CN102315480A - Button lithium cell and preparation method thereof - Google Patents

Button lithium cell and preparation method thereof Download PDF

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Publication number
CN102315480A
CN102315480A CN2010102163876A CN201010216387A CN102315480A CN 102315480 A CN102315480 A CN 102315480A CN 2010102163876 A CN2010102163876 A CN 2010102163876A CN 201010216387 A CN201010216387 A CN 201010216387A CN 102315480 A CN102315480 A CN 102315480A
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CN
China
Prior art keywords
looped network
ring
anode ring
integrated
lithium battery
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Pending
Application number
CN2010102163876A
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Chinese (zh)
Inventor
王建
黄建昌
陈汉珠
王保军
黎传宝
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Lijia Power Source Technology (shenzhen) Co ltd
BOTEKE TECHNOLOGY (SHENZHEN) CO LTD
Original Assignee
Lijia Power Source Technology (shenzhen) Co ltd
BOTEKE TECHNOLOGY (SHENZHEN) CO LTD
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Application filed by Lijia Power Source Technology (shenzhen) Co ltd, BOTEKE TECHNOLOGY (SHENZHEN) CO LTD filed Critical Lijia Power Source Technology (shenzhen) Co ltd
Priority to CN2010102163876A priority Critical patent/CN102315480A/en
Priority to PCT/CN2011/000670 priority patent/WO2012000303A1/en
Publication of CN102315480A publication Critical patent/CN102315480A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • H01M10/0422Cells or battery with cylindrical casing
    • H01M10/0427Button cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/66Selection of materials
    • H01M4/661Metal or alloys, e.g. alloy coatings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/70Carriers or collectors characterised by shape or form
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/70Carriers or collectors characterised by shape or form
    • H01M4/72Grids
    • H01M4/74Meshes or woven material; Expanded metal
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/04Cells with aqueous electrolyte
    • H01M6/06Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
    • H01M6/12Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid with flat electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/102Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure
    • H01M50/109Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure of button or coin shape
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention discloses a button lithium cell, which comprises a cathode, an anode, a diaphragm, electrolyte, an anode shell and a cathode shell, wherein the diaphragm is arranged between the cathode and the anode; and the diaphragm is arranged on one side of the anode, the opposite side of the anode is covered by a current collector, a metal ring is arranged on the external side of the anode, the metal ring and the current collector are integrally arranged to form a ring network integrated anode ring, and the ring network integrated anode ring is covered by an anode powder cake to form a ring network integrated anode. The button lithium cell has a high discharge platform and a very good power discharge characteristic, the utilization ratio of anode and cathode active substances is greatly promoted and the battery capacity is increased.

Description

A kind of button lithium battery and preparation method thereof
Technical field
The present invention relates to field of batteries, particularly relate to button lithium battery and preparation method thereof.
Background technology
Button lithium battery is a kind of novel chemical power source, and as the main fresh combatants of chemical power source, its market prospects are very extensive, can do electrical source of power and memory power supply.As electrical source of power, the applied more and more of lithium battery aspect medical product, telecontrol engineering; As the memory power supply, fields such as computer main board have been widely used in.Especially, lithium battery has been used more widely on RFID, and along with the development of RFID technology, its range of application will be very wide.But at the button lithium battery that use in these fields, its requirement on electric performance is higher, and it needs lithium battery that " power property flash-over characteristic, stable discharge platform and higher capacity " arranged better.
As shown in Figure 1, general button cell comprises anode coat, negative current collector, negative pole, barrier film, electrolyte, O-ring seal, positive pole, plus plate current-collecting body, anodal shell; A collector is wherein all arranged between both positive and negative polarity and the shell.
Original button lithium battery technology, the pattern of its positive electrode structure.
Fig. 2: the positive pole that collector is only arranged: anodal embedding stainless (steel) wire or anodal shell are coated with conducting resinl only as the collector effect.
Fig. 2 a: universal positive pole, stainless (steel) wire is as collector on it, and the metalolic network in length and breadth that is pressed in the positive powder has increased catchment area and electric conductivity.
Fig. 2 b: on Fig. 2 a basis, the stainless steel currect collecting net is pressed into ripple glaze to increase catchment area.
Fig. 2 c: do not have collector on the anode, on anodal outer casing inner wall, coat conducting resinl, reach the afflux effect.Word shell plane was prone to form arc when cause was sealed, and caused shell and anodal loose contact.
Fig. 2 d: anodal identical with Fig. 2 c, and on the anode cover inwall, put the sheet metal of burn-oning, and coat conducting resinl, with the deformation defect of compensation image 2c.
Fig. 3: ring is solid anodal: the anode ring of ring-type plays and prevents anodal radial expansion effect, and stainless (steel) wire plays the collector effect.It is a kind of positive pole of simple combination.
Battery is in electrochemical reaction process, and when lithium ion embedded positive polar crystal, anodal can the generation expanded; Its axial expansion can keep both positive and negative polarity closely to contact; Be necessary in the battery discharge procedure, but the anodal radial expansion that produces make positive pole be stuck in radial direction; Cause positive pole can not well contact with negative pole, battery capacity can not discharge fully.Thus, some battery manufacturer has added various " anode rings " on anodal muffin, guarantees that battery does not produce radial expansion at the discharge process positive pole.This positive pole is referred to as " ring is solid anodal ".Its structural shape has four kinds shown in Figure 3:
Fig. 3 a: the ring ring is anodal
Fig. 3 b: the through hole ring is anodal
Fig. 3 c: bearing ring is anodal
Fig. 3 d: sealing ring is anodal
The positive pole of above-mentioned eight kinds of structures because its design feature, show its effect and be separate or catchment effect or the solid effect of ring, its electrical property of the battery of being produced can't satisfy the requirement of " power property flash-over characteristic, stable discharge platform and higher capacity " fully; And manufacturing process is complicated, cost is high, efficient is low, is difficult to satisfy the frontier application demand.
Summary of the invention
The object of the invention aims to provide a kind of button lithium battery and preparation method thereof, and this button lithium battery has higher discharge platform and fabulous power property flash-over characteristic, and the utilance of both positive and negative polarity active material greatly promotes, and battery capacity increases.
For realizing above-mentioned purpose, the technical scheme that the present invention adopts is: a kind of button lithium battery comprises negative pole, positive pole, barrier film, electrolyte, both positive and negative polarity shell; Its septation is arranged between negative pole and the positive pole, and a said anodal side is provided with barrier film, and opposite side is coated by collector; The said anodal outside is provided with becket; Said becket and collector form the integrated anode ring of looped network for being wholely set, and form the integrated positive pole of looped network behind the integrated anode ring clad anode of looped network.
Said a kind of button lithium battery, the integrated anode ring of its looped network bottom is provided with sags and crests.
Said a kind of button lithium battery, the integrated anode ring of its looped network bottom is provided with sags and crests, and it is shaped as circle, square, triangle, rhombus.
Said a kind of button lithium battery, the integrated anode ring of its looped network bottom is provided with through hole, and through hole forms cracking shape burr.
Said a kind of button lithium battery, the integrated anode ring of its looped network inboard scribbles conducting resinl.
Said a kind of button lithium battery, the integrated anode ring of its looped network extrudes ripple glaze or ring-type ring grain shape.
Said a kind of button lithium battery, the used metal of the integrated anode ring of its looped network is stainless steel, stainless iron, nickel, aluminum metal conductor.
Said a kind of button lithium battery, the used metal material thickness of the integrated anode ring of its looped network is 0.02~1.0mm.
A kind of preparation method of button lithium battery the steps include: to make an integrated anode ring of looped network, is made into concavo-convex in looped network integrated anode ring bottom and side; Conducting resinl is coated in the integrated anode ring of looped network inboard; The integrated anode ring clad anode of looped network is pressed into ripple glaze with the integrated anode ring of looped network; Lithium battery anode, negative pole, barrier film and shell are packaged together.
A kind of button lithium battery preparation method the steps include: to make an integrated anode ring of looped network, is made into through hole in looped network integrated anode ring bottom and side; Conducting resinl is coated in the integrated anode ring of looped network inboard; The integrated anode ring clad anode of looped network is pressed into the ring-type ring grain with the integrated anode ring of looped network; Lithium battery anode, negative pole, barrier film and shell are packaged together.
Positive pole in this button lithium battery is the anodal structural shape of a kind of creativeness; Can be referred to as " the integrated positive pole of looped network ", the ring of clad anode muffin is referred to as " the integrated anode ring of looped network ", for one designs; It had both played the effect of collector; Play preventing anodal radial expansion in the battery discharge procedure again, the guiding positive pole is only made axial expansion, thereby guarantees both positive and negative polarity closely effect of contact in discharge process.The obvious increase of catchment effect causes the raising of lithium battery power property discharge performance; Behind the solid positive pole of ring, limit anodal radial expansion in electrochemical reaction process, made both positive and negative polarity in the electrochemical reaction process of whole discharge, remained tight contact, guaranteed discharge uniformity and higher discharge platform; Simultaneously, the utilance of both positive and negative polarity active material greatly promotes, and battery capacity also increases thereupon.
" the integrated anode ring of looped network " of this button lithium battery is that plus plate current-collecting body plays solid ring effect again; Extrude the shape that ripple glaze or ring-type ring grain etc. increase catchment effect at " the integrated positive pole of looped network ".
This button lithium battery removes the electrical property that has improved button cell, more outside the meeting the market requirement; The manufacture process of battery is especially being realized the condition of providing convenience aspect the automation.Be lower than the thin battery of 1.6mm like cell thickness, the positive plate breakage rate that original technology is made is high low with efficient, and assembling realizes that automation is also difficult; And very easily realize automation and efficient height, damaged few with the positive plate that this patent is made, also very easily realize automation during assembling.On the other hand, the present invention can improve the comprehensive utilization of material, reduces the battery cost greatly.
Description of drawings
Fig. 1 has the button lithium battery structure chart now;
The universal anodal sketch map that collector is only arranged of Fig. 2 a prior art;
Fig. 2 b prior art only has collector stainless steel currect collecting net to be pressed into the anodal sketch map of ripple glaze;
No collector sketch map on Fig. 2 c prior art anode;
No collector sketch map on Fig. 2 d prior art anode;
The anodal sketch map of the solid anodal ring ring of Fig. 3 a prior art ring;
The anodal sketch map of the solid anodal through hole ring of Fig. 3 b prior art ring;
The anodal sketch map of the solid anodal bearing ring of Fig. 3 c prior art ring;
The anodal sketch map of the solid anodal sealing ring of Fig. 3 d prior art ring;
Fig. 4 embodiment of the invention structural representation;
Fig. 5 a embodiment of the invention sketch map;
Fig. 5 b embodiment of the invention sketch map;
Fig. 5 c embodiment of the invention sketch map;
Fig. 5 d embodiment of the invention sketch map;
Fig. 5 e embodiment of the invention sketch map;
Fig. 5 f embodiment of the invention sketch map.
Embodiment
As shown in Figure 4, a kind of button lithium battery comprises the integrated anode ring of anode coat 401, negative current collector 402, negative pole 403, anodal 406, barrier film 404 (containing electrolyte), O-ring seal 405, looped network 407, anodal shell 408; Be provided with negative current collector 402 between negative pole 403 and the anode coat 401; Be provided with the integrated anode ring 407 of looped network between positive pole 406 and the anodal shell 408, its septation 404 is arranged between negative pole 403 and anodal 406, and said anodal 406 1 sides are provided with barrier film 404; Opposite side is coated by collector; The said anodal outside is provided with becket, and said becket and collector form the integrated anode ring 407 of looped network for being wholely set.This button lithium battery is the anodal structural shape of a kind of creativeness; Be referred to as " the integrated positive pole of looped network ", the ring of clad anode muffin is referred to as " the integrated anode ring of looped network ", for one designs; It had both played the effect of collector; Play preventing anodal radial expansion in the battery discharge procedure again, the guiding positive pole is only made axial expansion, thereby guarantees both positive and negative polarity closely effect of contact in discharge process.Said a kind of button lithium battery, the integrated anodal 407 ring bottoms of its looped network are provided with sags and crests, and it is shaped as geometries such as circle, square, triangle, rhombus.The integrated anodal 407 ring bottoms of its looped network also can be provided with through hole, and through hole forms cracking shape burr.
A kind of button lithium battery; Comprise the integrated anode ring of anode coat 401, negative current collector 402, negative pole 403, anodal 406, barrier film 404 (containing electrolyte), O-ring seal 405, looped network 407, anodal shell 408, be provided with negative current collector 402 between negative pole 403 and the anode coat 401, anodal 406 and anodal shell 408 between be provided with the integrated anode ring 407 of looped network; Its septation 404 is arranged between negative pole 403 and anodal 406; Said anodal 406 1 sides are provided with barrier film 404, and opposite side is coated by collector, and the said anodal outside is provided with becket; Said becket and collector form the integrated anode ring 407 of looped network for being wholely set.This button lithium battery is the anodal structural shape of a kind of creativeness; Be referred to as " the integrated positive pole of looped network ", the ring of clad anode muffin is referred to as " the integrated anode ring of looped network ", for one designs; It had both played the effect of collector; Play preventing anodal radial expansion in the battery discharge procedure again, the guiding positive pole is only made axial expansion, thereby guarantees both positive and negative polarity closely effect of contact in discharge process.The integrated anode ring of its looped network 407 inboards scribble conducting resinl.The integrated anode ring 407 of its looped network extrudes the shape of ripple glaze or ring-type ring grain.The integrated anode ring 407 used metals of its looped network be stainless steel, stainless iron, nickel, aluminium etc. can not with the metallic conductor of positive electrode generation chemical reaction.The used metal material thickness of the integrated anode ring of its looped network is 0.02~1.0mm.
Of Fig. 5 a is the compound structural representation of a kind of looped network, and a kind of button lithium battery comprises anode ring 501, positive polar net 502 and positive pole 503, wherein anodal 503 is provided with anode ring 501; Anodal 503 1 sides are provided with positive polar net 502, and wherein anode ring 501 is with just polar net 502 is for being wholely set, and anode ring 501 becomes the integrated anode ring 407 of looped network with positive polar net 502 integrated setting.
Of Fig. 5 b is the compound structural representation that adds conducting resinl of a kind of looped network, and a kind of button lithium battery comprises anode ring 501, positive polar net 502 and positive pole 503, wherein anodal 503 is provided with anode ring 501; Anodal 503 1 sides are provided with positive polar net 502, and wherein anode ring 501 and positive polar net 502 are being coated with last layer conducting resinl 504 for being wholely set on positive polar net 502, and anode ring 501 becomes the integrated anode ring 407 of looped network with positive polar net 502 integrated setting.
Of Fig. 5 c is the compound structural representation that adds conducting resinl of a kind of looped network, and a kind of button lithium battery comprises anode ring 501, positive polar net 502 and positive pole 503, wherein anodal 503 is provided with anode ring 501; Anodal 503 1 sides are provided with positive polar net 502; Wherein anode ring 501 and positive polar net 502 are for being wholely set; On positive polar net 502, be coated with last layer conducting resinl 504; Anode ring 501 becomes the integrated anode ring 407 of looped network with positive polar net 502 integrated setting, simultaneously integrated anodal 407 rings of looped network is pressed into the ripple glaze shape.
Of Fig. 5 d is the compound structural representation of a kind of looped network, and a kind of button lithium battery comprises that anode ring 501 is pin hole anode ring 501, positive polar net 502 and positive pole 503, wherein anodal 503 is provided with pin hole anode ring 501; Anodal 503 1 sides are provided with positive polar net 502, and wherein pin hole anode ring 501 is with just polar net 502 is for being wholely set, and pin hole anode ring 501 becomes the integrated anode ring 407 of looped network with positive polar net 502 integrated setting.
Of Fig. 5 e is the compound structural representation of a kind of looped network, and a kind of button lithium battery comprises that anode ring 501 is pin hole anode ring 501, positive polar net 502 and positive pole 503, wherein anodal 503 is provided with pin hole anode ring 501; Anodal 503 1 sides are provided with positive polar net 502, on positive polar net 502, are coated with last layer conducting resinl 504, and wherein pin hole anode ring 501 is with just polar net 502 is for being wholely set, and pin hole anode ring 501 becomes the integrated anode ring 407 of looped network with positive polar net 502 integrated setting.
Of Fig. 5 f is the compound structural representation of a kind of looped network, and a kind of button lithium battery comprises that anode ring 501 is pin hole anode ring 501, positive polar net 502 and positive pole 503, wherein anodal 503 is provided with pin hole anode ring 501; Anodal 503 1 sides are provided with positive polar net 502; On positive polar net 502, be coated with last layer conducting resinl 504; Wherein pin hole anode ring 501 and positive polar net 502 are for being wholely set; Pin hole anode ring 501 becomes the integrated anode ring 407 of looped network with positive polar net 502 integrated setting, simultaneously integrated anodal 407 rings of looped network is pressed into the ripple glaze shape.
The positive pole that the present invention implemented is referred to as " the integrated positive pole of looped network ", comprises anodal muffin and " the integrated anode ring of looped network ".It had both played the effect of plus plate current-collecting body " the integrated anode ring of looped network ", played again to prevent anodal radial expansion in the battery discharge procedure, and the guiding positive pole is only made axial expansion, thereby guaranteed both positive and negative polarity closely contact in discharge process; And its catchment effect obviously is superior to original technological collector." the integrated anode ring of looped network " clad anode muffin, " the integrated positive pole of looped network " scribbles the conducting resinl side and closely contacts with anodal shell, and opposite side contacts with barrier film.
A kind of preparation method of button lithium battery the steps include: to make an integrated anode ring of looped network, is made into concavo-convex in looped network integrated anode ring bottom and side; Conducting resinl is coated in the integrated anode ring of looped network inboard; The integrated anode ring clad anode of looped network is pressed into ripple glaze with the integrated anode ring of looped network; Lithium battery anode, negative pole, barrier film, electrolyte and shell are packaged together.In the embodiment of the present invention, " the integrated anode ring of looped network " punching out forms, and punching out goes out through hole shape or concavo-convex on it, the inboard cracking shape burr that forms of ring; Be coated with conducting resinl in the bottom of ring then.Second step was that anodal muffin is pressed in the anode ring; At last, go up concave-convexes such as extruding ripple glaze or circular whorl at " the integrated positive pole of looped network ".
A kind of button lithium battery preparation method the steps include: to make an integrated anode ring of looped network, is made into through hole in looped network integrated anode ring bottom and side; Conducting resinl is coated in the integrated anode ring of looped network inboard; The integrated anode ring clad anode of looped network is pressed into the ring-type ring grain with the integrated anode ring of looped network; Lithium battery anode, negative pole, barrier film, electrolyte and shell are packaged together.In the embodiment of the present invention, " the integrated anode ring of looped network " punching out forms, and punching out goes out through hole shape or concavo-convex on it, the inboard cracking shape burr that forms of ring; Be coated with conducting resinl in the bottom of ring then.Second step was that anodal muffin is pressed in the anode ring; At last, go up concave-convexes such as extruding ripple glaze or circular whorl at " the integrated positive pole of looped network ".
More than the technical scheme that the embodiment of the invention provided has been carried out detailed introduction; Used concrete example among this paper the principle and the execution mode of the embodiment of the invention are set forth, the explanation of above embodiment only is applicable to the principle that helps to understand the embodiment of the invention; Simultaneously, for one of ordinary skill in the art, according to the embodiment of the invention, the part that on embodiment and range of application, all can change, in sum, this description should not be construed as limitation of the present invention.

Claims (10)

1. a button lithium battery comprises negative pole, positive pole, barrier film, electrolyte, both positive and negative polarity shell, and its septation is arranged between negative pole and the positive pole; It is characterized in that a said anodal side is provided with barrier film, opposite side is coated by collector; The said anodal outside is provided with becket; Said becket and collector form the integrated anode ring of looped network for being wholely set, and form the integrated positive pole of looped network behind the integrated anode ring clad anode of looped network.
2. according to the said a kind of button lithium battery of claim 1, it is characterized in that the integrated anode ring of said looped network bottom is provided with sags and crests.
3. according to the said a kind of button lithium battery of claim 2, it is characterized in that the integrated anode ring of said looped network bottom is provided with sags and crests, it is shaped as circle, square, triangle, rhombus.
4. according to the said a kind of button lithium battery of claim 1, it is characterized in that said looped network integrated anode ring bottom and side are provided with through hole, through hole forms cracking shape burr.
5. according to the said a kind of button lithium battery of claim 1, it is characterized in that the integrated anode ring of said looped network inboard scribbles conducting resinl.
6. according to the said a kind of button lithium battery of claim 1, it is characterized in that the integrated anode ring of said looped network extrudes ripple glaze or ring-type ring grain.
7. according to the said a kind of button lithium battery of claim 1, it is characterized in that the used metal of the integrated anode ring of said looped network is stainless steel, stainless iron, nickel, aluminium.
8. according to the said a kind of button lithium battery of claim 7, it is characterized in that the used metal material thickness of the integrated anode ring of said looped network is 0.02~1.0mm.
9. the preparation method of a button lithium battery is characterized in that, the steps include: to make an integrated anode ring of looped network, is made into concavo-convex in looped network integrated anode ring bottom and side; Conducting resinl is coated in the integrated anode ring of looped network inboard; The integrated anode ring clad anode of looped network is pressed into ripple glaze with the integrated anode ring of looped network; Lithium battery anode, negative pole, barrier film and shell are packaged together.
10. according to the said a kind of button lithium battery preparation method of claim 9, it is characterized in that, the steps include: to make an integrated anode ring of looped network, be made into through hole in looped network integrated anode ring bottom and side; Conducting resinl is coated in the integrated anode ring of looped network inboard; The integrated anode ring clad anode of looped network is pressed into the ring-type ring grain with the integrated anode ring of looped network; Lithium battery anode, negative pole, barrier film and shell are packaged together.
CN2010102163876A 2010-07-02 2010-07-02 Button lithium cell and preparation method thereof Pending CN102315480A (en)

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PCT/CN2011/000670 WO2012000303A1 (en) 2010-07-02 2011-04-18 Button lithium battery and preparing method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
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CN102780008A (en) * 2012-08-15 2012-11-14 东莞市天球实业有限公司 Current collector, battery comprising same and lithium-manganese battery
EP3809484A4 (en) * 2018-06-15 2021-07-28 Yichang Power Glory Technology Co., Ltd. Button battery and preparation method therefor

Families Citing this family (2)

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CN104124428A (en) * 2014-08-12 2014-10-29 宁波星锐能源科技有限公司 Positive pole piece of winding lithium-manganese battery
FR3048363A1 (en) 2016-03-04 2017-09-08 Oreal COSMETIC ELECTRICAL ARTICLE WITH REPOSITIONABLE BATTERY

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1064176A (en) * 1991-02-06 1992-09-02 瓦尔达电池股份公司 Primary cell
CN101290990A (en) * 2008-05-29 2008-10-22 潮州正龙电池工业有限公司 Non-mercury alkaline button shape cell with conductive film on positive pole and preparing method of conductive film on positive pole
CN101299462A (en) * 2008-06-18 2008-11-05 李青海 Expansion-proof button type lithium iron disulfide battery and manufacturing method thereof
CN201717321U (en) * 2009-12-15 2011-01-19 武汉力兴(火炬)电源有限公司 High-capacity button lithium battery
CN201773903U (en) * 2010-07-02 2011-03-23 博特科科技(深圳)有限公司 Button lithium battery

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1064176A (en) * 1991-02-06 1992-09-02 瓦尔达电池股份公司 Primary cell
CN101290990A (en) * 2008-05-29 2008-10-22 潮州正龙电池工业有限公司 Non-mercury alkaline button shape cell with conductive film on positive pole and preparing method of conductive film on positive pole
CN101299462A (en) * 2008-06-18 2008-11-05 李青海 Expansion-proof button type lithium iron disulfide battery and manufacturing method thereof
CN201717321U (en) * 2009-12-15 2011-01-19 武汉力兴(火炬)电源有限公司 High-capacity button lithium battery
CN201773903U (en) * 2010-07-02 2011-03-23 博特科科技(深圳)有限公司 Button lithium battery

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102780008A (en) * 2012-08-15 2012-11-14 东莞市天球实业有限公司 Current collector, battery comprising same and lithium-manganese battery
CN102780008B (en) * 2012-08-15 2016-02-24 东莞市天球实业有限公司 Collector and comprise battery and the lithium-manganese cell of this collector
EP3809484A4 (en) * 2018-06-15 2021-07-28 Yichang Power Glory Technology Co., Ltd. Button battery and preparation method therefor

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