CN102352264A - Treating agent for dehydrating aging oil in oil field - Google Patents

Treating agent for dehydrating aging oil in oil field Download PDF

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Publication number
CN102352264A
CN102352264A CN2011102309336A CN201110230933A CN102352264A CN 102352264 A CN102352264 A CN 102352264A CN 2011102309336 A CN2011102309336 A CN 2011102309336A CN 201110230933 A CN201110230933 A CN 201110230933A CN 102352264 A CN102352264 A CN 102352264A
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oil
ether
alkylphenol
ageing
polyethenoxy
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CN2011102309336A
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CN102352264B (en
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付亚荣
吴泽美
龙政军
李冬青
刘春平
付丽霞
梁喜堂
蔡远红
曹瑾
徐定光
付茜
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Petrochina Co Ltd
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Petrochina Co Ltd
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Abstract

The oil field ageing oil dewatering treating agent is used in dewatering petroleum ageing oil. The weight ratio of each component is as follows: alkylphenol polyoxyethylene (9) ethers: 13.25 to 13.75 percent; alkylphenol polyoxyethylene (12) ethers: 14.5 to 14.75 percent; ethylene oxide propylene oxide polyether modified dimethyl siloxane: 2.5-2.75%; octylphenol polyoxyethylene (35) ether: 6.25 to 6.5 percent. Nitric acid: 0.5-0.55%; potassium nitrate: 5.5-6.75%; ammonium nitrate: 2.75-3.0%; the balance of water, and the sum of the weight percentages of the components is one hundred percent. The effect is as follows: when the temperature of the treated aged oil is 55-60 ℃, and the addition of the treating agent is 100-120 mg/L, the water content of the treated aged crude oil is less than 3.0%, and the oil content of the sewage is less than 300 mg/L. The labor intensity of workers is reduced.

Description

The treatment agent of a kind of oil field ageing oil dehydration
Technical field
The present invention relates to petroleum industry chemical agent technical field, relate in particular to a kind of treatment agent of ageing oil dehydration, solve the treatment agent of the dehydration problem of the aging crude oil of field joint stations.
Background technology
Along with oil-field development gets into middle and high Water-cut Period, comprise the various intensified oil reduction measure sequential use of chemical flooding, it is complicated more that the character of ground extraction liquid becomes.The ageing oil that causes forming in the joint station dewatering system slurry tank is thickeied; The breaking emulsion and dewatering of ageing oil is difficulty very; It can be along with the self-cleaning oil after separating, sewage etc. get into other processing links; The havoc oil water separation process; Influence dehydrating of crude oil quality and oily water treatment effect, threaten the normal operation of extraction liquid and oily water treatment facility.
The ageing oil treatment system is all had in the big oil field of ageing oil intractability in western countries.Ageing oil after the processing gets into the processed oil system.High for asphalt content, the chemical treatment difficulty is big especially and do not have contaminated crude oil, adopts that to pave the way after the nature weathering also be a good place to go of ageing oil.
At home, the Oilfield using high temperature circulation that has constantly reclaims non-oil in water emulsion wherein, reduces the volume of ageing oil; The Oilfield using that has is ageing oil concentration method such as natural subsidence in hold-up vessel, but finally all can't break away from the puzzlement of ageing oil, and these methods only limit to the lower place of output.The oil field that also has turns back to the production separation system with ageing oil, and a part of ageing oil wherein can get into production separation water system, makes water quality deterioration, and the water quality after the deterioration is regained by the sewage oil recovery system, returns the sewage slurry tank again and causes vicious cycle.
Yang Zhong equality people is published in the aging crude oil origin cause of formation of field joint stations on 2010 the 4th phases of oil-gas field environment protection and studies a literary composition with dewatering and point out ageing oil is reclaimed processing again; Not only can make it reach the sale of dispatching from the factory of self-cleaning oil standard, can also ensure the normal operation of dewatering system simultaneously., at first aging oil composition is analyzed for this reason, and the formation reason of ageing oil is launched research, on this basis, carry out the technological assessment of chemical demulsification and oxidation to harness emulsion ageing oil dehydration.Result of study shows; Oil recovery factory, Fuyu County ageing oil water ratio average 62.2%; Emulsified state is stable; The a large amount of existence of colloid FeS particulate are major causes that ageing oil generates; Oxidation to harness emulsion is more effective for the ageing oil dehydration; Under 3% dosage, the water ratio of ageing oil can be reduced to below 5%, reaches the crude oil index of dispatching from the factory.
People such as Huang Jiaxiao are published in a preferred literary composition of the ageing oil recovery method of oil-gas field surface engineering on 2007 the 12nd phases and point out; Problem for ageing oil influence dehydration is the problem that people study always, go back up till now none fast, terms of settlement completely.Through the production operation process is groped meticulously; Adopt different receipts oil methods; Carry out scrutiny, summing up experience, utilization Mathematical Statistics Analysis principle optimizes a kind of method that discharge capacity reclaims ageing oil of controlling in proportion: i.e. the ageing oil and proportioning≤11% of defeated self-cleaning oil outward.Use after the oily method of this receipts the water trap electric field stable, not defeated outward moisturely do not exceed standard, dehydrating effect is good, and its working method is convenient feasible.
People such as Zhao Shouming are published in discussion one literary composition of the central treatment station ageing oil treatment process on 2003 the 6th phases of oil planning and design through the central treatment station ageing oil being formed the analysis of reason; Discussed the harm that ageing oil brings dehydrating of crude oil, the electroconductibility of ageing oil milk sap is apparently higher than crude oil emulsion; The particle dispersion of emulsion has big stability; Ageing oil goes back to the dehydrating of crude oil system of mixing, and will cause serious detrimentally affect to dehydrating of crude oil.Through to the ageing oil Study on Properties, the individual curing technology of several ageing oils has been proposed.
Taked different measures though colloid FeS particulate ageing oil is contained to processing in each oil field, and obtained effect preferably, the method that the different oil product in each oil field is handled differs greatly.
Summary of the invention
The objective of the invention is: the treatment agent of a kind of oil field ageing oil dehydration is provided, solves the unmanageable problem of field joint stations ageing oil.
The technical scheme that the present invention adopts is:
One, raw material and each components by weight of the treatment agent of oil field ageing oil dehydration:
Raw material comprises:
1, alkylphenol-polyethenoxy (9) ether, another name: polyoxyethylene nonylphenol ether E-9 (industrial goods), Huang Hongzhou edit Chinese tensio-active agent overview one book, the 339th page of Chemical Industry Press;
Character: faint yellow thick liquid dissolves in the various hard water.Acid-and base-resisting, anti-hard water, antioxidant, anti-reductive agent, stable to salt.
Purposes: in textile and dyeing industry, make levelling agent.
Production unit: general petrochemical works, Jingzhou City.
2, alkylphenol-polyethenoxy (12) ether, another name: polyoxyethylene nonylphenol ether E-12 (industrial goods), Huang Hongzhou edit Chinese tensio-active agent overview one book, the 339th page of Chemical Industry Press;
Character: faint yellow thick liquid dissolves in the various hard water.Acid-and base-resisting, anti-hard water, antioxidant, anti-reductive agent, stable to salt.
Purposes: in textile and dyeing industry, make levelling agent.
Production unit: general petrochemical works, Jingzhou City.
3, the polyether-modified dimethyl siloxane of oxyethane propylene oxide, another name: hydrophilic silicone oil (industrial goods), Huang Hongzhou are edited Chinese tensio-active agent overview one book, the 437th page of Chemical Industry Press;
Character: but arbitrary proportion is water-soluble, can or add in the resination working fluid with the independent use of the form of the aqueous solution, and working fluid is stable, not breakdown of emulsion, not floating oil.
Purposes: fabric softener.
Production unit: Shaoxin City's applied chemistry institute, long Shen, Shanghai dyeing and printing auxiliary factory.
4, octyl phenol polyoxy ethene (35) ether, another name: polyoxyethylene nonylphenol ether E-35 (industrial goods), (Huang Hongzhou edits Chinese tensio-active agent overview one book, the 341st page of Chemical Industry Press);
Character: soluble in water, emulsification, wetting, diffusion is good, and is and acidproof, alkaline-resisting.
Purposes: and make emulsifying agent, also as the agent of acid and alkali-resistance industrial emulsion.
5, nitric acid (industrial goods, content 50%);
6, saltpetre (industrial goods);
7, ammonium nitrate (industrial goods);
8, water.
The treatment agent of oil field ageing oil dehydration, each components by weight is:
1, alkylphenol-polyethenoxy (9) ether, (industrial goods): 13.25~13.75%;
2, alkylphenol-polyethenoxy (12) ether, (industrial goods): 14.5~14.75%;
3, the polyether-modified dimethyl siloxane of oxyethane propylene oxide (industrial goods): 2.5~2.75%;
4, octyl phenol polyoxy ethene (35) ether, (industrial goods): 6.25~6.5%.
5, nitric acid: industrial goods) 0.5~0.55%;
6, saltpetre (industrial goods): 5.5~6.75%;
7, ammonium nitrate (industrial goods): 2.75~3.0%;
8, all the other are water, and each weight percentages of components sum is absolutely.
Two, the working method of the treatment agent of oil field ageing oil dehydration
Major equipment:
Enamel reaction still with 2000L of stirring, heating, cooling and vacuum system.
Working method:
At first, four kinds of raw materials such as alkylphenol-polyethenoxy (9) ether, alkylphenol-polyethenoxy (12) ether, the polyether-modified dimethyl siloxane of oxyethane propylene oxide, octyl phenol polyoxy ethene (35) ether are by weight adding enamel reaction still.Slowly be warmed up to 65~75 ℃.Secondly, under continuous the stirring, add entry earlier and answer 10% of add-on, continue to stir after 30 minutes, stop heating, temperature was controlled at 45 ℃ ± 2 ℃ stirrings after 30 minutes, add nitric acid, saltpetre, ammonium nitrate more successively by weight proportion, the limit edged stirs; Add residue water down at last, stirs and stop heating after 30 minutes, the stirring while cooling off is cooled off and is stirred to normal temperature, obtains the treatment agent that the oil field ageing oil dewaters.
Field technician and operator are familiar with the method for use of the treatment agent of oil field ageing oil dehydration.
Beneficial effect of the present invention: the treatment agent of oil field of the present invention ageing oil dehydration; The treatment agent that is used for the ageing oil dehydration in oil field, North China; In the treatment of aged oil temperature is 55~60 ℃; This treatment agent dosage is when 100~120mg/L; Moisture less than 3.0% after the aging crude Treatment, sewage with oil is less than 300mg/L.Alleviated working strength of workers.
Embodiment
Embodiment 1: the treatment agent of oil field ageing oil dehydration, and each components by weight is:
1, alkylphenol-polyethenoxy (9) ether: 13.25%;
2, alkylphenol-polyethenoxy (12) ether: 14.75%;
3, the polyether-modified dimethyl siloxane of oxyethane propylene oxide: 2.75%;
4, octyl phenol polyoxy ethene (35) ether: 6.25%.
5, nitric acid: 0.55%;
6, saltpetre: 5.5%;
7, ammonium nitrate: 2.75%;
8, water is 54.2%, and each weight percentages of components sum is absolutely.
The preparation method: at first, four kinds of raw materials such as alkylphenol-polyethenoxy (9) ether, alkylphenol-polyethenoxy (12) ether, the polyether-modified dimethyl siloxane of oxyethane propylene oxide, octyl phenol polyoxy ethene (35) ether are by weight adding enamel reaction still.Slowly be warmed up to 65~75 ℃.Secondly, under continuous the stirring, add entry earlier and answer 10% of add-on, continue to stir after 30 minutes, stop heating, temperature was controlled at 45 ℃ ± 2 ℃ stirrings after 30 minutes, add nitric acid, saltpetre, ammonium nitrate more successively by weight proportion, the limit edged stirs; Add residue water down at last, stirs and stop heating after 30 minutes, the stirring while cooling off is cooled off and is stirred to normal temperature, obtains the treatment agent that the oil field ageing oil dewaters.
The treatment of aged oil temperature is 56 ℃, this treatment agent dosage 110mg/L, and moisture after the aging crude Treatment is 2.3%, isolating sewage with oil is 288mg/L.
Embodiment 2: the treatment agent of oil field ageing oil dehydration, and each components by weight is:
1, alkylphenol-polyethenoxy (9) ether: 13.4%;
2, alkylphenol-polyethenoxy (12) ether: 14.7%;
3, the polyether-modified dimethyl siloxane of oxyethane propylene oxide: 2.75%;
4, octyl phenol polyoxy ethene (35) ether: 6.3%.
5, nitric acid: 0.54%;
6, saltpetre: 5.8%;
7, ammonium nitrate: 2.8%;
8, water is 53.71%, and each weight percentages of components sum is absolutely.
The preparation method is identical with embodiment 1.The treatment of aged oil temperature is 58 ℃, and this treatment agent dosage is 120mg/L, and is moisture 2.50% after the aging crude Treatment, separates sewage with oil 285mg/L.
Embodiment 3: the treatment agent of oil field ageing oil dehydration, and each components by weight is:
1, alkylphenol-polyethenoxy (9) ether: 13.55%;
2, alkylphenol-polyethenoxy (12) ether: 14.65%;
3, the polyether-modified dimethyl siloxane of oxyethane propylene oxide: 2.7%;
4, octyl phenol polyoxy ethene (35) ether: 6.35%.
5, nitric acid: 0.53%;
6, saltpetre: 6%;
7, ammonium nitrate: 2.8%;
8, water is 53.42%, and each weight percentages of components sum is absolutely.
The preparation method is identical with embodiment 1.In the treatment of aged oil temperature is 56 ℃, moisture 2.10% after the aging crude Treatment when this treatment agent dosage is 115mg/L, separates sewage with oil 287mg/L.
Embodiment 4: the treatment agent of oil field ageing oil dehydration, and each components by weight is:
1, alkylphenol-polyethenoxy (9) ether: 13.65%;
2, alkylphenol-polyethenoxy (12) ether: 14.6%;
3, the polyether-modified dimethyl siloxane of oxyethane propylene oxide: 2.6%;
4, octyl phenol polyoxy ethene (35) ether: 6.4%.
5, nitric acid: 0.5%;
6, saltpetre: 6.5%;
7, ammonium nitrate: 2.9%;
8, water is 52.85%, and each weight percentages of components sum is absolutely.
The preparation method is identical with embodiment 1.In the treatment of aged oil temperature is 58 ℃, this treatment agent dosage 115mg/L, and it is 2.1% that aging crude separation is handled the back moisture, separation sewage with oil 270mg/L.
Embodiment 5: the treatment agent of oil field ageing oil dehydration, and each components by weight is:
1, alkylphenol-polyethenoxy (9) ether: 13.75%;
2, alkylphenol-polyethenoxy (12) ether: 14.5%;
3, the polyether-modified dimethyl siloxane of oxyethane propylene oxide: 2.5%;
4, octyl phenol polyoxy ethene (35) ether: 6.5%.
5, nitric acid: 0.5%;
6, saltpetre: 6.75%;
7, ammonium nitrate: 3%;
8, water is 52.5%, and each weight percentages of components sum is absolutely.
The preparation method is identical with embodiment 1.In the treatment of aged oil temperature is 55 ℃, and when this treatment agent dosage was 120mg/L, it is moisture 2.7% that aging crude separation is handled the back, sewage with oil 259mg/L.

Claims (2)

1. the treatment agent of an oil field ageing oil dehydration, each components by weight is:
Alkylphenol-polyethenoxy (9) ether: 13.25~13.75%;
Alkylphenol-polyethenoxy (12) ether: 14.5~14.75%;
The polyether-modified dimethyl siloxane of oxyethane propylene oxide: 2.5~2.75%;
Octyl phenol polyoxy ethene (35) ether: 6.25~6.5%.
Nitric acid: 0.5~0.55%;
Saltpetre: 5.5~6.75%;
Ammonium nitrate: 2.75~3.0%;
All the other are water, and each weight percentages of components sum is absolutely.
2. the treatment agent of oil field according to claim 1 ageing oil dehydration; It is characterized in that: working method is: at first, four kinds of raw materials such as alkylphenol-polyethenoxy (9) ether, alkylphenol-polyethenoxy (12) ether, the polyether-modified dimethyl siloxane of oxyethane propylene oxide, octyl phenol polyoxy ethene (35) ether are by weight adding enamel reaction still.Slowly be warmed up to 65~75 ℃.Secondly, under continuous the stirring, add entry earlier and answer 10% of add-on, continue to stir after 30 minutes, stop heating, temperature was controlled at 45 ℃ ± 2 ℃ stirrings after 30 minutes, add nitric acid, saltpetre, ammonium nitrate more successively by weight proportion, the limit edged stirs; Add residue water down at last, stirs and stop heating after 30 minutes, the stirring while cooling off is cooled off and is stirred to normal temperature, obtains the treatment agent that the oil field ageing oil dewaters.
CN 201110230933 2011-08-12 2011-08-12 Treating agent for dehydrating aging oil in oil field Active CN102352264B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105623714A (en) * 2014-10-28 2016-06-01 中国石油化工股份有限公司 Dehydration composition, dehydrator, application of dehydration composition and dehydrator, and oil well acidification produced liquid dehydration method

Citations (2)

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Patent Citations (2)

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CN101721841A (en) * 2008-10-10 2010-06-09 中国石油化工股份有限公司 Lubrication oil composite type demulsifier and application thereof

Non-Patent Citations (2)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105623714A (en) * 2014-10-28 2016-06-01 中国石油化工股份有限公司 Dehydration composition, dehydrator, application of dehydration composition and dehydrator, and oil well acidification produced liquid dehydration method
CN105623714B (en) * 2014-10-28 2017-08-25 中国石油化工股份有限公司 A kind of water displacement composition and a kind of dehydrating agent and its application and a kind of oil well acidation Produced Liquid dewatering

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