CN102336963B - PP (polypropylene) meltblown special composite material and preparation process thereof - Google Patents

PP (polypropylene) meltblown special composite material and preparation process thereof Download PDF

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Publication number
CN102336963B
CN102336963B CN 201110207084 CN201110207084A CN102336963B CN 102336963 B CN102336963 B CN 102336963B CN 201110207084 CN201110207084 CN 201110207084 CN 201110207084 A CN201110207084 A CN 201110207084A CN 102336963 B CN102336963 B CN 102336963B
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China
Prior art keywords
composite material
woven fabrics
melt spraying
spraying non
material special
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Expired - Fee Related
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CN 201110207084
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Chinese (zh)
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CN102336963A (en
Inventor
冯建强
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FOSHAN HENGLONG TECHNOLOGY Co Ltd
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FOSHAN HENGLONG TECHNOLOGY Co Ltd
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Priority to CN 201110207084 priority Critical patent/CN102336963B/en
Publication of CN102336963A publication Critical patent/CN102336963A/en
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Publication of CN102336963B publication Critical patent/CN102336963B/en
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  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Artificial Filaments (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The invention discloses a PP (polypropylene) meltblown special composite material and a preparation process thereof. The PP meltblown special composite material is characterized by being mainly prepared from nanometer calcium carbonate, surface treating agent, POE (polyolefin elastomer), polypropylene and polyisobutylene with the weight ratio of (95-110) : (1-2) : (4-6) : (58-62) : (1-3). The PP meltblown special composite material disclosed by the invention has good filtration performance, good spinnability, no slurry drip, good coloring performance, uniform lapping, normal gram weight, good tensile strength and flexible performance, good surface gloss and good application value.

Description

A kind of PP melt spraying non-woven fabrics composite material special and preparation technology thereof
Technical field
The present invention relates to PP melt spraying non-woven fabrics technical field, relate in particular a kind of PP melt spraying non-woven fabrics matrix material and preparation technology.
Background technology
The quality and performance of melt spraying non-woven fabrics depends on the selecting properly of pp material (melting index) and the optimization of processing conditions.At present, what melt and spray that producer mainly adopts is the pp material that height melts finger, but lacks necessary handiness to adapt to the different market requirements, also exists simultaneously expensive pressure.In the nineteen forty-six invention, the product main application fields has the melt-blown process of very early time by Van Mr. Vente: filter, the fibre web uniformity coefficient is had relatively high expectations; Isolation, higher to the continuous coherence request of fibre web, wire side can not have broken hole or not have the good agglomerate of drawing-off to occur; Warming, high to the fluffiness requirement of fibre web.Wire side has broken hole or occurs not having the agglomerate of drawing-off will reduce the total quality of fibre web, melt and spray the fritter film that " shot " usually said in the product just refers to not pass through drawing-off, regional fast more than other in the regional water seepage velocity that " shot " occur, this fault can check by measurement hydrostaticpressure height.Therefore, one that how further improves the hydrostaticpressure height that spins molten product and be product design and development pursues a goal, on the one hand can be by the improvement to production process control, such as the optimization to device parameter and production stage, avoid that agglomerate appears in fiber in the fibre web; Start with from the feed change quality on the other hand, for this reason, be necessary the matrix material that non-woven fabrics uses is carried out more research work, prepare the PP melt spraying non-woven fabrics composite material special of advantages such as a kind ofly having that lapping is even, grammes per square metre normal, tensile strength, softness are good.
Summary of the invention
Purpose of the present invention is exactly that a kind of not only strainability that provides for the deficiency that solves prior art is good, good spinnability, do not drip slurry, tinctorial property is good, lapping is even, grammes per square metre is normal, tensile strength, softness is good, surface gloss is good, and has the PP melt spraying non-woven fabrics composite material special of environment-friendly function.
Another object of the present invention provides a kind of preparation technology of PP melt spraying non-woven fabrics composite material special.
The present invention adopts following technical solution to realize above-mentioned purpose: a kind of PP melt spraying non-woven fabrics composite material special, it is characterized in that, it is mainly made by nano-calcium carbonate, surface treatment agent, POE, polypropylene and polyisobutene, and the weight ratio of nano-calcium carbonate, surface treatment agent, POE, polypropylene and polyisobutene is (95-110): (1-2): (4-6): (58-62): (1-3).
As further specifying of such scheme: the preferred 100:1.5:5:60:2 of the weight ratio of described nano-calcium carbonate, surface treatment agent, POE, polypropylene and polyisobutene.
The particle diameter of described nano-calcium carbonate is the 4500-5500 order, and surface treatment agent is end amino polybasic alcohol ester.
A kind of preparation technology of PP melt spraying non-woven fabrics composite material special is characterized in that it comprises the steps:
A, nano-calcium carbonate is added in horizontal double helical ribbon mixer first, the heating middling speed was mixed 25-35 minute;
B, add surface treatment agent, high-speed mixing 10-20 minute;
C, add POE and polypropylene, high-speed mixing 5-15 minute;
D, by screw feeding machine, the mass transport that mixes is to continuous internal mixer material storage tank;
E, by the powder metering feeding machine, feeding is to continuous internal mixer;
F, polyisobutene is added to the liquid meter feeding machine, feeding is to continuous internal mixer;
G, extruding pelletization;
E, finished product packing.
In described processing step a process, described mixed powder water content<2%.
In described processing step a process, heating mixed 30 minutes.
In the high-speed mixing process of described processing step b, treatment agent is wanted complete coated powder.
In described processing step b process, high-speed mixing 15 minutes.
In described processing step c process, high-speed mixing 10 minutes.
The beneficial effect that the present invention adopts above-mentioned technical solution to reach is:
1, this matrix material of the present invention by original PP Production Technology, is fully normally produced on the melt spraying non-woven fabrics machine.
2, good, the good spinnability of strainability, do not drip slurry, tinctorial property is good, lapping is even, grammes per square metre is normal, tensile strength, softness is good, surface gloss is good.
3, reach environment-friendly function.
Embodiment
A kind of PP melt spraying non-woven fabrics of the present invention composite material special, it is mainly made by nano-calcium carbonate, surface treatment agent, POE, polypropylene and polyisobutene, and the weight ratio of nano-calcium carbonate, surface treatment agent, POE, polypropylene and polyisobutene is (95-110): (1-2): (4-6): (58-62): (1-3).In the present embodiment, the preferred 100:1.5:5:60:2 of the weight ratio of nano-calcium carbonate, surface treatment agent, POE, polypropylene and polyisobutene.The particle diameter of nano-calcium carbonate is 5000 orders, and surface treatment agent is end amino polybasic alcohol ester.
The preparation technology of PP spun-bonded non-woven fabrics composite material special, its processing step is following rapid:
1, first nano-calcium carbonate is added in horizontal double helical ribbon mixer, the heating middling speed was mixed 30 minutes, reached the combination drying effect, water content<2%;
2, add surface treatment agent, high-speed mixing 15 minutes, the complete coated powder for the treatment of agent;
3, add POE and polypropylene, high-speed mixing 10 minutes, each component distributes and mixes;
4, by screw feeding machine, the mass transport that mixes is to continuous internal mixer material storage tank;
5, by the powder metering feeding machine, feeding is to continuous internal mixer;
6, polyisobutene is added to the liquid meter feeding machine, feeding is to continuous internal mixer;
7, extruding pelletization;
8, finished product packing.
Above-described only is preferred implementation of the present invention, should be pointed out that for the person of ordinary skill of the art, under the prerequisite that does not break away from the invention design, can also make some distortion and improvement, and these all belong to protection scope of the present invention.

Claims (1)

1. PP melt spraying non-woven fabrics composite material special, it is characterized in that, it is mainly made by nano-calcium carbonate, surface treatment agent, POE, polypropylene and polyisobutene, and the weight ratio of nano-calcium carbonate, surface treatment agent, POE, polypropylene and polyisobutene is (95-110) in the component: (1-2): (4-6): (58-62): (1-3).
2 .A kind of PP melt spraying non-woven fabrics composite material special according to claim 1 is characterized in that the preferred 100:1.5:5:60:2 of the weight ratio of described nano-calcium carbonate, surface treatment agent, POE, polypropylene and polyisobutene.
3 .A kind of PP melt spraying non-woven fabrics composite material special according to claim 1 and 2 is characterized in that, described surface treatment agent is end amino polybasic alcohol ester.
4 .A kind of preparation technology such as the described PP melt spraying non-woven fabrics of claim 1-3 any one composite material special is characterized in that it comprises the steps:
A, nano-calcium carbonate is added in horizontal double helical ribbon mixer first, heating, middling speed were mixed 25-35 minute;
B, add surface treatment agent, high-speed mixing 10-20 minute;
C, add POE and polypropylene, high-speed mixing 5-15 minute;
D, by screw feeding machine, the mass transport that mixes is to the continuous internal mixer storage tank;
E, by the powder metering feeding machine, feeding is to continuous internal mixer;
F, polyisobutene is added to the liquid meter feeding machine, feeding is to continuous internal mixer;
G, extruding pelletization;
E, finished product packing.
5 .The preparation technology of a kind of PP melt spraying non-woven fabrics composite material special according to claim 4 is characterized in that, in described processing step a process, and described mixed powder water content<2%.
6 .The preparation technology of a kind of PP melt spraying non-woven fabrics composite material special according to claim 4 is characterized in that, in described processing step a process, heating mixed 30 minutes.
7 .The preparation technology of a kind of PP melt spraying non-woven fabrics composite material special according to claim 4 is characterized in that, in the high-speed mixing process of described processing step b, treatment agent is wanted complete coated powder.
8 .The preparation technology of a kind of PP melt spraying non-woven fabrics composite material special according to claim 4 is characterized in that, in described processing step b process, and high-speed mixing 15 minutes.
9 .The preparation technology of a kind of PP melt spraying non-woven fabrics composite material special according to claim 4 is characterized in that, in described processing step c process, and high-speed mixing 10 minutes.
CN 201110207084 2011-07-23 2011-07-23 PP (polypropylene) meltblown special composite material and preparation process thereof Expired - Fee Related CN102336963B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201110207084 CN102336963B (en) 2011-07-23 2011-07-23 PP (polypropylene) meltblown special composite material and preparation process thereof

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Application Number Priority Date Filing Date Title
CN 201110207084 CN102336963B (en) 2011-07-23 2011-07-23 PP (polypropylene) meltblown special composite material and preparation process thereof

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CN102336963B true CN102336963B (en) 2013-02-27

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CN103147227A (en) * 2013-03-04 2013-06-12 武汉华丽生物材料有限公司 Bio-based non-woven fabrics and preparation method thereof

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CN101798419B (en) * 2009-11-30 2012-08-22 芜湖同达新材料科技有限公司 Spun-bounded polypropylene non-woven compound modified resin product and preparation method thereof

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