertaken by existing following common process step that described step F base skin is processed: by existing following common process step with rinsing after the base skin process: degreasing, flushing, dyeing, flushing, water dumping, brush stuffing, drying, moisture regain, stretching, extension, toggling, placement, swabbing, scald hair, brush formic acid liquid two times, scald hair two times, cropping, do and scald hair, cropping, inspection after construction, gage friendship storehouse.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011103060496A CN102392083B (en) | 2011-10-11 | 2011-10-11 | Method for manufacturing high temperature-resistant wool sheepskin for shoes and boots |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011103060496A CN102392083B (en) | 2011-10-11 | 2011-10-11 | Method for manufacturing high temperature-resistant wool sheepskin for shoes and boots |
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| Publication Number | Publication Date |
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| CN102392083A CN102392083A (en) | 2012-03-28 |
| CN102392083B true CN102392083B (en) | 2013-04-24 |
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| CN2011103060496A Expired - Fee Related CN102392083B (en) | 2011-10-11 | 2011-10-11 | Method for manufacturing high temperature-resistant wool sheepskin for shoes and boots |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105624340B (en) * | 2015-12-08 | 2018-07-27 | 浙江中辉裘革科技有限公司 | A kind of black waxy soil is by the production technology of the matte Qiu Ge of, white dermatotome |
| CN105349710B (en) * | 2015-12-17 | 2018-07-10 | 湖南科技职业学院 | A kind of method of ox-hide Chrome-free combination tanning |
| CN108424983B (en) * | 2018-03-19 | 2020-07-24 | 江西隆华材料科技股份有限公司 | Sheep skin thickening method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB817101A (en) * | 1955-04-01 | 1959-07-22 | Basf Ag | Improvements in the production of tanning agents |
| CN101993962A (en) * | 2009-08-27 | 2011-03-30 | 际华三五一五皮革皮鞋有限公司 | Method for manufacturing waterproof soft-surface leather |
| CN102199675A (en) * | 2011-04-12 | 2011-09-28 | 王学川 | Clean process for producing leather by using sturgeon skin |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19621219A1 (en) * | 1996-05-25 | 1997-11-27 | Klaus Prof Dr Sommer | Leather and its manufacture |
| CN100494408C (en) * | 2005-12-02 | 2009-06-03 | 四川大学 | Method for tanning high-temperature stable chromium-free costume soft leather |
| CN101717833A (en) * | 2009-11-30 | 2010-06-02 | 温州大学 | Method for tanning pigskin shoe lining leather by utilizing non-chromium metal compound tanning agent |
| RU2402615C1 (en) * | 2009-12-21 | 2010-10-27 | Российская Федерация, От Имени Которой Выступает Министерство Промышленности И Торговли Российской Федерации | Method of producing heat-resistant leather |
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2011
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB817101A (en) * | 1955-04-01 | 1959-07-22 | Basf Ag | Improvements in the production of tanning agents |
| CN101993962A (en) * | 2009-08-27 | 2011-03-30 | 际华三五一五皮革皮鞋有限公司 | Method for manufacturing waterproof soft-surface leather |
| CN102199675A (en) * | 2011-04-12 | 2011-09-28 | 王学川 | Clean process for producing leather by using sturgeon skin |
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