CN102285767B - Vacuum glass comprising metal edges and preparation method thereof - Google Patents

Vacuum glass comprising metal edges and preparation method thereof Download PDF

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Publication number
CN102285767B
CN102285767B CN2011101495722A CN201110149572A CN102285767B CN 102285767 B CN102285767 B CN 102285767B CN 2011101495722 A CN2011101495722 A CN 2011101495722A CN 201110149572 A CN201110149572 A CN 201110149572A CN 102285767 B CN102285767 B CN 102285767B
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CN
China
Prior art keywords
metal
vacuum
glass
plate
welding
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Expired - Fee Related
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CN2011101495722A
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Chinese (zh)
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CN102285767A (en
Inventor
朱雷
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Nanjing Chengyuan Solar Heating Co ltd
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Individual
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Priority to CN2011101495722A priority Critical patent/CN102285767B/en
Priority to PCT/CN2011/076506 priority patent/WO2012162921A1/en
Publication of CN102285767A publication Critical patent/CN102285767A/en
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Publication of CN102285767B publication Critical patent/CN102285767B/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06Joining glass to glass by processes other than fusing
    • C03C27/08Joining glass to glass by processes other than fusing with the aid of intervening metal
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/6612Evacuated glazing units
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/663Elements for spacing panes
    • E06B3/66309Section members positioned at the edges of the glazing unit
    • E06B3/66371Section members positioned at the edges of the glazing unit positioned entirely outside the gap between the panes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/24Structural elements or technologies for improving thermal insulation
    • Y02A30/249Glazing, e.g. vacuum glazing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B80/00Architectural or constructional elements improving the thermal performance of buildings
    • Y02B80/22Glazing, e.g. vaccum glazing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Joining Of Glass To Other Materials (AREA)

Abstract

The invention relates to vacuum glass comprising metal edges and a preparation method thereof. The vacuum glass comprises upper and lower layers of flat plates, wherein a supporting body is arranged between the upper and lower layers of the flat plates, and the periphery is sealed and vacuumized to form a vacuum sealed cavity. The vacuum glass is characterized in that the two layers of the flat plates are glass flat plates with consistent geometrical shapes, or one layer of the flat plate is a glass flat plate and the other layer of the flat plate is a metal flat plate with a consistent geometrical shape; integrated metal belts are bonded at the periphery of the glass flat plate, the thickness of the metal belts is 0.03-1.5 mm, and the metal belts extend outwards and exceed the peripheral edges of the glass flat plate; and the periphery sealing is realized by sealed welding of the peripheral metal belts between the two layers of the flat plates, or the metal belts and the metal flat plate, or the metal belts and peripheral metal frames with rectangular profile cross sections between the two layers of the flat plates.

Description

Contain vacuum glass of metal edges and preparation method thereof
Technical field
The present invention relates to a kind of vacuum glass and preparation method thereof, especially a kind of vacuum glass that contains metal edges and preparation method thereof.
Background technology
The concept of vacuum glass appears at an external patent documentation in 1913 the earliest, until the eighties in 20th century is just active gradually to its research, July calendar year 2001, Xi'an friendship Da Deng is grand flies to wait the people to deliver the research experiment achievement, claims to adopt 0.8mm special glass to make 4 * 4mm 2Support manufacturing 500 * 500mm 2Area vacuum glass, and carried out the solar energy heating experiment, " solar collecting performance is more superior than double glazing, and heat-collecting temperature is higher 15~30 ℃ than double glazing "; Beijing Xin Liji vacuum glass company claims, under the guidance of the Tang Jianya of Peking University professor (once participating in vacuum glass research in the Sydney University), do support with metal, can produce the area vacuum glass of different size, its vacuum glass adopts glass powder with low melting point to melt, and two sheet glass are bonding, belongs to positiver sealing and connects.
Which kind of vacuum glass no matter, their peripheral sealing is all generally to adopt inorganic materials, as adopt the low melting glass bonding mode, because organic materials is easily aging, directly have influence on the work-ing life of vacuum glass, and adopt the low melting glass bonding mode to produce vacuum glass, belong to positiver sealing glass, the two-sided temperature difference that can bear is generally 60 degree, the highest can not spending over 80.The temperature difference is too high, can cause vacuum glass to occur bursting.The sealing material of How to choose circumference of vacuum glass is the long-term focus of paying close attention in this area always.
In addition, adopt flexible materials or low melting glass as sealing material at circumference of vacuum glass, the periphery of vacuum glass is not all had rigid protective, especially toughened vacuum glass in carrying and the process of installing, also easily makes area vacuum glass break and burst.
Summary of the invention
The object of the invention is to, generally adopt positiver sealing for present circumference of vacuum glass, adopt the glass powder with low melting point welding, assembling and welding technique require too high, the qualification rate of product is lower, can't realize at present the manufacturing in enormous quantities of tempering safety vacuum glass glass; The ability that the vacuum glass of present vacuum rigidity edge sealing bears high temperature difference is lower, and the use field is limited; And circumference of vacuum glass lacks the protection of rigid material, in the process of carrying, very easily causes the series of problems such as damages, provide a kind of newly contain vacuum glass of metal edges and preparation method thereof.
The object of the present invention is achieved like this: a kind of vacuum glass that contains metal edges, comprise the two-layer flat board in up and down, be provided with contour supporter between two-layer flat board, the surrounding sealing vacuumizes rear formation vacuum-sealed cavity again, it is characterized in that, two-layer flat board is the consistent glass plate of geometrical shape, or one deck is glass plate, and another layer is the consistent metal plate of geometrical shape; Be the metal strip that sticks to one along the glass plate periphery, the thickness of described metal strip is 0.03~1.5mm, and metal strip stretches out, and surmounts the edge around glass plate; The sealing of described surrounding is between metal strip by two-layer dull and stereotyped periphery, or between metal strip and metal plate, or they are seal welding realization between the metal frame of rectangle with section bar cross section at two-layer dull and stereotyped periphery.
In the present invention, in described vacuum chamber, getter is set.
In the present invention, be provided with the probe of vacuum tightness detecting unit in described vacuum chamber.
A kind of preparation method of the above-mentioned vacuum glass that contains metal edges is characterized in that,
A) will meet the glass plate periphery of shape of product bonding by low melting glass and metal water stop, or plate metallic membrane at the glass plate periphery, with metal strip by with the metallic membrane welding after to form sealing bonding;
B) between the glass plate that geometrical shape is consistent, contour supporter is set evenly, or between the glass plate metal plate consistent with geometrical shape, contour supporter is set evenly;
C) along the Metal Material Welding of two-layer plate edge with corresponding sides, form annular seal space, annular seal space is reserved with vacuum orifice, vacuumizes by vacuum orifice; Described metallic substance refers to: metal strip or metal plate or cross section are that the cross section is the metal frame of rectangle;
D) after vacuumizing, vacuum orifice is sealed, form the vacuum glass that contains metal edges.
In preparation method of the present invention, described Metal Material Welding with two-layer dull and stereotyped corresponding sides refers to: the metal strip extension of the dull and stereotyped corresponding sides of layer glass is bent in opposite directions implement welding after intersecting; Or will and the metal frame of vacuum glass consistency of thickness be held between the metal strip extension of levels glass plate, with metal strip and metal frame welding; Or with the metal strip extension of glass plate to the consistent metal plate bending of geometrical shape, weld with the metal plate corresponding sides after intersecting; Or with the one side of metal frame and metal strip extension welding with glass plate, another side welds with metal plate.
In preparation method of the present invention, before forming annular seal space between with two-layer flat board, should place getter, or insert the probe of vacuum tightness detecting unit, or place simultaneously getter and insert the probe of vacuum tightness detecting unit.
In preparation method of the present invention, the section bar cross section of processing metal frame is the rectangle of hollow, in the square-section of hollow, be provided with air drain or pore towards the wall of vacuum-sealed cavity, the probe of described getter and vacuum tightness detecting unit is located at the hollow region of rectangle.
The invention has the advantages that: due to peripheral sealing employing of the present invention is metal solder, namely there is not the problem of aging of flexible materials, can absorb two glass plates by the distortion of metallic substance because the temperature difference causes the flexible inconsistent stress that produces again, prevent that planar vacuum glass is burst by high temperature difference; Due to a circle metal being arranged at circumference of vacuum glass, can reduce the damage that the collision in handling process causes; The probe of getter or vacuum tightness detecting unit is set in the vacuum chamber of vacuum glass, can guarantees the vacuum tightness in annular seal space, and can detect it, improve the reliability of vacuum glass.
Description of drawings
Fig. 1 is the cross-sectional view of a kind of embodiment of the present invention;
Fig. 2 is the cross-sectional view of another embodiment of the present invention;
Fig. 3 is the cross-sectional view of another kind of embodiment of the present invention;
Fig. 4 is the cross-sectional view of the 4th kind of embodiment of the present invention;
Fig. 5 is the cross-sectional view of the 5th kind of embodiment of the present invention;
Fig. 6 is the sectional view of a kind of bonding way between glass plate and metal strip in preparation;
Fig. 7 is the sectional view of the another kind of bonding way between glass plate and metal strip in preparation;
Fig. 8 is take Fig. 1 as example, the cross-sectional view before peripheral sealing.
In figure: 1, glass plate, 2, metal strip, 3, low temperature glass, 4, supporter, 5, vacuum-sealed cavity, 6, metal frame, 8, getter, 9, probe, 10, metal plate, 11, metallic membrane, 12, seal welding,
Embodiment
As seen from Figure 1, vacuum glass, comprise the two-layer flat board in up and down, be provided with contour supporter 4 between two-layer flat board, the surrounding sealing vacuumizes rear formation vacuum-sealed cavity 5 again, in the present embodiment, two-layer flat board is the consistent glass plate of geometrical shape 1, be the metal strip 2 that sticks to one along the glass plate periphery, described metal strip 2 stretches out, and surmounts the edge around glass plate 1; The metal strip 2 that described surrounding sealing is levels glass plate 1 periphery carries out seal welding 12 after bending in opposite directions and intersecting.
As seen from Figure 2, the difference of the present embodiment and Fig. 1 is: will and the metal frame 6 of vacuum glass 1 consistency of thickness and being held between metal strip 2 extensions of levels glass plate 1, with metal strip 2 and metal frame 6 welding, in the present embodiment, the cross section of described metal frame 6 is hollow, in the metal frame 6 of cross section hollow, be provided with air drain or pore towards annular seal space 5 one sides.
As seen from Figure 3, the difference of the present embodiment and Fig. 2 only is: in two-layer flat board, one deck is glass plate 1, and another layer is the consistent metal plate of geometrical shape 10, described metal frame 6 one sides and metal frame 6 welding, another side and metal plate 10 welding.
As seen from Figure 4, the difference of the present embodiment and Fig. 2 only is: before forming annular seal space 5 between with two-layer flat board, should place getter 8, in the present embodiment, described getter 8 is placed in metal frame 6 cavitys of hollow.
As seen from Figure 5, the difference of the present embodiment and Fig. 4 only is: not only be provided with getter 8 in metal frame 6 cavitys of hollow, also be provided with the probe 9 of vacuum tightness detecting unit.
The basic preparation method of the various embodiments described above is:
The glass plate 1 that at first will meet shape of product is bonding with metal strip 2 sealings;
Contour supporter 4 evenly is set between two-layer flat board again;
Then along the Metal Material Welding of two-layer plate edge with corresponding sides, form annular seal space 5, annular seal space 5 should be reserved with vacuum orifice; Described metallic substance refers to: metal strip 2 or metal plate 10 or cross section are that the cross section is the metal frame 6 of rectangle
After vacuumizing, vacuum orifice is sealed again at last, form the vacuum glass that contains metal edges.
Fig. 6 discloses a kind of glass plate 1 method bonding with metal strip 2 sealings in the mode of cross section structure, and it realizes sealing bonding by low temperature glass 3 between glass plate 1 and metal strip 2.
Fig. 7 discloses another kind of glass plate 1 method bonding with metal strip 2 sealings in the mode of cross section structure, it is at first to plate layer of metal film 11 at glass plate 1 periphery, then metallic membrane 11 and metal strip 2 are carried out seal welding 12, make seal between glass plate 1 and metal strip 2 bonding.
During concrete enforcement, metallic membrane 11 shown in Figure 7 can plate and be single or multiple lift, and the method that plates metallic membrane 11 at glass plate 1 periphery can adopt magnetron sputtering, vacuum evaporation, spraying plating, plating etc. technique plated film mode to realize.
Fig. 8 has just exemplified the cross section structure schematic diagram of the described embodiment of Fig. 1 before periphery does not have seal welding, as seen from Figure 8, before the peripheral sealing welding, at first contour supporter 4 should be set evenly between layer glass flat board 1.
The thickness of the metal strip 2 that relates in the present invention, is between 0.03~1.5mm; Seal welding 12 between the metallic substance that relates to, namely comprise the seal welding 12 between the metal strip 2 in Fig. 1, comprise again metal strip 2 in Fig. 7 and the seal welding 12 between metallic membrane 11, also comprise metal strip 2 and the seal welding 12 between metal frame 6 and the metal frame 6 in Fig. 3 and the seal welding 12 between metal plate 10 in Fig. 2~Fig. 5, they namely can adopt the mode of silver-colored Sn-Cu solder transition, also can adopt the maturation process such as laser, ultrasonic wave to realize that metal realizes from the mode of fusion welding.
Above each embodiment is not to concrete restriction of the present invention; as long as the common staff of this area; basic general knowledge in conjunction with this area; carry out the improvement of unstructuredness under the enlightenment of the embodiment of the present invention; for example described improvement only limits to the variation of probe 9 placement locations of supporter 4 materials and variation highly or getter 8 and vacuum tightness detecting unit; or the material of getter 8 types and metallic substance (comprising metal strip 2, metal plate 10, metal frame 6) changes, and still falls into the protection domain of claim of the present invention.

Claims (6)

1. vacuum glass that contains metal edges, comprise the two-layer flat board in up and down, be provided with contour supporter between two-layer flat board, the surrounding sealing vacuumizes rear formation vacuum-sealed cavity again, it is characterized in that, two-layer flat board is the consistent glass plate of geometrical shape, or one deck is glass plate, and another layer is the consistent metal plate of geometrical shape; Be the metal strip that sticks to one along the glass plate periphery, the thickness of described metal strip is 0.03~1.5mm, and metal strip stretches out, and surmounts the edge around glass plate; At two-layer dull and stereotyped periphery, the rectangular metal frame that the cross section is hollow is set, the thickness of rectangular metal frame is consistent with two-layer flat board, and its wall towards vacuum-sealed cavity is provided with air drain or pore; The metal strip of layer glass flat board respectively with rectangular metal frame seal welding; Or the metal strip of one deck glass plate and rectangular metal frame seal welding, another layer metal plate edge and rectangular metal frame seal welding simultaneously.
2. the vacuum glass that contains metal edges according to claim 1, is characterized in that, in described vacuum-sealed cavity, getter is set; Or in the hollow region of rectangular metal frame, getter is set.
3. the vacuum glass that contains metal edges according to claim 1, is characterized in that, the probe of vacuum tightness detecting unit is set in described vacuum-sealed cavity; Or the probe of vacuum tightness detecting unit is set in the hollow region of rectangular metal frame.
4. a preparation method who contains the vacuum glass of metal edges as described in one of claim 1~3, is characterized in that,
A) will meet the glass plate periphery of shape of product bonding by low melting glass and metal water stop, or plate metallic membrane at the glass plate periphery, with metal strip by with the metallic membrane welding after to form sealing bonding;
B) between the glass plate that geometrical shape is consistent, contour supporter is set evenly, or between the glass plate metal plate consistent with geometrical shape, contour supporter is set evenly;
C) along the Metal Material Welding of two-layer plate edge with corresponding sides, form annular seal space, annular seal space is reserved with vacuum orifice, vacuumizes by vacuum orifice; Described metallic substance refers to: metal strip or metal plate or cross section are the metal frame of rectangle; Described Metal Material Welding with two-layer dull and stereotyped corresponding sides refers to: will and the rectangular metal frame of vacuum glass consistency of thickness be held between the metal strip extension of levels glass plate, with metal strip and metal frame welding; Or with the one side of metal frame and the metal strip extension welding of glass plate, another side and metal plate edge welding;
D) after vacuumizing, vacuum orifice is sealed, form the vacuum glass that contains metal edges.
5. the preparation method who contains the vacuum glass of metal edges according to claim 4, it is characterized in that, before forming annular seal space between with two-layer flat board, place getter, or insert the probe of vacuum tightness detecting unit, or place simultaneously getter and insert the probe of vacuum tightness detecting unit.
6. the preparation method who contains the vacuum glass of metal edges according to claim 5, it is characterized in that, the section bar cross section of processing metal frame is the rectangle of hollow, in the square-section of hollow, wall towards vacuum-sealed cavity is provided with air drain or pore, and the probe of described getter and vacuum tightness detecting unit is located at the hollow region of rectangular metal frame.
CN2011101495722A 2011-05-31 2011-05-31 Vacuum glass comprising metal edges and preparation method thereof Expired - Fee Related CN102285767B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN2011101495722A CN102285767B (en) 2011-05-31 2011-05-31 Vacuum glass comprising metal edges and preparation method thereof
PCT/CN2011/076506 WO2012162921A1 (en) 2011-05-31 2011-06-28 Vacuum glass with metal periphery and making method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011101495722A CN102285767B (en) 2011-05-31 2011-05-31 Vacuum glass comprising metal edges and preparation method thereof

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CN102285767A CN102285767A (en) 2011-12-21
CN102285767B true CN102285767B (en) 2013-06-05

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CN103979805B (en) * 2014-05-27 2017-07-28 张曹 Flexible sealing vacuum glass and its manufacture craft
US10689900B2 (en) * 2014-10-07 2020-06-23 Agc Glass Europe Process for manufacturing insulating glazing
CN105522863A (en) * 2015-12-16 2016-04-27 常熟市赛蒂镶嵌玻璃制品有限公司 Manufacturing method for mosaic glass
CN106014125A (en) * 2016-08-03 2016-10-12 常熟市赛蒂镶嵌玻璃制品有限公司 Vacuum glass for window
CN108947279B (en) * 2017-05-25 2021-06-04 张跃 Vacuum glass
CN111302659B (en) * 2018-12-11 2023-11-24 淄博环能海臣环保技术服务有限公司 Glass plate frame supporting complementary buckling metal brazing stainless steel frame vacuum glass plate
WO2020118670A1 (en) * 2018-12-11 2020-06-18 淄博环能海臣环保技术服务有限公司 Double epoxy resin-based grooved vacuum insulated sandwich glass panel having support fastening
CN111305715B (en) * 2018-12-11 2023-07-18 淄博环能海臣环保技术服务有限公司 Metal brazing sandwich hollow heat-insulating glass plate with protective frame rolling support
WO2020118676A1 (en) * 2018-12-11 2020-06-18 淄博环能海臣环保技术服务有限公司 Glass composite braced frame and stainless braced frame obtained by metal-to-glass vacuum brazing

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US7755818B2 (en) * 2002-01-25 2010-07-13 Kaiser Optical Systems High-integrity seal for optical elements, dichromated gelatin holographic optical elements in particular
CN2690398Y (en) * 2004-04-03 2005-04-06 李毅 Frame structure solar energy photo valtaic hollow glass
US7919157B2 (en) * 2007-01-10 2011-04-05 Guardian Industries Corp. Vacuum IG window unit with metal member in hermetic edge seal
EP1978199B1 (en) * 2007-04-05 2016-05-25 Grenzebach Maschinenbau GmbH Vacuum insulation glass and method and device for its manufacture
CN102050585A (en) * 2009-11-02 2011-05-11 刘伟杰 Low-cost toughened vacuum glass and manufacture method thereof
CN202072624U (en) * 2011-05-31 2011-12-14 朱雷 Vacuum glass with metal edge

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WO2012162921A1 (en) 2012-12-06

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Effective date of registration: 20190711

Address after: 210032 No. 6 Xinke No. 4 Road, Nanjing High-tech Development Zone, Jiangsu Province

Patentee after: NANJING CHENGYUAN SOLAR HEATING Co.,Ltd.

Address before: 210003 Room 202, Building 4, New Gate, Gulou District, Nanjing City, Jiangsu Province

Patentee before: Zhu Lei

CF01 Termination of patent right due to non-payment of annual fee
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Granted publication date: 20130605