CN102349643A - Salt - Google Patents

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Publication number
CN102349643A
CN102349643A CN2011103169696A CN201110316969A CN102349643A CN 102349643 A CN102349643 A CN 102349643A CN 2011103169696 A CN2011103169696 A CN 2011103169696A CN 201110316969 A CN201110316969 A CN 201110316969A CN 102349643 A CN102349643 A CN 102349643A
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CN
China
Prior art keywords
salt
sodium chloride
potassium ferrocyanide
equal
product
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Pending
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CN2011103169696A
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Chinese (zh)
Inventor
左敏
陈学德
潘秀云
程春山
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Benefits Of Salt Tang (yingcheng) Health Salt Salt Co Ltd
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Benefits Of Salt Tang (yingcheng) Health Salt Salt Co Ltd
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Priority to CN2011103169696A priority Critical patent/CN102349643A/en
Publication of CN102349643A publication Critical patent/CN102349643A/en
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Abstract

The invention relates to the technical field of food, in particular to salt, which is characterized in that: in the salt, sodium chloride is more than or equal to 99.3 weight percent, moisture is less than or equal to 0.5 percent, insoluble substances is less than or equal to 0.05 percent, the whiteness of the salt is more than or equal to 80 degrees, the granularity of more than 80 percent of the salt is more than 0.85 mm, and the salt also comprises 35mg/kg to 60mg/kg of potassium iodate. By controlling the content of the sodium chloride, the moisture content and the granularity of a product, the hardening problem of the salt product can be solved, and the salt is free from containing an anti-caking agent--yellow prussiate of potash, so when the salt is used under the conditions of high temperature and existence of acid substances or strong oxidant substances, the salt can be prevented from releasing prussiate to harm the body of an eater, and beneficial elements of the human body can be prevented from being combined with the yellow prussiate of potash to be precipitated so as to influence the absorption of partial trace elements by the human body. The salt also comprises 35mg/kg to 60mg/kg of potassium iodate, so the requirement of pregnant women on thyroid hormone can be satisfied, and the health of the pregnant women and the normal growth of fetus can be guaranteed.

Description

A kind of salt
Technical field
The present invention relates to food technology field, relate to a kind of salt specifically.
Background technology
Salt is claimed dining table salt again, is to one of most important material of human survival, also is the most frequently used flavoring in the culinary art.The main chemical sodium chloride of salt (chemical formula NaCl) content in salt is 99%.
Very easily harden in the storage and transport process of common common salt when depositing and transport, thereby influence people's use.Therefore the salt that uses in the market adds the iodide except that part, also adds potassium ferrocyanide as anticaking agent, to prevent hardening of salt.
Potassium ferrocyanide, English Potassium ferrocyanide by name, formal name used at school is that three hydrations, six cyanogen close the sour potassium of iron (II), molecular formula is K 4Fe (CN) 63H 2O, molecular weight are 422.39.Potassium ferrocyanide is a pale yellow crystals, is commonly called as potassium ferrocyanide, is the complex that iron and cyanogen form, and is soluble in water, in the aqueous solution, dissociates into K +[Fe (CN) 6] 4 -Potassium ferrocyanide is stable in the air, is heated to 70 ℃ and loses the crystallization water, decomposes behind the heat-flash.Potassium ferrocyanide is widely used in the salt manufacture field as the salt anticaking agent, and potassium ferrocyanide also can be used for making paint, printing ink, pigment, pharmacy, metal heat treatmet, food additives, steel and iron industry and rubs leather or the like in addition.
Improving constantly of Along with people's living standard; People have requirement higher to security, the trophism of the food that eaten; Salt is as a kind of most popular food flavor, nutritional agents, and its security, health are more paid close attention to, and the use of potassium ferrocyanide shows its deficiency gradually.
At first, the security in edible salt, used of potassium ferrocyanide is under suspicion.Potassium ferrocyanide can decompose behind heat-flash, produces hydrogen cyanide; It and halogen, the hydrogen peroxide generation potassium ferricyanide that reacts, its aqueous solution is met light and is then decomposited cyanide and generate iron hydroxide in air; It and watery hydrochloric acid heat altogether produce hydrogen cyanide; Potassium ferrocyanide generates cementite, cyanide, cyanogen and nitrogen when calcination.Though China has formulated strict national standard to the addition of potassium ferrocyanide, the general content of potassium ferrocyanide in sodium chloride is no more than 10mg/kg, and edible is safe.If but we in use contact high temperature or acidic materials or strong oxidizer material, potassium ferrocyanide is decomposed, emit cyanide, a small amount of cyanide gets in the body through alimentary canal for a long time, can produce chronic murder by poisoning to health.Therefore, the edible salt for adding potassium ferrocyanide has only us to guarantee correct method for using, just can be unharmful to health.And potassium ferrocyanide can dewater in the time of 100 ℃ and become white powdered anhydrous thing, so salt is in drying bed when dry, and potassium ferrocyanide is prone to dehydration and becomes white powdery by lenticular; And the proportion of potassium ferrocyanide is lower than the proportion of sodium chloride, and when drying bed reclaimed powder salt, potassium ferrocyanide can get in the powder salt more; The amount that makes powder salt contain potassium ferrocyanide surpasses 6~7 times of normal value; When these powder salts are got back in the finished product salt again, if in follow-up packaging process insufficient mixing, will make the ferrocyanide potassium content in the local finished product salt surpass 20mg/kg; Be far longer than the addition that country allows, and then harm eater's health.
Secondly, potassium ferrocyanide influences people to the part trace elements absorbed.Potassium ferrocyanide can generate sediment with most metallic element reactions; Under the situation that does not have air to exist, generating the water insoluble ferric ferrocyanide with diluted acid of white with ferrous salt precipitates; Zinc ion meeting and potassium ferrocyanide react, and the zinc ferrocyanide that generates the gluey water insoluble and diluted acid of white precipitates; Mantoquita and ferrocyanide nak response generate the iron copper cyanider deposition of indissoluble.In these reactions, though there is not the decomposition of complex compound, can not discharge hydrocyanic acid or cyanide with hypertoxicity, it will be combined into deposition with human body beneficial's element, influence the absorption of people to these elements.
Once more, potassium ferrocyanide is to the limitation of food processing with salt.China stipulates clearly that in food additives potassium ferrocyanide can be used as anti-solid agent, but in pollution-free food, does not allow to occur, and comprises that the used sodium chloride of seasoning bag must not detect potassium ferrocyanide in the pollution-free food.After in salt, adding ferrocyanide, because the existence of the ferrous cyanide ion that adds in the salt, it is difficult to obtain the approval of developed countries such as America and Europe as the security of edible additive, has limited the use of food processing with salt greatly.
Iodine is the thyroxine constituent, and thyroxine can promote the biosynthesis of protein, promotes embryo growth and development.The gestational period, thyroid function was active, and the requirement of iodine increases, and so just was prone to cause the not enough or shortage of gestational period Iodine intake, particularly had a lot of areas to belong to the iodine deficiency district in China, more was prone to cause pregnant woman's iodine deficiency.Discover that the pregnant woman takes in iodine subalimentation and possibly exist related with premature labor, stillbirth and fetal anomaly.Also have some cases to show; The pregnant woman takes in the iodine deficiency possibly cause baby's congenital hypothyroidism and neurological dysfunction, and cretinism appears in the severe patient neonate, and tired, unable, chilly, drowsiness, metabolism and the variation of circulatory function property such as interest is little are to external world arranged clinically; Skeleton development is unusual; Brain growth defective and delay, the dried flakey that forms of skin, hair, nail is unglazed, fragility etc.For pregnant woman's itself health and normal fetal development, the pregnant woman must be noted that can not iodine deficiency, especially more will note supplementing iodine at iodine deficient area.Iodized salt is a kind of economy, safety, convenience and effective methods to supply iodine.
Summary of the invention
In view of this, the object of the invention provides and does not a kind ofly contain the pregnant woman that potassium ferrocyanide, good dispersion be difficult for hardening, be rich in iodine and use salt.
For realizing the object of the invention, the present invention adopts following technical scheme:
A kind of salt, sodium chloride>=99.3wt%, moisture≤0.5%, water-insoluble≤0.05%, whiteness>=80 degree, granularity accounts for more than 80% greater than 0.85mm's, and said salt also comprises Potassiumiodate 35mg/kg~60mg/kg.。
Salt sodium chloride content according to the invention is greater than 99.3%, and the purity of sodium chloride is high, can avoid impurity and moisture in the salt to combine to make salt deliquescence, caking.
A key factor of salt product caking is a moisture content, when moisture content is high, can generate dihydrate, i.e. NaCl2H 2O is prone to caking.Salt moisture according to the invention≤0.5% can guarantee the aridity of product, prevents salt product caking.
Salt according to the invention adopts the macrogranule salt crystallizer to increase by the granularity of product, and granularity accounts for more than 80% greater than 0.85mm's, keeping intergranular effective clearance, thereby guarantees that the salt product does not lump.
Salt according to the invention also comprises the Potassiumiodate of 35mg/kg~60mg/kg; To increase the intake of iodine; Satisfy the demand of pregnant woman to thyroid hormone, synthetic more thyroid gland is usually dealt with the needs of pregnant woman self and fetus, guarantees pregnant woman's health and normal fetal development.
Salt according to the invention solves the problem that the salt product hardens through sodium chloride content, moisture and the granularity of control product.Salt according to the invention does not contain anticaking agent-potassium ferrocyanide; Can avoid in the presence of high temperature, acidic materials or strong oxidizer material, using salt; Discharge cyanide harm eater's health; The other potassium ferrocyanide of element that can prevent the human body beneficial combines deposition, influences people to the part trace elements absorbed.The Potassiumiodate that comprises 35mg/kg~60mg/kg in the said salt satisfies the demand of pregnant woman to thyroid hormone, guarantees pregnant woman's health and normal fetal development.
Test shows that salt according to the invention is deposited, and can ensure 18 months at least and not lump after packing.
The specific embodiment
The embodiment of the invention discloses a kind of salt.Those skilled in the art can use for reference this paper content, suitably improve technological parameter and realize.Special needs to be pointed out is that all similarly replace and change apparent to those skilled in the art, they all are regarded as and are included in the present invention.Product of the present invention is described through preferred embodiment, and the related personnel obviously can change or suitably change and combination product as herein described in not breaking away from content of the present invention, spirit and scope, realizes and use technology of the present invention.
In order further to understand the present invention, the present invention is elaborated below in conjunction with embodiment.
Embodiment 1: salt according to the invention
Sodium chloride 99.5wt%, moisture 0.45%, water-insoluble 0.05%, whiteness 85 degree, granularity accounts for 85% greater than 0.85mm's, Potassiumiodate 35mg/kg.
Embodiment 2: salt according to the invention
Sodium chloride 99.4wt%, moisture 0.4%, water-insoluble 0.045%, whiteness 80 degree, granularity accounts for 80% greater than 0.85mm's, Potassiumiodate 40mg/kg.
Embodiment 3: salt according to the invention
Sodium chloride 99.5wt%, moisture 0.5%, water-insoluble 0.04%, whiteness 85 degree, granularity accounts for 80% greater than 0.85mm's, Potassiumiodate 60mg/kg.
Embodiment 4: salt according to the invention
Sodium chloride 99.3wt%, moisture 0.45%, water-insoluble 0.05%, whiteness 80 degree, granularity accounts for 85% greater than 0.85mm's, Potassiumiodate 50mg/kg.
Embodiment 5: with the salt of potassium ferrocyanide as anticaking agent
Sodium chloride 98.3wt%, moisture 0.45%, water-insoluble 0.05%, whiteness 80 degree, granularity accounts for 65% greater than 0.85mm's, Potassiumiodate 40mg/kg, potassium ferrocyanide 8mg/kg.
Embodiment 6:
Sodium chloride 98.5wt%, moisture 0.45%, water-insoluble 0.05%, whiteness 80 degree, granularity accounts for 85% greater than 0.85mm's, Potassiumiodate 40mg/kg.
Embodiment 7:
Sodium chloride 99.3wt%, moisture 0.65%, water-insoluble 0.05%, whiteness 80 degree, granularity accounts for 85% greater than 0.85mm's, Potassiumiodate 40mg/kg.
Embodiment 8:
Sodium chloride 99.3wt%, moisture 0.45%, water-insoluble 0.05%, whiteness 80 degree, granularity accounts for 65% greater than 0.85mm's, Potassiumiodate 40mg/kg.
Embodiment 9: the resistive connection performance test
The salt product of embodiment 1~8 is preserved by the sealing of packing in the plastics inner wrapping of the specification of 400g, under 20 ℃ ± 2 ℃ of temperature, relative humidity 60% ± 10% condition, deposited 18 months, salt Product Status relatively, the result sees table 1.
Table 1 resistive connection performance data
Figure BDA0000099809180000051
Visible by table 1 result, to compare with other conditions, the granularity of salt product is maximum to the resistive connection performance impact of product; Granularity is greater than the salt product more than 80% that accounts for of 0.85mm; Deposit 6 monthly not cakings, and salt according to the invention is deposited after packing, can ensure 18 months at least and not lump.And under air-proof condition, salt product of the present invention and the product resistive connection performance basically identical that adds potassium ferrocyanide.It is safer to show that salt according to the invention does not contain potassium ferrocyanide, and good dispersion is difficult for hardening.
The explanation of above embodiment just is used for helping to understand method of the present invention and core concept thereof.Should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention, can also carry out some improvement and modification to the present invention, these improvement and modification also fall in the protection domain of claim of the present invention.

Claims (1)

1. a salt is characterized in that, sodium chloride>=99.3wt%, and moisture≤0.5%, water-insoluble≤0.05%, whiteness>=80 degree, granularity accounts for more than 80% greater than 0.85mm's, and said salt also comprises Potassiumiodate 35mg/kg~60mg/kg.
CN2011103169696A 2011-10-18 2011-10-18 Salt Pending CN102349643A (en)

Priority Applications (1)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106690245A (en) * 2016-11-15 2017-05-24 安徽味仙食品有限公司 Special salt for pregnant women
CN107173779A (en) * 2017-06-30 2017-09-19 益盐堂(应城)健康盐制盐有限公司 A kind of additive that can effectively prevent edible salt from luming
CN113548681A (en) * 2021-09-23 2021-10-26 山东省鲁盐集团东方海盐有限公司 Production method of salt without anticaking agent, salt without anticaking agent and application

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101234124A (en) * 2008-03-06 2008-08-06 四川久大索贝斯日化有限责任公司 Method of preparing crystallization physiotherapeutic salt
CN101792159A (en) * 2010-04-08 2010-08-04 山东肥城精制盐厂 Method for preparing refined salt without antitackiness agent

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101234124A (en) * 2008-03-06 2008-08-06 四川久大索贝斯日化有限责任公司 Method of preparing crystallization physiotherapeutic salt
CN101792159A (en) * 2010-04-08 2010-08-04 山东肥城精制盐厂 Method for preparing refined salt without antitackiness agent

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
中华人民共和国农业部: "《绿色食品标准汇编》", 26 January 2006, 农业出版社 *
张传德: "绿色食品盐生产技术研究及应用", 《中国井矿盐》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106690245A (en) * 2016-11-15 2017-05-24 安徽味仙食品有限公司 Special salt for pregnant women
CN107173779A (en) * 2017-06-30 2017-09-19 益盐堂(应城)健康盐制盐有限公司 A kind of additive that can effectively prevent edible salt from luming
CN113548681A (en) * 2021-09-23 2021-10-26 山东省鲁盐集团东方海盐有限公司 Production method of salt without anticaking agent, salt without anticaking agent and application

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Application publication date: 20120215