CN102290579A - Pure-lead colloid storage battery - Google Patents

Pure-lead colloid storage battery Download PDF

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Publication number
CN102290579A
CN102290579A CN2011102056900A CN201110205690A CN102290579A CN 102290579 A CN102290579 A CN 102290579A CN 2011102056900 A CN2011102056900 A CN 2011102056900A CN 201110205690 A CN201110205690 A CN 201110205690A CN 102290579 A CN102290579 A CN 102290579A
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CN
China
Prior art keywords
pure
positive
negative
storage battery
lead
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Pending
Application number
CN2011102056900A
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Chinese (zh)
Inventor
王金生
周庆申
曹岁平
刘刚
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Shandong Sacred Sun Power Sources Co Ltd
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Shandong Sacred Sun Power Sources Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Shandong Sacred Sun Power Sources Co Ltd filed Critical Shandong Sacred Sun Power Sources Co Ltd
Priority to CN2011102056900A priority Critical patent/CN102290579A/en
Publication of CN102290579A publication Critical patent/CN102290579A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

The invention relates to the field of lead-acid storage batteries, in particular to a pure-lead colloid storage battery, which mainly comprises a case, positive grids, positive plates, negative grids, negative plates, silicon-phosphor colloid electrolyte and partitions between the positive plates and the negative plates, pure-lead plates are adopted as the positive grids and the negative grids, the partitions are made of PVC (polyvinyl chloride) and nano silica polymer porous material, the diameter of the pore is 1Mu m to 10Mu m, moreover, a glass fiber adsorption layer is attached on the surface of the partition, which is opposite to the positive grid, and the thickness is 1.5mm to 2.0mm. The pure-lead colloid storage battery has the advantages that: since the pure-lead thin electrode plate design is adopted, the pure-lead colloid storage battery has the characteristics of wide working temperature range, long cycle life under the partial state of charge, excellent high-current charge acceptance, environment-friendliness, little internal resistance and good charge acceptance, and is mainly used in fields such as short-time high-power standby, a great deal of rapid and constant charging and discharging and the like.

Description

A kind of pure plumbous colloid storage battery
Technical field
The present invention relates to lead acid accumulator, is a kind of pure plumbous colloid storage battery more specifically.
Background technology
At present, storage battery commonly used is the AGM lead acid accumulator, this battery liquid overflows easily, the corrosion terminal, contaminated environment, and it is short etc. to recycle the life-span, in order to overcome above-mentioned defective, patent ZL92104882.3 discloses a kind of colloid storage battery and preparation method thereof, though this colloidal electrolyte has replaced mobile sulfuric acid electrolyte, the problems such as some leakages of AGM storage battery have been solved, the heavy-current discharge of battery, reserve capabillity is not ideal enough, patent ZL01259212.9 is also arranged, solved charge acceptance, the problem of large current discharging capability and capacity reserve ability, publication number is: it is quick that CN1503393A has solved self discharge, the problem that useful life is short, in the evolution, occurred some patents about the colloid battery new technology again afterwards, the colloid battery technology is improved once more and improves.But colloid storage battery still exists following two large problems not solve: 1, the designing material cost is 1.5~2 times of AGM battery, is difficult to be accepted by common carrier and commercial market; 2, colloid storage battery is because of thick plate designs, reason such as PVC dividing plate porosity is low and fixedly the colloidal electrolyte internal resistance is big, and big multiplying power discharging property is poor in the storage battery, is not suitable in uses of getting the market in gear such as high power ups system and vehicle, boats and ships.So far also there is not effective technology to solve above two large problems.
Summary of the invention
The purpose of this invention is to provide the defective that can overcome existing colloid storage battery design and performance existence, adopt the corrosion-resistant thin plate designs of pure lead, the heavy-current discharge performance excellence, material cost reduces, and can satisfy a kind of pure plumbous colloid storage battery that use in fields such as communication, electric power, solar energy storage, UPS, boats and ships simultaneously.
The present invention realizes in the following way: a kind of pure plumbous colloid storage battery, mainly comprise the dividing plate between housing, positive grid, positive plate, negative grid, negative plate, silicon phosphorus micelle colloid electrolyte and positive plate and the negative plate, it is characterized in that positive grid, negative grid all adopt pure stereotype; Dividing plate is PVC and nano silicon mixture poromerics, micro-pore diameter 1~10um, and on the surface of its relative anode plate grid with the glass fibre adsorption layer, thickness is 1.5~2.0mm.
Particularly, described positive grid, negative slab lattice thickness are 0.8~2.2mm; Positive plate, negative plate thickness are 1.0~2.6mm.
Described silicon phosphorus micelle colloid electrolyte comprises following components in weight percentage: nano-silica powder end 10~20%, and adsorbent 0.3~0.8%, stabilizer 3~8%, additive 0.1~0.3%, surplus is acid and water.
The invention has the beneficial effects as follows: adopt pure lead to approach the plate designs technology, guarantee the decay resistance of pole plate and discharge and recharge reaction efficiency, reduce the design direct material cost, big multiplying power discharging ability in the raising.Solved existing colloid storage battery material cost height, heavy-current discharge performance poor, can not satisfy the defective that the high-multiplying power discharge occasion is used; Have battery operated temperature range wide (40 ℃~65 ℃), part under charged recycle the life-span long, the large current charge receiving ability is superior, environmental protection no leakage, internal resistance is little, charge acceptance is good characteristics, being mainly used in needs the short time high power standby, fast and continue to discharge and recharge in a large number and field uses such as satisfied communication, electric power, solar energy storage, UPS, boats and ships.
Description of drawings
Fig. 1 partly cuts open schematic diagram for the present invention assembles;
Fig. 2 is positive/negative plate of the present invention, dividing plate assembly drawing.
Among the figure, 1. negative plate, 2. dividing plate, 3. positive plate.
Embodiment
A kind of pure plumbous colloid storage battery mainly comprises square casing, positive grid, positive plate 3, negative grid, negative plate 1, silicon phosphorus micelle colloid electrolyte; Clamped PVC dividing plate 2 between positive plate 3, the negative plate 1, and all be coated with barrier film near anodal surface; Positive slab lattice thickness 2.0mm, negative slab lattice thickness 1.0mm all adopts pure stereotype; Positive plate 3 thickness are 2.4mm, and negative plate 1 thickness is 1.4mm; Dividing plate 2 is PVC and nano silicon polymer microporous material, and has the glass fibre adsorption layer on the surface of its relative anode plate grid, and thickness is 1.8mm; Silicon phosphorus micelle colloid electrolyte comprises following components in weight percentage: nano-silica powder end 18%, and adsorbent 0.5%, stabilizer 4%, additive 0.2%, surplus is acid and water.

Claims (3)

1. a pure plumbous colloid storage battery mainly comprises the dividing plate between housing, positive grid, positive plate, negative grid, negative plate, silicon phosphorus micelle colloid electrolyte and positive plate and the negative plate, it is characterized in that positive grid, negative grid all adopt pure stereotype; Dividing plate is PVC and nano silicon polymer microporous material, micro-pore diameter 1~10um, and on the surface of its relative anode plate grid with the glass fibre adsorption layer, thickness is 1.5~2.0mm.
2. a kind of pure plumbous colloid storage battery as claimed in claim 1 is characterized in that described positive grid, negative slab lattice thickness are 0.8~2.2mm; Positive plate, negative plate thickness are 1.0~2.6mm.
3. a kind of pure plumbous colloid storage battery as claimed in claim 1, it is characterized in that described silicon phosphorus micelle colloid electrolyte comprises following components in weight percentage: nano-silica powder end 10~20%, adsorbent 0.3~0.8%, stabilizer 3~8%, additive 0.1~0.3%, surplus are acid and water.
CN2011102056900A 2011-07-15 2011-07-15 Pure-lead colloid storage battery Pending CN102290579A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011102056900A CN102290579A (en) 2011-07-15 2011-07-15 Pure-lead colloid storage battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011102056900A CN102290579A (en) 2011-07-15 2011-07-15 Pure-lead colloid storage battery

Publications (1)

Publication Number Publication Date
CN102290579A true CN102290579A (en) 2011-12-21

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110931690A (en) * 2019-11-13 2020-03-27 江苏长海复合材料股份有限公司 Colloid battery separator sheet and preparation method thereof
CN112436196A (en) * 2020-11-23 2021-03-02 旭派电源有限公司 Lead-carbon energy storage battery

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0645001A (en) * 1992-07-27 1994-02-18 Shin Kobe Electric Mach Co Ltd Electrolytic for lead-acid battery
CN1797834A (en) * 2004-12-23 2006-07-05 钟发平 Colloid lead-cloth batteries in high energy, and preparation method
CN201345380Y (en) * 2008-12-31 2009-11-11 湖北骆驼蓄电池股份有限公司 Pure lead thin polar plate lead-acid storage battery

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0645001A (en) * 1992-07-27 1994-02-18 Shin Kobe Electric Mach Co Ltd Electrolytic for lead-acid battery
CN1797834A (en) * 2004-12-23 2006-07-05 钟发平 Colloid lead-cloth batteries in high energy, and preparation method
CN201345380Y (en) * 2008-12-31 2009-11-11 湖北骆驼蓄电池股份有限公司 Pure lead thin polar plate lead-acid storage battery

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110931690A (en) * 2019-11-13 2020-03-27 江苏长海复合材料股份有限公司 Colloid battery separator sheet and preparation method thereof
CN112436196A (en) * 2020-11-23 2021-03-02 旭派电源有限公司 Lead-carbon energy storage battery

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Application publication date: 20111221