CN102294851A - Hydrophobic scratch-resistant coating on organic polymer surface and preparation method thereof - Google Patents
Hydrophobic scratch-resistant coating on organic polymer surface and preparation method thereof Download PDFInfo
- Publication number
- CN102294851A CN102294851A CN2011101872009A CN201110187200A CN102294851A CN 102294851 A CN102294851 A CN 102294851A CN 2011101872009 A CN2011101872009 A CN 2011101872009A CN 201110187200 A CN201110187200 A CN 201110187200A CN 102294851 A CN102294851 A CN 102294851A
- Authority
- CN
- China
- Prior art keywords
- organic
- organic polymer
- polymer surface
- coating
- scratch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to a hydrophobic scratch-resistant coating on an organic polymer surface and a preparation method thereof. The coating is a double layer coating, a first layer (a base layer) of which is prepared by UV solidification of an organic-inorganic hybrid paint consisting of 30-70% of organic-inorganic hybrid resin, 20-50% of oligomer, 5-25% of active diluent, 1-2% of photoinitiator and 0.2-3% of auxiliary agent, and a second layer (a top layer) of which comprises non-saturated double bond monomer hydrophobicity modified particles that are fixed by resin that can be cured by UV. The coating has characteristics of strong adhesion, high hardness and good hydrophobicity, and can be used in finishing protection of an organic polymer surface.
Description
Technical field
The present invention relates to a kind of ultraviolet curable coating material, especially relate to a kind of hydrophobic scratch-resistant organic-inorganic hybridization ultraviolet cured paint and coating production, specifically be used for frosting.
Background technology
Organic polymer material has a lot of good performances, and is good as processing characteristics, weatherability, electrical insulating property, excellent in optical properties, and light weight is tough, has been widely used in fields such as agricultural, aviation, building, traffic, optical instrument.Along with development of science and technology, this material practices in novel high-end product at present, as novel organic display, optical mirror slip and device, high-grade ornament materials, sound barrier, aviation window, high-speed track train window, organic-biological vessel, premium package package material etc.Yet with glassy phase than also coming with some shortcomings part, poor as scratch resistance, easily combine and difficulty cleans with greasy dirt.For the advantage of giving full play to organic polymer material and overcome shortcomings such as material easily scratches, difficult cleaning, expansion material service life and range of application, people have carried out extensive studies to this.
In order to improve organic polymer surface scratch resistant performance, what the researcher was more is to adopt nanometer technology, and has obtained good effect.CN1772820A has reported and added wear-resisting-hardness additive of 0.1 ~ 8.0% in traditional ultraviolet-curing paint, can improve abrasion property to a certain extent, but there is the inconsistent problem of inorganic filler and resin, even cause macroface to separate, wearability improves and is not obvious, and transmitance descends.CN101045833A has reported a kind of preparation method of in-situ modified ultraviolet-curing paint, this method is selected one or more matrixes as reaction in-situ in the lower esters of acrylic acid reactive diluent of viscosity, adopt positive esters of silicon acis as presoma, with with amino silane coupler as catalyst and surface conditioning agent, one step was finished the preparation and the surface treatment of nano material, and then make ultraviolet-curing paint, gained hardness of film height efficiently solves the problem that nano particle and organic resin compatibility and nano particle are easily reunited.But the easy clean property that above research does not all have consideration to film.
Aspect the easy clean property in raising organic polymer surface, the researcher has invented a lot of methods and has prepared super-hydrophobic coat, mainly contain template, particle-filled method, etching method, nano-array method, vapour deposition process, phase separation method, sol-gel process, photochemical method etc., it mainly prepares thought is that the micro-nano coarse structure of constructing the surface reaches the character that makes surface super hydrophobic.Along with going deep into of recent super-hydrophobic research, more and more highlight the drawback and the fatal shortcoming thereof that obtain surface microstructure by the whole bag of tricks.Have contact angle and low hysteresis effect although have the film or the surface of micro-nano compound structure, such film or surperficial bad mechanical strength and come off easily greater than 150 °.
Summary of the invention
In order to solve the deficiency of above existence; the invention provides a kind of preparation method of organic polymer surface hydrophobicity scratch resistant coatings; this method has advantages such as cost is low, technology is simple; coating has characteristics such as strong adhesion, hardness height, hydrophobicity are good, can be used for the covering with paint protection on organic polymer surface.
The organic polymer surface hydrophobicity scratch resistant coatings that the present invention proposes comprises organic-inorganic hybridization coating scratch-resistant bottom and hydrophobic top layer through ultra-violet curing, described bottom sticks to the organic polymer surface, described hydrophobic top layer comprises the particle of the organic silicon monomer hydrophobically modified through containing unsaturated double-bond, and this particle is fixed by the resin of UV curable.
The organic polymer that the present invention proposes is polymethyl methacrylate (PMMA), Merlon (PC), a kind of in the PET (PET).
The used organic-inorganic hybridization coating of scratch-resistant bottom that the present invention proposes, each component and the weight percentage thereof of coating are as follows:
Form weight percentage wt%
Organic-inorganic hybrid resin 30-70
Oligomer 20-50
Reactive diluent 5-25
Light trigger 1-2
Auxiliary agent 0.2-3
Optional in urethane acrylate, bisphenol A epoxy acrylate, polyester acrylate one or more of the oligomer that the present invention proposes.
The reactive diluent that the present invention proposes is 1, one or more in 6-hexanediyl ester, tripropylene glycol diacrylate, trimethylolpropane triacrylate, ethoxyquin trimethylolpropane triacrylate, the third oxidation trimethylolpropane triacrylate.
The organic-inorganic hybrid resin that the present invention proposes is to be made by following component:
Weight percentages of components wt%
Alkoxy silane 10-20
The organic silicon monomer 20-50 that contains unsaturated double-bond
Ludox 2-20
Solvent 10-20
Water 5-20
Acidic catalyst 0.01-1
Concrete preparation method is: add alkoxy silane, the organic silicon monomer that contains unsaturated double-bond and solvent in reactor earlier, 0.5-1 drip the mixture of water, Ludox and acidic catalyst in hour, ageing is 24 hours after stirring reaction 6-8 hour, promptly gets organic-inorganic hybrid resin.
The used coating of hydrophobic top layer that the present invention proposes is made by following component:
Weight percentages of components wt%
Hydrophobically modified particle suspension 45-70
The resin 0.2-10 of UV curable
Solvent 30-50
Light trigger 1-2
Auxiliary agent 0.2-3
Concrete preparation technology is as follows: resin, solvent, light trigger, auxiliary agent mixing and stirring with hydrophobically modified particle suspension, UV curable make the top coat ultraviolet-curing paint.
The hydrophobically modified particle suspension that the present invention proposes is made by following component:
Weight percentages of components wt%
Alkoxy silane 10-17
Fluorine-containing siloxanes 1-3
The organic silicon monomer 0.2-5 that contains unsaturated double-bond
Solvent 75-85
Base catalyst 2.5-2.7
Concrete preparation technology is as follows: add ethyl orthosilicate, the organic silicon monomer that contains unsaturated double-bond, fluorine-containing siloxanes and ethanol in reactor earlier, 0.5-1 drip the mixture of water and base catalyst in hour, behind the stirring reaction 20 hours, promptly get the suspension of hydrophobically modified particle.
The fluorine-containing siloxanes that the present invention proposes is a kind of in ten trifluoro octyl group trimethoxy silanes, ten trifluoro octyltri-ethoxysilane, 17 fluorine decyl trimethoxy silanes and the 17 fluorine decyl triethoxysilanes.
The resin of the UV curable that the present invention proposes is the oligomer in the subbing and the mixture of reactive diluent.
The preparation technology of coating that the present invention proposes comprises the steps:
(1) first weighing organic-inorganic hybrid resin, oligomer, reactive diluent, light trigger, auxiliary agent; Then load weighted component is mixed together, obtains primer coating coating, adopt the mode of brushing, spraying or showering directly to coat substrate surface, treat levelling after, adopt high-pressure sodium lamp direct ultraviolet radiation curing, make it form the bottom of semi-solid preparation.
(2) first weighing resin, hydrophobically modified particle suspension, light trigger, solvent; Then load weighted component is mixed together, adopt spraying method directly to coat on the bottom of semi-solid preparation.
(3) described surface is heated to after 70-100 ° of C vapor away solvent, adopts high-pressure sodium lamp direct ultraviolet radiation curing bottom and top layer, obtains the scratch-resistant hydrophobic coating.
In the preparation technology of coating that the present invention proposes, because the hydrophobically modified particle surface in the top layer contains the unsaturated double-bond of UV curable, in the crosslinking curing process of resin, hydrophobically modified particle in the top layer is fixedly secured in the resinous substrates that disperses at it, then by covalent bonding to the bottom resin, this coating can be regarded as single continuous resin bed and the hydrophobically modified particle embeds its surface.
The hydrophobic scratch resistant coatings of the present invention preparation, have the following advantages: organic and inorganic is a hydridization in nano-scale range, and the coating of preparation has performances such as strong adhesion, hardness height, hydrophobicity are good, and coating reaches more than 130 ° water contact angle.
Hydrophobic scratch resistant coatings provided by the invention can be used for the covering with paint and the protection on organic polymer surface.
Description of drawings
Fig. 1 is the coating surface water contact angle state diagram of embodiment 10 gained.
The specific embodiment
Below in conjunction with example the present invention is further described in detail, but is not limited to this.
One, the preparation of organic-inorganic hybrid resin
Embodiment 1:
In the reactor that agitator, dropping funel are housed, add 46.8g ethyl orthosilicate, 168g γ-methacryloxy trimethoxy silane, 53.7g ethanol, stirring at room 10 minutes, 9g Ludox, 0.4g nitric acid, 58.5g water mixed be placed on dropping funel, 0.5-1 hour drip, stirred 6-8 hour, ageing 24 hours obtains organic-inorganic hybrid resin.
Embodiment 2:
In the reactor that agitator, dropping funel are housed, add 46.8g ethyl orthosilicate, 168g γ-methacryloxy trimethoxy silane, 53.7g ethanol, stirring at room 10 minutes, 18g Ludox, 0.41g nitric acid, 52.2g water mixed be placed on dropping funel, 0.5-1 hour drip, stir ageing 6-8 hour, ageing 24 hours obtains organic-inorganic hybrid resin.
Two, the primer coating preparation of organic-inorganic hybridization ultraviolet cured paint
Embodiment 3:
Resin 97.5g, urethane acrylate 11.2g, epoxy acrylate 8.4g, trimethylolpropane triacrylate 8.4g, light trigger Darocur 1173 1.12g, levelling agent 0.38g that embodiment 1 is made, mixing and stirring makes organic-inorganic hybridization coating.
Embodiment 4:
Resin 17.9g, urethane acrylate 11.2g, epoxy acrylate 8.4g, trimethylolpropane triacrylate 8.4g, light trigger Darocur 1173 1.12g, levelling agent 0.14g that embodiment 1 is made, mixing and stirring makes organic-inorganic hybridization coating.
Embodiment 5:
Resin 93g, urethane acrylate 11.2g, epoxy acrylate 8.4g, trimethylolpropane triacrylate 8.4g, light trigger Darocur 1173 1.12g, levelling agent 0.39g that embodiment 2 is made, mixing and stirring makes organic-inorganic hybridization coating.
Embodiment 6:
Resin 69.2g, urethane acrylate 19.1g, epoxy acrylate 14.3g, trimethylolpropane triacrylate 14.3g, light trigger Darocur 1173 1.20g, levelling agent 0.35g that embodiment 2 is made, mixing and stirring makes organic-inorganic hybridization coating.
Three, the preparation of hydrophobically modified particle
Embodiment 7:
In the reactor that agitator, dropping funel are housed, add ethyl orthosilicate 4.7g, ammoniacal liquor 1.37g, ethanol 39.5g, stirring at room 10 minutes, with ten trifluoro octyltri-ethoxysilane 1.15g, γ-methacryloxy trimethoxy silane 2.8g mixes and is placed on dropping funel, 0.5-1 hour drip, stirred 20-24 hour, and ultrasonic 15 minutes, obtained the hydrophobically modified nano particle.
Four, the top coat preparation of ultraviolet-curing paint
Embodiment 8:
Hydrophobically modified particle 60g, urethane acrylate 0.08g, epoxy acrylate 0.06g, trimethylolpropane triacrylate 0.06g, ethanol 39.8g, light trigger Darocur 1173 0.008g, levelling agent 0.3g mixing and stirring with embodiment 7 makes make the top coat ultraviolet-curing paint.
Embodiment 9:
Hydrophobically modified particle 60g, urethane acrylate 0.24g, epoxy acrylate 0.18g, trimethylolpropane triacrylate 0.18g, ethanol 39.4g, light trigger Darocur 1173 0.024g, levelling agent 0.3g mixing and stirring with embodiment 7 makes make the top coat ultraviolet-curing paint.
Five, the preparation of hydrophobic scratch resistant coatings
Embodiment 10:
The primer coating organic-inorganic hybridization ultraviolet cured paint of being prepared with embodiment 6 by spraying method, is coated on the PMMA base material respectively, treat levelling after, adopt high-pressure sodium lamp direct ultraviolet radiation curing, make it form the bottom of semi-solid preparation.To spray on the bottom of semi-solid preparation with ultraviolet-curing paint by the top coat of embodiment 8 preparations then, at 70-100 ° of C baking 5-10min, after vaporing away solvent, adopt high-pressure sodium lamp direct ultraviolet radiation curing bottom and top layer, obtain the scratch-resistant hydrophobic coating.
The above only is preferred embodiment of the present invention, not in order to restriction the present invention, all any modifications of being done within the spirit and principles in the present invention, is equal to and replaces and improvement etc., all should be included within protection scope of the present invention.
Claims (11)
1. organic polymer surface hydrophobicity scratch resistant coatings, it is characterized in that this coating comprises organic-inorganic hybridization coating scratch-resistant bottom and hydrophobic top layer through ultra-violet curing, described scratch-resistant bottom sticks to the organic polymer surface, described hydrophobic top layer comprises the particle of the organic silicon monomer hydrophobically modified through containing unsaturated double-bond, and this particle is fixed by the resin of UV curable.
2. organic polymer according to claim 1 is a polymethyl methacrylate, Merlon, a kind of in the PET.
3. organic polymer surface hydrophobicity scratch resistant coatings according to claim 1 is characterized in that the used organic-inorganic hybridization coating of described scratch-resistant bottom, and each component and the weight percentage thereof of this coating are as follows:
Form weight percentage wt%
Organic-inorganic hybrid resin 30-70
Oligomer 20-50
Reactive diluent 5-25
Light trigger 1-2
Auxiliary agent 0.2-3.
4. organic polymer surface hydrophobicity scratch resistant coatings according to claim 3 is characterized in that described oligomer is selected from one or more in urethane acrylate, bisphenol A epoxy acrylate, the polyester acrylate.
5. organic polymer surface hydrophobicity scratch resistant coatings according to claim 3, it is characterized in that described reactive diluent is 1, one or more in 6-hexanediyl ester, tripropylene glycol diacrylate, trimethylolpropane triacrylate, ethoxyquin trimethylolpropane triacrylate, the third oxidation trimethylolpropane triacrylate.
6. organic polymer surface hydrophobicity scratch resistant coatings according to claim 3 is characterized in that described organic-inorganic hybrid resin is to be made by following component:
Weight percentages of components wt%
Alkoxy silane 10-20
The organic silicon monomer 20-50 that contains unsaturated double-bond
Ludox 2-20
Solvent 10-20
Water 5-20
Acidic catalyst 0.01-1
Its preparation method is: add alkoxy silane, the organic silicon monomer that contains unsaturated double-bond and solvent in reactor earlier, 0.5-1 drip the mixture of water, Ludox and acidic catalyst in hour, ageing is 24 hours after stirring reaction 6-8 hour, promptly gets organic-inorganic hybrid resin.
7. organic polymer surface hydrophobicity scratch resistant coatings according to claim 1 is characterized in that the used coating of hydrophobic top layer is made by following component:
Weight percentages of components wt%
Hydrophobically modified particle suspension 45-70
The resin 0.2-10 of UV curable
Solvent 30-50
Light trigger 1-2
Auxiliary agent 0.2-3
Concrete preparation technology is as follows: resin, solvent, light trigger, auxiliary agent mixing and stirring with hydrophobically modified particle suspension, UV curable make the top coat ultraviolet-curing paint.
8. organic polymer surface hydrophobicity scratch resistant coatings according to claim 1, the suspension that it is characterized in that described hydrophobically modified particle is to be made by following component:
Weight percentages of components wt%
Alkoxy silane 10-17
Fluorine-containing siloxanes 1-3
The organic silicon monomer 0.2-5 that contains unsaturated double-bond
Solvent 75-85
Base catalyst 2.5-2.7
Concrete preparation technology is as follows: add ethyl orthosilicate, the organic silicon monomer that contains unsaturated double-bond, fluorine-containing siloxanes and ethanol in reactor earlier, 0.5-1 drip the mixture of water and base catalyst in hour, behind the stirring reaction 20 hours, promptly get the suspension of hydrophobically modified particle.
9. organic polymer surface hydrophobicity scratch resistant coatings according to claim 7 is characterized in that described fluorine-containing siloxanes is a kind of in ten trifluoro octyl group trimethoxy silanes, ten trifluoro octyltri-ethoxysilane, 17 fluorine decyl trimethoxy silanes and the 17 fluorine decyl triethoxysilanes.
10. organic polymer surface hydrophobicity scratch resistant coatings according to claim 7, the resin that it is characterized in that UV curable in the described top layer are the oligomer in the subbing and the mixture of reactive diluent.
11. the preparation method of organic polymer surface hydrophobicity scratch resistant coatings is characterized in that this method comprises the steps:
A) by the first weighing organic-inorganic hybrid resin of the described prescription of claim 3, oligomer, reactive diluent, light trigger, auxiliary agent; Then load weighted component is mixed together, adopts the mode of brushing, spraying or showering directly to coat substrate surface, treat levelling after, adopt high-pressure sodium lamp direct ultraviolet radiation curing, make it form the bottom of semi-solid preparation;
B) by the first weighing resin of the described prescription of claim 7, hydrophobically modified particle, light trigger, solvent; Then load weighted component is mixed together, adopt spraying method directly to coat on the bottom of semi-solid preparation;
C) described surface be heated to 70-100 ℃ vapor away solvent after, adopt high-pressure sodium lamp direct ultraviolet radiation curing bottom and top layer, obtain the scratch-resistant hydrophobic coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101872009A CN102294851A (en) | 2011-07-06 | 2011-07-06 | Hydrophobic scratch-resistant coating on organic polymer surface and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101872009A CN102294851A (en) | 2011-07-06 | 2011-07-06 | Hydrophobic scratch-resistant coating on organic polymer surface and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102294851A true CN102294851A (en) | 2011-12-28 |
Family
ID=45355636
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011101872009A Pending CN102294851A (en) | 2011-07-06 | 2011-07-06 | Hydrophobic scratch-resistant coating on organic polymer surface and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102294851A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103612452A (en) * | 2013-11-22 | 2014-03-05 | 袁伟 | Environment-friendly multifunctional water-based coating |
| CN104694036A (en) * | 2015-02-15 | 2015-06-10 | 滁州云林数码影像耗材有限公司 | Anti-scratch paint protecting film and preparation method thereof |
| CN105176157A (en) * | 2015-09-30 | 2015-12-23 | 江苏耀兴安全玻璃有限公司 | Preparation method of hydrophobic paint for automotive glass |
| CN106497183A (en) * | 2016-10-26 | 2017-03-15 | 江苏怡丽科姆新材料股份有限公司 | A kind of low rainbow line oil-stain-preventing cured film |
| CN107226920A (en) * | 2017-07-12 | 2017-10-03 | 中物院成都科学技术发展中心 | A kind of preparation method of light-cured type super-hydrophobic composite film |
| CN107236449A (en) * | 2016-03-29 | 2017-10-10 | 沙河市湡久新材料有限公司 | UV curing types hard coating and it is coated with weatherability hard coat film obtained by the hard coating |
| CN109913055A (en) * | 2019-03-01 | 2019-06-21 | 西安交通大学 | It is a kind of improve polymer insulation along the face rice of resistance to susceptance modified membrane preparation method |
| CN110511415A (en) * | 2019-08-30 | 2019-11-29 | 华南理工大学 | Using epoxy soybean oil acrylate as waterproof starch film of coating and preparation method thereof |
| CN110720666A (en) * | 2019-07-02 | 2020-01-24 | 昆山联滔电子有限公司 | Aerosol delivery device |
| CN111962049A (en) * | 2020-08-26 | 2020-11-20 | 佛山市思博睿科技有限公司 | Plasma chemical vapor deposition nano super-hydrophobic coating and preparation method thereof |
| CN112236493A (en) * | 2018-04-06 | 2021-01-15 | 欧提腾股份有限公司 | Flexible and foldable abrasion resistant photopatternable silicone hardcoats |
| CN112752474A (en) * | 2020-10-30 | 2021-05-04 | 天津七所精密机电技术有限公司 | Wetting modification processing method for case body and high-protection reinforced electronic equipment |
| CN116716034A (en) * | 2023-05-24 | 2023-09-08 | 华东理工大学华昌聚合物有限公司 | Flame-retardant super-hydrophobic coating and application method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1810912A (en) * | 2006-03-03 | 2006-08-02 | 清华大学 | Soft template and ultraviolet curing process to prepare surface super hydrophobic material |
| CN101235249A (en) * | 2006-12-23 | 2008-08-06 | 赢创德固赛有限责任公司 | Silica-containing radiation-curable formulations with increased corrosion protection on metal substrates |
| CN101307194A (en) * | 2008-06-27 | 2008-11-19 | 江苏科技大学 | Organic-inorganic hybridization ultraviolet cured paint for protecting metallic surface |
| CN101349867A (en) * | 2007-07-16 | 2009-01-21 | 韩国电气研究院 | Organic-inorganic compound sensitization resin composition and LCD element using sclerotium thereof |
| CN101962514A (en) * | 2010-09-27 | 2011-02-02 | 复旦大学 | High-durability super-hydrophobic self-cleaning coating material and preparation method thereof |
| CN102061127A (en) * | 2011-02-17 | 2011-05-18 | 上海衡峰氟碳材料有限公司 | UV-solidified nanometer inorganic/organic hybrid painting preparation method and application thereof |
| CN102086333A (en) * | 2010-11-29 | 2011-06-08 | 江苏足迹涂料有限公司 | Organic-inorganic composite coating in chrysanthemum-shaped micro-nano structure and preparation method thereof |
-
2011
- 2011-07-06 CN CN2011101872009A patent/CN102294851A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1810912A (en) * | 2006-03-03 | 2006-08-02 | 清华大学 | Soft template and ultraviolet curing process to prepare surface super hydrophobic material |
| CN101235249A (en) * | 2006-12-23 | 2008-08-06 | 赢创德固赛有限责任公司 | Silica-containing radiation-curable formulations with increased corrosion protection on metal substrates |
| CN101349867A (en) * | 2007-07-16 | 2009-01-21 | 韩国电气研究院 | Organic-inorganic compound sensitization resin composition and LCD element using sclerotium thereof |
| CN101307194A (en) * | 2008-06-27 | 2008-11-19 | 江苏科技大学 | Organic-inorganic hybridization ultraviolet cured paint for protecting metallic surface |
| CN101962514A (en) * | 2010-09-27 | 2011-02-02 | 复旦大学 | High-durability super-hydrophobic self-cleaning coating material and preparation method thereof |
| CN102086333A (en) * | 2010-11-29 | 2011-06-08 | 江苏足迹涂料有限公司 | Organic-inorganic composite coating in chrysanthemum-shaped micro-nano structure and preparation method thereof |
| CN102061127A (en) * | 2011-02-17 | 2011-05-18 | 上海衡峰氟碳材料有限公司 | UV-solidified nanometer inorganic/organic hybrid painting preparation method and application thereof |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103612452B (en) * | 2013-11-22 | 2016-03-02 | 袁伟 | A kind of aqueous, environmental protective multi-functional coatings |
| CN103612452A (en) * | 2013-11-22 | 2014-03-05 | 袁伟 | Environment-friendly multifunctional water-based coating |
| CN104694036A (en) * | 2015-02-15 | 2015-06-10 | 滁州云林数码影像耗材有限公司 | Anti-scratch paint protecting film and preparation method thereof |
| CN105176157A (en) * | 2015-09-30 | 2015-12-23 | 江苏耀兴安全玻璃有限公司 | Preparation method of hydrophobic paint for automotive glass |
| CN107236449A (en) * | 2016-03-29 | 2017-10-10 | 沙河市湡久新材料有限公司 | UV curing types hard coating and it is coated with weatherability hard coat film obtained by the hard coating |
| CN107236449B (en) * | 2016-03-29 | 2018-06-29 | 沙河市湡久新材料有限公司 | UV curing types hard coating and weatherability hard coat film obtained by being coated with the hard coating |
| CN106497183A (en) * | 2016-10-26 | 2017-03-15 | 江苏怡丽科姆新材料股份有限公司 | A kind of low rainbow line oil-stain-preventing cured film |
| CN106497183B (en) * | 2016-10-26 | 2021-03-26 | 江苏怡丽科姆新材料股份有限公司 | Low-rainbow-grain oil-stain-resistant hardened film |
| CN107226920B (en) * | 2017-07-12 | 2020-02-04 | 中物院成都科学技术发展中心 | Preparation method of photo-curing type super-hydrophobic composite membrane |
| CN107226920A (en) * | 2017-07-12 | 2017-10-03 | 中物院成都科学技术发展中心 | A kind of preparation method of light-cured type super-hydrophobic composite film |
| CN112236493A (en) * | 2018-04-06 | 2021-01-15 | 欧提腾股份有限公司 | Flexible and foldable abrasion resistant photopatternable silicone hardcoats |
| CN109913055B (en) * | 2019-03-01 | 2020-05-22 | 西安交通大学 | Preparation method of nano modified film material for improving electric resistance of polymer insulation edge surface |
| CN109913055A (en) * | 2019-03-01 | 2019-06-21 | 西安交通大学 | It is a kind of improve polymer insulation along the face rice of resistance to susceptance modified membrane preparation method |
| CN113661218B (en) * | 2019-07-02 | 2022-06-03 | 昆山联滔电子有限公司 | Product with protective coating and preparation method thereof |
| US11801529B2 (en) | 2019-07-02 | 2023-10-31 | Kunshan Liantao Electronic Co., Ltd. | Product for preventing deterioration of adhesive layer and manufacturing method thereof |
| CN111526684A (en) * | 2019-07-02 | 2020-08-11 | 昆山联滔电子有限公司 | Product for preventing adhesive layer from deterioration and manufacturing method thereof |
| CN113661218A (en) * | 2019-07-02 | 2021-11-16 | 昆山联滔电子有限公司 | Product with protective coating and preparation method thereof |
| CN110484129B (en) * | 2019-07-02 | 2022-01-25 | 昆山联滔电子有限公司 | Product with protective coating and preparation method thereof |
| US11904351B2 (en) | 2019-07-02 | 2024-02-20 | Lanto Electronic Limited | Product with protective coating and manufacturing method thereof |
| CN110720666A (en) * | 2019-07-02 | 2020-01-24 | 昆山联滔电子有限公司 | Aerosol delivery device |
| CN110720666B (en) * | 2019-07-02 | 2022-06-14 | 昆山联滔电子有限公司 | Aerosol delivery device |
| CN110511415A (en) * | 2019-08-30 | 2019-11-29 | 华南理工大学 | Using epoxy soybean oil acrylate as waterproof starch film of coating and preparation method thereof |
| CN111962049A (en) * | 2020-08-26 | 2020-11-20 | 佛山市思博睿科技有限公司 | Plasma chemical vapor deposition nano super-hydrophobic coating and preparation method thereof |
| CN111962049B (en) * | 2020-08-26 | 2023-06-27 | 佛山市思博睿科技有限公司 | Nanometer super-hydrophobic coating by plasma chemical vapor deposition and preparation method thereof |
| CN112752474A (en) * | 2020-10-30 | 2021-05-04 | 天津七所精密机电技术有限公司 | Wetting modification processing method for case body and high-protection reinforced electronic equipment |
| CN112752474B (en) * | 2020-10-30 | 2022-05-10 | 天津七所精密机电技术有限公司 | Wetting modification processing method for case body and high-protection reinforced electronic equipment |
| CN116716034A (en) * | 2023-05-24 | 2023-09-08 | 华东理工大学华昌聚合物有限公司 | Flame-retardant super-hydrophobic coating and application method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102294851A (en) | Hydrophobic scratch-resistant coating on organic polymer surface and preparation method thereof | |
| CN105802483B (en) | A kind of double curing coating and preparation method and application | |
| CN105176371B (en) | Ultraviolet-curing paint and preparation method and ultra-hydrophilic transparent antifogging coating and preparation method | |
| KR100325530B1 (en) | Functional coated articles, method of their production, and application thereof | |
| CN1984970B (en) | Multi-layer coatings and related methods | |
| CN101307194B (en) | Organic-inorganic hybridization ultraviolet cured paint for protecting metallic surface | |
| CN101679598B (en) | Method for the production of a coating material | |
| CN110358340B (en) | Ultra-wear-resistant curtain coating UV coating and preparation method and application thereof | |
| CN104419234B (en) | Cured composition, cured product thereof, hard primer and hard coating | |
| CN107236425B (en) | Self-cleaning ultraviolet curing transparent heat-insulating coating and preparation method thereof | |
| CN105907287B (en) | UV resistance anti-dazzle anti-fingerprint hardening masking liquid composition, coating and preparation method thereof | |
| CN102304204A (en) | Fluorine-containing bi-functional microspheres and application thereof | |
| WO1998041589A1 (en) | Antifouling silicone emulsion coating composition, process for producing the same and antifouling article coated therewith | |
| CN101338086A (en) | Organic-inorganic hybridization coating cured by photothermal for protecting metallic surface | |
| CN104761934A (en) | Antimicrobial non-viscous aqueous inorganic nano coating finishing paint and application thereof | |
| CN109897503A (en) | A kind of normal temperature cure modifying epoxy resin by organosilicon coating and the preparation method and application thereof | |
| CN106905837A (en) | A kind of preparation method of the antifouling anti-fingerprint resin coating film of photo-cured fluorine-containing | |
| CN106675133A (en) | High-hardness acrylate-modified polysiloxane resin and coating employing high-hardness acrylate-modified polysiloxane resin as base material | |
| CN107207906A (en) | For the resin combination of hard conating and including hard coat film of its cured form as coating | |
| CN107033296A (en) | Extra-weather-proof polysiloxane-modified acrylic resin and finish paint preparation method | |
| CN108047924A (en) | It is a kind of to strengthen weather-proof coating varnish and preparation method and application | |
| WO2012086723A1 (en) | Contamination-resistant coating composition with excellent durability | |
| CN104910756A (en) | Modified nanometer titanium dioxide ultraviolet-curable coating | |
| CN112300393B (en) | Polysiloxane resins, coating compositions containing them and their use | |
| CN108239296A (en) | Hydrophobic rain-proof film of vehicle rearview mirror and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20111228 |