CN102348847A - Printed matter providing optically readable information - Google Patents

Printed matter providing optically readable information Download PDF

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Publication number
CN102348847A
CN102348847A CN2010800111926A CN201080011192A CN102348847A CN 102348847 A CN102348847 A CN 102348847A CN 2010800111926 A CN2010800111926 A CN 2010800111926A CN 201080011192 A CN201080011192 A CN 201080011192A CN 102348847 A CN102348847 A CN 102348847A
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CN
China
Prior art keywords
printed matter
information
printed
external member
readable information
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2010800111926A
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Chinese (zh)
Inventor
神田幸夫
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EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
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Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of CN102348847A publication Critical patent/CN102348847A/en
Pending legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/42—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators with wetness indicator or alarm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01—Ink jet
    • B41J2/17—Ink jet characterised by ink handling
    • B41J2/175—Ink supply systems ; Circuit parts therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J29/00—Details of, or accessories for, typewriters or selective printing mechanisms not otherwise provided for
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425—Cellulose series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282—Addition polymers
    • D04H1/4291—Olefin series
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
    • D06P5/2011—Application of vibrations, pulses or waves for non-thermic purposes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing

Abstract

[Problem] To provide a printed matter that provides optically readable information, has excellent durability against wind, rain, and light, and that can be produced more simply and at low cost. In addition, to provide a printed matter set that contains a plurality of the aforementioned printed matters, and a method for producing this printed matter set. [Solution] A printed matter characterized by a non-woven fabric base material having a basis weight of 20.0-120.0 g/m2 and a thickness of 0.020-0.400 mm, and optically readable information formed by printing an ultraviolet-curable ink on this base material using an inkjet printing method.

Description

The printed matter of optical readable information is provided
[technical field]
The present invention relates to a kind of printed matter, it is suitable for as the bib that supplies the marathon runner to dress, and comprises nonwoven web matrix material and optical readable information, but and randomly on this matrix material, comprises additional vision identification information.
[background technology]
In recent years, along with the appearance of body-building upsurge etc., it is extremely popular that whole people's marathon race and ski race become, and present many citizen participate in the activity of the type.In sort of activity; Can provide bib to the entrant; The title of the clear show events of these bibs and player's number, player on the same day will wear these bibs in activity, but because the player's number on each bib is all different; Therefore current must being printed on the bib (having printed activity name in the above) each player's number is manual, thus the for example increase of workload and expense of variety of issue caused.In addition, in recent years,, activity can require the entrant to register their blood group and medical history before carrying out, so that between active stage, there is the player injured or make quick response when running into accident.Yet; Because People more and more is concerned about the processing mode of personal information in recent years; Therefore thinking following is Perfected process: merge on every player's the bib with the information of certain mode with this type; Thereby this information of fast searching when needed, and can not give other people with information leakage, but do not invent out such processing mode as yet.
In addition, hoping provides braille to entrant visually impaired on bib, but but still untapped go out to be used for can simple and easy technology of producing the bib with sense of touch identification information (for example braille) apace.
On the other hand, ink jet printing is a kind of being used for through forming the technology of image according to numerical data to the object ink-jet, and since its have at a high speed, advantages such as polychrome function and low noise, begun to be widely used in out plate material, poster or the like.Form image through ink jet printing and need not prepare solarization plate originals (hectographic printing need be shone plate originals), need not carry out heat fixation processing (the for example employed xerography of duplicator and laser printer), this means that ink-jet printer has the simple advantage of mechanism.In addition; Conventional hectographic printing need at first be printed for the identical information of all printed matters; Print every distinctive information of printed matter then; One of each printing, and ink jet printing has the following advantages: can print simultaneously for all printed matters identical information and every distinctive information of printed matter.
Paper wood is used as the matrix material of printed matter usually; On this matrix material, form image through ink jet printing; If but using this printing material under the exacting terms relatively; If for example use this printed matter out of doors, then be necessary to use to have windproof property, anti-rain property and sunproof matrix material.Proposed not only in light weight but also pliable and tough supatex fabric as this type of matrix material (for example, referring to patent file 1).
Yet; Be known that; Through the for example optical readable information of two-dimensional bar forms such as (for example QR Code, Data Matrix, PDF 417, Maxi Code or VeriCode) is provided on printed matter, can a printed matter and the difference of another part printed matter be come through information (this information preferably reads through Optical devices) is encoded.
Patent file 2 discloses a kind of brand discrimination method; It is characterized in that using magnetic ink embroidering or weaving label marked brand name or logo (for example literal, figure or symbol); So that can distinguish genuine piece board and false brand, but unexposed a kind of comprising through utilizing ink jet printing on the nonwoven web matrix material, to print the printed matter of the optical readable information that forms.
Patent file 3 discloses a kind of basic skills in ink jet dyeing field; This method uses a kind of printing ink (this printing ink has dyestuff as key component) on cloth, to write down the information such as literal, image or identification marking, and this method relates to following steps: (1) makes cloth stand antimigration and handles; (2) use ink-jet printer etc. will have dyestuff and infiltrate as the printing ink of key component or be distributed in the fiber of cloth (forming intermediate images in the above), so that cloth is dyeed; (3) dye through using heat treatment etc. that the dyestuff that forms intermediate images is infiltrated or being distributed in the fiber of cloth; (4) remove excess dye through reduction cleaning etc., its purpose is various problems intrinsic in the heat treatment of settlement steps to deal (3).Specifically; Patent file 3 discloses a kind of method for preparing the information fabric; It is characterized in that variety of issue intrinsic in the heat treatment of preceding text step (3) solves through following process: use to have the printing ink of dyestuff, go up at fabric, knitted fabric or supatex fabric (A) and form image (for example literal, image or identification marking) as key component; At least go up stacked fabric, knitted fabric or supatex fabric or paper wood (B) on the surface of fabric, knitted fabric or supatex fabric (A) (forming image in the above); Carry out heat treatment then, thereby the dyestuff that forms above-mentioned intermediate images is infiltrated or be distributed in the fiber that constitutes fabric, knitted fabric or supatex fabric (A).Yet, being employed in a plurality of aforesaid complex steps of printing process needs that printing ink (it has dyestuff as key component) used in the information textile method of patent file 3 carries out, this relates to expensive and many technology barriers.In addition, from point of view of environment protection, be disadvantageous based on the printing ink method of dyestuff (wherein because the cleaning after the heat treatment and effluent discharge).
Still untapped go out can be simply and effectively in printing on the single bib common information (for example activity name) and technology of the distinctive information of each bib (personal information of for example player's number, and player) for employed whole bibs in a certain activity (for example whole people's marathon race).
[ The background technology document]
[ Patent file]
The open H08-187933 of [patent file 1] Japanese uncensored patent application
The open 2004-334144 of [patent file 2] Japanese uncensored patent application
The open H05-247838 of [patent file 3] Japanese uncensored patent application
[ Summary of the invention]
[ The problem that the present invention will solve]
An object of the present invention is to provide such printed matter: on said printed matter, print every distinctive information of printed matter with the mode of any optical readable; Can quite accurately read the optical readable information of printing from said printed matter; Said printed matter has excellent weatherability; And said printed matter can prepare with low cost simply.
Another object of the present invention provides such printed matter: but said printed matter has for every printed matter identical haptic identification information; And every distinctive optical readable information of printed matter.
Another purpose of the present invention provides such printed matter: but said printed matter has for every printed matter identical haptic identification information; Every distinctive optical readable information of printed matter; But and every distinctive sense of touch identification information of printed matter.
A further object of the present invention provide a kind of can be simply and prepare the method for above-mentioned printed matter at low cost.
[ The method of dealing with problems]
Inventor of the present invention has accomplished the present invention according to some discoveries; Make through using ultraviolet-curing printing ink to carry out ink jet printing and optical readable information being printed on the specific nonwoven web matrix material; Can extremely clearly print optical readable information, thereby improve optically read accuracy and address the above problem.
Specifically, the invention provides a kind of printed matter, it comprises basic weight is 20.0 to 120.0g/m 2, thickness is 0.020 to 0.400mm nonwoven web matrix material and through using ink jet printing method ultraviolet-curing printing ink to be printed on the optical readable information that forms on this matrix material.
The present invention also provides a kind of printed matter external member; It comprises a plurality of aforementioned printed matters; Wherein but each printed matter in the external member all comprises optical readable information and vision identification information; The information that said optical readable information shows is different from other printed matter in the external member, but and the vision identification information is identical for all printed matters in the external member.
The present invention also provides a kind of method for preparing the printed matter external member, and said external member is made up of a plurality of printed matters, and each printed matter all is printed on optical readable information, and the information that this optical readable information shows is different from the information on other printed matter in the external member,
This method may further comprise the steps: import an aforesaid inequality type information,
Aforementioned input information translation is become signal, in order to the generation optical readable information corresponding with this input information,
Aforementioned signal is sent to printing equipment, and
Based on aforementioned signal, utilize ultraviolet-curing printing ink that aforementioned optical readable information is printed on the nonwoven web matrix material through using ink jet printing method, the basic weight of said matrix material is 20.0 to 120.0g/m 2, thickness is 0.020 to 0.400mm.
[ Effect of the present invention]
According to the present invention, a kind of printed matter can be provided, it comprises optical readable information, has excellent windproof property, anti-rain property and light resistance, and can prepare with low cost more simply.Specifically,, optical readable information can be provided extremely clearly on printed matter, thereby avoid when using Optical devices to read this optical readable information, makeing mistakes through with supatex fabric and ultraviolet-curing ink combination.In addition, according to the present invention, a kind of printed matter can be provided, it is after the information that can preferably read through Optical devices is encoded, to print, and therefore a kind of convenient printed matter that comprises necessary information such as managing personal information can be provided.Also can under the situation that does not need complicated technology, prepare the printed matter external member that comprises a plurality of printed matters simply; Wherein but each printed matter in the external member all comprises optical readable information and vision identification information; The information that said optical readable information shows is different from other printed matter in this external member, but and the vision identification information is to be identical for all printed matters in the external member.In addition,, compare, use ultraviolet-curing printing ink less the influence of environment with the method that relates to based on the printing ink of dyestuff etc. from the angle of liquid waste processing.
[ The accompanying drawing summary]
[Fig. 1] Fig. 1 is the diagram that the embodiment of bib of the present invention (1) is shown.
[Fig. 2] Fig. 2 illustrates the instance of the database of storage entrant's number (personally identifiable information).
[Fig. 3] Fig. 3 illustrates bar code and the QR Code on the bib TMEnlarged photograph, this bib uses the Tyvek that is made by E.I.DuPont TMSupatex fabric (production code member 1056D) and the ultraviolet-curing printing ink of being made by E.I.DuPont (SD108) that is used for ink-jet printer prepare.
[Fig. 4] Fig. 4 illustrates bar code and the QR Code on the bib TMEnlarged photograph, the Tyvek that this bib uses E.I.DuPont to make TMThe printing ink of supatex fabric (production code member 1056D) and commercially available acquisition (is used for by Canon the printing ink of the Pixus 455i printer that Inc. makes; Name of product is BCI-24Color and BCI-24Black) rather than ultraviolet-curing printing ink prepare.
[ Carry out mode of the present invention]
In the present invention, be 20.0 to 120.0g/m with basic weight 2, thickness is that 0.020 to 0.400mm nonwoven web matrix material is as the matrix material that prints in the above.In this article, can measure " basic weight " (g/m of supatex fabric according to JIS-L1096 2).In addition, " thickness " that also can measure supatex fabric according to JIS-L1096 (mm).
Employed supatex fabric with above-mentioned characteristic can be hydrophilic fibre (for example cellulose or silk), hydrophobic fibre (for example polyolefin (polyethylene, polypropylene etc.) or their mixture, and can adopt conventional method under the situation of using or do not use adhesive, to prepare among the present invention.In the middle of these materials, the preferred supatex fabric that uses through the polyethylene fiber preparation.
Employed basis weight of nonwoven fabrics is preferably 30.0 to 100.0g/m among the present invention 2, more preferably be 30.0 to 80.0g/m 2, also more preferably be 35.0 to 70.0g/m 2, and be most preferably 38.0 to 60.0g/m 2Herein, basic weight means every 1m 2Average quality (g/m 2), its through get three parts be measured as 20cm * 20cm and according to the sample of JIS-L1096 (6. method of testing, 6.3) preparation, measure the adiabatic drying quality (g) of every part of sample and obtain according to specifying formula to confirm to revise quality.
The thickness of employed supatex fabric is preferably 0.050 to 0.350mm among the present invention, more preferably is 0.060 to 0.300mm, and is most preferably 0.070 to 0.250mm.This thickness (mm) is according to the measuring method of stipulating among the JIS-L1096, and the used thickness tester prepares sample to portion under initial load five parts are carried out the measurement of one period set time and used the average of five values and obtain.
The tearing strength of employed supatex fabric is preferably 3.0 to 35.0N among the present invention, more preferably is 4.0 to 30.0N, and is most preferably 4.5 to 25.0N.For example, when with printed matter during as bib etc., even use intermediate plate etc. to connect bib, this should not become the starting point of tearing yet, so supatex fabric is necessary to have high-tear strength." tearing strength " that can measure supatex fabric according to JIS-L8116 here, (N).
The TENSILE STRENGTH of employed supatex fabric is preferably 30N/5cm to 1000N/5cm among the present invention, is 40N/5cm to 500N/5cm more preferably, and is most preferably 70N/5cm to 350N/5cm." tearing strength " that can measure supatex fabric according to JIS-L1096 here, (N/5cm).
The rupture strength of employed supatex fabric is preferably 100 to 2500kPa among the present invention, and more preferably 200 to 1500kPa, and most preferably is 300 to 900kPa.Can measure the rupture strength of supatex fabric according to JIS-P8112.
In the present invention, through the ink jet printing of using ultraviolet-curing printing ink optical readable information is printed on the above-mentioned nonwoven web matrix material." the ultraviolet-curing printing ink " that uses in the present invention can be any kind, as long as this printing ink can solidify under the irradiation of ultraviolet radiation, wherein ultraviolet radiation is a kind of form of actinic radiation.For example, can use disclosed ultraviolet-curing printing ink among the open 2008-280427 of Japanese uncensored patent application, 2007-231082,2008-81516 and the 2008-223014.In order to form optical readable information clearly, be especially preferred based on the ultraviolet-curing printing ink of acrylic acid ester.Wherein the content of acrylic acid ester is that the printing ink of about 30 to 45 quality % especially is preferably the ultraviolet-curing printing ink based on acrylic acid ester.For example, can use " SD-108 " or " SD-111 " ultraviolet-curing printing ink of E.I.DuPont, but used printing ink is not limited to these among the present invention.
Employed ultraviolet-curing ink composite can comprise polymerization initiator among the present invention.This polymerization initiator can be well-known a kind of initator, and the use radical polymerization initiator is especially preferred.Employed polymerization initiator is a kind of like this compound in the ultraviolet-curing ink composite of the present invention, and it generates the material that polymerization causes through ultraviolet radiation-absorbing, and wherein ultraviolet radiation is a kind of form of external enwergy.
The preferred radical polymerization initiator that can be used for the present invention comprises aromatic ketone, acylphosphanes compound, aromatics salt, organic peroxide, thio-compounds, Hexaarylbiimidazole compound, ketone group oxime ester compound, borate compound, azinium compound, metallocene compound, active ester compound, the compound with carbon-halogen bond and alkyl ammonium compounds.
In the present invention, can use single type polymerization initiator, maybe can use the combination of the polymerization initiator of two kinds or more kinds of types.With respect to the ultraviolet-curing ink composite that is 100 parts in mass; Can use these polymerization initiators of following concentration: preferably be 0.01 to 30 part in mass; More preferably be 0.1 to 20 part in mass, and more preferably be 0.5 to 10 part in mass.
The free redical polymerization compound that is comprised in the ultraviolet-curing ink composite of the present invention is a kind of compound with ethylenic unsaturated bond of free redical polymerization; And can be any monomer, oligomer or polymer, prerequisite is the ethylenic unsaturated bond that has at least one free redical polymerization in the molecule of this compound.In addition, can use single type free redical polymerization compound, maybe can use the free redical polymerization combination of compounds of two kinds or more kinds of types.
The instance of polymerizable compound with ethylenic unsaturated bond of free redical polymerization comprises: unsaturated carboxylic acid (for example acrylic acid, methacrylic acid, itaconic acid, crotonic acid, iso-crotonic acid or maleic acid) or its salt; Acid anhydrides with ethylenic unsaturated group, and free redical polymerization compound (for example acrylonitrile, styrene, unsaturated polyester (UP), unsaturated polyether, unsaturated polyester acid amides and unsaturated urethane).
Specifically; Can use: acrylic acid derivative, for example acrylic acid-2-ethyl caproite, acrylic acid-2-hydroxyethyl ester, acrylic acid butoxy ethyl ester, acrylic acid card must ester, cyclohexyl acrylate, acrylic acid tetrahydro furfuryl ester, benzyl acrylate, bisphenol A polyethenoxy ether diacrylate, diacrylic acid pentyl diol ester, two (ethylene glycol) diacrylate, three (ethylene glycol) diacrylate, four (ethylene glycol) diacrylate, gather (ethylene glycol) diacrylate, gather (propylene glycol) diacrylate, pentaerythritol triacrylate, tetramethylol methane tetraacrylate, dipentaerythritol tetraacrylate, trimethylolpropane triacrylate, tetramethylol methane tetraacrylate, few ester acrylic acid ester, N hydroxymethyl acrylamide, DAAM and epoxy acrylate; Methacrylic acid derivative; For example methyl methacrylate, n-BMA, methacrylic acid 2-Octyl Nitrite, lauryl methacrylate, allyl methacrylate, GMA, benzyl methacrylate, dimethylaminoethyl methacrylate, 1,6-hexanediol dimethacrylate, GDMA, three (ethylene glycol) dimethylacrylate, gather (ethylene glycol) dimethylacrylate, gather (propylene glycol) dimethylacrylate, trimethylolethane trimethacrylate methacrylate, trimethylol-propane trimethacrylate and biphenol A ethoxy acid dimethacrylate; And allyl compound, for example allyl glycidyl ether, diallyl phthalate and benzenetricarboxylic acid triallyl.The especially preferred compound that is to use based on acrylic acid ester.
Gross mass with respect to the ultraviolet-curing ink composite; Among the present invention in the employed ultraviolet-curing ink composite total content of free redical polymerization compound be preferably 1 to 97 quality %; More preferably be 30 to 95 quality %, and be most preferably 30 to 45 quality %.
When attempting using ultraviolet-curing ink composite used among the present invention to form coloured image, can mix colouring agent.The not special restriction of colouring agent, and can select well-known adequate colouration agent (pigment, dyestuff) according to the desired use of ink composite.From the angle of weatherability, pigment is preferred.
The not special restriction of the pigment that can in the used ultraviolet-curing ink composite of the present invention, use, but (for example) organic or inorganic pigment can be used, and these pigment have following number and list in the color index.
Can use pigment red 3 number, No. 5, No. 19, No. 22, No. 31, No. 38, No. 43,48:1 number, 48:2 number, 48:3 number, 48:4 number, 48:5 number, 49:1 number, 53:1 number, 57:1 number, 57:2 number, 58:4 number, 63:1 number, No. 81,81:1 number, 81:2 number, 81:3 number, 81:4 number, No. 88, No. 104, No. 108, No. 112, No. 122, No. 123, No. 144, No. 146, No. 149, No. 166, No. 168, No. 169, No. 170, No. 177, No. 178, No. 179, No. 184, No. 185, No. 208, No. 216, No. 226 and No. 257 according to the desired use of printing ink; Pigment violet 3 number, No. 19, No. 23, No. 29, No. 30, No. 37, No. 50 and No. 88, and pigment orange 13 number, No. 16, No. 20 and No. 36 are as redness or cochineal; Use pigment blue 1 number, No. 15,15:1 number, 15:2 number, 15:3 number, 15:4 number, 15:6 number, No. 16,17-1 number, No. 22, No. 27, No. 28, No. 29, No. 36 and No. 60 as blueness or green pigment; Use pigment Green 7 number, No. 26, No. 36 and No. 50 as viridine green; Use pigment yellow No. 1, No. 3, No. 12, No. 13, No. 14, No. 17, No. 34, No. 35, No. 37, No. 55, No. 74, No. 81, No. 83, No. 93, No. 94, No. 95, No. 97, No. 108, No. 109, No. 110, No. 137, No. 138, No. 139, No. 153, No. 154, No. 155, No. 157, No. 166, No. 167, No. 168, No. 180, No. 185 and No. 193 are as yellow uitramarine; Use pigment black No. 7, No. 28 and No. 26 are as black pigment; And use Pigment white No. 6, No. 18 and No. 21 are as Chinese white.
Can in the used ultraviolet-curing ink composite of the present invention, add sensitizing dye, to help decomposing polymerization initiator through ultraviolet radiation.Sensitizing dye gets into excited electronic state through ultraviolet radiation-absorbing, and wherein ultraviolet radiation is a kind of actinic radiation of particular form.The sensitizing dye of excited electronic state contacts with polymerization initiator, and causes the effect such as electronics transmission, energy transmission and heating.Thereby polymerization initiator causes chemical change, that is, decompose to form group, acid or alkali.
Sensitizing dye should be according to the selected compound of the wavelength of ultraviolet radiation; Generate in its polymerization initiator used in the ultraviolet-curing ink composite and cause material; But consider that this sensitizing dye is used for the curing reaction of general uv line curable ink composition, can quote that to belong to following type of compounds and absorbing wavelength be 350 to 450nm the sensitizing dye instance as preferred sensitizing dye.
Specifically, (for example can use polynuclear aromatic compound (for example, pyrene 、 perylene class, triphenylene), xanthene compounds; Fluorescein, eosin, edible bright cherry-red, rhodamine toner B, rose-red), the flower cyanine compound (for example; Thia-carbonyl cyanine, oxa-carbocyanine), merocyanine compound (for example, merocyanine, carbonyl merocyanine), thiazine compounds (for example, thionine, methylenum careuleum, toluidine blue), acridine compound (for example; Acridine orange, chloroflavin, acridine yellow), anthraquinone compounds (for example; Anthraquinone), squalium compound (for example, squalium), coumarin compound (for example, 7-lignocaine-4-methylcoumarin) etc.
Because used ultraviolet-curing ink composite is a ultraviolet hardening among the present invention, thus preferably do not mix solvent so that produce reaction, and printing ink solidifies after ink composite is run into matrix material immediately.Yet, can mix designated solvent, prerequisite is this solvent solidification rate of not influencing ink composite etc.Can be with an organic solvent or water as solvent.Specifically, organic solvent improves the adhesiveness of ink composite and recording medium (carrier of supatex fabric or paper wood and so on), therefore can add this solvent.
The amount of organic solvent is 0.1 to 5 quality % of overall ultraviolet-curing ink composite used among (for example) the present invention, is preferably 0.1 to 3 quality %.
In addition, can in the used ultraviolet-curing ink composite of the present invention, add other known compound as required.For example, can suitably select and add surfactant, leveling auxiliary agent, delustering agent and mylar, polyurethane resin, vinyl, acrylic resin, rubber resin and wax, in order to regulate the characteristic of film.
" optical readable information " that use ultraviolet-curing printing ink to print means one dimension, two dimension or 3-dimensional encoding information; For example; Can't be deciphered by the people (decoding), but can decipher the information of (decoding) through specialized readers, for example bar code, QR Code, Data Matrix, PDF417, Maxi Code or VeriCode.In addition; The instance that is associated with optical readable information and is stored in the customizing messages in the database comprises: the emergency treatment agent of printed matter user's name, surname, age, address, sex, telephone number (landline telephone and mobile phone), e-mail address, programmed emergency, nationality, blood group, medical history, clinical medical history and appointment; The title of sports or contest, and the storeroom number of article that the entrant submits between active stage.
In the present invention, except the optical readable information that uses ultraviolet-curing printing ink to print, the information that can be deciphered by the people (that is, but vision identification information) also can be printed on the same nonwoven web matrix material.This need not print through ink jet printing, is preferred but print through the ink jet printing of using ultraviolet-curing printing ink.But the not special restriction of this type of vision identification information; But angle from personal information protection; It preferably is not that those should not be in visually cognizable information, and it can be the logo of title, activity or the contest of activity or contest, printed matter user's identification number, printed matter user's portrait etc.
In the present invention, but also can with the sense of touch identification information be printed on be printed with optical readable information and (randomly) in the above but on the nonwoven web matrix material of vision identification information.But this sense of touch identification information need not printed through ink jet printing, but is preferred through the printing that three-D pattern is carried out in the ink jet printing of using ultraviolet-curing printing ink.But this type of sense of touch identification information can be (for example) braille.
The not special restriction of the type of printed matter of the present invention, but be preferably single distinctive mark.Said single distinctive mark can be the bib that is used for activity or contest, perhaps admission ticket of amusement park etc., but be not limited to these.Bib is preferred especially single distinctive mark.
That printed matter external member of the present invention should comprise is a plurality of (that is, two or more) printed matter.In addition, printed matter external member of the present invention needn't simultaneously or printed on the same day, and should be two or more printed matters relevant with same or similar activity or contest.Printed matter external member of the present invention is such: but each printed matter in the external member all should comprise optical readable information and vision identification information; The information that said optical readable information shows is different from other printed matter in this external member; And but the vision identification information is identical for all printed matters in the external member; And each printed matter in the external member can comprise for the identical optical readable information of two or more printed matters in the external member, but and the information that can comprise demonstration be different from the vision identification information of other printed matter in the external member.
For example; When as the bib of marathon race etc.; Can be visually the title of marathon race be recognized as for the identical information of all printed matters in the printed matter external member with logo; To be recognized as optical readable information such as information such as personal information (being preferably optical readable information) simultaneously, different between the printed matter of information in external member that this optical readable information shows.
A kind of method for preparing bib will be described now, and said bib is the instance of the embodiment of printed matter of the present invention.Fig. 1 is the diagram that the embodiment of bib of the present invention (1) is shown.Bib (1) is for being used for the bib of marathon race, and the bib quantity of preparation is at least marathon entrant's quantity.
As shown in Figure 1, the title of marathon race (2), bib number (3), bar code (4) and QRCode (5) are printed on the bib (1).The title of marathon race (2) is identical for bib, and bib number (3), bar code (4) and QR Code (5) are variant for each bib.
Bar code (4) and QR Code (5) relate to the personal information that is stored in the database, for example bib wearer's address, name, age, blood group and medical history, and this type of personal information of bib wearer can read through barcode reader.
At first, generate the data that are used to prepare bar code.The personal information of obtaining through the each item of on entry blank, filling in (for example every entrant's address, name, age, blood group and medical history) is associated with entrant's number (personally identifiable information); As shown in Figure 2; Thereby this database of information of preparation storage is subsequently through this database of memory device stores.
Next, generate the bar code signal that is used for printed bar code (optical readable information) to each entrant's number, this bar code is corresponding with entrant's number.
Carry out printing operation subsequently.Use is such as Adobe Illustrator TMDeng software, be the numerical data of every entrant (every bib) preparation combination through following signal: be used to print marathon race title (2) signal, be used to print the signal of the bib number (3) of specifying the entrant and be used to print and specify entrant's corresponding bar code of entrant's number (personally identifiable information) (4) and the signal of QR Code (5).
Then, these data are sent to ink-jet printer, and use above-mentioned ultraviolet-curing printing ink that title (2), bib number (3), bar code (4) and the QR Code (5) of marathon race are printed on the surface of above-mentioned supatex fabric.
Replace bar code (4) and/or QR Code (5) or in addition, can use ultraviolet-curing printing ink on supatex fabric, to form braille information.
[ Embodiment]
To come more detailed ground explain the present invention through using embodiment now, but the present invention does not receive the restriction of these embodiments fully.
( Embodiment 1)
Use following operation preparation to be used for the bib of marathon race.
Tyvek with the E.I.DuPont manufacturing TM(name of product 1056D, basic weight are 52.5 to 57.5g/m to supatex fabric 2, thickness is 0.110 to 0.230mm, tearing strength is 4.8 to 9.8N/5cm) and be cut into the size of 245 * 280mm.When preparation finished product bib on the automatic gas cutting machine that is being connected to printer (200 * 40mm) time; Formed the monomark part (be used to indicate top and bottom, with the position of the left side and the right equidistance and the mark that shines four angles of plate originals, these marks are used for confirming shining the cutting position that plate originals is cut into finished size and perhaps are used for the polychrome printing chromatography).With the title of marathon race and player's number, photo and name (with the form of English alphabet symbol) but arrangement be the vision identification information, with in its implantation bib.In addition; With the emergency treatment agent of the contest of player's name (with Chinese form), surname, age, address, sex, telephone number (landline telephone and mobile phone), programmed emergency, nationality, blood group, participation, medical history, clinical medical history, appointment and between active stage the storeroom number arrangement of the article of being submitted be virtual information, so that it is implanted as optical readable information.
Create database through this virtual information is associated with entrant's personally identifiable information, and can read bar code or the QR Code that is printed on the bib through using barcode reader TMCome the information in the reading database.
Use Adobe TMIllustrator TMThe numerical data that is used for these contents are combined as single image for every player's preparation.Use the ultraviolet-curing printing ink (SD-108 that is used for ink-jet printer of Roland D.C.Versa UV LEC-300 and DuPont E.I. based on acrylic acid ester; This printing ink comprises the acrylic acid ester of about 30 to 45 quality %); Above-mentioned numerical data is printed on the supatex fabric, thereby obtains bib into every player's customization.
The bar code of resulting one of them bib and QR Code TMThe enlarged photograph of part is shown in Fig. 3.As shown in Figure 3, bar code on the bib and QR Code TMEdge clear and do not have smudgyly, and formed and can be easy to detected image through Optical devices.In addition, hue and luminance is particularly excellent.
( Embodiment 2)
Use with embodiment 1 in identical mode make bib, that different is the Tyvek with the E.I.DuPont manufacturing TM(name of product 1443R, basic weight are 41.0 to 45.0g/m to supatex fabric 2, thickness is 0.080 to 0.200mm, tearing strength is 9.8 to 22.5N/5cm) and as supatex fabric.Adopt with embodiment 1 in identical manufacture, bar code and QR Code TMEdge clear and do not have smudgyly, and formed and can be easy to detected image through Optical devices.In addition, hue and luminance is all very excellent.
( Comparing embodiment 1)
Tyvek with the E.I.DuPont manufacturing TMSupatex fabric (name of product 1056D) is cut into the size of 245 * 280mm.The ink-jet printer that uses commercially available acquisition is (by Canon; The Pixus 455i that makes) and non-ultraviolet-curing printing ink (BCI-24Color and BCI-24Black) Inc.; To be printed on the supatex fabric with identical numerical data in the embodiment 1, thereby obtain bib into every player's customization.
The bar code of resulting one of them bib and QR Code TMThe enlarged photograph of part is shown in Fig. 4.As shown in Figure 4, bar code and QR Code TMEdge blurry unclear, some bars can't distinguish with contiguous bar, and can't detect through Optical devices.In addition, hue and luminance is obviously inferior to the bib for preparing in embodiment 1 and 2.

Claims (8)

1. it is 20.0 to 120.0g/m that printed matter, said printed matter comprise basic weight 2, thickness is 0.020 to 0.400mm nonwoven web matrix material and the optical readable information through using ink jet printing method that the ultraviolet-curing ink printing is formed to the said matrix material.
2. according to the printed matter of claim 1, wherein said nonwoven web matrix material has 3.0 to 35.0N tearing strength.
3. according to the printed matter of claim 1 or claim 2, but also comprise the vision identification information that on said matrix material, forms through using ink jet printing method to utilize ultraviolet-curing printing ink to print.
4. according to each printed matter in the claim 1 to 3, but also comprise the sense of touch identification information that on said matrix material, forms through using ink jet printing method to utilize ultraviolet-curing printing ink to print.
5. according to each printed matter in the claim 1 to 4, said printed matter is single distinctive mark.
6. according to each printed matter in the claim 1 to 5, wherein said single distinctive mark is a bib.
7. printed matter external member; Said printed matter external member comprises a plurality of according to each printed matter in the claim 1 to 6; Wherein but each printed matter in said external member all comprises optical readable information and vision identification information; Said optical readable information shows the information that is different from other printed matter in the said external member, but and said vision identification information is identical for all printed matters in the said external member.
8. the method for preparing the printed matter external member; Said printed matter external member is made up of a plurality of printed matters; On each of said printed matter, all be printed on optical readable information, the information that said optical readable information shows is different from the information on other printed matter in the said external member, and said method comprises:
Import a kind of step in the mutually different information type,
Said input information translation is become the step of signal in order to the generation optical readable information corresponding with said input information,
Above-mentioned signal is sent to the step of printing equipment, and
According to above-mentioned signal, utilize ultraviolet-curing printing ink that above-mentioned optical readable information is printed on the step on the nonwoven web matrix material through using ink jet printing method, said matrix material has 20.0 to 120.0g/m 2Basic weight and 0.020 to 0.400mm thickness.
CN2010800111926A 2009-03-13 2010-03-12 Printed matter providing optically readable information Pending CN102348847A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112218604A (en) * 2018-06-15 2021-01-12 易希提卫生与保健公司 Absorbent article comprising a skin benefit agent and an ink composition and method of printing a material layer of an absorbent article

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2007148598A1 (en) * 2006-06-22 2009-11-19 コニカミノルタエムジー株式会社 Inkjet printer and image forming method
ITTO20110285A1 (en) * 2011-03-30 2012-10-01 Monica Milani CLOTHING AND SYSTEM INCLUDING THE GARMENT AND A DIGITAL ELECTRONIC DEVICE
ITMO20110160A1 (en) * 2011-06-27 2012-12-28 Tecno Label S R L INFORMATION SUPPORT.
JP6204826B2 (en) * 2013-12-27 2017-09-27 イビデン株式会社 Manufacturing method of holding sealing material
CN115049032A (en) 2014-04-07 2022-09-13 艾利丹尼森零售信息服务公司 Thermal transfer printing and method for use on specific articles of commerce for specific activities
ES2929842T3 (en) 2014-05-19 2022-12-02 Avery Dennison Retail Information Services Llc Composite image thermal transfer with scan-readable mark
GB201417718D0 (en) * 2014-10-07 2014-11-19 Sockatyes Holdings Ltd Display arrangement
KR101521492B1 (en) * 2014-11-26 2015-05-19 하태석 Mask pack and manufacturing method thereof
KR101801858B1 (en) * 2015-12-17 2017-12-29 주식회사 마로로봇 테크 Logistics conveyance robot position calibration method of wheel drive

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1344302A (en) * 1998-12-11 2002-04-10 太阳化学公司 Radiation curable water based cationic inks and coatings
CN1675270A (en) * 2002-08-08 2005-09-28 3M创新有限公司 Photocurable composition
CN101045351A (en) * 2006-03-30 2007-10-03 李瑞祥 Substrate comprising information and its production method

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0821068B2 (en) * 1991-11-14 1996-03-04 東レ株式会社 Bar code recording body
JP3074905B2 (en) 1992-03-02 2000-08-07 東レ株式会社 Manufacturing method of information cloth
JPH08187933A (en) 1995-01-12 1996-07-23 Mitsubishi Paper Mills Ltd Ink jet recording sheet
WO1999033669A1 (en) * 1997-12-30 1999-07-08 E.I. Du Pont De Nemours And Company Fibrous ink-jet printing media
JP2004334144A (en) 2003-05-08 2004-11-25 Tayano Kiyoji Brand discrimination method
JP5034265B2 (en) 2006-02-28 2012-09-26 Ｄｉｃ株式会社 UV-curable ink composition for inkjet recording
JP2008081516A (en) 2006-09-25 2008-04-10 Fujifilm Corp Radiation-curing type ink composition for ink jet, method for ink-jet recording, method for producing lithographic printing plate and lithographic printing plate
JP2008223014A (en) 2007-02-15 2008-09-25 Seiko Epson Corp Ultraviolet-ray curable ink composition, inkjet recording method using the same ultraviolet-ray curable ink composition, ink container and inkjet recording apparatus containing the same composition
JP2008280427A (en) 2007-05-10 2008-11-20 Konica Minolta Holdings Inc Ultraviolet-curable ink, and image recording method
CN101468555A (en) * 2007-12-26 2009-07-01 北京华旗资讯数码科技有限公司 Ink jet printer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1344302A (en) * 1998-12-11 2002-04-10 太阳化学公司 Radiation curable water based cationic inks and coatings
CN1675270A (en) * 2002-08-08 2005-09-28 3M创新有限公司 Photocurable composition
CN101045351A (en) * 2006-03-30 2007-10-03 李瑞祥 Substrate comprising information and its production method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112218604A (en) * 2018-06-15 2021-01-12 易希提卫生与保健公司 Absorbent article comprising a skin benefit agent and an ink composition and method of printing a material layer of an absorbent article

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WO2010105190A1 (en) 2010-09-16

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