CN102304344A - Sealant special for solar module and preparation method for sealant - Google Patents

Sealant special for solar module and preparation method for sealant Download PDF

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Publication number
CN102304344A
CN102304344A CN201110009693A CN201110009693A CN102304344A CN 102304344 A CN102304344 A CN 102304344A CN 201110009693 A CN201110009693 A CN 201110009693A CN 201110009693 A CN201110009693 A CN 201110009693A CN 102304344 A CN102304344 A CN 102304344A
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CN
China
Prior art keywords
weight part
weight parts
solar cell
cell assembly
seal gum
Prior art date
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Pending
Application number
CN201110009693A
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Chinese (zh)
Inventor
张开祥
施吉慧
刘祥涛
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Hailong Nuclear Material Technology (jiangsu) Co Ltd
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Hailong Nuclear Material Technology (jiangsu) Co Ltd
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Application filed by Hailong Nuclear Material Technology (jiangsu) Co Ltd filed Critical Hailong Nuclear Material Technology (jiangsu) Co Ltd
Priority to CN201110009693A priority Critical patent/CN102304344A/en
Publication of CN102304344A publication Critical patent/CN102304344A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

Abstract

The invention discloses a sealant for a solar module. The sealant consists of 50 to 90 weight parts of polydimethylsiloxane, 20 to 50 weight parts of methyl triethoxysilane, 5 to 30 weight parts of flame retardant, 5 to 20 weight parts of filler and 5 to 20 weight parts of thixotropic agent. A preparation method for the sealant comprises the following steps of: mixing and stirring the polydimethylsiloxane and the methyl triethoxysilane for 10 to 30 minutes; and adding the flame retardant, the filler and the thixotropic agent, and stirring and mixing uniformly. The sealant is neutral, does not have toxicity, corrosion and environmental pollution basically, has the advantages of good constructability, high elasticity, high bonding strength, high insulativity, ageing, ultraviolet and radiation resistance and the like, and can meet performance requirements of sealing and packaging the solar module.

Description

A kind of special seal gum for solar cell assembly and preparation method thereof
Technical field
The present invention relates to a kind of special seal gum for solar cell assembly and preparation method thereof, specifically, relate to a kind of silicone sealant of modification, belong to the matrix material technical field.
Background technology
Solar energy power generating is meant and utilizes photovoltaic effect to make solar radiation can be transformed into electric energy.Face the dual restriction of the energy and environmental protection day by day along with the human economy and the Sustainable development of society; This generation mode more and more receives people's attention; Each country all actively gets involved, the preemption techniques commanding elevation, and China also classifies sun power as one of opera involving much singing and action of new forms of energy industry.Therefore, over nearly 20 years, the photovoltaic industry has experienced develop rapidly, and the kind of solar cell is on the increase, range of application is wide day by day, market scale also enlarges rapidly.The photovoltaic industry will continue rapid growth in several years of future.IEA makes multiple prediction to global photovoltaic industry development prospect, and the most conservative prediction is that the photovoltaic production capacity will quadruple to the year two thousand twenty.
Solar battery sheet is the core component of solar photovoltaic generation system.Because physics, chemical imperfections such as thin, crisp, easy oxidation that solar battery sheet self exists are exposed to and are easy to cause permanent damage under the natural condition such as air, rainwater, make solar electrical energy generation be difficult to large-scale application under abominable natural condition.Therefore, realize the industrial applications of solar electrical energy generation, just require it is carried out protective seal and encapsulation, thereby form solar module.This protective seal is a guardian technique realizing photovoltaic generation suitability for industrialized production and large-scale application with encapsulation.In sealer; Silicone sealant is because its superior high and low temperature resistance, weather resistance, good air-tightness and be easy to characteristic such as construction; Being specially adapted to the protective seal and the encapsulation of solar module, is one of international and domestic solar sealant Development Trend.
Summary of the invention
The purpose of this invention is to provide a kind of special seal gum that can satisfy solar module sealing and encapsulation performance requirement and preparation method thereof,, satisfy the demand of existing market to overcome existing in prior technology defective and deficiency.
For realizing the foregoing invention purpose, the technical scheme that the present invention adopts is following:
Special seal gum for solar cell assembly provided by the invention, its composition and composition proportioning are following:
YSR 3286 50~90 weight parts
Union carbide A-162 20~50 weight parts
Fire retardant 5~30 weight parts
Filler 5~20 weight parts
Thixotropic agent 5~20 weight parts.
Described fire retardant is any one or more than one the combination in polyphosphoric acid ammonia, white lake, the Marinco H.
Described filler is any one or more than one the combination in light calcium carbonate, water-ground limestone, talcum powder, ultra-fine mica powder, the ultra-fine barium sulfate.
Described thixotropic agent is any one or more than one the combination in cured of organobentonite, aerosil, THIXCIN, polymeric amide.
The preparation method of special seal gum for solar cell assembly of the present invention is following:
At first 50~90 weight part YSR 3286s are mixed with 20~50 weight part Union carbide A-162s and stirred 10~30 minutes; Add 5~30 parts by weight of flame retardant, 5~20 weight part fillers and 5~20 weight part thixotropic agent then; Mix, promptly get described special seal gum for solar cell assembly.
Compared with prior art; It is neutral that special seal gum for solar cell assembly provided by the invention is, nontoxic basically, no burn into non-environmental-pollution, and it is good to have a good resistant of high or low temperature (60~250 ℃), ageing-resistant, anti-ozone, anti-arcing and corona, UV resistant, anti-general chemical reagent, electrical insulation capability; Characteristics such as long service life; And has a good high pressure resistant electrical insulating property, powerful bonding force and sticking power, higher elongation low-shrinkage; High resilience and toughness; Remarkable weather-proof resistance to deterioration, ability long term operation can satisfy the performance requriements of the sealing and the encapsulation of solar module among severe environment such as water, oil, ozone, strong magnetic high pressure, uv-radiation and wind and weather.
Embodiment
Below in conjunction with embodiment the present invention is done further detailed, complete explanation, but the present invention is not limited in following embodiment.
Embodiment 1
At first 50 weight part YSR 3286s are mixed with 30 weight part Union carbide A-162s and stirred 10 minutes; Add 5 weight part white lakes, 5 weight part light calcium carbonates and 5 weight part aerosils then; Mix, promptly get described special seal gum for solar cell assembly.
Embodiment 2
At first 60 weight part YSR 3286s are mixed with 20 weight part Union carbide A-162s and stirred 15 minutes; Add 10 weight part Marinco Hs, 15 weight part water-ground limestones and 10 weight part organobentonites then; Mix, promptly get described special seal gum for solar cell assembly.
Embodiment 3
At first 70 weight part YSR 3286s are mixed with 40 weight part Union carbide A-162s and stirred 20 minutes; Add 15 weight part polyphosphoric acid ammonia, the ultra-fine mica powder of 5 weight parts and 15 weight part THIXCINs then; Mix, promptly get described special seal gum for solar cell assembly.
Embodiment 4
At first 80 weight part YSR 3286s are mixed with 50 weight part Union carbide A-162s and stirred 25 minutes; It is cured to add 20 weight part polyphosphoric acid ammonia, 5 weight part white lakes, 20 weight part talcum powder and 20 weight parts of polyamide then; Mix, promptly get described special seal gum for solar cell assembly.
Embodiment 5
At first 90 weight part YSR 3286s are mixed with 25 weight part Union carbide A-162s and stirred 30 minutes; Add 10 weight part white lakes, 10 weight part Marinco Hs, 15 weight part ultra-fine barium sulfates and 5 weight part organobentonites then; Mix, promptly get described special seal gum for solar cell assembly.
Embodiment 6
At first 50 weight part YSR 3286s are mixed with 35 weight part Union carbide A-162s and stirred 15 minutes; Add 15 weight part polyphosphoric acid ammonia, 15 weight part Marinco Hs, the ultra-fine mica powder of 10 weight parts and 15 weight part aerosils then; Mix, promptly get described special seal gum for solar cell assembly.
Embodiment 7
At first 80 weight part YSR 3286s are mixed with 45 weight part Union carbide A-162s and stirred 15 minutes; Add 10 weight part white lakes, 20 weight part Marinco Hs, the ultra-fine mica powder of 10 weight parts and 15 weight part THIXCINs then; Mix, promptly get described special seal gum for solar cell assembly.
Solar components special seal gum of the present invention is according to GB/T528, GB/T531, and GB/T1692, GB/T1408-2006, GB/T13477, the results of property that standards such as UL94 detect is as shown in table 1.
The performance test results of table 1 solar components special seal gum of the present invention
Figure BDA0000044142300000041
Visible by the performance test results of table 1: advantages such as special seal gum for solar cell assembly provided by the invention is prone to construction, elasticity is high, and bonding strength is big, and insulativity is high, ageing-resistant, can satisfy the performance requriements of the sealing and the encapsulation of solar module.

Claims (5)

1. a special seal gum for solar cell assembly is characterized in that, its composition and composition proportioning are following:
YSR 3286 50~90 weight parts
Union carbide A-162 20~50 weight parts
Fire retardant 5~30 weight parts
Filler 5~20 weight parts
Thixotropic agent 5~20 weight parts.
2. special seal gum for solar cell assembly according to claim 1 is characterized in that: described fire retardant is any one or more than one the combination in polyphosphoric acid ammonia, white lake, the Marinco H.
3. special seal gum for solar cell assembly according to claim 1 is characterized in that: described filler is any one or more than one the combination in light calcium carbonate, water-ground limestone, talcum powder, ultra-fine mica powder, the ultra-fine barium sulfate.
4. special seal gum for solar cell assembly according to claim 1 is characterized in that: described thixotropic agent is any one or more than one the combination in cured of organobentonite, aerosil, THIXCIN, polymeric amide.
5. described special seal gum for solar cell assembly of claim 1; It is characterized in that: be at first 50~90 weight part YSR 3286s to be mixed with 20~50 weight part Union carbide A-162s to stir 10~30 minutes; Add 5~30 parts by weight of flame retardant, 5~20 weight part fillers and 5~20 weight part thixotropic agent then; Mix, promptly get described special seal gum for solar cell assembly.
CN201110009693A 2011-01-17 2011-01-17 Sealant special for solar module and preparation method for sealant Pending CN102304344A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201110009693A CN102304344A (en) 2011-01-17 2011-01-17 Sealant special for solar module and preparation method for sealant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201110009693A CN102304344A (en) 2011-01-17 2011-01-17 Sealant special for solar module and preparation method for sealant

Publications (1)

Publication Number Publication Date
CN102304344A true CN102304344A (en) 2012-01-04

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Country Status (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876289A (en) * 2012-09-04 2013-01-16 博侃电气(合肥)有限公司 Sealing plaster for sealing cable terminal
CN111690369A (en) * 2019-03-15 2020-09-22 贝克西弗股份有限公司 Coating structure of radiation-resistant glue and method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005006471A1 (en) * 2003-07-10 2005-01-20 Seoul National University Industry Foundation Nanostructured carbon materials having good crystallinity and large surface area suitable for electrodes, and method for synthesizing the same using catalytic graphitization of polymeric carbon precursors
CN101747631A (en) * 2008-12-01 2010-06-23 中国科学院过程工程研究所 Flame-retardant room temperature vulcanized silicone rubber composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005006471A1 (en) * 2003-07-10 2005-01-20 Seoul National University Industry Foundation Nanostructured carbon materials having good crystallinity and large surface area suitable for electrodes, and method for synthesizing the same using catalytic graphitization of polymeric carbon precursors
CN101747631A (en) * 2008-12-01 2010-06-23 中国科学院过程工程研究所 Flame-retardant room temperature vulcanized silicone rubber composition

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
李子东等: "《胶黏剂助剂》", 28 February 2005, 化学工业出版社 *
黄应昌等: "《弹性体密封胶与胶黏剂》", 30 September 2003, 化学工业出版社 *
黄文润: "《液体硅橡胶》", 30 June 2009, 四川科学技术出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876289A (en) * 2012-09-04 2013-01-16 博侃电气(合肥)有限公司 Sealing plaster for sealing cable terminal
CN111690369A (en) * 2019-03-15 2020-09-22 贝克西弗股份有限公司 Coating structure of radiation-resistant glue and method thereof

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Application publication date: 20120104