CN102382558A - Short-oil-length alkyd resin and matte varnish - Google Patents
Short-oil-length alkyd resin and matte varnish Download PDFInfo
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- CN102382558A CN102382558A CN2011102791742A CN201110279174A CN102382558A CN 102382558 A CN102382558 A CN 102382558A CN 2011102791742 A CN2011102791742 A CN 2011102791742A CN 201110279174 A CN201110279174 A CN 201110279174A CN 102382558 A CN102382558 A CN 102382558A
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- alcohol
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- matte varnish
- short oil
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Abstract
The invention provides a short-oil-length alkyd resin and a matte varnish utilizing the short-oil-length alkyd resin as a key film-forming material. The oil length of the short-oil-length alkyd resin is 30% to 30.5%, and when the matte varnish is in synthesis, part of ethylene glycol is added to adjust functionality so a to achieve the goal of improvement of molecular weight. The matte varnish solves the problem that a traditional short-oil-length alkyd resin coating often grows dim and is scratched easily in autumn and winter seasons.
Description
Technical field
The present invention relates to a kind of Synolac and with the clear finish of said alkyd resin production, relate in particular to a kind of short oil-ity alcohol acid resin and with the matte varnish that do not grow dim of said short oil-ity alcohol acid resin preparation.
Background technology
Synolac is the relatively low polymkeric substance of a kind of molecular weight, and the esterification through polyprotonic acid and polyvalent alcohol makes, and carries out modification with grease or lipid acid.In air dried process, can carry out oxidation to unsaturated fatty acids, thereby form cross-linked network.
Along with skyrocketing of oil price; And the worsening shortages of the energy, oil is relied on less phthalic resin coating demonstrate its meliority day by day, and; Along with the restricted rules about the VOC discharging constantly increase; The alkide resin emulsion used water substitutes organic solvent, thereby can be used as a kind of effective tool of the VOC of reduction content, has been widely used at present to produce high-quality decorative paint.
Phthalic resin coating itself does not exist the many shortcomings on the performance, and is high like hardness of paint film, drying property is poor.The oil content of Synolac has very big influence to performance, and Synolac oil content is short more, and second-order transition temperature is high more, and is fast more to the release of solvent, and drying property is good more, and protect light tint retention ability better.The Synolac that therefore present coating is used is short oil-ity alcohol acid resin, and especially oil content is at the short oil-ity alcohol acid resin more than 31%.
But the practice through for many years finds that the short oil-ity alcohol acid resin that uses at present changes over to after autumn and winter season every year, and the scuffing phenomenon of growing dim all appears in the furniture surface of a lot of furniture manufacturers easily; Tracing it to its cause is every autumn and winter season, and temperature reduces significantly, and particularly the region following the line of the sea is influenced by the ocean; Atmospheric moisture is than higher, and when under this low temperature and high humidity environment, constructing, the paint film temperature reduces rapidly with solvent evaporates; Cause moisture in the high humidity environment to condense into steam rapidly and invest coating surface; Because envrionment temperature is low, be easy to reach the freezing point of water, so the moisture in the paint film is difficult to volatilization in the drying process; Long term causes uneven drying even in paint film, and causes paint film grey hair flower and scuffing easily.And, the phase reversion phenomenon can appear during the phthalic resin coating solvent evaporates, and the paint film that causes forming no longer has homogeneity.
Summary of the invention
The invention provides a kind of new Synolac and the phthalic resin coating that uses said alkyd resin production; Utilize special short-oil alkyd to adjust paint film and do speed; Make the paint film top layer stable rapidly; Let the water function paint film time shorten, the easy problem that scratches thereby solution traditional alkyd resins coating grows dim.
First purpose of the present invention provides a kind of new short oil-ity alcohol acid resin, and said short oil-ity alcohol acid resin is prepared through polycondensation by sour and/or oily and alcohol, wherein:
Said acid comprises lipid acid, polycarboxylic acid and/or its acid anhydrides;
Said alcohol is the mixture that comprises at least two kinds of polyvalent alcohols of terepthaloyl moietie.
The short oil-ity alcohol acid resin that the present invention is above-mentioned, oil content is preferably 30 ~ 30.5%.
The short oil-ity alcohol acid resin that the present invention is above-mentioned, number-average molecular weight is preferably 10000 ~ 100000.
Second purpose of the present invention provides a kind of preparation method of above-mentioned short oil-ity alcohol acid resin, is raw material with sour and/or oily and alcohol, carries out polycondensation, wherein:
Acid comprises lipid acid, polycarboxylic acid and/or its acid anhydrides;
Said alcohol is the mixture that comprises at least two kinds of polyvalent alcohols of terepthaloyl moietie.
The 3rd purpose of the present invention provides a kind of matte varnish that comprises above-mentioned short oil-ity alcohol acid resin.Said short oil-ity alcohol acid resin is prepared through polycondensation by sour and/or oily and alcohol, wherein:
Said acid comprises lipid acid, polycarboxylic acid and/or its acid anhydrides;
Said alcohol is the mixture that comprises at least two kinds of polyvalent alcohols of terepthaloyl moietie.
In the above-mentioned clear finish of the present invention, said short oil-ity alcohol acid resin, oil content is preferably 30 ~ 30.5%, most preferably is 30.1%.
In the above-mentioned clear finish of the present invention, said short oil-ity alcohol acid resin, number-average molecular weight is preferably 5000 ~ 100000.
Said matte varnish also comprises solvent, auxiliary agent, filler or the like, and said clear finish solid content is preferably 65 ~ 80%, most preferably is 70%.
A kind of preferred implementation of above-mentioned matte varnish according to the present invention, component comprises:
Above-mentioned short oil-ity alcohol acid resin 75 ~ 80 weight parts;
Solvent 10 ~ 15 weight parts;
Can also comprise:
Filler 7 ~ 9 weight parts;
Auxiliary agent 1 ~ 3 weight part.
Wherein, said solvent can be water, aromatic hydrocarbons, esters solvent;
Said filler can be toughener, pigment, like lime carbonate, calcium sulfate, Calucium Silicate powder, silicon-dioxide, Magnesium Silicate q-agent (talcum powder), pure aluminium silicate (kaolin, china clay), permanent white (tiff), mica.
Said auxiliary agent can be softening agent, skimmer, oxidation inhibitor, UV stabilizer or UV light absorber, dispersion agent, wetting agent, flow agent or the like.
Foregoing of the present invention, wherein:
Said polycarboxylic acid and/or its acid anhydrides comprise phthalic acid and/or Tetra hydro Phthalic anhydride, can also comprise a spot of MALEIC ANHYDRIDE (cis-butenedioic anhydride) and/or maleic acid.
Said alcohol also comprises trivalent alcohol and/or tetravalent alcohol, trivalent alcohol such as glycerine, TriMethylolPropane(TMP) (2-ethyl-2-methylol-1, ammediol), tetravalent alcohol such as tetramethylolmethane or the like; Said trivalent alcohol or tetravalent alcohol also can be preparation Synolac other polyvalent alcohols commonly used.
In said alcohol mixture, said terepthaloyl moietie and other polyvalent alcohol mol ratio are 6 ~ 7.5:10.
Said unsaturated fatty acids can be soybean oleic acid, linolic acid, cocinic acid or preparation Synolac other lipid acid commonly used; Should be understood that; Unsaturated fatty acids described in the present invention also can adopt corresponding oil to replace; Like glycerine three unsaturated fatty acid esters, VT 18, Oleum Cocois or the like, and comprise within the scope of the present invention equally.
Oil content of the present invention refers to the weight percent of oil-containing in the alkyd solids (lipid acid).
The present invention adds the adjustment that part terepthaloyl moietie carries out functionality; The Synolac molecular weight is increased, design the shorter Synolac of oil content, use the short oil-ity alcohol acid resin coatings formulated that is designed; Rate of drying is fast; The paint film steady speed is fast, therefore, reduced that growing dim appears in coating surface that attachment of moisture causes and being easy to of becoming scratches.
Embodiment
The matte varnish that the invention provides a kind of short oil-ity alcohol acid resin and comprise said short oil-ity alcohol acid resin, said short oil-ity alcohol acid resin is prepared through polycondensation by sour and/or oily and alcohol, wherein:
Said acid comprises unsaturated fatty acids, diprotic acid or its acid anhydrides;
Said alcohol comprises polyvalent alcohol and terepthaloyl moietie, and said polyvalent alcohol and terepthaloyl moietie mol ratio are 10:7.
Said short oil-ity alcohol acid resin oil content is 30 ~ 30.5%, and molecular weight is preferably 5000 ~ 100000.
Said matte varnish component comprises:
Above-mentioned short oil-ity alcohol acid resin 75 ~ 80 weight parts;
Solvent 10 ~ 15 weight parts;
Can also comprise:
Filler 7 ~ 9 weight parts;
Auxiliary agent 1 ~ 3 weight part.
Below through specific embodiment, to short oil-ity alcohol acid resin of the present invention and comprise that the matte varnish of said short oil-ity alcohol acid resin carries out detailed introduction and description, consciousness is better understood the scope of the invention, but following embodiment does not limit the scope of the invention.
Embodiment 1
In the present embodiment, the short oil-ity alcohol acid resin oil content that is designed is 30.1%.According to this oil content, with soybean oleic acid, Tetra hydro Phthalic anhydride, with tetramethylolmethane and terepthaloyl moietie polycondensation, the polycondensation method can adopt state of the art to implement.
Wherein, tetramethylolmethane and terepthaloyl moietie mol ratio are 10:7.
The matte varnish component is following in the present embodiment:
Above-mentioned short oil-ity alcohol acid resin 75 weight parts;
Solvent 12 weight parts.
Embodiment 2
In the present embodiment, the short oil-ity alcohol acid resin oil content that is designed is 30.1%.According to this oil content, with soybean oleic acid, Tetra hydro Phthalic anhydride, with tetramethylolmethane and terepthaloyl moietie polycondensation, the polycondensation method can adopt state of the art to implement.
Wherein, TriMethylolPropane(TMP) and terepthaloyl moietie mol ratio are 10:7.
The matte varnish component is following in the present embodiment:
Above-mentioned short oil-ity alcohol acid resin 78 weight parts;
Solvent 12 weight parts.
Filler 7 ~ 9 weight parts;
Auxiliary agent 1 ~ 3 weight part.
Embodiment 3
In the present embodiment, the short oil-ity alcohol acid resin oil content that is designed is 30.1%.According to this oil content, with soybean oleic acid, Tetra hydro Phthalic anhydride, a small amount of cis-butenedioic anhydride, with tetramethylolmethane and terepthaloyl moietie polycondensation, the polycondensation method can adopt state of the art to implement.
Wherein, tetramethylolmethane and terepthaloyl moietie mol ratio are 10:7.
The matte varnish component is following in the present embodiment:
Above-mentioned short oil-ity alcohol acid resin 78 weight parts;
Solvent 12 weight parts.
Filler 7 ~ 9 weight parts;
Auxiliary agent 1 ~ 3 weight part.
Embodiment 4
In the present embodiment, the short oil-ity alcohol acid resin oil content that is designed is 30.5%.According to this oil content, with soybean oleic acid, Tetra hydro Phthalic anhydride, a small amount of cis-butenedioic anhydride, with tetramethylolmethane, TriMethylolPropane(TMP) and terepthaloyl moietie polycondensation, the polycondensation method can adopt state of the art to implement.
Wherein, TriMethylolPropane(TMP), tetramethylolmethane summation and terepthaloyl moietie mol ratio are 10:6.5.
The matte varnish component is following in the present embodiment:
Above-mentioned short oil-ity alcohol acid resin 80 weight parts;
Solvent 10 weight parts.
Filler 9 weight parts;
Auxiliary agent 2 weight parts.
Embodiment 5
In the present embodiment, the short oil-ity alcohol acid resin oil content that is designed is 30.3%.According to this oil content, with soybean oleic acid, Tetra hydro Phthalic anhydride, a small amount of cis-butenedioic anhydride, with tetramethylolmethane, TriMethylolPropane(TMP) and terepthaloyl moietie polycondensation, the polycondensation method can adopt state of the art to implement.
Wherein, TriMethylolPropane(TMP), tetramethylolmethane summation and terepthaloyl moietie mol ratio are 10:6.
The matte varnish component is following in the present embodiment:
Above-mentioned short oil-ity alcohol acid resin 76 weight parts;
Solvent 15 weight parts.
Filler 7 weight parts;
Auxiliary agent 3 weight parts.
Embodiment 6
In the present embodiment, the short oil-ity alcohol acid resin oil content that is designed is 30.4%.According to this oil content, with soybean oleic acid, Tetra hydro Phthalic anhydride, a small amount of cis-butenedioic anhydride, with tetramethylolmethane, TriMethylolPropane(TMP) and terepthaloyl moietie polycondensation, the polycondensation method can adopt state of the art to implement.
Wherein, TriMethylolPropane(TMP), tetramethylolmethane summation and terepthaloyl moietie mol ratio are 10:7.5.
The matte varnish component is following in the present embodiment:
Above-mentioned short oil-ity alcohol acid resin 80 weight parts;
Solvent 15 weight parts.
Filler 8 weight parts;
Auxiliary agent 1 weight part.
Clear finish in the foregoing description becomes paint film according to prior art for preparing, and through transmission electron microscope observation, the paint film density homogeneous of the present invention's preparation is explained the paint film property homogeneous.And the paint film structure basically no longer changes after 10 minutes, explains that the paint film steady speed of the above-mentioned clear finish formation of the present invention is fast.Through test, the hardness of paint film that clear finish of the present invention forms is more than H, and sticking power is 1 grade, meets the furniture production requirement.
In the matte varnish provided by the invention, short oil-ity alcohol acid resin is crucial filmogen, and it has the characteristics of hardness height, fast drying; The oil content of general short oil-ity alcohol acid resin component design is more than 31%, and the present invention 30 ~ 30.5, carries out the design of short oil-ity alcohol acid resin oil content in order to react normally; And do molecular weight greatly, add part terepthaloyl moietie adjustment functionality, to guarantee molecular balance; Molecular weight is done greatly, reached that sold resin is done soon, the stable advantage of paint film.
Than traditional phthalic resin coating, matte varnish provided by the invention, coating surface can be stablized rapidly, has reduced the time of water function in paint film, thereby has solved the problem that furniture surface grows dim and scratches easily.
Through the description of the foregoing description, those skilled in the art can be understood that, the difference of the lipid acid that adopts in the short oil-ity alcohol acid resin according to the present invention can be prepared into dry alkyd resin, and air dry or adding siccative carry out oxidation cross-linked drying and forming-film; Or the adding POLYMETHYLENE POLYPHENYLISOCYANATE is made into the two-component air-dry lacquer.
More than specific embodiment of the present invention is described in detail, but it is just as example, the present invention is not restricted to the specific embodiment of above description.To those skilled in the art, any equivalent modifications that the present invention is carried out with substitute also all among category of the present invention.Therefore, not breaking away from impartial conversion and the modification of being done under the spirit and scope of the present invention, all should contain within the scope of the invention.
Claims (10)
1. a matte varnish is characterized in that, comprises short oil-ity alcohol acid resin; Said short oil-ity alcohol acid resin is prepared through polycondensation by sour and/or oily and alcohol, wherein:
Said acid comprises unsaturated fatty acids, polycarboxylic acid and/or its acid anhydrides;
Said alcohol is the mixture that comprises at least two kinds of polyvalent alcohols of terepthaloyl moietie.
2. matte varnish according to claim 1 is characterized in that, said polycarboxylic acid and/or its acid anhydrides comprise phthalic acid and/or Tetra hydro Phthalic anhydride.
3. matte varnish according to claim 2 is characterized in that, said polycarboxylic acid and/or its acid anhydrides also comprise MALEIC ANHYDRIDE and/or maleic acid.
4. matte varnish according to claim 1 is characterized in that said alcohol also comprises trivalent alcohol and/or tetravalent alcohol.
5. matte varnish according to claim 4 is characterized in that, said terepthaloyl moietie and other polyvalent alcohol mol ratio are 6 ~ 7.5:10.
6. matte varnish according to claim 1 is characterized in that, said matte varnish solid content is 75 ~ 90%.
7. matte varnish according to claim 1 is characterized in that, the weight content of said short oil-ity alcohol acid resin in said matte varnish is 60% ~ 85%.
8. matte varnish according to claim 1 is characterized in that, the oil content of said short oil-ity alcohol acid resin is 30% ~ 30.5%.
9. a short oil-ity alcohol acid resin is characterized in that, said short oil-ity alcohol acid resin is prepared through polycondensation by sour and/or oily and alcohol, wherein:
Said acid comprises lipid acid, polycarboxylic acid or its acid anhydrides;
Said alcohol comprises polyvalent alcohol and terepthaloyl moietie.
10. the preparation method of a short oil-ity alcohol acid resin is characterized in that, is raw material with sour and/or oily and alcohol, carries out polycondensation, wherein:
Acid comprises lipid acid, polycarboxylic acid or its acid anhydrides;
Alcohol comprises polyvalent alcohol and terepthaloyl moietie.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110279174.2A CN102382558B (en) | 2011-09-20 | 2011-09-20 | Short-oil-length alkyd resin and matte varnish |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110279174.2A CN102382558B (en) | 2011-09-20 | 2011-09-20 | Short-oil-length alkyd resin and matte varnish |
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| CN102382558A true CN102382558A (en) | 2012-03-21 |
| CN102382558B CN102382558B (en) | 2014-07-09 |
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| CN201110279174.2A Expired - Fee Related CN102382558B (en) | 2011-09-20 | 2011-09-20 | Short-oil-length alkyd resin and matte varnish |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105622908A (en) * | 2014-11-28 | 2016-06-01 | 合众（佛山）化工有限公司 | Preparation method of nano-SiO2 modified alkyd resin |
| CN105936666A (en) * | 2016-06-03 | 2016-09-14 | 滁州市龙飞化工有限公司 | Alkyd resin for PU wood lacquer and adhesion promoter thereof |
| CN105949447A (en) * | 2016-06-03 | 2016-09-21 | 滁州市龙飞化工有限公司 | Alkyd resin for polyurethane paint |
| CN106065069A (en) * | 2016-06-03 | 2016-11-02 | 滁州市龙飞化工有限公司 | A kind of nitrate paint alkyd resin |
| CN112574653A (en) * | 2020-12-11 | 2021-03-30 | 武汉双虎涂料有限公司 | High-solid alkyd resin coating and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1425705A (en) * | 2003-01-02 | 2003-06-25 | 深圳市飞扬实业有限公司 | Process for preparing quick-drying type alkyd resin compatible with polyurethane curing agent |
| CN1657550A (en) * | 2004-02-18 | 2005-08-24 | 方学平 | Benzeneless alkyd resin for environmental protection decorative paint and its preparation method |
-
2011
- 2011-09-20 CN CN201110279174.2A patent/CN102382558B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1425705A (en) * | 2003-01-02 | 2003-06-25 | 深圳市飞扬实业有限公司 | Process for preparing quick-drying type alkyd resin compatible with polyurethane curing agent |
| CN1657550A (en) * | 2004-02-18 | 2005-08-24 | 方学平 | Benzeneless alkyd resin for environmental protection decorative paint and its preparation method |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105622908A (en) * | 2014-11-28 | 2016-06-01 | 合众（佛山）化工有限公司 | Preparation method of nano-SiO2 modified alkyd resin |
| CN105936666A (en) * | 2016-06-03 | 2016-09-14 | 滁州市龙飞化工有限公司 | Alkyd resin for PU wood lacquer and adhesion promoter thereof |
| CN105949447A (en) * | 2016-06-03 | 2016-09-21 | 滁州市龙飞化工有限公司 | Alkyd resin for polyurethane paint |
| CN106065069A (en) * | 2016-06-03 | 2016-11-02 | 滁州市龙飞化工有限公司 | A kind of nitrate paint alkyd resin |
| CN112574653A (en) * | 2020-12-11 | 2021-03-30 | 武汉双虎涂料有限公司 | High-solid alkyd resin coating and preparation method thereof |
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| Publication number | Publication date |
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| CN102382558B (en) | 2014-07-09 |
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Address after: 578 Xiasheng Road, Second Industrial Zone, Jinshan District, Shanghai Patentee after: SHANGHAI LIBANG CHANGRUNFA COATING Co.,Ltd. Address before: 578 Xiasheng Road, Second Industrial Zone, Jinshan District, Shanghai Patentee before: SHANGHAI CHANGRUNFA PAINT Co.,Ltd. |
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Granted publication date: 20140709 Termination date: 20210920 |