CN102329600B - 一种油井纳米颗粒封窜堵水剂 - Google Patents

一种油井纳米颗粒封窜堵水剂 Download PDF

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CN102329600B
CN102329600B CN201110310707.9A CN201110310707A CN102329600B CN 102329600 B CN102329600 B CN 102329600B CN 201110310707 A CN201110310707 A CN 201110310707A CN 102329600 B CN102329600 B CN 102329600B
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白杨
谭晓华
刘建仪
张广东
王平全
胡亚琴
李丽
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XINJIANG GRAND OILFIELD TECHNOLOGY Co Ltd
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Abstract

本发明涉及一种用于封堵微裂缝及低渗地层的油井纳米颗粒封窜堵水剂。它可克服封堵微裂缝及低渗地层出水的油井水泥封堵半径小,有机类强度低、封堵有效期短的缺陷,其技术方案是:制备该堵水剂所用原料的各组分及含量为,质量单位为克:氧化钙23-25;氧化硅18-21;氧化铝7-8.5;氧化铁4-5.4;三乙醇胺0.15-0.18;KCL0.06-0.08;Na2SiO30.04-0.05;膨润土0.42-0.5;丙酮和甲醛缩聚物0.1-0.12;铁铬木质素磺酸盐0.1-0.15;淡水39.02-47.13。本发明堵水剂在井下温度和压力条件下,通过有机和无机组分的协调效应和化学反应,能在封堵层位形成抗压强度高、韧性好、微膨胀和有效期长的固化体,能严实封堵各种类型的地层,用于油井原油开发。

Description

一种油井纳米颗粒封窜堵水剂
技术领域
本发明涉及一种用于封堵微裂缝及低渗地层的油井纳米颗粒封窜堵水剂,特别适合于管外窜、套管变形及损坏、层间窜等情况下微裂缝的封堵。
背景技术
随着油井原油开发的逐步深入,油田进入高含水开发期,油井存在不同类型的水窜、水害。特别的是对于低渗地层的油井管外窜、套管变形及损坏、层间窜、难卡封已射开高含水井的封堵,最常用的方法是向采油井或注水井特定层段挤注高强度堵水剂进行永久性封堵或重新射孔,来稳油控水,提高采收率。目前采用的油井堵水剂主要有油井水泥类堵水剂和有机类堵水剂。但是由于油井水泥的颗粒大不能够进入微缝通道,且封堵半径小,成功率只有30%左右;采用有机类堵水剂封堵,由于受其自身性质的影响往往耐久性低、强度低、老化现象严重、成本高,使用受到限制。
发明内容
本发明的目的是:为了克服封堵微裂缝及低渗地层出水的油井水泥封堵半径小,有机类强度低、封堵有效期短的缺陷,特提供一种油井纳米颗粒封窜堵水剂。
为了达到上述目的,本发明采用以下技术方案:一种油井纳米颗粒封窜堵水剂,其特征是制备该堵水剂所用原料的各组分及其含量如下,其质量单位为克或千克:氧化钙23-25;氧化硅18-21;氧化铝7-8.5;氧化铁4-5.4;三乙醇胺0.15-0.18;KCL 0.06-0.08;Na2SiO3 0.04-0.05;膨润土0.42-0.5;丙酮和甲醛缩聚物0.1-0.12;铁铬木质素磺酸盐0.1-0.15;淡水39.02-47.13。
本发明油井纳米颗粒封窜堵水剂的制备方法是:
先采用德国Restsch公司出产的行星式球磨仪PM400分别将氧化钙,氧化硅,氧化铝,氧化铁, Na2SiO3,膨润土,丙酮和甲醛缩聚物进行研磨,使其颗粒粒径达到1-100nm;再将三乙醇胺0.15-0.18克,KCL 0.06-0.08克,铁铬木质素磺酸盐0.1-0.15克,倒入盛有39.02-47.13克淡水的高速搅拌杯中充分溶解,再加入研磨后的氧化钙23-25克,氧化硅18-21克,氧化铝7-8.5克,氧化铁4-5.4克,Na2SiO3 0.04-0.05克,膨润土0.42-0.5克,丙酮和甲醛缩聚物0.1-0.12克,在高速搅拌杯中以8000-10000转/分钟的速度搅拌3分钟,即得到用于封堵微裂缝及低渗地层的油井纳米颗粒封窜堵水剂。
本发明提供的封堵微裂缝及低渗地层的油井纳米颗粒封窜堵水剂与现有技术相比具有以下有益效果:(1)该堵水剂能够在微裂缝、小孔道快速形成网架结构,有效地滞留在封堵层内;(2)该堵水剂在井下温度和压力的养护条件下,通过有机和无机组分的协同效应和化学反应,能够在封堵层位形成抗压强度高、韧性好、微膨胀和有效期长的固化体;(3)配制的堵浆流动性和稳定性好,挤注压力低,固化时间易于调整;(4)该堵水剂的封堵半径大,封堵有效期长,封堵强度高,能够严实的封堵各种类型的水层,用于油井原油开发。
具体实施方式
下面结合具体实例对本发明作进一步的说明。
实施例1:采用纳米粒度仪对本发明溶液进行了粒度测定
表1油井纳米颗粒封窜堵水剂的粒径特征
Figure 2011103107079100002DEST_PATH_IMAGE001
实施例2:首先采用德国Restsch公司出产的行星式球磨仪PM400分别对氧化钙,氧化硅,氧化铝,氧化铁, Na2SiO3,膨润土,丙酮和甲醛缩聚物进行研磨,使其颗粒粒径达到纳米1-100nm。再将三乙醇胺0.15克,KCL 0.06克,铁铬木质素磺酸盐0.1克,倒入盛有39.02克淡水的高速搅拌杯中充分溶解,再加入研磨后的氧化钙23克,氧化硅18克,氧化铝7克,氧化铁4克,Na2SiO0.04克,膨润土0.42克,丙酮和甲醛缩聚物0.1克,在高速搅拌杯以10000转/分钟搅拌3分钟,将搅拌后的堵剂倒入特制的测压模具制成测压模块,在50℃下分别水浴3天、7天、28天,用抗压、抗折强度仪测定各模块强度
表2 油井纳米颗粒封窜堵水剂抗折抗压强度
Figure 84447DEST_PATH_IMAGE002
实施例3:首先采用德国Restsch公司出产的行星式球磨仪PM400分别对氧化钙,氧化硅,氧化铝,氧化铁, Na2SiO3,膨润土,丙酮和甲醛缩聚物进行研磨,使其颗粒达到1-100nm。再将三乙醇胺0.18克,KCL 0.08克,铁铬木质素磺酸盐0.15克,倒入盛有47.13克淡水的高速搅拌杯中充分溶解,再加入研磨后的氧化钙25克,氧化硅21克,氧化铝8.5克,氧化铁5.4克,Na2SiO3 0.05克,膨润土0.5克,丙酮和甲醛缩聚物0.12克,在高速搅拌杯以10000转/分钟搅拌3分钟,将搅拌好的试验浆体,与浸泡过的岩心颗粒混合均匀后倒入钢筒中(由于岩心-钢筒界面粘接差,预先将堵剂与岩心颗粒混合),钢筒下端垫一层10目筛网(模拟大漏失),开平流泵,模拟现场挤堵工况,驱替清水20ml(1PV),出口端有清澈滤液流出,取出钢筒密封后放入水浴锅中养护48-72h,温度为50℃。再置于ZLX评价仪的岩心夹持器内,加环压3MPa,开平流泵,随时保持环压大于平流泵的压力3MPa,直到岩心夹持器下端滴出第一滴水时所施加的水压,定义为封堵强度
表3封堵强度试验结果
Figure DEST_PATH_IMAGE003
样品 驱替压力(MPa) 滤液量(ml) 封堵强度(MPa) 抗冲击力(MPa)
油井纳米颗粒封窜堵水剂 1.0 10.5 32 23
由表1可以看出油井纳米颗粒封窜堵水剂已经达到了纳米剂。由表2、3可以看出油井纳米颗粒封窜堵水剂在50℃下具有很高的抗压强度、及封堵强度。

Claims (1)

1.一种油井纳米颗粒封窜堵水剂,其特征是:制备该堵水剂所用原料的各组分及其含量如下,其质量单位为克:氧化钙23-25;氧化硅18-21;氧化铝7-8.5;氧化铁4-5.4;三乙醇胺0.15-0.18;KCL 0.06-0.08;Na2SiO3 0.04-0.05;膨润土0.42-0.5;丙酮和甲醛缩聚物0.1-0.12;铁铬木质素磺酸盐0.1-0.15;淡水39.02-47.13;该堵水剂的制备方法,先采用球磨仪分别将氧化钙,氧化硅,氧化铝,氧化铁,Na2SiO3,膨润土,丙酮和甲醛缩聚物进行研磨,使其颗粒粒径达到1-100nm;再将三乙醇胺0.15-0.18克,KCL 0.06-0.08克,铁铬木质素磺酸盐0.1-0.15克,倒入盛有39.02-47.13克淡水的高速搅拌杯中充分溶解,再加入研磨后的氧化钙23-25克,氧化硅18-21克,氧化铝7-8.5克,氧化铁4-5.4克,Na2SiO3 0.04-0.05克,膨润土0.42-0.5克,丙酮和甲醛缩聚物0.1-0.12克,在高速搅拌杯中以8000-10000转/分钟的速度搅拌3分钟,制得本油井纳米颗粒封窜堵水剂。
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