CN102277035A - Magnetic resonant antiforgery ink - Google Patents

Magnetic resonant antiforgery ink Download PDF

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Publication number
CN102277035A
CN102277035A CN2011102390658A CN201110239065A CN102277035A CN 102277035 A CN102277035 A CN 102277035A CN 2011102390658 A CN2011102390658 A CN 2011102390658A CN 201110239065 A CN201110239065 A CN 201110239065A CN 102277035 A CN102277035 A CN 102277035A
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chloride
iron
sodium
ink
ion
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吴克墀
敬刚
焦鑫
王仕华
刘岩
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SHENZHEN LEAGUER ANTI-COUNTERFEITING TECHNOLOGY Co Ltd
Shenzhen Research Institute Tsinghua University
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SHENZHEN LEAGUER ANTI-COUNTERFEITING TECHNOLOGY Co Ltd
Shenzhen Research Institute Tsinghua University
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Priority to CN2011102390658A priority Critical patent/CN102277035A/en
Publication of CN102277035A publication Critical patent/CN102277035A/en
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Abstract

The invention relates to magnetic resonant antiforgery ink. In the magnetic resonant antiforgery ink, a magnetic resonant antiforgery material is added into ink. The magnetic resonant antiforgery ink comprises the following raw materials in percentage by weight: 50 to 95 percent of ink and 5 to 50 percent of magnetic resonant antiforgery material, wherein the magnetic resonant antiforgery material comprises elements of which the nuclear spin or the nuclear magnetic moment is not zero or elements of which the spin quantum number of detected atomic nucleus is not zero, a materials containing nonzero nuclear quadrupole moment elements, elements of which the nuclear spin and the nuclear magnetic moment are not zero, a material detected by electron paramagnetic resonance (EPR) or electron spin resonance (ESR), a material detected by sequence magnetic resonance and a material detected by magnetic double resonance. The magnetic resonant antiforgery ink is identified by utilizing a magnetic resonance combination effect, a magnetic resonance digital signal at the specific position of a label containing the magnetic resonant antiforgery ink is read by using an identifier, the signal is detected to identify the attribute of label materials, and thus, whether an object is true or fake can be told; and the information on truth and falsity, varieties, areas and the like of objects can be identified.

Description

The mr anti-forgery ink
Technical field
The present invention relates to a kind of mr anti-forgery ink, belong to the anti-counterfeiting printing technology field, is to be mixed with the mr anti-fake material by commercially available pigment, synthetic resins, vegetables oil, mineral oil, filler, stablizer and auxiliary agent, forms through attrition process.
Background technology
Valued Securities, bill, famous-brand and high-quality trade mark are often forged by the lawless person, alter and adulterium, and this has become current one big public hazards, and existing anti-forgery ink is single antiforge function, and is with low content of technology, and be easily imitated.Along with the raising of social scientific and technological level, offender's the impetus is becoming increasingly rampant, and technology content and the counterfeit difficulty of strengthening anti-fake product are imperative.Existing anti-forgery ink is single antiforge function, and is with low content of technology, easily imitated.
Summary of the invention
The purpose of this invention is to provide a kind of three kinds of combined effects of mr (NMR NQR ESR) that utilize, read the magnetic resonance signal of label material production on the article by recognizer, thus the identify objects true and false.As invoice, the specific label material mixes with printing ink, is printed on the sign, reads the mr numerary signal that identifies specific position with recognizer, and recognizer can be discerned the mr anti-forgery ink of information such as true from false of bills, kind and area.
Technical solution of the present invention is described mr anti-forgery ink, comprises printing ink, and its special character is: add the mr anti-fake material in the described printing ink, the weight proportion of each raw material is:
Printing ink 50%~95%;
Mr anti-fake material 5%~50%.
As preferably: described mr anti-fake material is the material of surveying with nuclear magnetic resonance technique, that is: non-vanishing element of nuclear spin or nuclear magnetic moment or the tested non-vanishing element of nuclear spin quantum number.
As preferably: described material comprises: contain hydrogen 1H, carbon 13C, nitrogen 14N, phosphorus 31P, sodium 23Na, aluminium 27Al, chlorine 35Cl, potassium 39K, manganese 55Mn, iron 57Fe, cobalt 59Co, arsenic 75As, gold 79Au, bromine 81Br, iodine 127One or more materials of I element.
As preferably: described material further comprises: water, yellow soda ash, nitrogen 14N, nitric acid phosphorus, sodium phosphate, sodium-chlor, sodium sulfate, aluminum chloride, potassium chloride (KCl), vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate one or more materials.
As preferably: described mr anti-fake material is the detecting material with nuclear quadrupole resonance NQR, contains the material of non-zero nuclear quadrupole moment element that is:.
As preferably: contain lithium 7Li, beryllium 9Be, boron 11B, nitrogen 14N, sodium 23Na, aluminium 27Al, chlorine 35Cl, potassium 39K, manganese 55Mn, iron 57Fe, cobalt 59Co, arsenic 75As, gold 79Au, bromine 81Br, iodine 127I, bismuth 209One or more materials of Bi element.
As preferably: contain lithium water salt LiCLLi 2SO 4H 2O, beryllium sulfate BeSO 4, borophosphoric acid, SODIUMNITRATE 23Na, sodium-chlor, sodium sulfate, aluminum chloride, Repone K, vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate, Bismuth trinitrate Bi (NO 3) 35H 2One or more materials of O.
As preferably: described mr anti-fake material is with spin echo nucleus magnetic resonance detecting material, that is: the non-vanishing element of nuclear spin and nuclear magnetic moment.
As preferably: described detecting material comprises: contain hydrogen 1H, carbon 13C, nitrogen 14N, phosphorus 31P, sodium 23Na, aluminium 27Al, chlorine 35Cl, potassium 39K, manganese 55Mn, iron 57Fe, cobalt 59Co, arsenic 75As, gold 79Au, bromine 81Br, iodine 127One or more materials of I element.
As preferably: described detecting material further comprises: water, yellow soda ash, nitric acid, phosphoric acid, sodium-chlor, sodium sulfate, aluminum chloride, potassium chloride (KCl), Repone K, vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate, yttrium aluminum garnet, yttrium iron garnet one or more materials.
As preferably: described mr anti-fake material is the material of surveying with electron paramagnetic resonance EPR or spectrum ESR, selects transition metal ion or its inorganic salt or its compatibility compound for use that is:; Lanthanide ion or its inorganic salt or its compatibility compound; Contain a kind of of unpaired electron or paramagnetic organic molecule or several.
As preferably: the material of described detection comprises: contain cupric ion CU 2+, mn ion Mn 2+, iron ion Fe 3+, chromium ion Cr 3+, gadolinium ion Gd 3+, terbium ion Tb 3+, erbium ion Er 3+Material.
As preferably: the material of described detection further comprises: copper sulfate, cupric chloride, cyanogen potassium manganate K 4[Mn (CN) 6], ferric sulfate, iron(ic) chloride, chromium sulphate Cr 2(SO 4) 3, gadolinium sesquioxide, Erbium trinitrate, naphthalene, trityl, nitro hydrogen a kind of or number of substances.
As preferably: described mr anti-fake material is the material of surveying with the preface mr, contains the material of non-zero nuclear-magnetism element that is:, and described material specifically comprises: a kind of or number of substances that contains iron Fe, cobalt Co, nickel element material.
As preferably: the material of described detection further comprises: a kind of or number of substances that contains iron(ic) chloride, yttrium-lanthanite garnet type ferrite, cobalt chloride, nickel arsenide material.
As preferably: described mr anti-fake material is the material of surveying with magnetic double resonance, that is: with the material of interactional electron paramagnetic resonance and nuclear quadrupole resonance detection.
As preferably: the material of described detection comprises: contain lithium 7Li, beryllium 9Be, boron 11B, nitrogen 14N, sodium 23Na, aluminium 27Al, chlorine 35Cl, potassium 39K, manganese 55Mn, iron 57Fe, cobalt 59Co, arsenic 75As, gold 79Au, bromine 81Br, iodine 127I, bismuth 209Bi, cupric ion CU 2+, mn ion Mn 2+, iron ion Fe 3+, chromium ion Cr 3+, gadolinium ion Gd 3+, terbium ion Tb 3+, erbium ion Er 3+A kind of or the number of substances of element material.
As preferably: the material of described detection further comprises: contain lithium water salt LiCLLi 2SO 4H 2O, beryllium sulfate BeSO 4, borophosphoric acid, nitric acid, sodium-chlor, sodium sulfate, aluminum chloride, potassium chloride (KCl), Repone K, vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate, copper sulfate, cupric chloride, cyanogen potassium manganate K 4[Mn (CN) 6], ferric sulfate, iron(ic) chloride, chromium sulphate Cr 2(SO 4) 3, a kind of or number of substances in the gadolinium sesquioxide, Erbium trinitrate.
Compared with prior art, advantage of the present invention is:
1, since the characteristic of mr anti-fake material be contain NMR NQR the material that can identify under the ESR effect, utilize mr NMR NQR three kinds of combined effects of ESR, read the magnetic resonance signal that the mr label material produces on the article by the mr recognizer, thus the identify objects true and false.As invoice, the specific label material mixes with printing ink, is printed on the sign, reads the mr numerary signal that identifies specific position with the mr recognizer, information such as recognizer identification true from false of bills, kind and area.
2, technology door height, optical effect anti-counterfeiting technology different from the past is as micro printing, anti-forgery ink, laser hologram etc.The material usable range is wide, and is strongly professional, extract duplicate substantially cannot, antifalse effect is good.
3, insensitive to surrounding environment, for example magnetic field, electric field, dust, strong tea, alcohol, fruit juice, beverage, grease, ink, glue, salt solution, temperature limitation (100 ℃ to 600 ℃).
4, compatible strong, easily and Ultraluminescence, watermark, other anti-counterfeiting technology compatibility such as miniature printed.
5, high identification certainty, extremely low error rate reaches 6sigma level (promptly read make mistakes for 1,000,000 times 3.4 times probability).
6, printing is convenient, and label material is blended in the material such as printing ink, need not special printing and waits equipment, does not change complete processing and the equipment of having now.
Embodiment
The present invention will now be further detailed embodiment:
[embodiment 1]
Described mr anti-forgery ink is to add the mr anti-fake material in anti-forgery ink, and the weight proportion of each raw material is:
Figure BDA0000084618690000031
Figure BDA0000084618690000041
Described mr anti-fake material is selected for use: water, yellow soda ash, nitrogen 14N, nitric acid phosphorus, sodium phosphate, sodium-chlor, sodium sulfate, aluminum chloride, potassium chloride (KCl), vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate one or more materials.
[embodiment 2]
Described mr anti-forgery ink is to add the mr anti-fake material in anti-forgery ink, and the weight proportion of each raw material is:
Figure BDA0000084618690000042
Described mr anti-fake material is selected for use: water, yellow soda ash, nitrogen 14N, nitric acid phosphorus, sodium phosphate, sodium-chlor, sodium sulfate, aluminum chloride, potassium chloride (KCl), vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate one or more materials.
[embodiment 3]
Described mr anti-forgery ink is to add the mr anti-fake material in anti-forgery ink, and the weight proportion of each raw material is:
Described mr anti-fake material is selected for use: water, yellow soda ash, nitrogen 14N, nitric acid phosphorus, sodium phosphate, sodium-chlor, sodium sulfate, aluminum chloride, potassium chloride (KCl), vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate one or more materials.
[embodiment 4]
Described mr anti-forgery ink is to add the mr anti-fake material in anti-forgery ink, and the weight proportion of each raw material is:
Figure BDA0000084618690000051
Described mr anti-fake material is selected for use: contain lithium water salt LiCLLi 2SO 4H 2O, beryllium sulfate BeSO 4, borophosphoric acid, SODIUMNITRATE, sodium-chlor, sodium sulfate, aluminum chloride, potassium chloride (KCl), Repone K, vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate, Bismuth trinitrate Bi (NO 3) 35H 2One or more materials of O.
[embodiment 5]
Described mr anti-forgery ink is to add the mr anti-fake material in anti-forgery ink, and the weight proportion of each raw material is:
Figure BDA0000084618690000052
Described mr anti-fake material is selected for use: contain lithium water salt LiCLLi 2SO 4H 2O, beryllium sulfate BeSO 4, borophosphoric acid, SODIUMNITRATE, sodium-chlor, sodium sulfate, aluminum chloride, potassium chloride (KCl), Repone K, vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate, Bismuth trinitrate Bi (NO 3) 35H 2One or more materials of O.
[embodiment 6]
Described mr anti-forgery ink is to add the mr anti-fake material in anti-forgery ink, and the weight proportion of each raw material is:
Figure BDA0000084618690000061
Described mr anti-fake material is selected for use: contain lithium water salt LiCLLi 2SO 4H 2O, beryllium sulfate BeSO 4, borophosphoric acid, SODIUMNITRATE, sodium-chlor, sodium sulfate, aluminum chloride, potassium chloride (KCl), Repone K, vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate, Bismuth trinitrate Bi (NO 3) 35H 2One or more materials of O.
[embodiment 7]
Described mr anti-forgery ink is to add the mr anti-fake material in anti-forgery ink, and the weight proportion of each raw material is:
Described mr anti-fake material comprises: water, yellow soda ash, nitric acid, phosphoric acid, sodium-chlor, sodium sulfate, aluminum chloride, potassium chloride (KCl), Repone K, vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate, yttrium aluminum garnet, yttrium iron garnet one or more materials.
[embodiment 8]
Described mr anti-forgery ink is to add the mr anti-fake material in anti-forgery ink, and the weight proportion of each raw material is:
Figure BDA0000084618690000063
Described mr anti-fake material comprises: copper sulfate, cupric chloride, cyanogen potassium manganate K 4[Mn (CN) 6], ferric sulfate, iron(ic) chloride, chromium sulphate Cr 2(SO 4) 3, gadolinium sesquioxide, Erbium trinitrate, naphthalene, trityl, nitro hydrogen, potassium 39K, manganese 55Mn, iron 57Fe, cobalt 59Co, arsenic 75As, gold 79A kind of or the number of substances of Au.
[embodiment 9]
Described mr anti-forgery ink is to add the mr anti-fake material in anti-forgery ink, and the weight proportion of each raw material is:
Described mr anti-fake material comprises: copper sulfate, cupric chloride, cyanogen potassium manganate K 4[Mn (CN) 6], ferric sulfate, iron(ic) chloride, chromium sulphate Cr 2(SO 4) 3, gadolinium sesquioxide, Erbium trinitrate, naphthalene, trityl, nitro hydrogen, potassium 39K, manganese 55Mn, iron 57Fe, cobalt 59Co, arsenic 75As, gold 79A kind of or the number of substances of Au.
[embodiment 10]
Described mr anti-forgery ink is to add the mr anti-fake material in anti-forgery ink, and the weight proportion of each raw material is:
Figure BDA0000084618690000072
Described mr anti-fake material comprises: copper sulfate, cupric chloride, cyanogen potassium manganate K 4[Mn (CN) 6], ferric sulfate, iron(ic) chloride, chromium sulphate Cr 2(SO 4) 3, gadolinium sesquioxide, Erbium trinitrate, naphthalene, trityl, nitro hydrogen, potassium 39K, manganese 55Mn, iron 57Fe, cobalt 59Co, arsenic 75As, gold 79A kind of or the number of substances of Au.
[embodiment 11]
Described mr anti-forgery ink is to add the mr anti-fake material in anti-forgery ink, and the weight proportion of each raw material is:
Figure BDA0000084618690000081
Described mr anti-fake material comprises: the material of described detection further comprises: a kind of or number of substances that contains iron(ic) chloride, yttrium-lanthanite garnet type ferrite, cobalt chloride, nickel arsenide material.
[embodiment 12]
Described mr anti-forgery ink is to add the mr anti-fake material in anti-forgery ink, and the weight proportion of each raw material is:
Described mr anti-fake material comprises: contain lithium water salt LiCLLi 2SO 4H 2O, beryllium sulfate BeSO 4, borophosphoric acid, nitric acid, sodium-chlor, sodium sulfate, aluminum chloride, potassium chloride (KCl), Repone K, vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate, copper sulfate, cupric chloride, cyanogen potassium manganate K 4[Mn (CN) 6], ferric sulfate, iron(ic) chloride, chromium sulphate Cr 2(SO 4) 3, a kind of or number of substances in the gadolinium sesquioxide, Erbium trinitrate.
The above only is preferred embodiment of the present invention, and all equalizations of being done according to claim scope of the present invention change and modify, and all should belong to the covering scope of claim of the present invention.

Claims (18)

1. a mr anti-forgery ink comprises printing ink, it is characterized in that: add the mr anti-fake material in the described printing ink, the weight proportion of each raw material is:
Printing ink 50%~95%;
Mr anti-fake material 5%~50%.
2. according to the described mr anti-forgery ink of claim 1, it is characterized in that: described mr anti-fake material is the material of surveying with nuclear magnetic resonance technique, that is: non-vanishing element of nuclear spin or nuclear magnetic moment or the tested non-vanishing element of nuclear spin quantum number.
3. according to the described mr anti-forgery ink of claim 2, it is characterized in that: described material comprises: contain hydrogen 1H, carbon 13C, nitrogen 14N, phosphorus 31P, sodium 23Na, aluminium 27Al, chlorine 35Cl, potassium 39K, manganese 55Mn, iron 57Fe, cobalt 59Co, arsenic 75As, gold 79Au, bromine 81Br, iodine 127One or more materials of I element.
4. according to the described mr anti-forgery ink of claim 3, it is characterized in that: described material further comprises: water, yellow soda ash, nitrogen 14N, nitric acid phosphorus, sodium phosphate, sodium-chlor, sodium sulfate, aluminum chloride, potassium chloride (KCl), vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate one or more materials.
5. according to the described mr anti-forgery ink of claim 1, it is characterized in that: described mr anti-fake material is the material of surveying with nuclear quadrupole resonance NQR, contains the material of non-zero nuclear quadrupole moment element that is:.
6. according to the described mr anti-forgery ink of claim 5, it is characterized in that: described detecting material comprises: contain lithium 7Li, beryllium 9Be, boron 11B, nitrogen 14N, sodium 23Na, aluminium 27Al, chlorine 35Cl, potassium 39K, manganese 55Mn, iron 57Fe, cobalt 59Co, arsenic 75As, gold 79Au, bromine 81Br, iodine 127I, bismuth 209One or more materials of Bi element.
7. according to the described mr anti-forgery ink of claim 6, it is characterized in that: described detecting material further comprises: contain lithium water salt LiCLLi 2SO 4H 2O, beryllium sulfate BeSO 4, borophosphoric acid, SODIUMNITRATE, sodium-chlor, sodium sulfate, aluminum chloride, Repone K, vitriolate of tartar, manganous hydroxide, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate, Bismuth trinitrate Bi (NO 3) 35H 2One or more materials of O.
8. according to the described mr anti-forgery ink of claim 1, it is characterized in that: described mr anti-fake material is the material of surveying with the spin echo nucleus magnetic resonance, that is: the non-vanishing element of nuclear spin and nuclear magnetic moment.
9. described according to Claim 8 mr anti-forgery ink, it is characterized in that: described detecting material comprises: contain hydrogen 1H, carbon 13C, nitrogen 14N, phosphorus 31P, sodium 23Na, aluminium 27Al, chlorine 35Cl, potassium 39K, manganese 55Mn, iron 57Fe, cobalt 59Co, arsenic 75As, gold 79Au, bromine 81Br, iodine 127One or more materials of I element.
10. according to the described mr anti-forgery ink of claim 9, it is characterized in that: described detecting material further comprises: water, yellow soda ash, nitric acid, phosphoric acid, sodium-chlor, sodium sulfate, aluminum chloride, potassium chloride (KCl), Repone K, vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate, yttrium aluminum garnet, yttrium iron garnet one or more materials.
11. according to the described mr anti-forgery ink of claim 1, it is characterized in that: described mr anti-fake material is the material of surveying with electron paramagnetic resonance EPR or spectrum ESR, selects transition metal ion or its inorganic salt or its compatibility compound for use that is:; Lanthanide ion or its inorganic salt or its compatibility compound; Contain a kind of of unpaired electron or paramagnetic organic molecule or several.
12. according to the described mr anti-forgery ink of claim 11, it is characterized in that: the material of described detection comprises: contain cupric ion CU 2+, mn ion Mn 2+, iron ion Fe 3+, chromium ion Cr 3+, gadolinium ion Gd 3+, terbium ion Tb 3+, erbium ion Er 3+Material.
13. according to the described mr anti-forgery ink of claim 12, it is characterized in that: the material of described detection further comprises: copper sulfate, cupric chloride, cyanogen potassium manganate K 4[Mn (CN) 6], ferric sulfate, iron(ic) chloride, chromium sulphate Cr 2(SO 4) 3, gadolinium sesquioxide, Erbium trinitrate, naphthalene, trityl, nitro hydrogen a kind of or number of substances.
14. according to the described mr anti-forgery ink of claim 1, it is characterized in that: described mr anti-fake material is the material of surveying with the preface mr, that is: contain the material of non-zero nuclear-magnetism element, described material specifically comprises: a kind of or number of substances that contains iron Fe, cobalt Co, nickel element material.
15. according to the described mr anti-forgery ink of claim 14, it is characterized in that: the material of described detection further comprises: a kind of or number of substances that contains iron(ic) chloride, yttrium-lanthanite garnet type ferrite, cobalt chloride, nickel arsenide material.
16. according to the described mr anti-forgery ink of claim 1, it is characterized in that: described mr anti-fake material is the material of surveying with magnetic double resonance, that is: the material of surveying with interactional electron paramagnetic resonance and nuclear quadrupole resonance.
17. according to the described mr anti-forgery ink of claim 16, it is characterized in that: the material of described detection comprises: contain lithium 7Li, beryllium 9Be, boron 11B, nitrogen 14N, sodium 23Na, aluminium 27Al, chlorine 35Cl, potassium 39K, manganese 55Mn, iron 57Fe, cobalt 59Co, arsenic 75As, gold 79Au, bromine 81Br, iodine 127I, bismuth 209Bi, cupric ion CU 2+, mn ion Mn 2+, iron ion Fe 3+, chromium ion Cr 3+, gadolinium ion Gd 3+, terbium ion Tb 3+, erbium ion Er 3+A kind of or the number of substances of element material.
18. according to the described mr anti-forgery ink of claim 17, it is characterized in that: the material of described detection further comprises: contain lithium water salt LiCLLi 2SO 4H 2O, beryllium sulfate BeSO 4, borophosphoric acid, nitric acid, sodium-chlor, sodium sulfate, aluminum chloride, potassium chloride (KCl), Repone K, vitriolate of tartar, manganous hydroxide Mn (OH) 2, iron(ic) chloride, cobalt chloride, white arsenic, tribromophenol, sodium iodate, copper sulfate, cupric chloride, cyanogen potassium manganate K 4[Mn (CN) 6], ferric sulfate, iron(ic) chloride, chromium sulphate Cr 2(SO 4) 3, a kind of or number of substances in the gadolinium sesquioxide, Erbium trinitrate.
CN2011102390658A 2011-08-05 2011-08-19 Magnetic resonant antiforgery ink Pending CN102277035A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103366209A (en) * 2012-09-19 2013-10-23 深圳市深国瑞印刷服务中心 Bill structure with multiple anti-counterfeit marks and recognition method of bill structure
CN104046122A (en) * 2013-07-04 2014-09-17 徐晓彬 Cyclotron resonance anti-counterfeit printing ink and its application
CN105608582A (en) * 2014-10-30 2016-05-25 上海天臣防伪技术股份有限公司 Anti-counterfeiting method based on low-frequency resonance induction characteristic of materials
CN105694545A (en) * 2016-01-30 2016-06-22 欧阳杰 Quantum resonance coating and construction process thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070075865A1 (en) * 2005-09-30 2007-04-05 Paul Spencer Method and system for producing and reading labels based on magnetic resonance techniques
CN101787257A (en) * 2009-01-22 2010-07-28 中国印钞造币总公司 Anti-counterfeiting material with special optical and magnetic characteristics

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070075865A1 (en) * 2005-09-30 2007-04-05 Paul Spencer Method and system for producing and reading labels based on magnetic resonance techniques
CN101787257A (en) * 2009-01-22 2010-07-28 中国印钞造币总公司 Anti-counterfeiting material with special optical and magnetic characteristics

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103366209A (en) * 2012-09-19 2013-10-23 深圳市深国瑞印刷服务中心 Bill structure with multiple anti-counterfeit marks and recognition method of bill structure
CN103366209B (en) * 2012-09-19 2017-02-08 深圳力合防伪技术有限公司 Bill structure with multiple anti-counterfeit marks and recognition method of bill structure
CN104046122A (en) * 2013-07-04 2014-09-17 徐晓彬 Cyclotron resonance anti-counterfeit printing ink and its application
CN105608582A (en) * 2014-10-30 2016-05-25 上海天臣防伪技术股份有限公司 Anti-counterfeiting method based on low-frequency resonance induction characteristic of materials
CN105694545A (en) * 2016-01-30 2016-06-22 欧阳杰 Quantum resonance coating and construction process thereof

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