Embodiment
Below, with reference to accompanying drawing, embodiments of the present invention are elaborated.In addition, in following a plurality of embodiments, include same integrant.Thereby below to the identical symbol of these same integrant marks, and the repetitive description thereof will be omitted.
[first embodiment]
Fig. 1~Fig. 3 is the figure of the electrolytic water generating device 1 of expression first embodiment of the present invention.
As shown in Figure 1, constituting substantially of the electrolytic water generating device 1 of present embodiment: it possesses the water purification portion 2 that has used nanofilter 21 and imports the electrolyzer 3 that is generated basic ion water by purifying waste water of these water purification portion 2 generations.
Water purification portion 2 has the main channel P0 of importing as the tap water of former water, from the upstream side of this main channel P0 downstream side dispose successively: first prefilter 22, force (forcing) pump 23, first activated charcoal filter 24, second prefilter 25, above-mentioned nanofilter 21 and second activated charcoal filter 26.
First prefilter 22 is removed the macroparticle of sneaking into or rubbish etc. in the tap water that is imported, (for example the being 0.4MPa) side pressure downstream of pressurizeing of this water of having removed rubbish etc. of 23 pairs of force (forcing) pumps is sent, thereby produces the reverse osmotic pressure of nanofilter 21.
First activated charcoal filter 24 is removed free residual chlorine from the water by force (forcing) pump 23 pressurization, second prefilter 25 is further removed particulate from this has removed the water of chlorine, the water that supplies to nanofilter 21 is carried out pre-treatment.
Nanofilter 21 is utilized NF (nanofiltration, nanofiltration) film is removed low-molecular-weight ion components such as organism (for example haloform or musty and agricultural chemicals etc.), heavy metal ion (for example lead, chromium, cadmium, mercury, arsenic etc.) and sodium, calcium etc. and water is seen through, and this permeate water is supplied in second activated charcoal filter 26.
In the present embodiment, as reverse osmosis membrane filt, the special nanofilter 21 that has through the big NF film of boring ratio RO (reverse osmosis, reverse osmosis) film of using.Used the nanofilter 21 of this NF film to have following characteristic: to demonstrate roughly the height more than 90% for particle or organism and heavy metal and remove rate, but for low-molecular-weight ion component, then this composition is in permeate water residual about about 10~30%.The permeate water of in this case, residual low molion obtains the specific conductivity about about 60uS/cm.In addition, the condensed water that generates in nanofilter 21 is discharged to foreign side from the draining road P1 that is provided with throttling valve 27.
The permeate water of nanofilter 21 can fully be used as purifying waste water, but in the present embodiment, make this permeate water further by second activated charcoal filter 26, after finally having removed chlorine component or composition frowzy, supply in the electrolyzer 3 after in the micro-filter 28 that is built-in with the tubular fibre film filter, filtering.
Be provided with the anolyte compartment 32 and the cathode compartment 33 that utilize electrolytic film 31 to separate in the electrolyzer 3, in anolyte compartment 32, be provided with as anodic positive plate 34, and, in cathode compartment 33, be provided with negative plate 35, the position relation configuration that these positive plates 34 are relative mutually to clip electrolytic film 31 with negative plate 35 as negative electrode.
And, the main channel P0 in the downstream side of micro-filter 28 branches into first fen branch road P2 that is connected to anolyte compartment 32 and the second fen branch road P3 that is connected to cathode compartment 33, having passed through purifying waste water of water purification portion 2 is directed in the anolyte compartment 32 via first fen branch road P2, and, be directed in the cathode compartment 3 via second fen branch road P3.At this moment, the purification water yield that is directed in anolyte compartment 32 and the cathode compartment 33 is distributed to scale, and in the present embodiment, the ratio of the import volume Q1 of anolyte compartment 32 and the import volume Q2 of cathode compartment 33 is Q1: Q2=1: 4.
And then, import to purifying waste water in anolyte compartment 32 and the cathode compartment 33 respectively on the sunny side by pole plate 34 and negative plate 35 apply electrolysis voltage (or Faradaic current) and decomposed by electricity, import to that purifying waste water in the anolyte compartment 32 becomes sour water and supply to the first water spray mouth of pipe 37 from sour water outlet 36, and, import to that purifying waste water in the cathode compartment 33 becomes basic ion water and supply to the second water spray mouth of pipe 39 from alkaline water outlet 38.Thereby, can take out sour water from the first water spray mouth of pipe 37, and, can take out basic ion water from the second water spray mouth of pipe 39.
At this moment, by using nanofilter 21 as reverse osmosis membrane filt, residual in the purifying waste water in importing to electrolyzer 3 have a low-molecular-weight ion component, and can be under the situation of not adding the electrolysis auxiliary agent carry out electricity to decompose purifying waste water and generate basic ion water.Like this, decomposing and to generate sour water and basic ion water by carry out electricity with electrolyzer 3, is basic ion water but be specifically designed to what drink, and sour water is except being used for other special purposes and go out of use.
The positive plate 34 of force (forcing) pump 23 and electrolyzer 3 is connected with power supply 4 via wiring H1, H2, H3 with negative plate 35, and by controlling these power supplys 4 by pilot circuit 41, force (forcing) pump 23 and electrolyzer 3 are driven control.
At this, in the present embodiment, as shown in Figure 1, electrolytic water generating device possesses: water quality detection portion 100, the water quality of purifying waste water of having passed through water purification portion 2 is detected; Storage part 101 is to being stored by these water quality detection portion 100 initial water quality detected, when bringing into use water purification portion 2; As the above-mentioned pilot circuit 41 of control part, to being stored in the initial water quality in this storage part 101 and comparing, thereby judge the deterioration state of nanofilter 21 by water quality detection portion 100 detected current water quality; Display part 102 shows the deterioration state by the nanofilter 21 of these pilot circuit 41 judgements; And notice portion 103, according to the deterioration state of the nanofilter of judging by control part 102 21, notify the Maintenance and Repair information of this nanofilter 21.
In the present embodiment, for the judgement of the deterioration state of nanofilter 21, use above-mentioned pilot circuit 41, the power supply 4 of 41 pairs of force (forcing) pumps 23 of this pilot circuit and positive plate 34 and negative plate 35 is controlled.
In addition, use the water quality detection portion 100 of electrolyzer 3 as present embodiment, and will be by the specific conductivity ρ of magnitude of voltage V and the current value I decision decision content as water quality, this magnitude of voltage V and current value I are magnitude of voltage and the current values that is applied on the negative plate 35 of the positive plate 34 that utilizes the anolyte compartment 32 that electrolytic film 31 separates and cathode compartment 33.
That is, the opposed positive plate 34 of electrolyzer 3 and negative plate 35 double as are measured the transmitter of specific conductivity ρ, and pilot circuit 41 is when bringing into use nanofilter 21, that is, the initial conduction ρ 0 after the initial or replacing of nanofilter 21 is stored in the storage part 101.And then, according to the initial conductivity ρ 0 of this storage and the ratio (specific conductivity ratio=ρ/ρ 0) of the current specific conductivity ρ after the use, judge washing, the replacing or unusual of nanofilter 21.And,, show and notify by display part shown in Figure 3 102 and notice portion 103 according to this result of determination.
At this moment, in electrolyzer 3, so that the pH value of the basic ion water that generates at cathode compartment 33 becomes the mode of constant, change is applied to magnitude of voltage V or the current value I on positive plate 34 and the negative plate 35; (ρ=V/I) calculates the specific conductivity ρ as the judgement basis of the deterioration state of nanofilter 21 to utilize the ratio of these magnitudes of voltage V and current value I.In addition, for convenience of explanation, both of positive plate 34 and negative plate 35 are designated as battery lead plate 34,35 describe.
Promptly, in the schema of Fig. 2, if begin the control of pilot circuit 41 along with water flowing, then at first, in step S1, measurement is applied to initial current value I0 and the initial voltage value V0 on the battery lead plate 34,35, based on this, in next step S2, calculate initial conductivity ρ 0=f (I0, V0), and at storage part 101 store this initial conductivity ρ 0.
Then, utilize step S3 measurement to be applied to after the current current value I and magnitude of voltage V on the battery lead plate 34,35, enter next step S4, calculate current specific conductivity ρ=f (I, V).
And then, in step S5, obtain the initial conductivity ρ that stored 0 and use after the ratio of current specific conductivity ρ, judge this specific conductivity than (ρ/ρ 0) whether greater than 1.2.That is, (ρ/ρ 0)>1.2 o'clock is the smaller situation of deterioration state of nanofilter 21, can judge to capture foreign matters such as sand, silica or be the situation of reason with the accumulation of calcium dirt in the NF film.Therefore, be judged to be at step S5 under the situation of "Yes", enter step S6, show the deterioration state of nanofilter 21, and notify the necessity of the washing of nanofilter 21 by notice portion 103 by display part 102.Be judged to be at step S5 under the situation of "No", return step S3.
Then, in step S7, judge specific conductivity than (ρ/ρ 0) whether greater than 1.5.That is, (ρ/ρ 0)>1.5 o'clock is the bigger situation of deterioration state of nanofilter 21, can judge that with the deterioration of NF film self or breakage etc. be the situation of reason.Therefore, in this case, also enter step S8, by the deterioration state of display part 102 demonstration nanofilter 21, and, by the necessity of notice portion 103 notice replacings.Be judged to be at step S7 under the situation of "No", return step S3.
Then, in step S9, judge specific conductivity than (ρ/ρ 0) whether greater than 2.0.That is, (ρ/ρ 0)>2.0 o'clock, it is former thereby unusual because of certain to be judged to be nanofilter 21, and the operation that is stopped electrolyzer 3 and force (forcing) pump 23 by step S10 comes finishing control, thereby makes electrolytic water generating device 1 stop the supply of water.In addition, in the present embodiment,, also notify by notice portion 103 being judged to be under the unusual situation.Be judged to be at step S9 under the situation of "No", return step S3.
As shown in Figure 3, for display part 102, except being provided with above-mentioned notice portion 103, also be provided with the display part 105 of power knob 104, electrolysis mode and flow display part 106 etc.Be provided with the first notice hurdle 103A of the deterioration state that is used to notify nanofilter 21 in notice portion 103, in this first notice hurdle 103A, be provided with the lamp group 103Aa, the replacing lamp 103Ab that notice is changed, the washing lamp 103Ac of notice washing that notify the usage quantity of nanofilter 21 by the number of times of lighting a lamp.
Therefore, be judged to be at the step S7 of above-mentioned schema under the situation of "Yes", replacing lamp 103Ab lit a lamp notify, and be judged to be at step S5 under the situation of washing, washing lamp 103Ac is lit a lamp notify.In addition, be judged to be under the unusual situation, make and change lamp 103Ab and glittering notice of washing lamp 103Ac at step S9.
In addition, also be provided with other lamp ﹠ lantern or button class, be provided with, describe in second embodiment of narration below about these at display part 102.
By above structure, electrolytic water generating device 1 according to present embodiment, the water purification portion 2 that can form by the arranged in order according to first prefilter 22, force (forcing) pump 23, first activated charcoal filter 24, second prefilter 25, above-mentioned nanofilter 21 and second activated charcoal filter 26 as the tap water of former water generates and purifies waste water, in micro-filter 28, further filtered after this purifies waste water, a part is purified waste water in the cathode compartment 33 that is directed to electrolyzer 3, thereby generates healthy and helpful basic ion water.
At this moment, in the present embodiment, the water quality detection portion 100 of electrolyzer 3 has been used in utilization, based on the specific conductivity ρ that obtains with the ratio of magnitude of voltage V by the current value I that is applied on the battery lead plate 34,35, can detect and import to purifying waste water in the electrolyzer 3, promptly pass through to comprise the water quality of purifying waste water of the water purification portion 2 of nanofilter 21.In addition, the initial conductivity ρ 0 that is stored in the storage part 101 by 41 pairs of pilot circuits compares with current specific conductivity ρ, thereby judge the corresponding deterioration state of reason with nanofilter 21, deterioration state after this judgement is according to former thereby be shown in display part 102, and notified by notice portion 103.
Therefore, in the present embodiment, by Maintenance and Repair information such as the washing of notice portion 103 notice nanofilter 21 or replacing periods, thus not the deterioration state of judging nanofilter 21 by the people, and can correctly notify according to the reason of deterioration.Thus, can correctly distinguish the deterioration state with the corresponding nanofilter 21 of reason, promptly whether must must change for having washed still, thus nanofilter 21 need not optionally be changed, so both economical.
In addition, in the present embodiment, because the electrolyzer 3 that uses electrolytic water generating device 1 to be possessed is used as water quality detection portion 100, thus do not need newly to be provided with in addition water quality detection portion 100, so also both economical in this.
[second embodiment]
Then, with reference to accompanying drawing, second embodiment of the present invention is described.Fig. 4 is the one-piece construction figure that schematically represents the electrolytic water generating device of present embodiment, Fig. 5 is the schema that is used to judge the deterioration state of the water purification portion that comprises nanofilter, and Fig. 6 is the explanatory view with the decision table of the washing of employed nanofilter in the schema shown in the sheet form diagrammatic sketch 5 and replacing.
In addition, Fig. 7 is an explanatory view of representing the decision table of the replacing of the prefilter that employed purification portion was possessed in the schema shown in Figure 5 with sheet form, and Fig. 8 is the explanatory view of decision table that is illustrated in the replacing of the strainer except that nanofilter that employed purification portion was possessed in the schema shown in Figure 5 with sheet form.
The key distinction point of the electrolytic water generating device 1A of present embodiment and the electrolytic water generating device 1 of above-mentioned first embodiment is, the flow sensor 5 of the upstream side that is configured in nanofilter 21 and the force (forcing) pump 23 that is configured in the upstream side of nanofilter 21 have been added in water quality detection portion 100, will be by the decision content of flow sensor 5 detected flows as water quality, and, will be by the driving current value Ip of force (forcing) pump 23 decision content as water quality.
Promptly, in the above-described first embodiment, use electrolyzer 3 as water quality detection portion 100, by by being applied to the deterioration state that specific conductivity ρ that current value I on the electrolyzer 3 and magnitude of voltage V obtain judges nanofilter 21, but in the present embodiment, by adding flow sensor 5 and force (forcing) pump 23, can also judge the deterioration state of the prefilter class except that nanofilter 21 22,25 or the activated charcoal filter class 24,26 of water purification portion 2 thus at this electrolyzer 3.
As shown in Figure 4, flow sensor 5 is arranged on the main channel P0 between second prefilter 25 and the nanofilter 21, measures to import to the flow Q in the nanofilter 21 and output to pilot circuit 41.Initial flow Q0 when pilot circuit 41 will be brought into use water purification portion 2 in advance stores in the storage part 101, the throughput ratio (Q/Q0) of the current flow Q after calculating this initial flow Q0 again and using.In addition, reach the specific conductivity that illustrated is in the first embodiment judged nanofilter 21 than (ρ/ρ 0) washing, replacing or unusual according to this throughput ratio (Q/Q0).
As first embodiment was described, force (forcing) pump 23 was located at water purification portion 2, and this force (forcing) pump 23 is to be applied in constant voltage to move, and the pressure that causes owing to the mesh obstruction of water purification portion 2 etc. rises the load of the motor that is applied to force (forcing) pump 23 is changed.Pilot circuit 41 is measured the current value I p that changes along with the load of the motor of this moment, initial current value Ip0 in the time of will bringing into use water purification portion 2 in advance stores storage part 101 into, calculate this initial current value Ip0 again and use after current current value I p between current ratio (Ip/Ip0).And then, reach the throughput ratio of measuring by flow sensor 5 (Q/Q0) according to this current ratio (Ip/Ip0), judge the user mode of first prefilter 22 and second prefilter 25.
And then, in pilot circuit 41, the flow of being measured by flow sensor 5 is added up to calculate integrated flow Qt, and judge the user mode of first prefilter 22, first activated charcoal filter 24, second prefilter 25 and second activated charcoal filter 26 according to this integrated flow Qt.
That is, in pilot circuit 41, carry out control according to schema shown in Figure 5, if begin the control of pilot circuit 41 along with water flowing, then at first, in step S20, same with first embodiment, measure the initial current value I0 and the initial voltage value V0 that are applied on the battery lead plate 34,35.Based on this, in next step S21, (I0 V0), and stores this initial conductivity ρ 0 into storage part 101 to calculate initial conductivity ρ 0=f.
At next step S22, measure initial flow Q0 by flow sensor 5, and measure the initial current value Ip0 of force (forcing) pump 23, in step S23, store these Q0, Ip0 into storage part 101.
And then, in step S24, measurement is applied to current current value I and magnitude of voltage V, the current flow Q of flow sensor 5 and the current current value I p of force (forcing) pump 23 of the battery lead plate 34,35 of electrolyzer 3, calculates the current specific conductivity ρ {=f (I, V) } of electrolyzer 3 by step S25.
In step S26, according to the specific conductivity ρ that obtains by step S25 and the flow Q that measures than (=ρ/ρ 0) and by step S24 by the specific conductivity of the initial conductivity ρ 0 of step S21 storage with by the throughput ratio of the initial flow Q0 of step S23 storage (=Q/Q0), uses decision table (table 1) shown in Figure 6 to judge the deterioration state of nanofilter 21 (washing, change and unusually).And, by step S27, this result of determination is shown in display part 102 (Fig. 3 reference), and notifies by notice portion 103.
In this case, because except using specific conductivity than (=ρ/ρ 0), also use traffic than (=Q/Q0), so with only judge that than (=ρ/ρ 0) first embodiment of the deterioration state of nanofilter 21 compares with specific conductivity, can know deterioration state in further detail.
Then, in step S28, according to the current current value I p that measures by step S24 and the flow Q that measures by the current ratio (Ip/Ip0) of the initial current value Ip0 of step S23 storage and by step S24 with by the throughput ratio of the initial flow Q0 of step S23 storage (=Q/Q0), use decision table (table 2) shown in Figure 7 to judge and used the user mode (replacing) of first prefilter 22 and second prefilter 25.And then by step S29, (with reference to Fig. 3) shows this result of determination by display part 102, and notified by notice portion 103.
In this case, can know at first embodiment do not have first prefilter 22 of judgement and the user mode of second prefilter 25.In addition, in table 2, be in a ratio of under the worse situation of water quality, be shorter with the lifetime settings of first prefilter 22 and second prefilter 25, thereby take the security strategy of the purifying property of water purification portion 2 than common water quality with general common water quality.
Then, in step S30, flow during from the initial flow Q0 that measured by step S22 to the current flow Q that is measured by step S24 is added up, according to the integrated flow Qt after this accumulative total, use decision table (table 3) shown in Figure 8, judge and used the user mode (replacing) of first prefilter 22, first activated charcoal filter 24 and second prefilter 25 and the user mode (replacing) of second activated charcoal filter 26.In addition, by step S31, (with reference to Fig. 3) shows its result of determination by display part 102, and notified by notice portion 103.
In this case, can know do not judge at first embodiment and used first prefilter 22, first activated charcoal filter 24 and the user mode of second prefilter 25 and the user mode of second activated charcoal filter 26.
In addition, first prefilter 22, first activated charcoal filter 24, second prefilter 25 and second activated charcoal filter 26 are judged as under the normal situation under first prefilter 22 and second prefilter, the 25 normal situations and in step S30 in step S26 under the nanofilter 21 normal situations, in step S28, return step S24.
At this, be located at the notice portion 103 of display part shown in Figure 3 102, except the notice hurdle 103A that is provided with nanofilter 21, also be provided with and with first prefilter 22, first activated charcoal filter 24 and second prefilter 25 inform deterioration state second the notice hurdle 103B and inform second activated charcoal filter 26 deterioration state the 3rd the notice hurdle 103C.
At the second notice hurdle 103B and the 3rd notice hurdle 103C, be provided with the first notice hurdle 103A and utilize the number of lighting a lamp to notify lamp group 103Ba, the 103Ca of usage quantity and replacing lamp 103Bb, the 103Cb that notice is changed equally.In addition, corresponding to each hurdle 103A, 103B, 103C, be provided with reset switch 103Ad, the 103Bc, the 103Cc that after changing or washing, each lamp group 103Aa, 103Ba, 103Ca are resetted.
In addition, in the decision table of table 1 shown in Figure 6, so-called washing means washing lamp 103Ac, and so-called replacing means changes lamp 103Ab.In addition, so-called full the light-off is to instigate washing lamp 103Ac and change lamp 103Ab that the two is not lit a lamp, and carries out abnormity notifying by these two lamp 103Ac, 103Ab are glimmered simultaneously.
In addition, in the decision table of table 2 shown in Figure 7, the so-called replacing means replacing lamp 103Bb, and so-called full the light-off is meant that this replacing lamp 103Bb does not light a lamp.
And in the decision table of table 3 shown in Figure 8, lighting a lamp in the hurdle of first prefilter, first gac and second prefilter is meant that changing lamp 103Bb lights a lamp, and so-called the light-off is to instigate replacing lamp 103Bb not light a lamp.In addition, lighting a lamp in the hurdle of second gac is to instigate replacing lamp 103Cb to light a lamp, and so-called the light-off is to instigate this replacing lamp 103Cb not light a lamp.
By above structure, electrolytic water generating device 1A according to present embodiment, as water quality detection portion 100, except using the electrolyzer 3 that first embodiment uses, also use traffic transmitter 5 and force (forcing) pump 23, and with the specific conductivity ρ of electrolyzer 3, at the driving current value Ip of flow sensor 5 detected flow Q and force (forcing) pump 23 respectively as the decision content of water quality.Thus, can know the deterioration state of nanofilter 21 in further detail, and, can know the user mode of prefilter classes such as first prefilter 22 that can not judge at first embodiment and second prefilter 25, and can know and use the user mode in each strainer class of the upstream side of nanofilter 21 such as first prefilter 22, first activated charcoal filter 24 and second prefilter 25, can also know the user mode of such as second activated charcoal filter, 26 grades in the strainer class in the downstream side of nanofilter 21.
Therefore, by display part 102 and notice portion 103 state of the water purification portion 2 that possessed of Visual Confirmation electrolytic water generating device 1A in more detail, thereby can provide the sense of feeling at ease that brings thus to the user.In addition, can wash each strainer, and can utilize each strainer, so more economically according to the practical situation of using in the last stage of the performance degradation of purifying waste water.
More than, preferred embodiment be illustrated of the present invention, but the present invention is not limited to above-mentioned embodiment, in the scope that does not break away from aim of the present invention, can carry out various distortion.Therefore, above-mentioned explanation and accompanying drawing are not to be used to limit technological thought of the present invention, and should be interpreted as illustration of the present invention.
For example can at random set configurable number or the configuration position and the kind thereof of the prefilter of water purification portion or activated charcoal filter etc.