CN102336976A - Resin composition for manufacturing diffusion plate for lighting and signboard - Google Patents

Resin composition for manufacturing diffusion plate for lighting and signboard Download PDF

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Publication number
CN102336976A
CN102336976A CN2011102041229A CN201110204122A CN102336976A CN 102336976 A CN102336976 A CN 102336976A CN 2011102041229 A CN2011102041229 A CN 2011102041229A CN 201110204122 A CN201110204122 A CN 201110204122A CN 102336976 A CN102336976 A CN 102336976A
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CN
China
Prior art keywords
resin combination
signboard
diffuser plate
resin
present
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Pending
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CN2011102041229A
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Chinese (zh)
Inventor
河荣埈
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SEWON PRECISION INDUSTRY Co Ltd
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SEWON PRECISION INDUSTRY Co Ltd
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Publication date
Application filed by SEWON PRECISION INDUSTRY Co Ltd filed Critical SEWON PRECISION INDUSTRY Co Ltd
Publication of CN102336976A publication Critical patent/CN102336976A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/16Solid spheres
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V3/00Globes; Bowls; Cover glasses
    • F21V3/04Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings
    • F21V3/06Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings characterised by the material
    • F21V3/062Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings characterised by the material the material being plastics
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/02Diffusing elements; Afocal elements

Abstract

The invention provides a resin composition for manufacturing a diffusion plate for lighting and a signboard, the resin composition in the invention is manufactured via polystyrene; PS and high impact polystyrene; HIPS. According to the invention, the resin composition can improve light diffusion from light source, impact resistance, transmittivity, and shielding performance, and reduce manufacture cost.

Description

Be used to make illumination and signboard resin combination with diffuser plate
The cross reference of related application
Right of priority and rights and interests that the korean patent application case of the application's case request submission on July 19th, 2010 is 10-2010-0069527 number, the disclosed content of said korean patent application case is all incorporated this paper into way of reference.
Technical field
The present invention relates to be used to throw light on and the diffuser plate of signboard and the resin combination that is used to make said diffuser plate, and more particularly, relate to and use PS (polystyrene; PS) resin is made illumination and signboard with the resin combination of diffuser plate, said resin combination can increase light from the diffusion of light source, improve shock resistance, raising transsmissivity and shielding and reduction manufacturing cost.
Background technology
Generally speaking, the diffuser plate that is used to throw light on is positioned at the outside of outdoor signboard, exterior lighting or interior lighting, and diffuser plate is used for the light from the rear side emission is spread.
In addition, the required mechanical characteristics of diffuser plate changes according to desired use.Therefore for example, directly be exposed under the outdoor situation at signboard, in fact diffuser plate is exposed to physical environment all the time, needs high impulse strength and weather resistance preferably, lessly fades or is out of shape such as what caused by solar ray, temperature, humidity etc.Because most of signboard is the form that is fabricated to plate, so generally lower to the Mould Machining performance demands.On the contrary, be used at diffuser plate under the situation of interior lighting, diffuser plate directly is not exposed to solar ray and diffuser plate and is used for the less room of temperature and humidity change, and is therefore lower to the requirement of weather resistance.Yet plasticity-must be better so that diffuser plate can be according to designing quality and aesthetic quality formation different shape, and the outward appearance of diffuser plate should be neatly so that the people feel to loosen.
In view of these reasons, outside conventional chamber, under the situation of signboard, mainly use by polycarbonate (polycarbonate; PC) diffuser plate processed of resin, said polycarbonate resin has good shock resistance; And, under the situation of indoor signboard, be widely used by polymethylmethacrylate (polymethylmethacrylate; PMMA) diffuser plate processed of resin, said plexiglass has good plasticity-.Now, use the diffuser plate of PMMA resin generally to be used for outdoor signboard, the thickness of said PMMA resin increases to improve shock resistance.
As shown in Figure 1, diffuser plate 2 is used for signboard 1, so that advertising printing is attached to the surface on thin plate and with thin plate, said diffuser plate 2 is mainly processed by lighttight acryhic material or PC resin.In addition, as shown in Figure 2, the diffuser plate that is used for means of illumination 3 is used for radiative light-emitting device (not shown) as lid 4 or box with protection, and said diffuser plate comes the light of selfluminous device also as scatterer with diffusion.
In addition, diffuser plate be used for display unit (such as, watch-dog, televisor etc.) situation under, this is an important use of light diffusing sheet, diffuser plate is generally processed by the PS with plate shape (PS) resin.
Yet the PC resin that is used for indoor and outdoor illumination and signboard is costliness, and the PC resin can not form different shape, because relatively poor Mould Machining performance.Under the situation of acryhic material, price is low but acryhic material has lower intensity and lower transmittance and diffusivity.Therefore, the distance that the diffuser plate of being processed by acryhic material should be predetermined at interval with light, therefore said diffuser plate occupies than large space.
Therefore in addition, the PS resin has good transmittance and diffusivity, but the shock strength of PS resin is lower than the shock strength of acryhic material, said PS resin and not being suitable in existing means of illumination or the signboard.
Summary of the invention
The present invention makes great efforts to solve the above-mentioned problem that is associated with prior art; And target of the present invention provides and is used to make illumination and the resin combination of signboard with diffuser plate, said resin combination can increase light from the diffusion of light source, improve shock resistance, raising transsmissivity and shielding and reduction manufacturing cost.
The present invention has following characteristic to realize above-mentioned target.
Can prepare the resin combination that is used to make illumination and signboard with diffuser plate according to of the present invention through mixing PS (PS) and high-impact polystyrene (HIPS).
Preferably, weight ratio that can 80: 20 is mixed said PS and said HIPS.
In addition, weight ratio that can 70: 30 is mixed said PS and said HIPS.
In addition, resin combination of the present invention can further comprise at least one diffusant that is selected from by the following group that forms: the mixture of vinylformic acid pearl, silica bead and vinylformic acid pearl and silica bead, ultraviolet ray (ultraviolet; UV) absorption agent or UV stablizer and white dyes.
Description of drawings
Describe exemplary embodiment of the present invention in detail through consulting accompanying drawing, above-mentioned and other target of the present invention, feature and advantage will be more obvious to those skilled in the art, in the accompanying drawings:
Fig. 1 is the skeleton view that traditional signboard is shown; And
Fig. 2 is the skeleton view that conventional illuminator is shown.
Embodiment
Hereinafter, will consult accompanying drawing and describe preferred implementation of the present invention in more detail.Embodiment of the present invention can be revised as various forms, and should scope of the present invention be interpreted as and be defined in said embodiment.Provide embodiment of the present invention more fully to explain the present invention to those of ordinary skill in the art.Therefore, can lavish praise on oneself the component shape shown in the accompanying drawing to stress elaboration clearly.
Can prepare the resin combination that is used to make illumination and signboard with diffuser plate of the present invention through mixing PS (PS) and high-impact polystyrene (HIPS).
Preferably, mix said PS and said HIPS with 80: 20 weight ratio.
In addition, weight ratio that can 70: 30 is mixed said PS and said HIPS.
Simultaneously, resin combination of the present invention can further comprise at least one diffusant that is selected from by the following group that forms: the mixture of vinylformic acid pearl, silica bead and vinylformic acid pearl and silica bead.Preferably, resin combination of the present invention can further comprise UV absorption agent, UV stablizer, white dyes and photostabilizer.
Test case
It is performed test result on 2.0T and the diffuser plate processed by differing materials that following table is illustrated in thickness.
Figure BSA00000541852100031
* the physical property of PMMA is the representing characteristic of grade LGMMA HP202.
The physical property of * PC is the representing characteristic from the grade 106U of Cheil Industries Inc..
* * illuminance is represented the light quantity of passing diffuser plate with transmission from fluorescent emission, and diffuser plate and fluorescence distance apart are about 7cm.
* * * shielding representes to be in reverse to diffuser plate and the resolution of localized light source form, and shielding means and can not see light source form well preferably.
Can find out that from above-mentioned test result resin combination of the present invention has good shock strength compared to pure PS resin.
That is, resin combination of the present invention can improve shock strength, and the shortcoming of this pure just PS resin.
Yet the diffused transmission rate of resin combination, parallel transsmissivity and illuminance are lower than the diffused transmission rate of pure PS resin, parallel transsmissivity and illuminance relatively, but resin combination can be used for making means of illumination or signboard is used diffuser plate.Promptly; Resin combination of the present invention except the advantage of pure PS resin (such as; Transmittance and diffusivity, illumination and shielding preferably) outside; Also can improve shock strength,, thereby improve the advantage of pure PS resin so that resin combination of the present invention is used diffuser plate as indoor and outdoor illumination or signboard.
Simultaneously, resin combination of the present invention can further comprise diffusant and spread to increase light, and can contain the diffusant of 1 weight percent to 3 weight percent (preferably, 1.3 weight percents).The reason of this measure is that light diffusion, illumination and shielding can change according to the ratio of mixture of diffusant.Diffusant can comprise at least one that is selected from by the following group that forms: vinylformic acid pearl, silica bead with the mixture of vinylformic acid pearl and silica bead.
In addition, resin combination of the present invention can further comprise UV absorption agent or UV stablizer to improve weather resistance.The UV absorption agent or the UV stablizer that can contain 0.01 weight percent to 0.1 weight percent (preferably, 0.03 weight percent to 0.04 weight percent).
Resin combination of the present invention can further comprise white dyes, to improve illuminance and lightness.The white dyes that can contain 0.01 weight percent to 0.1 weight percent (preferably, 0.03 weight percent to 0.05 weight percent).
As stated, according to the present invention, said resin combination can increase diffusion, improvement shock resistance, raising transsmissivity and shielding and the reduction manufacturing cost of light from light source.
It will be apparent for a person skilled in the art that under the situation that does not break away from the spirit or scope of the present invention and can carry out various modifications above-mentioned exemplary embodiment of the present invention.Therefore, expection the present invention comprises the equivalent of all these type of modifications and said modification, as long as said being modified in the appended claims scope.

Claims (6)

1. one kind is used to make illumination and the resin combination of signboard with diffuser plate, prepares said resin combination through mixing PS (PS) and high-impact polystyrene (HIPS).
2. resin combination as claimed in claim 1 wherein mixes said PS and said HIPS with 80: 20 weight ratio.
3. resin combination as claimed in claim 1 wherein mixes said PS and said HIPS with 70: 30 weight ratio.
4. like each the described resin combination in the claim 1 to 3, said resin combination further comprises at least one diffusant that is selected from by the following group that forms: the mixture of vinylformic acid pearl, silica bead and vinylformic acid pearl and silica bead.
5. like each the described resin combination in the claim 1 to 3, said resin combination further comprises ultraviolet ray (UV) absorption agent or UV stablizer.
6. like each the described resin combination in the claim 1 to 3, said resin combination further comprises white dyes.
CN2011102041229A 2010-07-19 2011-07-19 Resin composition for manufacturing diffusion plate for lighting and signboard Pending CN102336976A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2010-0069527 2010-07-19
KR1020100069527A KR20120008649A (en) 2010-07-19 2010-07-19 Diffuser plate make resin composition

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105037986A (en) * 2015-06-16 2015-11-11 广东瑞捷光电股份有限公司 Master batches, resin composition, diffusion plate and preparation method of diffusion plate
CN106633450A (en) * 2015-08-15 2017-05-10 王福民 Ps diffusion plate and preparation method thereof
CN106751098A (en) * 2017-03-22 2017-05-31 东莞市精致光电科技有限公司 A kind of production technology of diffuser plate

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101231719B1 (en) * 2012-09-12 2013-02-08 세원정공 주식회사 Resin composition for a white sheet, a white sheet containing the same and manufacturing method thereof
KR101231718B1 (en) * 2012-09-12 2013-02-08 세원정공 주식회사 Resin composition for a light diffusion plate, a light diffusion plate containing the same and manufacturing method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06345925A (en) * 1993-06-10 1994-12-20 Daicel Chem Ind Ltd Flame-retardant styrenic resin composition and molded sheet made therefrom

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06345925A (en) * 1993-06-10 1994-12-20 Daicel Chem Ind Ltd Flame-retardant styrenic resin composition and molded sheet made therefrom

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105037986A (en) * 2015-06-16 2015-11-11 广东瑞捷光电股份有限公司 Master batches, resin composition, diffusion plate and preparation method of diffusion plate
WO2016202305A1 (en) * 2015-06-16 2016-12-22 广东瑞捷光电股份有限公司 Masterbatch, resin composition, diffusion plate and method for preparing the diffusion plate
CN106633450A (en) * 2015-08-15 2017-05-10 王福民 Ps diffusion plate and preparation method thereof
CN106751098A (en) * 2017-03-22 2017-05-31 东莞市精致光电科技有限公司 A kind of production technology of diffuser plate

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Application publication date: 20120201