CN102276983A - Method for manufacturing polyphenylene sulfide blow molding alloy - Google Patents
Method for manufacturing polyphenylene sulfide blow molding alloy Download PDFInfo
- Publication number
- CN102276983A CN102276983A CN2011102271377A CN201110227137A CN102276983A CN 102276983 A CN102276983 A CN 102276983A CN 2011102271377 A CN2011102271377 A CN 2011102271377A CN 201110227137 A CN201110227137 A CN 201110227137A CN 102276983 A CN102276983 A CN 102276983A
- Authority
- CN
- China
- Prior art keywords
- polyphenylene sulfide
- elastomerics
- vinylbenzene
- alloy
- sbs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004734 Polyphenylene sulfide Substances 0.000 title claims abstract description 113
- 229920000069 polyphenylene sulfide Polymers 0.000 title claims abstract description 113
- 239000000956 alloy Substances 0.000 title claims abstract description 44
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 238000000071 blow moulding Methods 0.000 title abstract description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000011347 resin Substances 0.000 claims abstract description 20
- 229920005989 resin Polymers 0.000 claims abstract description 20
- 238000002156 mixing Methods 0.000 claims abstract description 18
- 238000001816 cooling Methods 0.000 claims abstract description 12
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 11
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 11
- 238000007664 blowing Methods 0.000 claims description 48
- 238000001125 extrusion Methods 0.000 claims description 33
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 claims description 21
- 238000006116 polymerization reaction Methods 0.000 claims description 15
- 239000003112 inhibitor Substances 0.000 claims description 12
- 238000012545 processing Methods 0.000 claims description 12
- 239000012756 surface treatment agent Substances 0.000 claims description 12
- -1 4-epoxycyclohexyl Chemical group 0.000 claims description 11
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 238000005453 pelletization Methods 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 238000009826 distribution Methods 0.000 claims description 8
- QMBQNKZNTNORAY-UHFFFAOYSA-N ethyl(trimethoxy)silane;styrene Chemical compound C=CC1=CC=CC=C1.CC[Si](OC)(OC)OC QMBQNKZNTNORAY-UHFFFAOYSA-N 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 238000004381 surface treatment Methods 0.000 claims description 6
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 abstract description 6
- 239000000806 elastomer Substances 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 6
- 238000004925 denaturation Methods 0.000 abstract description 3
- 230000036425 denaturation Effects 0.000 abstract description 3
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 abstract 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- 201000007651 Brooke-Spiegler syndrome Diseases 0.000 description 39
- 239000011159 matrix material Substances 0.000 description 13
- 239000008187 granular material Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 238000003860 storage Methods 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 230000035939 shock Effects 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 229920006389 polyphenyl polymer Polymers 0.000 description 4
- 238000002791 soaking Methods 0.000 description 4
- 230000002194 synthesizing effect Effects 0.000 description 4
- 150000003568 thioethers Chemical class 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000009533 lab test Methods 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- XWUCFAJNVTZRLE-UHFFFAOYSA-N 7-thiabicyclo[2.2.1]hepta-1,3,5-triene Chemical compound C1=C(S2)C=CC2=C1 XWUCFAJNVTZRLE-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2011102271377A CN102276983B (en) | 2011-08-09 | 2011-08-09 | Method for manufacturing polyphenylene sulfide blow molding alloy |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2011102271377A CN102276983B (en) | 2011-08-09 | 2011-08-09 | Method for manufacturing polyphenylene sulfide blow molding alloy |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102276983A true CN102276983A (en) | 2011-12-14 |
CN102276983B CN102276983B (en) | 2013-03-13 |
Family
ID=45102741
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2011102271377A Active CN102276983B (en) | 2011-08-09 | 2011-08-09 | Method for manufacturing polyphenylene sulfide blow molding alloy |
Country Status (1)
Country | Link |
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CN (1) | CN102276983B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110225947A (en) * | 2017-02-16 | 2019-09-10 | 东丽株式会社 | Polyphenyl thioether resin composition and molded product |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1718635A (en) * | 2005-07-27 | 2006-01-11 | 广州金发科技股份有限公司 | High toughness packing reinforced polyphenyl thioether composite material and its preparation method |
CN101275015A (en) * | 2007-03-28 | 2008-10-01 | 四川得阳化学有限公司 | Preparation for fiberglass-containing polyphenyl thioether composite granulates |
CN101619168A (en) * | 2009-08-12 | 2010-01-06 | 深圳市华力兴工程塑料有限公司 | Modified polyphenylene sulfide resin and preparation method thereof |
-
2011
- 2011-08-09 CN CN2011102271377A patent/CN102276983B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1718635A (en) * | 2005-07-27 | 2006-01-11 | 广州金发科技股份有限公司 | High toughness packing reinforced polyphenyl thioether composite material and its preparation method |
CN101275015A (en) * | 2007-03-28 | 2008-10-01 | 四川得阳化学有限公司 | Preparation for fiberglass-containing polyphenyl thioether composite granulates |
CN101619168A (en) * | 2009-08-12 | 2010-01-06 | 深圳市华力兴工程塑料有限公司 | Modified polyphenylene sulfide resin and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110225947A (en) * | 2017-02-16 | 2019-09-10 | 东丽株式会社 | Polyphenyl thioether resin composition and molded product |
Also Published As
Publication number | Publication date |
---|---|
CN102276983B (en) | 2013-03-13 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Liu Hong Inventor before: Chen Xun |
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COR | Change of bibliographic data | ||
TR01 | Transfer of patent right |
Effective date of registration: 20151013 Address after: 610000 No. 1, No. 5, building 16, cloud shadow Road, 2, Chengdu, Sichuan, Wuhou District Patentee after: CHENGDU DANUO ENGINEERING TECHNOLOGY CONSULTING Co.,Ltd. Address before: 618000 Deyang city of Sichuan province Emei road two No. 159 Patentee before: DEYANG KEJI HIGH-TECH MATERIAL CO.,LTD. |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20151130 Address after: 620000 Meishan city of Sichuan province Meishan Jinxiang Chemical Industrial Park Patentee after: SICHUAN ZHONGKE XINGYE HIGH-TECH MATERIALS CO.,LTD. Address before: 610000 No. 1, No. 5, building 16, cloud shadow Road, 2, Chengdu, Sichuan, Wuhou District Patentee before: CHENGDU DANUO ENGINEERING TECHNOLOGY CONSULTING Co.,Ltd. |
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TR01 | Transfer of patent right |
Effective date of registration: 20200114 Address after: 100195 101-225, floor 2, building 1, yard 42, minzhuang Road, Haidian District, Beijing Patentee after: Beijing Zhongke Shengxin Technology Development Co.,Ltd. Address before: 620000 Meishan city of Sichuan province Meishan Jinxiang Chemical Industrial Park Patentee before: SICHUAN ZHONGKE XINGYE HIGH-TECH MATERIALS CO.,LTD. |
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TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20220419 Address after: 620038 Jinxiang chemical industry park, Dongpo District, Meishan City, Sichuan Province Patentee after: SICHUAN ZHONGKE XINGYE HIGH-TECH MATERIALS CO.,LTD. Address before: 100195 101-225, 2nd floor, building 1, courtyard 42, minzhuang Road, Haidian District, Beijing Patentee before: Beijing Zhongke Shengxin Technology Development Co.,Ltd. |
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TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20230426 Address after: 620200 Zone A, Economic Development Zone, Danling County, Meishan City, Sichuan Province Patentee after: Sichuan Zhongke Hangyu New Materials Co.,Ltd. Address before: 620038 Jinxiang chemical industry park, Dongpo District, Meishan City, Sichuan Province Patentee before: SICHUAN ZHONGKE XINGYE HIGH-TECH MATERIALS CO.,LTD. |