CN102339664B - Method for preparing high-field Nb3Sn superconducting strand with Nb47Ti bar to add Ti - Google Patents

Method for preparing high-field Nb3Sn superconducting strand with Nb47Ti bar to add Ti Download PDF

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CN102339664B
CN102339664B CN2011102472728A CN201110247272A CN102339664B CN 102339664 B CN102339664 B CN 102339664B CN 2011102472728 A CN2011102472728 A CN 2011102472728A CN 201110247272 A CN201110247272 A CN 201110247272A CN 102339664 B CN102339664 B CN 102339664B
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nb47ti
cunb
jacket
plug
core
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CN102339664A (en
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李春广
孙霞光
管军强
肖成举
李建峰
刘建伟
张丰收
刘向宏
冯勇
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Western Superconducting Technologies Co Ltd
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Abstract

The invention relates to a method for preparing a high-field Nb3Sn superconducting strand with a Nb47Ti bar to add Ti, which adopts Nb47Ti as an adding source to replace a partial Nb core wire so that the purpose of adding Ti is achieved, realizes a key technology for adopting Nb47Ti as the adding source to add Ti in a high-field Nb3Sn strand production process, and can be applied to the preparation of the high-field Nb3Sn strand. The distribution method, the number, the follow-up processing method, the parameters and the like of Nb47Ti have been successfully applied to production tests, the Nb47Ti is uniformly and symmetrically distributed in the middle of the Nb core wire, so that the uniformity of Ti diffusion in heat treatment is benefited, and the generation and the reaction of Nb3Sn are fully participated in; a set of mature procedures including cleaning, assembly, degassing, welding, extrusion and drawing are used; and metallurgy integration among all component interfaces of a CuNb multi-core composite bar with the Nb47Ti core is realized, and the composite bar is used for preparing the Nb3Sn superconducting strand which can be applied to high-filed magnet preparation.

Description

A kind ofly prepare High-Field Nb with the Nb47Ti rod as adding the Ti element 3The method of Sn Superconducting Strand
Technical field
The present invention relates to a kind ofly add the Ti element with the Nb47Ti rod as the interpolation source and prepare High-Field Nb 3The method of Sn Superconducting Strand belongs to the superconductor preparing technical field, relates to a kind of at High-Field Nb 3Add the method for Ti element in the Sn strand manufacture process with the form of Nb47Ti rod.
Background technology
Nei Xifa Nb 3The Sn strand is mainly used in the high-tech sectors such as thermonuclear fusion reaction experimental reactor (ITER), NMR, high-energy physics, particle accelerator magnet, in order to improve the current capacity of strand under the High-Field, commercial Nb 3The Sn strand all needs to add element Ti or Ta, considers cost and adding method, and it is first-selected adding the Ti element.At interior tin method Nb 3In the Sn strand manufacture technique, independent of one another because of Cu, Nb, each constituent element of Sn, flexible design is so that the adding method of Ti element has diversity and flexibility.Through development in recent years, comparatively ripe Ti addition manner has two kinds: a kind of is Ti to be added on form the Sn-Ti alloy in the Sn source, and another kind is as constituent element replacement minority Nb core independently with the Nb47Ti core.The first method development early also sees both at home and abroad relevant paper and patent, but because the cost of manufacture of Sn-Ti alloy is higher, and the hard fragility of large-size Ti6Sn5 particle has also limited further developing of the method in the alloy.The adding method cost of Nb47Ti is low, and plasticity is fine, is Nb 3The Ti adding method that the Sn strand manufacture is comparatively desirable.The method still is in the initial application stage, and key technology is wherein grasped as business secret by more external superconductor production companies, and relevant paper and patent also only only limit to introduce.
Add the Ti element in the mode of Nb47Ti, the design of distribution mode has determined the uniformity of Ti diffusion in the strand heat treatment process, thereby has determined the additive effect of Ti element; And interpolation quantity has determined the adding proportion of Ti; To guarantee that in the course of processing deform in same pace of Nb47Ti core silk and Nb core silk is to guarantee the normal stretching of strand, so processing mode and machined parameters have determined that then the method success is applied to produce.
Summary of the invention
The technical problem that solves
For fear of the deficiencies in the prior art part, the present invention proposes a kind ofly to prepare High-Field Nb with the Nb47Ti rod as adding the Ti element 3The method of Sn Superconducting Strand.
Technical scheme
A kind ofly prepare High-Field Nb with the Nb47Ti rod as adding the Ti element 3The method of Sn Superconducting Strand is characterized in that step is as follows:
Step 1 adopts the single plug of CuNb to carry out the jacket assembling: be followed successively by from outside to inside: Cu jacket, Nb barrier layer, the single plug of CuNb and the single plug of Nb47Ti, pure Cu plug; Assembling process is at the single plug of the peripheral solid matter distribution of the pure Cu plug central core CuNb of solid matter, in the middle of the single plug of CuNb, distribute symmetrically and evenly the single plug of some Nb47Ti is set, put into together in the Cu jacket after putting again the Nb barrier layer, at last with the slit between fine copper interpolation slit rod reeve Nb barrier layer and the single plug of CuNb, build upper and lower covers, finish assembling; The shape of the single plug of described CuNb, the single plug of Nb47Ti and pure Cu plug is six sides;
The single plug of described Nb47Ti is identical with the single plug size shape of CuNb;
The single plug of described CuNb is 200~400;
The single plug of described Nb47Ti is 5~20;
The step 2 pair CuNb multicore jacket that assembles carries out degassing processing: carry out in vacuum heat treatment furnace, open the end cap of jacket one end, degasification vacuum degree is 10 -2Pa, the degasification temperature is 450 ℃, treats can come out of the stove when the jacket temperature is down to below 50 ℃, finishes the degasification operation;
Jacket after the step 3 pair degasification carries out soldering: carry out in vacuum electron beam welder, when vacuum degree to 5.0 * 10 -3Up and down end cap to jacket behind the Pa carries out electron beam soldering and sealing, and each constituent element is sealed in the Cu jacket; Behind jacket cooling 30min, take out, finish welding;
The jacket of step 4 pair welding pushes: carry out at horizontal extruder, before the extruding jacket fully is heated to 600 ℃, according to the speed extruding of 10~30mm/S, extrusion ratio is controlled at 10~20, obtains High-Field Nb again 3Sn Superconducting Strand preparation appliance has the CuNb multicore composite rod of Nb47Ti core;
The preparation of step 5 subgroup unit: the CuNb multicore composite rod with Nb47Ti that will obtain blocks and is single 1.2~1.5m, carry out deep hole machining at deep hole processing equipment and remove the CuNb multicore multiple tube that core Cu district obtains to have Nb47Ti, be contained in the CuNb-Sn multicore complex that obtains to have the Sn source in the multiple tube through the Sn group of alloys of cleaning, redraw the subgroup unit that this species complex of processing obtains to be used for assembling final blank;
The final blank processing of step 6: according to product requirement first being assembled in the Cu pipe with pure Cu plug boundling of the subgroup of some numbers obtained final blank, this final blank acquisition High-Field Nb of stretched processing 3The Sn Superconducting Strand.
Beneficial effect
The a kind of of the present invention's proposition prepares High-Field Nb with Nb47Ti as interpolation source interpolation Ti element 3The method of Sn Superconducting Strand is replaced part Nb core silk with Nb47Ti as the interpolation source and is reached the purpose that the Ti element adds, and has solved High-Field Nb 3Add the key technology of Ti element in the Sn strand production process with Nb47Ti as the interpolation source, can be applicable to High-Field Nb 3The preparation of Sn strand.The distribution mode of Nb47Ti among the present invention, quantity, follow-up processing method and parameter etc. have been successfully applied to pilot production, and Nb47Ti is distributed in the middle of the Nb core silk symmetrically, the uniformity of Ti Elements Diffusion when being beneficial to heat treatment, attend fully Nb 3The reaction of formation of Sn; Used ripe cleaning, assembling, degasification, welding, extruding, the drawing procedure of a cover, having between each constituent element interface of Nb47Ti core CuNb multicore composite rod of preparation reached metallurgical binding, uses this compound bar to prepare and can be applicable to the Nb that high field magnet prepares 3The Sn Superconducting Strand.
This method has been used business-like Nb47Ti rod, and cost is lower; And Nb47Ti has excellent cold working plasticity, is beneficial to very much Nb 3The cold drawn processing of Sn strand; This technique machinability is good, can be used for production and application.
Description of drawings
Fig. 1: for having 8 Nb47Ti cores, the design of the CuNb jacket of 334 Nb cores;
Fig. 2: for having 18 Nb47Ti cores, the CuNb jacket design of 324 Nb cores;
Fig. 3: for having 18 Nb47Ti cores, the CuNb rod extruding sectional view of 324 Nb cores;
Fig. 4: be the Nb with the preparation of Nb47Ti core CuNb rod that utilizes this invention to obtain 3The diffusion profile of Ti during the heat treatment of Sn strand.
The 1-Cu jacket, 2-Nb barrier layer, 3-CuNb plug district, the NbTi plug that 4-distributes symmetrically, 5-center C u plug district.
Embodiment
Now in conjunction with the embodiments, the invention will be further described for accompanying drawing:
Embodiment 1: design has 334 CuNb plugs, the High-Field Nb of 8 NbTi/Cu plugs 3Sn strand production multicore CuNb jacket, as shown in Figure 1.1 is the Cu jacket among the figure, and 2 is the Nb barrier layer, and 3 is the CuNb plug district of 334 solid matters, and 4 is 8 NbTi/Cu plugs that distribute symmetrically, and centered by 5 Cu plug district.
Step 1 adopts the single plug of CuNb to carry out the jacket assembling: the single plug of pure Cu plug district peripheral solid matter distribution CuNb at the center, in the middle of the single plug of CuNb, distribute symmetrically and evenly the Nb47Ti/Cu core is set, put into together in the Cu jacket after putting again the Nb barrier layer, at last with the slit between the single plug of fine copper interpolation slit rod reeve CuNb and the Nb barrier layer, build upper and lower covers, finish assembling; The shape of the single plug of described CuNb, Nb47Ti/Cu plug and pure Cu plug is six sides;
The step 2 pair CuNb multicore jacket that assembles carries out degassing processing: open the end cap of jacket one end, degasification vacuum degree is 10 -2Pa, the degasification temperature is 450 ℃, treats to come out of the stove when temperature is reduced to below 50 ℃, finishes the degasification operation;
Jacket after the step 3 pair degasification carries out soldering: carry out in vacuum electron beam welder, welding vacuum degree is 5.0 * 10 -3Pa carries out electron beam soldering and sealing to the up and down end cap of jacket, and each constituent element is sealed in the Cu jacket; Behind jacket cooling 30min, take out, finish welding;
The jacket of step 4 pair welding pushes: carry out at horizontal extruder, before the extruding jacket fully is heated to 600 ℃, extrusion speed is 20mm/S, and extrusion ratio is 10.15, obtains High-Field Nb 3Sn Superconducting Strand preparation appliance has the CuNb multicore composite rod of Nb47Ti core.
Each constituent element interface reaches metallurgical binding fully in the rear bar of extruding, and regular shape, conforms to design.
The preparation of step 5 subgroup unit: the CuNb multicore composite rod with Nb47Ti that will obtain blocks and is single 1.2m, carries out deep hole machining at deep hole processing equipment and removes core Cu district, obtains to have the CuNb multicore multiple tube of Nb47Ti core.The Sn group of alloys of cleaning is contained in the CuNb multicore multiple tube with Nb47Ti core that cleaned, obtains to have the CuNb-Sn multicore complex in Sn source, redraw the subgroup unit that this species complex of processing obtains to be used for assembling final blank.
Step 6 High-Field Nb 3The processing of Sn strand: 54 subgroup units and 7 pure Cu plug boundlings are assembled in the final blank of acquisition in the Cu pipe, and this final blank of stretched processing obtains High-Field Nb 3The Sn Superconducting Strand.
Embodiment 2:
Change the NbTi/Cu plug quantity among the embodiment 1 into 18, CuNb plug quantity is 324 simultaneously, assembling, degasification, welding, extruding, the same embodiment of strand manufacturing procedure, and the oversensitive compound bar sectional view of the CuNb with NbTi core silk that obtains is as shown in Figure 3.1 is the Cu jacket among the figure, and 2 is the Nb barrier layer, and 3 is the CuNb plug district of 324 solid matters, and 4 is 18 NbTi/Cu plugs that distribute symmetrically, and centered by 5 Cu plug district.As seen from the figure, the shape of each constituent element in the cross section, arranging conforms to design drawing 2, and Cu and Nb barrier layer, and the Cu between the Cu between the CuNb plug and NbTi/Cu plug is without lamination, and reaches metallurgical binding.
The Nb with Nb47Ti core CuNb rod preparation of figure four for utilizing this invention to obtain 3The diffusion profile of Ti during the heat treatment of Sn strand, visible Ti has been uniformly distributed in the interface of strand, has reached good additive effect.

Claims (1)

1. one kind prepares High-Field Nb with the Nb47Ti rod as adding the Ti element 3The method of Sn Superconducting Strand is characterized in that step is as follows:
Step 1 adopts the single plug of CuNb to carry out the jacket assembling: be followed successively by from outside to inside: Cu jacket, Nb barrier layer, the single plug of CuNb and the single plug of Nb47Ti, pure Cu plug; Assembling process is at the single plug of the peripheral solid matter distribution of the pure Cu plug central core CuNb of solid matter, in the middle of the single plug of CuNb, distribute symmetrically and evenly the single plug of some Nb47Ti is set, put into together in the Cu jacket after putting again the Nb barrier layer, at last with the slit between fine copper interpolation slit rod reeve Nb barrier layer and the single plug of CuNb, build upper and lower covers, finish assembling; The shape of the single plug of described CuNb, the single plug of Nb47Ti and pure Cu plug is six sides;
The step 2 pair CuNb multicore jacket that assembles carries out degassing processing: carry out in vacuum heat treatment furnace, open the end cap of jacket one end, degasification vacuum degree is 10 -2Pa, the degasification temperature is 450 ℃, treats to come out of the stove when the jacket temperature is down to below 50 ℃, finishes the degasification operation;
Jacket after the step 3 pair degasification carries out soldering: carry out in vacuum electron beam welder, when vacuum degree to 5.0 * 10 -3Up and down end cap to jacket behind the Pa carries out electron beam soldering and sealing, and each constituent element is sealed in the Cu jacket; Behind jacket cooling 30min, take out, finish welding;
The jacket of step 4 pair welding pushes: carry out at horizontal extruder, before the extruding jacket fully is heated to 600 ℃, according to the speed extruding of 10~30mm/S, extrusion ratio is controlled at 10~20, obtains the CuNb multicore composite rod that High-Field Nb3Sn Superconducting Strand preparation appliance has the Nb47Ti core again;
The preparation of step 5 subgroup unit: the CuNb multicore composite rod with Nb47Ti core that will obtain blocks and is single 1.2~1.5m, carry out deep hole machining at deep hole processing equipment and remove the CuNb multicore multiple tube that core Cu district obtains to have the Nb47Ti core, be contained in the CuNb-Sn multicore complex that obtains to have the Sn source in the multiple tube through the Sn group of alloys of cleaning, redraw the subgroup unit that this species complex of processing obtains to be used for assembling final blank;
The final blank processing of step 6: according to product requirement first being assembled in the Cu pipe with pure Cu plug boundling of the subgroup of some numbers obtained final blank, this final blank acquisition High-Field Nb of stretched processing 3The Sn Superconducting Strand.
CN2011102472728A 2011-08-25 2011-08-25 Method for preparing high-field Nb3Sn superconducting strand with Nb47Ti bar to add Ti Active CN102339664B (en)

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CN110993185B (en) * 2019-12-23 2021-03-09 福建师范大学 Ti-doped internal tin method Nb3Preparation method of Sn precursor wire
CN115295243B (en) * 2022-09-30 2022-12-30 西部超导材料科技股份有限公司 Preparation method of element-doped high-critical-current-density niobium-tin superconducting strand
CN115295242B (en) * 2022-09-30 2023-01-24 西部超导材料科技股份有限公司 Preparation method of niobium tri-tin superconducting stranded wire with high critical current density
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