CN102388898A - Compounding herbicide for cotton field - Google Patents
Compounding herbicide for cotton field Download PDFInfo
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- CN102388898A CN102388898A CN2011102723641A CN201110272364A CN102388898A CN 102388898 A CN102388898 A CN 102388898A CN 2011102723641 A CN2011102723641 A CN 2011102723641A CN 201110272364 A CN201110272364 A CN 201110272364A CN 102388898 A CN102388898 A CN 102388898A
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- trifloxysulfuron
- quizalofopptefuryl
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- weed
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Abstract
The invention discloses compounding herbicide for a cotton field, which relates to the technical field of pesticide and consists of two kinds of active ingredients: trifloxysulfuron and tefuryl, wherein the weight ratio of the trifloxysulfuron to the tefuryl is 1/(0.5 to 1.5), and preferably, the mass percentage of the trifloxysulfuron and the tefuryl is 4 to 85 percent of the compounding herbicide. The compounding herbicide can be used for preventing and killing cotton field annual broadleaf weed and can also be used for preventing and killing graminaccae weed and nutgrass flatsedge, the weed killing effect is obvious, the obvious synergia effect is realized, in addition, the weed in the whole growth period of the crops can be prevented and killed through once herbicide application, no influence is caused on the later stubble of crops, and the herbicide belongs to the ideal herbicide.
Description
Technical field
The present invention relates to technical field of pesticide, be specifically related to a kind of complex weedicide that is used for the cotton field.
Background technology
Cotton is most important economic crops of China still not, also are very valuable strategic materials.About 7,592 ten thousand mu of the sowing areas of Cotton in China.
Along with the development of agricultural cience and farming techniques, one of the applying as the saving of labor, save time of chemical herbicide, cost-effective strong well stimulation.At present, the weeding of domestic cotton field mainly is weeding before the seedling.
Trifloxysulfuron is to belong to sulfonylurea herbicide; Can be absorbed by the root of weeds, stem, leaf after the dispenser; Can in plant corpus, conduct downwards with upwards; Through suppressing the activity of acetolactate synthestase (ALS), thereby influence the biosynthesis of branched-chain amino acid (as: leucine, isoleucine, valine etc.).Show as growing point necrosis, vein chlorosis behind the hazard of plant, plant growing receives severe inhibition, dwarfing, and final complete stool is withered.
Trifloxysulfuron mainly is because the difference of katabolism to the selectivity of weeds and crop.It can be the non-activity material by rapid metabolism in the cotton body, thereby crop plant is escaped injury.
Be mainly used in and prevent and kill off broad leaved weed and sedge weed.On endive (Sonchus), quinoa (Chenopodium album), a small quinoa, Chenopodium glaucum, purslane, redroot pigweed, Amaranthus lividus, green ear Amaranthus, Cephalanoplos, gill bud fruit, ragweed, Bidens, big Alondra, water, peanuts, wild rape, field bindweed, playing bowl of flowers, fruit, sweet wine intestine (Eclipta), Sesbania, Ageratum, Yu Mang Ju, Brachiaria, Euphorbia , vat wood sorrel (sour Mimi) and other broadleaf weeds with good control effect; pair of purple nutsedge (Spartina grass) have effects; against crabgrass, barnyard drought, goosegrass, foxtail, sorghum and other cereal weed control effect is poor.
QuizalofopPtefuryl is to be transferred in the plant corpus from Foliage Absorption, in xylem and phloem, moves, and in meristem, accumulates. be used for preventing and kill off the annual and perennial grassy weed on potato, flax, rape, soybean, beet, cotton and Peas ground.
Both are composite can to have complementary advantages, and increases the preventive effect to weeds, saving of work and time.
Summary of the invention
The purpose of this invention is to provide and a kind ofly can prevent and kill off grassy weed, can prevent and kill off broad leaved weed and nutgrass flatsedge again, and respond well complex weedicide.。
In order to realize the foregoing invention purpose, the present invention provides following technical scheme:
A kind of complex weedicide comprises trifloxysulfuron and quizalofopPtefuryl, and the weight ratio of trifloxysulfuron and quizalofopPtefuryl is 1: 0.50-1: 1.5.
As preferably, the weight ratio of trifloxysulfuron and quizalofopPtefuryl is 3 in the complex weedicide according to the invention: 2-7: 10.
More preferably, the weight ratio of trifloxysulfuron and quizalofopPtefuryl is 1: 1 in the complex weedicide according to the invention.
On the other hand, the present invention provides that the quality percentage composition of trifloxysulfuron and quizalofopPtefuryl is 4~85% of a said complex weedicide in the biological said complex weedicide.
As preferably, in the complex weedicide according to the invention, two kinds of active components of trifloxysulfuron and quizalofopPtefuryl according to above-mentioned weight ratio composite after, process the formulations of pesticide such as oil-suspending agent, wetting powder or water dispersible granules.
Synergy after using with the co-toxicity coefficient method evaluation of Sun Yunpei; The result shows that trifloxysulfuron, quizalofopPtefuryl are in 1: the composite co-toxicity coefficient of 0.5-1.5 ratio is obviously greater than 120; Reach remarkable synergistic effect; Explain that trifloxysulfuron, quizalofopPtefuryl are in 1: the 0.5-1.5 ratio is mixed comparatively suitable, and annual single broadleaf weed and nutgrass flatsedge are had significant synergies.
Safety determination test to cotton shows that the composite cauline leaf of trifloxysulfuron quizalofopPtefuryl is handled, and suppresses the ED of cotton growth 10%
10=633.5774, the ED of inhibition weed growth 90%
90=147.8637, selectivity factor is 633.5774/147.8637=4.28>2, thinks that this medicament has obvious selectivity, and the trifloxysulfuron quizalofopPtefuryl has good control efficiency to weeds.
Complex weedicide according to the invention shows that through the field control effectiveness test in 2 years in 2~4 leaf phases of cotton, weeds 2-5 leaf does not wait the phase, and cotton does not see symptom of chemical damage from the dispenser to the maturing stage, to cotton safety.The preventive effect of weeds reached more than 80% in 10 days, reached more than 90% in 30 days, along with the increase of dosage; Preventive effect obviously strengthens, and a dispenser can be controlled the weeds in the crop whole growth phase, and not only herbicidal effect is remarkable; And environmentally friendly, second stubble crop there is not influence.
Compared with prior art, complex weedicide according to the invention can be prevented and kill off grassy weed, can prevent and kill off broad leaved weed and nutgrass flatsedge again, to cotton safety, and succession crop is not had influence, has a good application prospect.
Embodiment
The invention discloses a kind of complex weedicide of being made up of trifloxysulfuron and two kinds of active components of quizalofopPtefuryl, those skilled in the art can use for reference this paper content, suitably improve technological parameter and realize.Special needs to be pointed out is that all similarly replace and change apparent to those skilled in the art, they all are regarded as and are included in the present invention.Product of the present invention and application are described through preferred embodiment; The related personnel obviously can change or suitably change and combination methods and applications as herein described in not breaking away from content of the present invention, spirit and scope, realizes and use technology of the present invention.
Below in conjunction with embodiment, further set forth the present invention:
Embodiment 1: the oil-suspending agent (trifloxysulfuron: quizalofopPtefuryl=1: 1) for preparing complex weedicide according to the invention
6% trifloxysulfuron quizalofopPtefuryl oil-suspending agent, 6% is meant that trifloxysulfuron and two kinds of active components of quizalofopPtefuryl account for the percentage of gross weight.Get the 3kg trifloxysulfuron, the 3kg quizalofopPtefuryl, 8kgPluronic125, the 5kg propane diols, the 8kg xanthans, the 1kg methylated vegetable oil, water complements to 100kg.Pass through abundant mixing preparation, ball mill grinding, adjust, be packaged to be oil-suspending agent.
Embodiment 2: the wetting powder (trifloxysulfuron: quizalofopPtefuryl=3: 2) for preparing complex weedicide according to the invention
50% trifloxysulfuron quizalofopPtefuryl wetting powder, 50% is meant that trifloxysulfuron and two kinds of active components of quizalofopPtefuryl account for the percentage of gross weight.Get the 30kg trifloxysulfuron, the 20kg quizalofopPtefuryl, 6kg dispersant NNO, 3kg wetting agent K12, white carbon black complements to 100kg.Through fully mixing, comminution by gas stream, mixing, obtain wetting powder.
Embodiment 3: the water dispersible granules (trifloxysulfuron: quizalofopPtefuryl=7: 10) for preparing complex weedicide according to the invention
85% trifloxysulfuron quizalofopPtefuryl water dispersible granules, 85% is meant that trifloxysulfuron and two kinds of active components of quizalofopPtefuryl account for the percentage of gross weight.Get the 35kg trifloxysulfuron, the 50kg quizalofopPtefuryl, 7kg D-425,5kg EFW, 5kg ammonium sulfate, the 2kg polyethylene glycol, kaolin supplies 100%, obtains water dispersible granules through fully mixing, comminution by gas stream, mixing, granulation, drying and screening.
Embodiment 6: trifloxysulfuron and quizalofopPtefuryl cauline leaf are handled the indoor determination of activity of synergy
1, test objective
Under greenhouse experiment; Adopt the pot experiment method; The herbicidal effect of research trifloxysulfuron, quizalofopPtefuryl binary built, and the synergy type after using with the two different proportion of co-toxicity coefficient method evaluation of Sun Yunpei are for rationally being mixed of trifloxysulfuron and quizalofopPtefuryl provides scientific basis.
2, experimental condition
2.1 supply to study the thing cotton variety: rich cotton No. 12 of state
2.2 supply examination weeds lady's-grass (Digitaria sanguinalis (Linn.) Scop.); Green foxtail (Setaria viridis (L.) Beauv.); Acalypha copperleaf (Acalypha australis L.), lamb's-quarters (Chenopodium album L.) (last one year the field seed of gathering, germination rate is more than 85%).
2.3 the cultivation of experimental condition and examination material
In the illumination cultivation chamber, the make an experiment cultivation of material, temperature 25-35 ℃.Choosing diameter is 15cm, highly is the vinyon basin alms bowl of 15cm, and the permeable hole of 1cm diameter is beaten in the bottom of basin alms bowl.Permeable hole covers with double-deck filter paper, and soil is soaked into clear water from the bottom in the high 10cm of loam to the alms bowl place that the preparation in advance of packing in the alms bowl was sterilized.During test, every kind of weed seed 30-40 grain is evenly put into basin, earthing 0.5cm should replenish the required moisture of growth between the weeds culture period.
2.4 other condition
With the regular moisturizing of mode (not watering in 2 days behind the medicine) of bottom infiltration, keep soil moisture.
3 experimental scheme
3.1 medicament
3.1.1 supply the reagent agent
The former medicine of 95% trifloxysulfuron (Anhui Fengle Agricultural Co., Ltd, lab scale sample);
The former medicine of 95% quizalofopPtefuryl (Shangyu Nutrichem Co., Ltd).
3.1.2 supply the preparation of reagent agent soup
Take by weighing quantitative former medicine with electronic balance, add an amount of emulsifier, use acetone solution, with 0.1% soil temperature 80 aqueous solution above-mentioned former medicine is diluted to desired concn at last.
3.1.3 experimental scheme
3.1.3.1 the synergy of trifloxysulfuron and quizalofopPtefuryl
Trifloxysulfuron, the agent of quizalofopPtefuryl list and 5 trifloxysulfurons and quizalofopPtefuryl mixture preparation are established 5 dosage respectively, and said ratio is the weight ratio of trifloxysulfuron and quizalofopPtefuryl.Other establishes blank, and repetition 4 times is handled in each test.Handle drug dose and see table 1 for details.
Table 1 test is handled and test level (concentration ga.i./mu)
3.2 application method
3.2.1 application method
Handle in 3 leaf phases of cotton, the spraying of weeds 2-5 leaf phase cauline leaf.The spray medicine adopts the indoor overhead traveling crane formula spray testing device of adjustable speed, the conventional spray method in simulation field.Shower nozzle is a Fan spray head, and model is the Teejer8002E type, 40 kilograms/mu of spray values.0.5 meter of spray height, 0.7 meter of spraying swath, leg speed 0.224 meter per second.Atomisation pressure 2.0 MPas, 697 liters/minute of flows.
3.2.2 spraying time and number of times
Test and carry out reagent spray on May 12nd, 2010 and handle dispenser 1 time.
4 investigation methods
The symptom of being injured of detail record cotton and weeds after the dispenser, 20d behind the medicine carries out fresh weight and measures, and compares with control treatment, calculates the fresh weight preventive effect.
4.1 synergy assay method
Synergy type after result of the test is used with the co-toxicity coefficient method evaluation of Sun Yunpei.
According to SUN, Y-P (Sun Yunpei) method is calculated its actual toxicity index, the theoretical toxicity index of mixture, co-toxicity coefficient.With the concentration logarithm is X, and damage by disease and insect preventive effect probit value is Y, asks regression equation.
Actual toxicity index=standard medicament LD
50The LD of/mixture
50* 100
Theoretical toxicity index=∑ (supplying the toxicity index * percentage of this medicament active ingredient in mixture of reagent agent)
The actual toxicity index of co-toxicity coefficient=mixture/theoretical toxicity index * 100
Be the standard medicament with the quizalofopPtefuryl in the test.
Criterion: co-toxicity coefficient<80 are antagonism, are summation action between 80-120, and>120 are synergistic effect.
5 results and analysis
5.1 the synergy of trifloxysulfuron and quizalofopPtefuryl
5.1.1 trifloxysulfuron and quizalofopPtefuryl are mixed to the fresh weight preventive effect of weeds, the result sees table 2.
Table 2 trifloxysulfuron and quizalofopPtefuryl are mixed behind the medicine 20d to the fresh weight preventive effect of weeds
Control efficiency is the mean value of four data in the table.
5.1.2 trifloxysulfuron and quizalofopPtefuryl are mixed to the synergy of weeds
Can be known by table 2: medicament is to toxic action situation and the preventive effect of weeds.Calculate its virulence regression equation, LD separately through formula
50, actual toxicity index, theoretical toxicity index and co-toxicity coefficient.List in table 3.
Table 3: trifloxysulfuron and quizalofopPtefuryl are mixed to the synergy of weeds
Handle | Regression equation | Correlation coefficient | LD 50 | Actual toxicity index | Theoretical toxicity index | Coefficient of synergism |
A | Y=1.3412x+4.9735 | 0.9934 | 1.0466 | 354.83 | / | / |
B | Y=0.8049x+4.5414 | 0.9895 | 3.7136 | 100 | / | / |
C | Y=1.2283x+4.8637 | 0.9928 | 1.2911 | 287.63 | 303.86 | 94.66 |
D | Y=1.3157x+5.1818 | 0.9928 | 0.7275 | 510.46 | 269.88 | 189.14 |
E | Y=1.3760x+5.3462 | 0.9966 | 0.5603 | 662.79 | 227.42 | 291.44 |
F | Y=1.3110x+5.0687 | 0.9889 | 0.8863 | 419.00 | 201.93 | 207.50 |
G | Y=1.1882x+4.7964 | 0.9935 | 1.4837 | 250.29 | 184.95 | 135.33 |
Can know that by test the co-toxicity coefficient of handling C, D, E, F, G is respectively: 94.66,189.14,291.44,207.50,135.33, wherein the co-toxicity coefficient of D, E, F, G has synergistic effect greater than 120.Wherein with the co-toxicity coefficient of handling E obviously greater than 120, reach remarkable synergistic effect.
5.1.3 conclusion (of pressure testing)
Can know that through test trifloxysulfuron, that quizalofopPtefuryl is mixed in 1: 0.5~1.5 ratios is comparatively suitable, annual single broadleaf weed and nutgrass flatsedge are had significant synergies.
6 overall merits
Measure the result by above synergy and show that the two is preferable with the composite effect of 1: 0.5~1.5 ratio for trifloxysulfuron and quizalofopPtefuryl, wherein both are with 1: 1 the ratio best results that is mixed.
Embodiment 7: the composite cauline leaf of trifloxysulfuron quizalofopPtefuryl is handled the safety determination test to cotton
1, test objective:
Under greenhouse experiment, adopt the pot experiment method, research trifloxysulfuron, quizalofopPtefuryl binary built cauline leaf are handled the safety to cotton, for rationally being mixed of trifloxysulfuron and quizalofopPtefuryl provides scientific basis.
2, experimental condition
2.1 supply to study the thing cotton variety: tuck in single No. 2
2.2 supply examination weeds lady's-grass (Digitaria sanguinalis (Linn.) Scop.); Green foxtail (Setaria viridis (L.) Beauv.); Acalypha copperleaf (Acalypha australis L.); Lamb's-quarters (Chenopodium album L.) (last one year the field seed of gathering, germination rate is more than 85%).
2.3 the cultivation of experimental condition and examination material
In the illumination cultivation chamber, the make an experiment cultivation of material, temperature 25-35 ℃.Choosing diameter is 15cm, highly is the vinyon basin alms bowl of 15cm, and the permeable hole of 1cm diameter is beaten in the bottom of basin alms bowl.Permeable hole covers with double-deck filter paper, and soil is soaked into clear water from the bottom in the high 10cm of loam to the alms bowl place that the preparation in advance of packing in the alms bowl was sterilized.During test, 20, every kind weed seed 30-40 of cotton seeds grain is evenly put into basin earthing 0.5cm, put into the greenhouse and cultivate (25-30 ℃), should replenish the required moisture of growth between cotton seedling and weeds culture period.Stay the healthy and strong seedling of 10 strains after all sprouting, treat that cotton seedling length to 3~4 leaves and weeds grow to handle to dispenser in 3~5 o'clock.
2.4 other condition
With the regular moisturizing of mode (not watering in 2 days behind the medicine) of bottom infiltration, keep soil moisture.
3 experimental scheme
3.1 medicament
3.1.1 supply the reagent agent
The former medicine of 95% trifloxysulfuron (Anhui Fengle Agricultural Co., Ltd, lab scale sample);
The former medicine of 95% quizalofopPtefuryl (Shangyu Nutrichem Co., Ltd).
3.1.2 supply the preparation of reagent agent soup
Take by weighing quantitative former medicine with electronic balance, add an amount of emulsifier, use acetone solution, with 0.1% soil temperature 80 aqueous solution above-mentioned former medicine is diluted to desired concn at last.
3.2 application method
3.2.1 application method
Handle in 3 leaf phases of cotton, the spraying of weeds 2-4 leaf phase cauline leaf.The spray medicine adopts the indoor overhead traveling crane formula spray testing device of adjustable speed, the conventional spray method in simulation field.Shower nozzle is a Fan spray head, and model is the Teejer8002E type, 40 kilograms/mu of spray values.0.5 meter of spray height, 0.7 meter of spraying swath, leg speed 0.224 meter per second.Atomisation pressure 2.0 MPas, 697 liters/minute of flows.
3.2.2 spraying time and number of times
Tested in the 3 leaf phases of cotton and carry out reagent spray processing, dispenser 1 time.
4 investigation and computational methods
4.1 crop investigation
After the dispenser, investigation is respectively handled cotton and is had or not symptom of chemical damage, if then detail record symptom of chemical damage, grade are arranged, and behind the medicine 20 days, measure that respectively to handle cotton fresh heavy, calculate the fresh weight inhibiting rate, with of the safety of clear and definite test medicine to cotton.
4.2 weeds investigation
The symptom of being injured of detail record weeds (like growth inhibition, chlorosis, deformity etc.) after the dispenser, behind medicine 20 days, weeds acrial part fresh weight was respectively handled in weighing, calculated the fresh weight preventive effect of weeds.
4.3 computational methods
With DPS software the logarithm value of drug dose and the probability value of cotton fresh weight inhibiting rate are carried out regression analysis, the dosage ED when calculating correlation coefficient and suppressing crop 10%
10, and suppress weeds 90%ED
90, obtain selectivity index.
Selectivity index=ED
10/ ED
90
5 results and analysis
5.1 trifloxysulfuron quizalofopPtefuryl cauline leaf is handled the safety to cotton
The safety evaluatio standard is seen table 4, observes in 3 days after the dispenser, and trifloxysulfuron quizalofopPtefuryl high concentration 1080mg/kg handles indivedual cotton lobus cardiacus distortions, and growth is suppressed, and it is normal basically that low concentration is handled cotton growth; After the dispenser 7-12 days, it is normal that low concentration is handled the cotton growing way, and 1080mg/kg handles cotton and also slowly recovers.20 days 85% trifloxysulfuron quizalofopPtefuryl oil-suspending agents are seen table 5 to the inhibitory action of cotton after the dispenser.
Table 4 activity of weeding and crop safety ocular estimate evaluation criterion
Table 5 85% trifloxysulfuron quizalofopPtefuryl water dispersible granules (WG) is to the inhibitory action of cotton
Table 6 85% trifloxysulfuron quizalofopPtefuryl water dispersible granules (WG) is to the fresh weight preventive effect of weeds
Can know toxic action situation and the preventive effect of this medicament by table 6, calculate its virulence regression equation, LD respectively through formula to weeds
50, list in table 7.
Table 7: virulence regression equation and LD
50
Handle | Regression equation | Correlation coefficient | LD 50 | 95% confidence interval |
A | Y=2.6104+0.6174x | 0.9960 | 47.7440 | 41.5264~54.0394 |
Can know by table 7: the LD of 85% trifloxysulfuron quizalofopPtefuryl water dispersible granules (WG)
50For: 47.6937,95% confidence intervals are 41.4710~53.9938.
5.2 trifloxysulfuron quizalofopPtefuryl cauline leaf is handled the selectivity index to cotton and weeds
By table 5, table 6, try to achieve the ED that suppresses cotton growth 10% through DPS software
10=633.5774, the ED of inhibition weed growth 90%
90=147.8637, selectivity factor is 633.5774/147.8637=4.28>2, thinks that this medicament has obvious selectivity, can carry out field control effectiveness test.
6 overall merits
6.1 this result of the test shows that trifloxysulfuron quizalofopPtefuryl cauline leaf treatment of high concentration is handled and can be caused cotton yellow, indivedual plant distortion to cotton, it is normal that other concentration is handled cotton growth.
6.2 can know that through Toxicity Determination the trifloxysulfuron quizalofopPtefuryl has good control efficiency to weeds.
Embodiment 8: complex weedicide field control effectiveness test according to the invention
Complex weedicide according to the invention shows through the field control effectiveness test in 2 years; In 2~4 leaf phases of cotton, weeds 2-5 leaf does not wait the phase, utilizes 80,100,120,150 milliliters/mu of 6% trifloxysulfuron quizalofopPtefuryl (3+3) oil-suspending agent dosage of the present invention; Converting water sprays for 40 kilograms/mu; 10,30 days and maturing stage range estimation cotton safety property and weeds preventive effect, surveyed at preventive effect result such as following table in 10,30 days:
Through range estimation, cotton does not see symptom of chemical damage from the dispenser to the maturing stage, to cotton safety.The preventive effect of weeds reached more than 80% in 10 days; Reached more than 90% in 30 days, along with the increase of dosage, preventive effect obviously strengthens; 100 milliliters/mu can reach good herbicidal effect in the cotton field; Compare with wherein a kind of active ingredient of independent use, enlarged and killed the grass spectrum, broad leaved weed is had obvious synergistic effect.A dispenser can be controlled the weeds in the crop whole growth phase, and not only herbicidal effect is remarkable, and environmentally friendly, and second stubble crop is not had influence, and is little to the pollution of environment, to people, animal, birds and beneficial organism safety, helps keeping ecological balance.In addition, weed killer herbicide of the present invention adopts physical method processing, and production technology is simple, and three-waste free discharge in the production process has no adverse effects to ecotope.It is the desirable complex weedicide of present control efficiency.
The above only is a preferred implementation of the present invention; Should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention; Can also make some improvement and retouching, these improvement and retouching also should be regarded as protection scope of the present invention.
Claims (5)
1. a complex weedicide that is used for the cotton field is characterized in that, comprises trifloxysulfuron and quizalofopPtefuryl, and the weight ratio of trifloxysulfuron and quizalofopPtefuryl is 1: 0.5-1: 1.5.
2. complex weedicide according to claim 1 is characterized in that, the weight ratio of trifloxysulfuron and quizalofopPtefuryl is 3: 2-7: 10.
3. complex weedicide according to claim 1 is characterized in that, the weight ratio of trifloxysulfuron and quizalofopPtefuryl is 1: 1.
4. complex weedicide according to claim 1 is characterized in that, the quality percentage composition of trifloxysulfuron and quizalofopPtefuryl is 4~85% of a said complex weedicide.
5. according to each described complex weedicide of claim 1-4, it is characterized in that said complex weedicide is agriculture common formulations such as oil-suspending agent, wetting powder, water dispersible granules.
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Cited By (3)
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CN105724405A (en) * | 2016-03-14 | 2016-07-06 | 南京华洲药业有限公司 | Herbicidal composition containing trifloxysulfuron and oxylfluorfen and application thereof |
CN105724404A (en) * | 2016-03-14 | 2016-07-06 | 南京华洲药业有限公司 | Herbicidal composition containing trifloxysulfuron and quizalofop-p-tefuryl and application thereof |
CN107318871A (en) * | 2016-04-28 | 2017-11-07 | 浙江中山化工集团股份有限公司 | A kind of potato ground weeding agricultural chemical compositions |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105724405A (en) * | 2016-03-14 | 2016-07-06 | 南京华洲药业有限公司 | Herbicidal composition containing trifloxysulfuron and oxylfluorfen and application thereof |
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CN105724405B (en) * | 2016-03-14 | 2018-07-17 | 南京华洲药业有限公司 | A kind of Herbicidal combinations and its application containing trifloxysulfuron and Oxyfluorfen |
CN107318871A (en) * | 2016-04-28 | 2017-11-07 | 浙江中山化工集团股份有限公司 | A kind of potato ground weeding agricultural chemical compositions |
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