CN102294470A - Anti-blocking type long water gap bowl part - Google Patents

Anti-blocking type long water gap bowl part Download PDF

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Publication number
CN102294470A
CN102294470A CN201110242954XA CN201110242954A CN102294470A CN 102294470 A CN102294470 A CN 102294470A CN 201110242954X A CN201110242954X A CN 201110242954XA CN 201110242954 A CN201110242954 A CN 201110242954A CN 102294470 A CN102294470 A CN 102294470A
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Prior art keywords
parts
type long
long nozzle
block
proof type
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CN201110242954XA
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CN102294470B (en
Inventor
邵建新
沈梅方
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HUZHOU YONGLIAN FIREPROOF MATERIAL CO Ltd
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HUZHOU YONGLIAN FIREPROOF MATERIAL CO Ltd
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Abstract

The invention discloses an anti-blocking type long water gap bowl part, which is made of the following materials in parts by weight: 8 parts of stabilized zirconia, 8-10 parts of electric fused zirconium mullite, 10-30 parts of tabular corundum, 10-30 parts of electric fused white corundum, 4-5 parts of crystalline flake graphite, 6 parts of light-burned alumina, 1 part of carborundum, 0.5 part of metal magnesium powder, 0.5 part of silicon metal, 10 parts of magnesia-alumina spinel, 8-10 parts of light refractory clay and 10-13 parts of liquid resin, wherein the sum of the parts by weight of the tabular corundum and the electric fused white corundum is 40 parts. The anti-blocking type long water gap bowl part disclosed by the invention has a reasonable formula, a good high temperature performance and strong anti-erosion ability, does not rupture or drop in a long time use process, and can not block a through hole of a long water gap, and simultaneously the sealing performance between the anti-blocking type long water gap bowl part and a carbon-aluminum stopper rod can not be affected, so the service life of the anti-blocking type long water gap bowl part is longer.

Description

Block-proof type long nozzle bowl portion
Technical field
The present invention relates to the steel-making continuous casting technical field, relate to the block-proof type long nozzle bowl portion that molten steel in the casting process is used from tundish to the crystallizer process in particular.
Background technology
In the process of continuous casting, need in the injection crystallizer with the molten steel continous-stable in the tundish, in this process, the use that matches of long nozzle and aluminium carbon stopper, when beginning casting time is unwrapped in the centre, aluminium carbon stopper is extracted from long nozzle bowl portion, make molten steel between long nozzle bowl portion and aluminium carbon stopper, flow into long nozzle, the rising that aluminium carbon stopper need not stop, descend, to regulate the gap between itself and the long nozzle bowl portion, and then adjustment enters the flow of molten steel, having very big scouring force between aluminium carbon stopper and the long nozzle bowl portion in this process (is caused by molten steel, the gap is more little, scouring force is big more), and existing long nozzle bowl portion stable material quality is poor, burst, peeling phenomenon takes place, so in a short period of time, can cause the damage of long nozzle bowl portion, cause long nozzle to stop up, perhaps phenomenon such as the uncontrollable flow of long nozzle causes tundish to stop watering, the tundish that more renews, and the refractory material price of tundish units up to ten thousand at least so not only cause the increase of steel mill's production cost, the more important thing is the ordinary production that also influences steel mill.
Summary of the invention
The objective of the invention is at the deficiencies in the prior art part, a kind of block-proof type long nozzle bowl portion be provided, its abrasion resistance by force, do not burst, do not peel off, long service life.
Technology solution of the present invention is as follows:
Block-proof type long nozzle bowl portion is made of following materials in weight portion:
8 parts of stabilizing zirconias;
Fused zirconia-mullite 8-10 part;
Plate diamond spar 10-30 part, fused white corundum 10-30 part; Described plate diamond spar and fused white corundum weight portion sum are 40 parts;
Crystalline flake graphite 4-5 part;
6 parts of calcined aluminas;
1 part in carborundum;
0.5 part of metal magnesium powder;
0.5 part of metallic silicon;
10 parts of magnesium aluminate spinels;
Light-weight refractory clay 8-10 part;
Liquid resin 10-13 part.
Described block-proof type long nozzle bowl portion, described liquid resin is a liquid phenolic resin.
Described block-proof type long nozzle bowl portion, 20 parts of described plate diamond spars, 20 parts of fused white corundums.
Described block-proof type long nozzle bowl portion, described crystalline flake graphite is 4 parts.
Described block-proof type long nozzle bowl portion, described light-weight refractory clay is 8 parts.
Beneficial effect of the present invention is: block-proof type long nozzle bowl of the present invention portion, its prescription rationally, antiscour, strong shock resistance, do not burst, do not peel off, long-time use can not stopped up the aperture of long nozzle, does not influence the sealing between block-proof type long nozzle bowl portion and the aluminium carbon stopper yet, and therefore the life-span of using is long, reduced the cost in steel mill's use, also guarantee the carrying out of the ordinary production of steel mill, saved the consumption of tundish refractory material, also saved the consumption of resource.
The specific embodiment
The following stated is preferred embodiment of the present invention only, is not that scope of the present invention is limited.
Embodiment 1, and block-proof type long nozzle bowl portion is made of following materials in weight portion:
Stabilizing zirconia 8kg;
Fused zirconia-mullite 8 kg;
Plate diamond spar 20 kg;
Fused white corundum 20 kg;
Crystalline flake graphite 4 kg;
Calcined alumina 6 kg;
Carborundum 1 kg;
Metal magnesium powder 0.5 kg;
Metallic silicon 0.5 kg;
Magnesium aluminate spinel 10 kg;
Light-weight refractory clay 8 kg;
After the above-mentioned material mixing, add liquid phenolic resin 10 kg, stir, phenolic resins plays the effect of adhesive, then mixed material is placed into and utilizes press compression moulding in the mould, the block-proof type long nozzle bowl portion with compression moulding carries out the drying processing again.
Embodiment 2, and block-proof type long nozzle bowl portion is made of following materials in weight portion:
Stabilizing zirconia 8kg;
Fused zirconia-mullite 8 kg;
Plate diamond spar 20 kg;
Fused white corundum 20 kg;
Crystalline flake graphite 4 kg;
Calcined alumina 6 kg;
Carborundum 1 kg;
Metal magnesium powder 0.5 kg;
Metallic silicon 0.5 kg;
Magnesium aluminate spinel 10 kg;
Light-weight refractory clay 10kg;
After the above-mentioned material mixing, add liquid phenolic resin 10 kg, stir, phenolic resins plays the effect of adhesive, then mixed material is placed into and utilizes press compression moulding in the mould, the block-proof type long nozzle bowl portion with compression moulding carries out the drying processing again.
Embodiment 3, and block-proof type long nozzle bowl portion is made of following materials in weight portion:
Stabilizing zirconia 8kg;
Fused zirconia-mullite 10 kg parts;
Plate diamond spar 10 kg;
Fused white corundum 30 kg;
Crystalline flake graphite 4 kg;
Calcined alumina 6 kg;
Carborundum 1 kg;
Metal magnesium powder 0.5 kg;
Metallic silicon 0.5 kg;
Magnesium aluminate spinel 10 kg;
Light-weight refractory clay 8kg;
After the above-mentioned material mixing, add liquid phenolic resin 10 kg, stir, phenolic resins plays the effect of adhesive, then mixed material is placed into and utilizes press compression moulding in the mould, the block-proof type long nozzle bowl portion with compression moulding carries out the drying processing again.
Embodiment 4, and block-proof type long nozzle bowl portion is made of following materials in weight portion:
Stabilizing zirconia 8kg;
Fused zirconia-mullite 10 kg;
Plate diamond spar 30 kg;
Fused white corundum 10 kg;
Crystalline flake graphite 4 kg;
Calcined alumina 6 kg;
Carborundum 1 kg;
Metal magnesium powder 0.5 kg;
Metallic silicon 0.5 kg;
Magnesium aluminate spinel 10 kg;
Light-weight refractory clay 8kg;
After the above-mentioned material mixing, add liquid phenolic resin 10 kg, stir, phenolic resins plays the effect of adhesive, then mixed material is placed into and utilizes press compression moulding in the mould, the block-proof type long nozzle bowl portion with compression moulding carries out the drying processing again.
Embodiment 5, and block-proof type long nozzle bowl portion is made of following materials in weight portion:
Stabilizing zirconia 8kg;
Fused zirconia-mullite 8 kg parts;
Plate diamond spar 30 kg;
Fused white corundum 10 kg;
Crystalline flake graphite 4kg;
Calcined alumina 6 kg;
Carborundum 1kg;
Metal magnesium powder 0.5 kg;
Metallic silicon 0.5 kg;
Magnesium aluminate spinel 10 kg;
Light-weight refractory clay 8kg;
After the above-mentioned material mixing, add liquid phenolic resin 10 kg, stir, phenolic resins plays the effect of adhesive, then mixed material is placed into and utilizes press compression moulding in the mould, the block-proof type long nozzle bowl portion with compression moulding carries out the drying processing again.
Embodiment 6, and block-proof type long nozzle bowl portion is made of following materials in weight portion:
Stabilizing zirconia 8kg;
Fused zirconia-mullite 8 kg parts;
Plate diamond spar 10 kg;
Fused white corundum 30 kg;
Crystalline flake graphite 4kg;
Calcined alumina 6 kg;
Carborundum 1kg;
Metal magnesium powder 0.5 kg;
Metallic silicon 0.5 kg;
Magnesium aluminate spinel 10 kg;
Light-weight refractory clay 8kg;
After the above-mentioned material mixing, add liquid phenolic resin 12 kg, stir, phenolic resins plays the effect of adhesive, then mixed material is placed into and utilizes press compression moulding in the mould, the block-proof type long nozzle bowl portion with compression moulding carries out the drying processing again.
Embodiment 7, and block-proof type long nozzle bowl portion is made of following materials in weight portion:
Stabilizing zirconia 8kg;
Fused zirconia-mullite 10 kg parts;
Plate diamond spar 30 kg;
Fused white corundum 10 kg;
Crystalline flake graphite 5kg;
Calcined alumina 6 kg;
Carborundum 1kg;
Metal magnesium powder 0.5 kg;
Metallic silicon 0.5 kg;
Magnesium aluminate spinel 10 kg;
Light-weight refractory clay 8kg;
After the above-mentioned material mixing, add liquid phenolic resin 12 kg, stir, phenolic resins plays the effect of adhesive, then mixed material is placed into and utilizes press compression moulding in the mould, the block-proof type long nozzle bowl portion with compression moulding carries out the drying processing again.
Embodiment 8, and block-proof type long nozzle bowl portion is made of following materials in weight portion:
Stabilizing zirconia 8kg;
Fused zirconia-mullite 10 kg parts;
Plate diamond spar 30 kg;
Fused white corundum 10 kg;
Crystalline flake graphite 5kg;
Calcined alumina 6 kg;
Carborundum 1kg;
Metal magnesium powder 0.5 kg;
Metallic silicon 0.5 kg;
Magnesium aluminate spinel 10 kg;
Light-weight refractory clay 10kg;
After the above-mentioned material mixing, add liquid phenolic resin 12 kg, stir, phenolic resins plays the effect of adhesive, then mixed material is placed into and utilizes press compression moulding in the mould, the block-proof type long nozzle bowl portion with compression moulding carries out the drying processing again.
Embodiment 9, and block-proof type long nozzle bowl portion is made of following materials in weight portion:
Stabilizing zirconia 8kg;
Fused zirconia-mullite 10 kg parts;
Plate diamond spar 30 kg;
Fused white corundum 10 kg;
Crystalline flake graphite 5kg;
Calcined alumina 6 kg;
Carborundum 1kg;
Metal magnesium powder 0.5 kg;
Metallic silicon 0.5 kg;
Magnesium aluminate spinel 10 kg;
Light-weight refractory clay 8kg;
After the above-mentioned material mixing, add liquid phenolic resin 13 kg, stir, phenolic resins plays the effect of adhesive, then mixed material is placed into and utilizes press compression moulding in the mould, the block-proof type long nozzle bowl portion with compression moulding carries out the drying processing again.
Embodiment 10, and block-proof type long nozzle bowl portion is made of following materials in weight portion:
Stabilizing zirconia 8kg;
Fused zirconia-mullite 10 kg parts;
Plate diamond spar 20 kg;
Fused white corundum 20 kg;
Crystalline flake graphite 5kg;
Calcined alumina 6 kg;
Carborundum 1kg;
Metal magnesium powder 0.5 kg;
Metallic silicon 0.5 kg;
Magnesium aluminate spinel 10 kg;
Light-weight refractory clay 10kg;
After the above-mentioned material mixing, add liquid phenolic resin 13 kg, stir, phenolic resins plays the effect of adhesive, then mixed material is placed into and utilizes press compression moulding in the mould, the block-proof type long nozzle bowl portion with compression moulding carries out the drying processing again.
Material composition for this block-proof type of more intuitive understanding long nozzle bowl portion, existing subordinate list is as follows, wherein, the content of subordinate list 1 is each material that constitutes block-proof type long nozzle bowl portion among the embodiment 1-5, and subordinate list 2 is each material that constitutes block-proof type long nozzle bowl portion among the embodiment 6-10.
Subordinate list 1:
Material Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Stabilizing zirconia 8 kg 8 kg 8 kg 8 kg 8 kg
Fused zirconia-mullite 8 kg 8 kg 10kg 10 kg 8 kg
Plate diamond spar 20kg 20kg 10kg ?30kg ?30kg
Fused white corundum 20kg 20kg 30kg ?10kg ?10kg
Crystalline flake graphite 4kg 4kg 4kg 4kg 4kg
Calcined alumina 6kg 6kg 6kg 6kg 6kg
Carborundum 1kg 1kg 1kg 1kg 1kg
Metal magnesium powder 0.5kg 0.5kg 0.5kg 0.5kg 0.5kg
Metallic silicon 0.5kg 0.5kg 0.5kg 0.5kg 0.5kg
Magnesium aluminate spinel 10kg 10kg 10kg 10kg 10kg
The light-weight refractory clay 8kg 10kg 8kg 8kg 8kg
Phenolic resins 10kg 10kg 10kg 10kg 10kg
Service time 22 hours 22 hours 21 hours 21 hours 21.5 hour
Subordinate list 2:
Material Embodiment 6 Embodiment 7 Embodiment 8 Embodiment 9 Embodiment 10
Stabilizing zirconia 8 kg 8 kg 8 kg 8 kg 8 kg
Fused zirconia-mullite 8 kg 10 kg 10 kg 10 kg 10 kg
Plate diamond spar ?10kg ?30kg ?30kg ?30kg ?20kg
Fused white corundum ?30kg ?10kg ?10kg ?10kg ?20kg
Crystalline flake graphite 4kg 4kg 5kg 5kg 5kg
Calcined alumina 6kg 6kg 6kg 6kg 6kg
Carborundum 1kg 1kg 1kg 1kg 1kg
Metal magnesium powder 0.5kg 0.5kg 0.5kg 0.5kg 0.5kg
Metallic silicon 0.5kg 0.5kg 0.5kg 0.5kg 0.5kg
Magnesium aluminate spinel 10kg 10kg 10kg 10kg 10kg
The light-weight refractory clay 8kg 8kg 10kg 8kg 10kg
Phenolic resins 12kg 12kg 12kg 13kg 13kg
Service time 21.5 hour 21.5 hour 20 hours 20 hours 20 hours

Claims (5)

1. block-proof type long nozzle bowl portion is characterized in that being made of following materials in weight portion:
8 parts of stabilizing zirconias;
Fused zirconia-mullite 8-10 part;
Plate diamond spar 10-30 part, fused white corundum 10-30 part; Described plate diamond spar and fused white corundum weight portion sum are 40 parts;
Crystalline flake graphite 4-5 part;
6 parts of calcined aluminas;
1 part in carborundum;
0.5 part of metal magnesium powder;
0.5 part of metallic silicon;
10 parts of magnesium aluminate spinels;
Light-weight refractory clay 8-10 part;
Liquid resin 10-13 part.
2. block-proof type long nozzle bowl according to claim 1 portion, it is characterized in that: described liquid resin is a liquid phenolic resin.
3. block-proof type long nozzle bowl according to claim 1 and 2 portion is characterized in that: 20 parts of described plate diamond spars, 20 parts of fused white corundums.
4. block-proof type long nozzle bowl according to claim 1 and 2 portion, it is characterized in that: described crystalline flake graphite is 4 parts.
5. block-proof type long nozzle bowl according to claim 1 and 2 portion, it is characterized in that: described light-weight refractory clay is 8 parts.
CN 201110242954 2011-08-23 2011-08-23 Anti-blocking type long water gap bowl part Active CN102294470B (en)

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Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 201110242954 CN102294470B (en) 2011-08-23 2011-08-23 Anti-blocking type long water gap bowl part

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CN102294470A true CN102294470A (en) 2011-12-28
CN102294470B CN102294470B (en) 2013-08-28

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104439229A (en) * 2014-12-25 2015-03-25 武汉科技大学 Sandwich type long nozzle sealing piece and manufacturing method thereof
CN105364061A (en) * 2012-11-22 2016-03-02 郑州思辩科技有限公司 Carbon-free submerged nozzle
CN109422530A (en) * 2017-08-24 2019-03-05 宝山钢铁股份有限公司 It is a kind of to prevent from opening the long water gap bowl part for pouring fracture
CN114075080A (en) * 2020-10-27 2022-02-22 上海劲远高温材料有限公司 Molding ultrahigh-temperature ceramic sealing gasket for steel-making submerged nozzle and preparation method thereof

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CN101927340A (en) * 2010-05-17 2010-12-29 王世泰 Aluminium (zirconium)-carbon long nozzle, submerged entry nozzle and monolithic stopper refractory products for continuous casting

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CN101712558A (en) * 2009-05-25 2010-05-26 上海宝明耐火材料有限公司 Stopper rod head and immersion water gap bowl material for continuous casting
CN101927340A (en) * 2010-05-17 2010-12-29 王世泰 Aluminium (zirconium)-carbon long nozzle, submerged entry nozzle and monolithic stopper refractory products for continuous casting

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105364061A (en) * 2012-11-22 2016-03-02 郑州思辩科技有限公司 Carbon-free submerged nozzle
CN104439229A (en) * 2014-12-25 2015-03-25 武汉科技大学 Sandwich type long nozzle sealing piece and manufacturing method thereof
CN109422530A (en) * 2017-08-24 2019-03-05 宝山钢铁股份有限公司 It is a kind of to prevent from opening the long water gap bowl part for pouring fracture
CN109422530B (en) * 2017-08-24 2022-02-22 宝山钢铁股份有限公司 Prevent to open cracked long mouth of a river bowl portion of watering
CN114075080A (en) * 2020-10-27 2022-02-22 上海劲远高温材料有限公司 Molding ultrahigh-temperature ceramic sealing gasket for steel-making submerged nozzle and preparation method thereof

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