Summary of the invention
The objective of the invention is: a kind of metallic film electric capacity and preparation method thereof is provided, and its each item performance is outstanding, with low cost, is easy to industrialization, to overcome the deficiency of prior art.
The present invention is achieved in that metallic film electric capacity; Comprise insulated substrate; Be provided with the metal film electrode
of band exit
at the top of insulated substrate; Be provided with dielectric film on metal film electrode
surface outside exit
interface, be provided with the metal film electrode
of band exit
at the top of dielectric film.
On exit
and exit
surface in addition, all be provided with the passivation protection film, its material is silicon dioxide or silicon nitride.Material requirements as the passivation protection film has good insulation performance and temperature stability.
The thickness of metal film electrode
and metal film electrode
is respectively 0.1~0.3 μ m, and their material is one or more the alloy in tantalum, niobium, aluminium, copper, the silver.It is very low that these metals and their alloy have resistivity, but high temperature high voltage resistant has high stability, can adapt to characteristics such as various complicated.
The thickness of dielectric film is 0.04~0.06 μ m, and its material is tantalum pentoxide or aluminium oxide.Their dielectric constant is high, good heat resistance, and good film-forming property, mechanical strength is high, and the insulating properties energy consumption of the dielectric film for preparing can prevent capacitance short-circuit, reduces leakage current.
The preparation method of metallic film electric capacity; Adopt mask technique; Deposition more than one metal film electrode
obtains semi-finished product A on insulated substrate; On semi-finished product A, adopt mask technique to deposit dielectric film, obtain semi-finished product B; On semi-finished product B, adopt mask technique to deposit metal film electrode
; And on metal film electrode
and metal film electrode
, reserve exit
and exit
respectively, obtain semi-finished product C; After semi-finished product C cut, obtain the single metal thin-film capacitor, and draw capacitance electrode from exit, packing obtains finished product after handling again.
On the semi-finished product C surface beyond the exit, deposit the passivation protection film.
Metal film electrodes
, dielectric film and metal film electrodes
deposition method is a physical or chemical vapor deposition.Through each film even compact that vapour deposition process obtains, capacitive property is high.
Semi-finished product A, semi-finished product B, semi-finished product C are heat-treated respectively, and heat treated temperature is 700~800 ℃, and the processing time is 25~35 minutes.As required metal film electrode
, dielectric film and metal film electrode
are heat-treated; Eliminate film defects, improve device performance.
Tantalum pentoxide and aluminium oxide have very high dielectric constant (tantalum pentoxide is 27, and aluminium oxide is 39.9, and plastic film is about 3), fusing point high (tantalum pentoxide is about 1800 ℃), stable chemical performance, corrosion-resistant and Heat stability is good.Be dielectric film capacitor CV density big (be under the same voltage conditions, the capacitance of unit volume is big) with tantalum pentoxide or aluminium oxide etc., (ESR) is little for equivalent series resistance, and leakage current is little.The metal film electrode of deposition has the self-recovery performance, and the reliability of opposing insulation breakdown is higher, can under extraordinary conditions such as high temperature or low temperature, use, and has long-term stability.This thin-film capacitor can be applied in numerous high-tech areas such as electronics, space flight, military affairs.
Owing to adopted above-mentioned technical scheme; Compared with prior art, the present invention adopts tantalum pentoxide etc. both to insulate, and has film that the material of good chemical stability processes again as dielectric; It is low to solve the dielectric dielectric constant of general film capacitor; Problems such as heat-resisting poor, film forming is poor, and mechanical strength is low.And through masking process, deposition double layer of metal film has greatly reduced metal consumption as upper/lower electrode, has reduced production cost, and manufacture craft is simple.Select for use metals such as tantalum, niobium, copper, silver or their alloys as metal film electrode, their resistivity is very low, but and high temperature high voltage resistant, have advantages of higher stability, can adapt to various complicated.In addition, utilize preparation method of the present invention can carry out industrialization production, have important practical significance.Method of the present invention is simple, easy realization of industrialization production, and the cost of making is comparatively cheap, and resulting product has better physical performance and chemical stability, long service life, cost of manufacture is lower, is with a wide range of applications.
Embodiment
Embodiments of the invention 1: the structure of metallic film electric capacity is as shown in Figure 1, comprises aluminium oxide (Al
2O
3) insulated substrate 4 processed, be provided with the band exit at the top of insulated substrate 4
7 metal film electrode
1, metal film electrode
1 thickness is 0.2 μ m, and material is a tantalum, at exit
The metal film electrode that 6 interfaces are outer
1 surface is provided with the dielectric film 2 that thickness is 0.05 μ m, and its material is a tantalum pentoxide; Be provided with the band exit at the top of dielectric film 2
7
metal film electrode
3,
metal film electrode
3 thickness is 0.2 μ m, and material is a niobium; At
exit
6 and exit
All being provided with the silicon nitride on the surface beyond 7 is the passivation protection film 5 of material.
The preparation method of metallic film electric capacity is at the aluminium oxide (Al of cleaning
2O
3) lay one deck mask on the insulated substrate, adopt magnetron sputtering method, be material with the tantalum, deposit the thick metal film electrode of more than one 0.20 μ m
, obtain semi-finished product A; A heat-treats with semi-finished product, and heat treated temperature is 750 ℃, and the processing time is 30 minutes; Laying mask handling on the semi-finished product A, and adopted magnetron sputtering method, is material with the tantalum pentoxide, and depositing thickness is the matter film of 0.05 μ m, obtains semi-finished product B; B heat-treats with semi-finished product, and heat treated temperature is 750 ℃, and the processing time is 30 minutes; On the semi-finished product B that handled, laying mask, adopt magnetron sputtering method, is material with the niobium, and depositing thickness is 0.20 μ m metal film electrode
, and at metal film electrode
,
On reserve exit respectively
And exit
, obtain semi-finished product C; C heat-treats with semi-finished product, and heat treated temperature is 750 ℃, and the processing time is 30 minutes; Adopt magnetron sputtering method; With the silicon nitride is material; Deposit the passivation protection film on the semi-finished product C surface beyond the exit, after the semi-finished product C that will deposit the passivation protection film again cuts, obtain the single metal thin-film capacitor; And with coated with graphite back spray silver slurry extraction electrode on exit, packing obtains finished product after handling again.
Embodiment 2 of the present invention: a metal film capacitors, including aluminum nitride insulating substrate 4, the top of the insulating substrate 4 has a leading end with
6 metal film electrodes
1, the metal film electrodes
1 has a thickness of 0.1μm, material is aluminum, the
terminals
6 interfaces of the metal film electrodes
1 has a thickness of 0.04μm on the surface of the dielectric film 2, the material is tantalum pentoxide; the top of the dielectric film 2 has a leading end with
7
metal film electrode
3, the
metal film electrodes
3 has a thickness of 0.1μm, material for the silver; at
terminals
6 and terminations
7 outside surface has a silica-based material passivation film 9.
The preparation method of metallic film electric capacity; On the aluminium nitride insulated substrate of cleaning, lay one deck mask; Adopt magnetron sputtering method; With aluminium is material, deposits the thick metal film electrode of more than one 0.10 μ m
, obtains semi-finished product A; A heat-treats with semi-finished product, and heat treated temperature is 700 ℃, and the processing time is 35 minutes; Laying mask handling on the semi-finished product A, and adopted magnetron sputtering method, is material with the tantalum pentoxide, and depositing thickness is the matter film of 0.04 μ m, obtains semi-finished product B; B heat-treats with semi-finished product, and heat treated temperature is 700 ℃, and the processing time is 35 minutes; On the semi-finished product B that handled, lay mask; Adopt magnetron sputtering method; With silver is material; Depositing thickness is 0.10 μ m metal film electrode
; And on metal film electrode
,
, reserve exit
and exit
respectively, obtain semi-finished product C; C heat-treats with semi-finished product, and heat treated temperature is 700 ℃, and the processing time is 35 minutes; Adopt the PECVD method; On the semi-finished product C surface beyond the exit, deposit silicon dioxide passivation protection film; After the semi-finished product C that will deposit the passivation protection film again cuts, obtain the single metal thin-film capacitor, and to the exit metal spraying; Through the wave-soldering extraction electrode, packing obtains finished product after handling again on gilding layer.
Embodiment 3 of the present invention: a metal film capacitor, including a ceramic substrate made of an insulating substrate 4, the top of the insulating substrate 4 has a leading end with
7 metal film electrodes
1, the metal film electrodes
1 has a thickness of 0.3μm, Material is copper alloy, in
terminations
6 interfaces of the metal film electrodes
1 on the surface of a dielectric film thickness of 0.06μm 2, the material is alumina; dielectric film 2 in the top of a bathroom with terminations
7
metal film electrode
3, the
metal film electrodes
3 has a thickness of 0.3μm, material is copper niobium alloys; at
terminals
6 and terminations
7 on a surface other than have a silicon nitride passivation film as the material 5.
The preparation method of metallic film electric capacity; On the ceramic substrate insulated substrate of cleaning, lay one deck mask; Adopt magnetron sputtering method; With the albronze is material, deposits the thick metal film electrode of more than one 0.30 μ m
, obtains semi-finished product A; A heat-treats with semi-finished product, and heat treated temperature is 800 ℃, and the processing time is 25 minutes; Laying mask handling on the semi-finished product A, and adopted magnetron sputtering method, is material with the aluminium oxide, and depositing thickness is the matter film of 0.06 μ m, obtains semi-finished product B; B heat-treats with semi-finished product, and heat treated temperature is 800 ℃, and the processing time is 25 minutes; On the semi-finished product B that handled, lay mask; Adopt magnetron sputtering; With the copper niobium alloy is material; Depositing thickness is 0.30 μ m metal film electrode
; And on metal film electrode
,
, reserve exit
and exit
respectively, obtain semi-finished product C; C heat-treats with semi-finished product, and heat treated temperature is 800 ℃, and the processing time is 25 minutes; Adopt the PECVD method; With the silicon nitride is material; Deposit the passivation protection film on the semi-finished product C surface beyond the exit, after the semi-finished product C that will deposit the passivation protection film again cuts, obtain the single metal thin-film capacitor; And with coated with graphite back spray silver slurry extraction electrode on exit, packing obtains finished product after handling again.