CN102345371A - Dual-layer flame-retardant polyvinyl chloride (PVC) plastic floor - Google Patents
Dual-layer flame-retardant polyvinyl chloride (PVC) plastic floor Download PDFInfo
- Publication number
- CN102345371A CN102345371A CN2010102439513A CN201010243951A CN102345371A CN 102345371 A CN102345371 A CN 102345371A CN 2010102439513 A CN2010102439513 A CN 2010102439513A CN 201010243951 A CN201010243951 A CN 201010243951A CN 102345371 A CN102345371 A CN 102345371A
- Authority
- CN
- China
- Prior art keywords
- parts
- pvc
- floor
- dual
- flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000004800 polyvinyl chloride Substances 0.000 title abstract description 29
- 229920003023 plastic Polymers 0.000 title abstract description 12
- 239000004033 plastic Substances 0.000 title abstract description 12
- 239000003063 flame retardant Substances 0.000 title abstract description 8
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract 4
- 239000002355 dual-layer Substances 0.000 title abstract 4
- 239000000463 material Substances 0.000 claims abstract description 16
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 12
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 12
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 10
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 7
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 claims abstract description 5
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 5
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims abstract description 5
- -1 ethoxylated aliphatic alkylamine Chemical class 0.000 claims abstract description 5
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000004615 ingredient Substances 0.000 claims description 11
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 5
- 239000004135 Bone phosphate Substances 0.000 claims description 4
- 150000003973 alkyl amines Chemical class 0.000 claims description 4
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 abstract description 27
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 abstract 2
- 230000003712 anti-aging effect Effects 0.000 abstract 1
- LKAVYBZHOYOUSX-UHFFFAOYSA-N buta-1,3-diene;2-methylprop-2-enoic acid;styrene Chemical compound C=CC=C.CC(=C)C(O)=O.C=CC1=CC=CC=C1 LKAVYBZHOYOUSX-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000010410 layer Substances 0.000 abstract 1
- OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 abstract 1
- ZMHZSHHZIKJFIR-UHFFFAOYSA-N octyltin Chemical compound CCCCCCCC[Sn] ZMHZSHHZIKJFIR-UHFFFAOYSA-N 0.000 abstract 1
- 239000002344 surface layer Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000004566 building material Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Floor Finish (AREA)
Abstract
The invention belongs to a polyvinyl chloride (PVC) floor, and particularly relates to a dual-layer flame-retardant PVC plastic floor, which is characterized in that the dual-layer flame-retardant PVC floor consists of a dual-layer structure, a surface layer is made of an auxiliary material and a bottom layer is made of a main material; the main material consists of 100-120 parts of polyvinyl chloride resin, 8-10 parts of octyltin mercaptide, 25-30 parts of dioctyl phthalate, 11-15 parts of ethoxylated aliphatic alkylamine, 5-10 parts of aluminum hydroxide, 5-10 parts of magnesium hydroxide and 2-4 parts of anti-aging agent by weight; and the auxiliary material consists of 100-120 parts of polyvinyl chloride resin, 10-12 parts of methacrylate-butadiene-styrene (MBS) resin, 3-5 parts of zinc stearate, 4-6 parts of dibutyl phthalate, 5-8 parts of tribasic lead sulfate, 2-4 parts of di-tert-butylhydroquinone resin and 5-10 parts of magnesium hydroxide by weight. The invention provides the PVC floor with good flame-retardant performance. Since flame retardants, i.e. aluminum hydroxide and magnesium hydroxide are added, flames can be retarded effectively, new pollution is not caused and the flame retardants can be used as filling materials to reinforce the strength of the floor.
Description
Technical field
The invention belongs to the PVC floor, particularly double-deck anti-combustion PVC plastic floor.
Background technology
Each the field tomb plinth construction of current China continues burning hot, and the PVC product is at the promise well of building materials market, and the application on PVC floor then becomes focus wherein.See that from product itself the PVC product has advantages such as uvioresistant, acid-alkali-corrosive-resisting, anti-olive are mothproof, good flame resistance, antistatic, well and have good non-skid property, the walking safety and comfort; See that from the angle of environmental protection PVC is unleaded, volatility is low, need not paint and decoration, use is safe and reliable. and PVC chemical building material lighter weight, convenient storage and fortune axle, the reduction of invisible cost also has facilitation to its popularization.But some special areas such as open air need the better PVC of fire resistance floor, and the present invention provides the anti-combustion of a kind of bilayer PVC plastic floor PVC the floor, and its fire resistance is distinguished.
Summary of the invention
Goal of the invention
The present invention provides a kind of novel double-layer flame-proof PVC floor, and its fire resistance is distinguished.
Technical scheme
A kind of double-deck flame-proof PVC floor is characterized in that being made up of double-decker, and auxiliary material is formed the top layer, and major ingredient constitutes bottom; By weight wherein,
The major ingredient prescription is: Corvic 100-120 part; Dimethyl dimercapto 2-ethyl hexyl ethanoate tin 8-10 part, dioctyl phthalate 25-30 part, the alkylamine 11-15 of ethoxylated fat family part; Aluminium hydroxide 5-10 part, magnesium hydroxide 5-10 part, age resister 2-4 part.
The prescription of auxiliary material is: Corvic 100-120 part, MBS resin 10-12 part, zinc stearate 3-5 part, dibutyl phthalate 4-6 part, lead sulfate tribasic 5-8 part, di-tert-butyl hydroquinone's resin 2-4 part, magnesium hydroxide 5-10 part.
The preparation technology on a kind of double-deck flame-proof PVC floor:
A, batch mixing mix above-mentioned prescription;
B, mixing: on two roller plastics processing mills that the PVC plasticizing is even; Temperature is about 140-160;
C, extrude: extrude by foamed plastic extruder and co-extrusion machine pressure after the mixing completion of major ingredient and auxiliary material, wherein about temperature 140-160, pressure 180-200kg/cm
2
D, synthetic double-deck processing typing, warp cooling traction again;
E, finished product.
Beneficial effect
1, the present invention provides a kind of fire resistance good PVC floor, and its prescription has increased fire retardant aluminium hydroxide and magnesium hydroxide, can be fire-retardant effectively, and do not produce new pollution, can strengthen the intensity on floor as filler simultaneously.
2, the present invention adopts double-decker, and surface structure adopts the bigger prescription of intensity, has and resistance to wears, characteristics such as resistance to compression.
The specific embodiment
Embodiment 1
A kind of double-deck flame-proof PVC floor is characterized in that being made up of double-decker, and auxiliary material is formed the top layer, and major ingredient constitutes bottom; By weight wherein,
The major ingredient prescription is: Corvic 100kg, dimethyl dimercapto 2-ethyl hexyl ethanoate tin 8kg, dioctyl phthalate 25kg, the alkylamine 11kg of ethoxylated fat family, aluminium hydroxide 5kg, magnesium hydroxide 5kg, age resister 2kg;
The prescription of auxiliary material is: Corvic 100kg, MBS resin 10kg, zinc stearate 3kg, dibutyl phthalate 4kg, lead sulfate tribasic 5kg, di-tert-butyl hydroquinone's resin 2kg, magnesium hydroxide 5kg.
The preparation technology on a kind of double-deck flame-proof PVC floor:
A, batch mixing mix above-mentioned prescription;
B, mixing: on two roller plastics processing mills that the PVC plasticizing is even; Temperature is about 140-160;
C, extrude: extrude by foamed plastic extruder and co-extrusion machine pressure after the mixing completion of major ingredient and auxiliary material, wherein about temperature 140-160, pressure 180-200kg/cm
2
D, synthetic double-deck processing typing, warp cooling traction again;
E, finished product.
Embodiment 2
A kind of double-deck flame-proof PVC floor is characterized in that being made up of double-decker, and auxiliary material is formed the top layer, and major ingredient constitutes bottom; By weight wherein,
The major ingredient prescription is: Corvic 120kg, dimethyl dimercapto 2-ethyl hexyl ethanoate tin 10kg, dioctyl phthalate 30kg, the alkylamine 15kg of ethoxylated fat family, aluminium hydroxide 10kg, magnesium hydroxide 10kg, age resister 4kg.
The prescription of auxiliary material is: Corvic 120kg, MBS resin 12kg, zinc stearate 5kg, dibutyl phthalate 6kg, lead sulfate tribasic 8kg, di-tert-butyl hydroquinone's resin 4kg magnesium hydroxide 10kg.
The preparation technology on a kind of double-decker antistatic polyvinyl chloride plastic floor:
A, batch mixing mix above-mentioned prescription;
B, mixing: on two roller plastics processing mills that the PVC plasticizing is even; Temperature is about 140-160;
C, extrude: extrude by foamed plastic extruder and co-extrusion machine pressure after the mixing completion of major ingredient and auxiliary material, wherein about temperature 140-160, pressure 180-200kg/cm
2
D, synthetic double-deck processing typing, warp cooling traction again;
E, finished product.
Claims (1)
1. a double-deck flame-proof PVC floor is characterized in that being made up of double-decker, and auxiliary material is formed the top layer, and major ingredient constitutes bottom; By weight wherein,
The major ingredient prescription is: Corvic 100-120 part; Dimethyl dimercapto 2-ethyl hexyl ethanoate tin 8-10 part, dioctyl phthalate 25-30 part, the alkylamine 11-15 of ethoxylated fat family part; Aluminium hydroxide 5-10 part, magnesium hydroxide 5-10 part, age resister 2-4 part.
The prescription of auxiliary material is: Corvic 100-120 part, MBS resin 10-12 part, zinc stearate 3-5 part, dibutyl phthalate 4-6 part, lead sulfate tribasic 5-8 part, di-tert-butyl hydroquinone's resin 2-4 part, magnesium hydroxide 5-10 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010243951.3A CN102345371B (en) | 2010-08-03 | 2010-08-03 | Dual-layer flame-retardant polyvinyl chloride (PVC) plastic floor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010243951.3A CN102345371B (en) | 2010-08-03 | 2010-08-03 | Dual-layer flame-retardant polyvinyl chloride (PVC) plastic floor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102345371A true CN102345371A (en) | 2012-02-08 |
| CN102345371B CN102345371B (en) | 2014-03-05 |
Family
ID=45544411
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010243951.3A Expired - Fee Related CN102345371B (en) | 2010-08-03 | 2010-08-03 | Dual-layer flame-retardant polyvinyl chloride (PVC) plastic floor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102345371B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103158315A (en) * | 2013-01-30 | 2013-06-19 | 合肥美的荣事达电冰箱有限公司 | Polyvinyl chloride (PVC) two-layer composite board used for refrigeration equipment |
| CN104512058A (en) * | 2015-01-22 | 2015-04-15 | 江苏海建股份有限公司 | Cooling and silencing PVC laminated board |
| CN104847082A (en) * | 2014-02-17 | 2015-08-19 | 上海劲嘉建材科技有限公司 | Inflaming-retarding PVC floor and manufacturing method for same |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4935281A (en) * | 1989-04-05 | 1990-06-19 | Springs Industries, Inc. | Flame barrier office building materials |
| KR20020096479A (en) * | 2001-06-20 | 2002-12-31 | 장홍근 | Thermoplastic resin-laminated structure, preparing method and use thereof |
| CN101152760A (en) * | 2007-09-11 | 2008-04-02 | 浙江永吉木业有限公司 | Production technology for wood-plastic water-proof outdoor floor and products produced thereby |
| CN101200971A (en) * | 2006-12-13 | 2008-06-18 | 郎玉山 | PVC micro-foaming macromolecular xylogen floor and method for making same |
| CN101481231A (en) * | 2008-12-19 | 2009-07-15 | 吴江市金晟塑胶制品有限公司 | Wear resistant plastic floor |
-
2010
- 2010-08-03 CN CN201010243951.3A patent/CN102345371B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4935281A (en) * | 1989-04-05 | 1990-06-19 | Springs Industries, Inc. | Flame barrier office building materials |
| KR20020096479A (en) * | 2001-06-20 | 2002-12-31 | 장홍근 | Thermoplastic resin-laminated structure, preparing method and use thereof |
| CN101200971A (en) * | 2006-12-13 | 2008-06-18 | 郎玉山 | PVC micro-foaming macromolecular xylogen floor and method for making same |
| CN101152760A (en) * | 2007-09-11 | 2008-04-02 | 浙江永吉木业有限公司 | Production technology for wood-plastic water-proof outdoor floor and products produced thereby |
| CN101481231A (en) * | 2008-12-19 | 2009-07-15 | 吴江市金晟塑胶制品有限公司 | Wear resistant plastic floor |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103158315A (en) * | 2013-01-30 | 2013-06-19 | 合肥美的荣事达电冰箱有限公司 | Polyvinyl chloride (PVC) two-layer composite board used for refrigeration equipment |
| CN104847082A (en) * | 2014-02-17 | 2015-08-19 | 上海劲嘉建材科技有限公司 | Inflaming-retarding PVC floor and manufacturing method for same |
| CN104847082B (en) * | 2014-02-17 | 2017-08-25 | 上海劲嘉建材科技有限公司 | Flame-proof PVC floor and its manufacture method |
| CN104512058A (en) * | 2015-01-22 | 2015-04-15 | 江苏海建股份有限公司 | Cooling and silencing PVC laminated board |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102345371B (en) | 2014-03-05 |
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| ASS | Succession or assignment of patent right |
Owner name: SUZHOU XIELV NETWORK TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SUZHOU FUTONG PLASTIC + ELECTRIC INDUSTRY CO., LTD. Effective date: 20150826 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20150826 Address after: Suzhou River Road in Wujiang District of Suzhou City, Jiangsu province 215200 No. 18 No. 4 305 Patentee after: Suzhou Xielv Network Technology Co., Ltd. Address before: 215211 Wujiang city of Jiangsu Province, Zhao Town Road No. 8 Patentee before: Suzhou Futong Plastic & Electric Industry Co., Ltd. |
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Effective date of registration: 20160420 Address after: Wujiang District of Suzhou City, Jiangsu province 215200, Zhao Town Road No. 8 Patentee after: Suzhou Futong New Materials Technology Co., Ltd. Address before: Suzhou River Road in Wujiang District of Suzhou City, Jiangsu province 215200 No. 18 No. 4 305 Patentee before: Suzhou Xielv Network Technology Co., Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140305 Termination date: 20190803 |
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| CF01 | Termination of patent right due to non-payment of annual fee |