CN102311554B - Technology for producing degradable and edible film by utilizing corn composite modified starch - Google Patents
Technology for producing degradable and edible film by utilizing corn composite modified starch Download PDFInfo
- Publication number
- CN102311554B CN102311554B CN201110156804.7A CN201110156804A CN102311554B CN 102311554 B CN102311554 B CN 102311554B CN 201110156804 A CN201110156804 A CN 201110156804A CN 102311554 B CN102311554 B CN 102311554B
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- Prior art keywords
- film
- modified starch
- composite modified
- corn
- package material
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- 239000002131 composite material Substances 0.000 title claims abstract description 19
- 229920000881 Modified starch Polymers 0.000 title claims abstract description 17
- 239000004368 Modified starch Substances 0.000 title claims abstract description 17
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 title claims abstract description 17
- 235000002017 Zea mays subsp mays Nutrition 0.000 title claims abstract description 17
- 235000005822 corn Nutrition 0.000 title claims abstract description 17
- 235000019426 modified starch Nutrition 0.000 title claims abstract description 17
- 240000008042 Zea mays Species 0.000 title claims description 15
- 238000005516 engineering process Methods 0.000 title abstract description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 235000013305 food Nutrition 0.000 claims abstract description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052802 copper Inorganic materials 0.000 claims abstract description 8
- 239000010949 copper Substances 0.000 claims abstract description 8
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000010418 carrageenan Nutrition 0.000 claims abstract description 7
- 229920001525 carrageenan Polymers 0.000 claims abstract description 7
- 235000011187 glycerol Nutrition 0.000 claims abstract description 7
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 7
- 239000000661 sodium alginate Substances 0.000 claims abstract description 7
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 7
- 238000004806 packaging method and process Methods 0.000 claims abstract description 6
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 238000001035 drying Methods 0.000 claims abstract description 4
- 239000003814 drug Substances 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 8
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims description 6
- 238000007766 curtain coating Methods 0.000 claims description 5
- QNXYWDCEYCCPFK-UHFFFAOYSA-N hydroxy propyl hydrogen phosphate Chemical compound CCCOP(O)(=O)OO QNXYWDCEYCCPFK-UHFFFAOYSA-N 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 238000012423 maintenance Methods 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052760 oxygen Inorganic materials 0.000 abstract description 2
- 239000001301 oxygen Substances 0.000 abstract description 2
- 241000209149 Zea Species 0.000 abstract 2
- HYCSHFLKPSMPGO-UHFFFAOYSA-N 3-hydroxypropyl dihydrogen phosphate Chemical compound OCCCOP(O)(O)=O HYCSHFLKPSMPGO-UHFFFAOYSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 abstract 1
- 239000000679 carrageenan Substances 0.000 abstract 1
- 229940113118 carrageenan Drugs 0.000 abstract 1
- 238000007872 degassing Methods 0.000 abstract 1
- 229940079593 drug Drugs 0.000 abstract 1
- 229960005150 glycerol Drugs 0.000 abstract 1
- 238000000265 homogenisation Methods 0.000 abstract 1
- 238000005096 rolling process Methods 0.000 abstract 1
- 239000000600 sorbitol Substances 0.000 abstract 1
- 229960002920 sorbitol Drugs 0.000 abstract 1
- 235000010356 sorbitol Nutrition 0.000 abstract 1
- 238000010345 tape casting Methods 0.000 abstract 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 abstract 1
- 239000010408 film Substances 0.000 description 34
- 238000011160 research Methods 0.000 description 6
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 235000021485 packed food Nutrition 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/90—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
Landscapes
- General Preparation And Processing Of Foods (AREA)
- Jellies, Jams, And Syrups (AREA)
Abstract
The invention provides technology for producing a degradable and edible film by utilizing corn composite modified starch, belonging to the technical field of food processing. The technology comprises the following main production processes: firstly gelatinizing the corn hydroxypropyl-phosphate monoester composite modified starch; then adding glycerin, sorbitol, sodium alginate, carrageenan and other components which improve the film performance; carrying out tape casting on the film solution on a copper plate after homogenization and degasification; adopting a copper plate film forming conveyer belt to firstly pass through steam drying pipeline equipment and then pass through cooling pipeline equipment with relative humidity being about 50% to form a film; and finally adopting mechanical film rolling equipment to roll the film, thus producing a degradable and edible film with high strength. The film material has good mechanical performance and oil, moisture and oxygen resistance. The film can be applied to packaging of various materials such as food, health products, drugs, feed and the like.
Description
Technical field
A production method for corn composite modified starch degradable edible film, belongs to food processing technology field.
Background technology
Degradable edible film be a kind of not only can coating-film fresh-keeping but also the new packaging material that the packaged form such as bag, box replaces the conventional synthesis wrapping material such as plastics can be processed into, simultaneously it can also be an integral part of food, and increases color, smell and taste and nutritive value for food.Degradable edible film has pollution-free, degradable advantage, be that plastic wrapping is unrivaled, this is on the rise at " white pollution ", and most developed country has forbidden or limited the use of plastic wrapping and advocate and select beyond doubt a kind of best selection today of " Green Packaging ".So the degradable edible film wrapping material technology of preparing integrating these advantages is just becoming one of important technology that food service industry generally has an optimistic view of, there is good development prospect.
In existing background technology, U.S. patent Nos 6162475 reports the making method of the edibility active packing utilizing PVA to be base-material, this packaging has good fresh-keeping effect to food, Robert R Holcomb reports the method and apparatus of charge distribution on the active film that changes and have the electric allomeric function stability of thin film physics, and this has vital role to the performance improving active film.China is in the intellecture property of edible film, mainly concentrate on the formula of film, ZL02139279.X reports a kind of edibility yam starch composite food package film and preparation method thereof, film forming is stirred mainly through starch pasting, ZL02151253.1 reports the preparation method of composite comestible shell polysaccharide membrane, it take Chitosan-phospholipid complex as the main raw of film forming, with membrane-forming agent or toughener, softening agent and linking agent for ancillary component, by temperature control film forming.These researchs all do not relate to the control method (stage by stage dry) of film forming properties, the mechanism (limit to) of pressure treatment, particularly film forming and technical study above.Report is had no to the inventions such as edible film component mechanical index intensity and research.
In sum, in the research of degradable edible film, mainly concentrate in film forming formulation and mechanism both at home and abroad, be conceived in the applied research of film.To the performance of film own as tensile strength, moisture-inhibiting, ventilation property, water-soluble research, processing mode and improve material aspect of performance research less, compared with other packing techniques modern, still there is imperfection part, as performance is not high, production technique imperfection, thus the range of application limiting degradable edible film.Excellent preservative film, especially degradable edible film, all should have high strength, good barrier and controlled atmosphere to a certain degree and certain biocidal property.
Summary of the invention
The present invention is to provide one with corn hydroxy propyl phosphate monoester composite modified starch for main raw material, with the use of components such as glycerine, sorbyl alcohol, sodium alginate and carrageenins, by the method for homogeneous, the obtained degradable edible film novel material such as degassed, dry.The present invention adopts the method for vacuum outgas, is conducive to except the bubble in striping liquid; The present invention adopts copper coin curtain coating, is conducive to taking off film, can prevent film from ftractureing.The corn hydroxy propyl phosphate monoester composite modified starch that the present invention adopts, can keep higher viscosity stability, thus keep its high strength ability under low temperature, high-shear conditions.The glycerine that product of the present invention adds, sorbyl alcohol, sodium alginate and carrageenin, effectively can improve the mechanical property of film, oil resistance performance, oxygen resistance and block-water performance, reaches the shelf-lives object extending packaged food.
Embodiment
A production method for corn composite modified starch degradable edible film,
1, component allotment: 100kg corn hydroxy propyl phosphate monoester composite modified starch, 1000L distilled water, 0.15L glycerine, 1.25kg sorbyl alcohol, 0.5kg sodium alginate and 0.4kg carrageenin is added under stirring, after homogeneous, under 50 DEG C of water bath condition, heated and stirred, until gelatinization completely, obtains starch pasting solution.
2, degassed: at 0.1MPa deaerated under vacuum (0.5h-2h), then leave standstill 1h.
3, curtain coating: require to arrange blade width and height according to film thickness, curtain coating is in can on the copper coin conveying belt of controlling diaphragm thickness.4, dry: copper coin film forming conveying belt first by drying with steam pipe-line equipment, and then by relative humidity about 50% cooling duct equipment, film forming.
5, film is taken off: machinery volume film, packaging, storage.
Claims (6)
1. the production method of a corn composite modified starch degradable edible package material, it is characterized in that: 1) 100kg corn hydroxy propyl phosphate monoester composite modified starch, 1000L distilled water, 0.15L glycerine, 1.25kg sorbyl alcohol, 0.5kg sodium alginate and 0.4kg carrageenin is added under stirring, after homogeneous, under 50 DEG C of water bath condition, heated and stirred, until gelatinization completely, obtains starch pasting solution; 2), after deaerated under vacuum, curtain coating is on the copper coin film forming conveying belt of the scraper with adjustable-height and width of controlled film thickness; 3) copper coin film forming conveying belt is first by drying with steam pipe-line equipment, and then by relative humidity 50% cooling duct equipment, film forming, finally roll up film device by machinery and roll up film, packaging forms.
2. the production method of a kind of corn composite modified starch degradable edible package material according to claim 1, it is characterized in that, 0.15L glycerine, 1.25kg sorbyl alcohol, 0.5kg sodium alginate and 0.4kg carrageenin is added in corn hydroxy propyl phosphate monoester composite modified starch, can make it under low temperature, high-shear conditions, keep higher viscosity stability, thus keep the high strength ability of film forming.
3. the production method of a kind of corn composite modified starch degradable edible package material according to claim 1, it is characterized in that, product adds glycerine, sorbyl alcohol, sodium alginate and carrageenin, effectively can improve tensile strength and the unit elongation of film.
4. the production method of a kind of corn composite modified starch degradable edible package material according to claim 1, is characterized in that, adopts vacuum outgas method, can controlling diaphragm liquid uniform bubble-free, the toughness that maintenance film is good and extensibility.
5. the production method of a kind of corn composite modified starch degradable edible package material according to claim 1, it is characterized in that, require to arrange width and height according to film thickness, film liquid curtain coating in can controlling diaphragm thickness the scraper with adjustable-height and width copper coin film forming conveying belt on, first by drying with steam pipe-line equipment, and then by relative humidity 50% cooling duct equipment, film forming, finally by machinery roll up film device roll up film.
6. the production method of a kind of corn composite modified starch degradable edible package material according to claim 1, is characterized in that, described degradable edible package material is used for the packaging of food, healthcare products, medicine or feed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110156804.7A CN102311554B (en) | 2010-06-30 | 2011-06-02 | Technology for producing degradable and edible film by utilizing corn composite modified starch |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102139627 | 2010-06-30 | ||
| CN201010213962 | 2010-06-30 | ||
| CN201010213962.7 | 2010-06-30 | ||
| CN201110156804.7A CN102311554B (en) | 2010-06-30 | 2011-06-02 | Technology for producing degradable and edible film by utilizing corn composite modified starch |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102311554A CN102311554A (en) | 2012-01-11 |
| CN102311554B true CN102311554B (en) | 2015-04-15 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110156804.7A Expired - Fee Related CN102311554B (en) | 2010-06-30 | 2011-06-02 | Technology for producing degradable and edible film by utilizing corn composite modified starch |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102311554B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2525926C1 (en) * | 2013-01-09 | 2014-08-20 | Мария Александровна Никулина | Water-soluble biologically degradable edible packing film |
| EP3004175A1 (en) | 2013-05-24 | 2016-04-13 | Metsä Fibre Oy | Method of modifying polymers |
| CN103844223B (en) * | 2014-03-12 | 2016-01-20 | 浙江大学 | Honey fruit paper and preparation method thereof |
| CN104059248B (en) * | 2014-06-27 | 2016-08-24 | 江南大学 | A kind of by adding the method that hydrophilic colloid improves starch base edible package film properties |
| CN105196634B (en) * | 2015-10-28 | 2017-03-08 | 吉林大学 | A kind of method that laminating prepares MULTILAYER COMPOSITE edible film |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687203A (en) * | 2005-04-07 | 2005-10-26 | 天津大学 | Vegetable capsule of starch composition and preparation method |
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- 2011-06-02 CN CN201110156804.7A patent/CN102311554B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687203A (en) * | 2005-04-07 | 2005-10-26 | 天津大学 | Vegetable capsule of starch composition and preparation method |
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| Publication number | Publication date |
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| CN102311554A (en) | 2012-01-11 |
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| PB01 | Publication | ||
| DD01 | Delivery of document by public notice |
Addressee: lively Document name: Notification of Publication of the Application for Invention |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150415 |