CN102265874A - Weeding composition containing carfentrazone-ethyl and flumetsulam - Google Patents
Weeding composition containing carfentrazone-ethyl and flumetsulam Download PDFInfo
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- CN102265874A CN102265874A CN2011101588727A CN201110158872A CN102265874A CN 102265874 A CN102265874 A CN 102265874A CN 2011101588727 A CN2011101588727 A CN 2011101588727A CN 201110158872 A CN201110158872 A CN 201110158872A CN 102265874 A CN102265874 A CN 102265874A
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- flumetsulam
- azoles humulone
- herbicidal combinations
- humulone
- auxiliary agent
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Abstract
The invention relates to a weeding composition containing carfentrazone-ethyl and flumetsulam, and the composition is mainly characterized in that the weeding composition comprises effective ingredients of 1-60% of carfentrazone-ethyl and 1-60% of flumetsulam, an accessory ingredient and the balance of other excipients and is prepared into wettable powder, water-dispersible granules, a suspension, emulsion in water and the like. The weeding composition is used for preventing and controlling broadleaf weeds and sedge.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to a kind of Herbicidal combinations that contains azoles humulone and Flumetsulam, be used to prevent and treat broad leaved weed and nutgrass flatsedge.
Background technology
Nineteen fifty-five has the people to report that Amrol can increase the prevent and kill off effect beginning of dalapon to the stone thatch, after, along with further developing of weed killer herbicide production and application, using with gradually between the weed killer herbicide grows up.China also comparatively payes attention to using with aspect the research of weed killer herbicide, is recognized extensively that to do be one of important measures of rationally using of weed killer herbicide, has worked out a series of Herbicidal compositions, has obtained bigger progress.
Azoles humulone (carfentrazone-ethyl), molecular formula: C
15H
14Cl
2F
3N
3O
3, chemical name: ethyl-2-chloro-3-{2-chloro-5-[4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxygen-1H-1,2,4-triazol-1-yl]-the 4-fluorophenyl } ethyl propionate.The azoles humulone is the protoporphyrin oxidase inhibitor, by suppressing the protoporphyrin oxidase, thereby make the film division. on cereal crop, use, be used for leaf surface treatment behind the seedling, responsive broad leaved weed conduction is obstructed and very fast withered death. to wheat, cereal crop safety such as corn. to having special efficacy, to succession crop safety in long-term weeds of using sulfonylureas weed killer herbicide area to develop immunity to drugs.
Flumetsulam (flumetsulam), molecular formula: C
12H
9F
2N
5O
2S, molecular formula: 2-(2,6-difluorophenyl sulfoamido)-5-methyl-[1,2,4]-triazole [1,5a] pyrimidine.Flumetsulam is the ALS inhibitor, and stripped ALS enzyme I 50 values of tobacco are 0.02mg/kg.No matter cauline leaf or soil treatment all have high activity to most of broad leaved weeds, grass family and sedge weed, soil treatment to kill the grass spectrum wider.
The chemical composition of each weed killer herbicide, structure and physicochemical property all are distinguishing.Therefore, they kill careless ability and scope is also different.It is narrower that some weed killer herbicide kills the grass spectrum, but have one's own knack, and can eradicate the weeds that are difficult to eliminate with other weed killer herbicide.
My company is devoted to the research and development of Herbicidal compositions.At present, do not appear in the newspapers with the relevant composite product of Flumetsulam about the azoles humulone.
Summary of the invention
The purpose of this invention is to provide a kind of Herbicidal combinations that contains the azoles humulone that is used for the wheat paddock control of weeds.
Technical scheme of the present invention is:
A kind of Herbicidal combinations that contains azoles humulone and Flumetsulam is characterized in that: Herbicidal combinations contains effective composition azoles humulone 1～60%, Flumetsulam 1～60%, auxiliary agent and other excipient surpluses.
Described Herbicidal combinations is characterized in that: Herbicidal combinations contains effective composition azoles humulone 5～50%, Flumetsulam 5～50%, auxiliary agent and excipient surplus.
Described Herbicidal combinations is characterized in that: Herbicidal combinations contains effective composition azoles humulone 10～40%, Flumetsulam 10～40%, auxiliary agent and excipient surplus.
Described Herbicidal combinations, by technology known in those skilled in the art, any formulation that can make on the agricultural chemicals to be allowed, wherein more preferably formulation has: wetting powder, water dispersible granules, suspending agent, suspension emulsion etc.
Described auxiliary agent and excipients comprise: dispersant, wetting agent, disintegrant, emulsifier, solvent, antifreeze, defoamer, thickener, filler, deionized water.
The described Herbicidal combinations that contains azoles humulone and Flumetsulam is characterized in that: comprise following constituent content when making wetting powder: azoles humulone 1～60%, Flumetsulam 1～60%, dispersant 5～10%, wetting agent 2～10%, filler add to 100%.
Active ingredient azoles humulone, Flumetsulam, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into azoles humulone Flumetsulam wetting powder product.
The described Herbicidal combinations that contains azoles humulone and Flumetsulam is characterized in that: comprise following constituent content when composition is made water dispersible granules: azoles humulone 1～60%, Flumetsulam 1～60%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, filler add to 100%.
Azoles humulone, Flumetsulam, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes azoles humulone Flumetsulam water dispersible granules product.
The described Herbicidal combinations that contains azoles humulone and Flumetsulam, it is characterized in that: comprise following constituent content when composition is made suspension emulsion: azoles humulone 1～50%, Flumetsulam 1～50%, emulsifier 2～12%, dispersant 2～10%, defoamer 0.1～2%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, deionized water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear, add the former medicine of Flumetsulam, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make the Flumetsulam suspending agent, then with the former medicine of azoles humulone, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make suspension emulsion product of the present invention.
The described Herbicidal combinations that contains azoles humulone and Flumetsulam is characterized in that: comprise following constituent content when composition is made suspending agent: azoles humulone 1～50%, Flumetsulam 1～50%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, emulsifier 0.5%～8%, solvent add to 100%.
The former medicine of azoles humulone, thickener, defoamer, solvent are joined in the sand milling axe after metering, adding emulsifier, after being ground to certain fineness, material is inputed to storage tank, put after metering to the average blender, with the former medicine of quantitative Flumetsulam, and emulsifier and certain amount of solvent join in the average blender, after homogenizer disperseed mixing, sample analysis was after product is qualified, the packing warehouse-in makes azoles humulone Flumetsulam suspending agent product.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, during the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, the glucose.
Described solvent is selected from: N, dinethylformamide, cyclohexanone, methyl alcohol, ethanol, 3-methyl cyclohexanol ketenes, N-octylpyrrolidone, N-pyrrolidones, propyl alcohol, butanols, ethylene glycol, diethylene glycol, ethylene glycol monomethyl ether, butyl ether, ethyl acetate, vegetable oil, acetonitrile.
Described emulsifier is selected from: farming breast 500
#(alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600
#Phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), farming breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), peaceful breast 36
#(phenethyl fluosite polyoxy ethyl ether), farming breast 1600
#(phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), farming breast 33
#(alkylaryl polyoxyethylene polyoxypropylene ether), farming breast 34
#In (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), the AEO series (the pure APEO of fat) one or more.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (as capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, the polyvinyl alcohol.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Herbicidal combinations of the present invention compared with prior art produces following beneficial effect:
Can enlarge herbicidal spectrum, improve herbicidal effect, prolong the optimum period for applying fertilizer, reduce poisoning, reduce residual activity, delay drug-fast generation of weed killer herbicide and development by using with of weed killer herbicide, quick-acting is good, to succession crop safety.Herbicidal combinations of the present invention is to the multiple broad leaved weed and the nutgrass flatsedge in wheat, barley, paddy rice, seeding corn and other crops field, as: preventive effects such as nutgrass flatsedge, difformed galingale herb, clearvers, white dead nettle, Veronica, blank pipe are led a cow, red heart lamb's-quarters, shepherd's purse, lamb's-quarters, salsola collina, Wang grass, chickweed, descurainia sophia (l.) webb ex prantl, summer cypress, Commeline communis, knotweed, Siberian cocklebur, conical silene herb, corn gromwell, amaranth, black nightshade, corn-bind are obvious.
Embodiment
Below in conjunction with embodiment to further instruction of the present invention.
Implementation of an application example one:
Azoles humulone and Flumetsulam are mixed to the active determination test report of wheat paddock weeds
Test objective: under the greenhouse pot culture condition, measure azoles humulone and Flumetsulam and different blended combo thereof and close herbicidal effect, and estimate its synergy, for the formulation development and the agriculture chemical registration field control effectiveness test of Mixed Pharmacy provides scientific basis to lamb's-quarters.
For trying target: lamb's-quarters (Chenopodium album).
Test medicine: azoles humulone (carfentrazone-ethyl) 90% former medicine, Flumetsulam (bromoxynil) 97% former medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
The medicament configuration:
Azoles humulone solution: accurately take by weighing the former medicine of 0.0127g 90% azoles humulone,, add the clear water 400mL that contains the 0.1%TWEEN80 emulsifier, stir, be configured to azoles humulone 45g a.i./hm with the 0.2mLDMF dissolving
2Solution is diluted to 30g a.i./hm with clear water again
2, 15ga.i./hm
2Concentration is standby.
Flumetsulam amine aqueous solution: accurately take by weighing the former medicine of 0.0157g 97% Flumetsulam,, add the clear water 400mL that contains the 0.1%TWEEN80 emulsifier, stir, be configured to Flumetsulam 60g a.i./hm with the 0.2mLDMF dissolving
2Solution is diluted to 40ga.i./hm with clear water again
2, 20g a.i./hm
2Concentration is standby.
Blank solution: 0.2mLDMF adds the water of 400mL 0.1%TWEEN80 emulsifier.
Test method: adopt potted plant cauline leaf facture (NY/T 1155.4-2006): the amount of setting soil in the polypots of high 6cm, diameter 9cm, will be in polypots for 15～20 sowings of examination target weed seed, be placed on cultivation in the greenhouse after covering the thick fine earth of 0.5～1cm, treat that weeds grew to for 2～4 leaf phases and carry out cauline leaf spraying processing, every alms bowl spraying liquid 1mL, every processing repeats 4 times, and establishes the contrast that is treated to that does not contain medicament.Processing is placed in the greenhouse cultivates, the growing state of routine observation target weeds, and be injured symptom and growth inhibition situation of range estimation target behind the 15d, and claim acrial part fresh weight or strain fresh weight, estimate the toxicity action of medicament with form fresh weight inhibiting rate to the target weeds.
Investigation method:
Range estimation target be injured symptom and growth inhibition situation are handled behind the 15d in test, and claim to calculate fresh weight inhibiting rate (%) by the acrial part fresh weight.
The synergy evaluation method:
Estimate weed killer herbicide synergy mode (NY/T 1155.7-2006) according to the Gowing method, its formula is as follows:
E
0＝X+Y-XY/100
In the formula, X is that the azoles humulone is with the fresh weight inhibiting rate of certain dosage list time spent to the target weeds; Y is that Flumetsulam is with the fresh weight inhibiting rate of certain dosage list time spent to the target weeds; E
0During for azoles humulone and two kinds of pharmacy mix of Flumetsulam to the theoretical value of target weeds fresh weight inhibiting rate; When E is azoles humulone and two kinds of pharmacy mix of Flumetsulam to the measured value of target weeds fresh weight inhibiting rate.
Evaluation criterion: work as E-E
0Be expressed as synergistic effect at＞10% o'clock, as-10%≤E-E
0Be expressed as summation action, and worked as E-E in≤10% o'clock
0Be expressed as antagonism at＜-10% o'clock.
Table 1 azoles humulone and Flumetsulam and the toxicity test result of combination that be mixed thereof to lamb's-quarters
Evaluating drug effect: azoles humulone and Flumetsulam and the composition that is mixed thereof see Table 1 to the herbicidal effect measurement result of lamb's-quarters.As seen, azoles humulone and Flumetsulam with 15+20,15+40,15+60,30+20,30+40,30+60,45+20,45+40,45+60 be mixed composition to its E-E0 value of blite all greater than 10%, show obvious synergistic effect.
Application Example two: the azoles humulone composite product embodiments (following content be folding hundred percentage compositions) of being correlated with.
Embodiment 180% azoles humulone Flumetsulam wetting powder
Azoles humulone 40%, Flumetsulam 40%, polycarboxylate 5%, alkyl benzene sulfonate calcium salt 2%, spaonin powder 2%, diatomite add to 100%, and mixture carries out comminution by gas stream, make 80% azoles humulone Flumetsulam wetting powder.
Embodiment 2 60% azoles humulone Flumetsulam wetting powders
Azoles humulone 25%, Flumetsulam 35%, polycarboxylate 4%, lauryl sodium sulfate 3%, soapberry powder 5%, kaolin add to 100%, and mixture carries out comminution by gas stream, make 60% azoles humulone Flumetsulam wetting powder.
Embodiment 3 70% azoles humulone Flumetsulam wetting powders
Azoles humulone 40%, Flumetsulam 30%, polycarboxylate 4%, lauryl sodium sulfate 3%, soapberry powder 5%, kaolin add to 100%, and mixture carries out comminution by gas stream, make 70% azoles humulone Flumetsulam wetting powder.
Embodiment 4 80% azoles humulone Flumetsulam water dispersible granules
Azoles humulone 30%, Flumetsulam 50%, SDS 6%, sodium lignin sulfonate 2%, ammonium sulfate 4%, polyethylene glycol 1%, aluminium chloride 2%, bentonite add to 100%, make 80% azoles humulone Flumetsulam water dispersible granules.
Embodiment 5 60% azoles humulone Flumetsulam water dispersible granules
Azoles humulone 20%, Flumetsulam 40%, neopelex 5%, sodium lignin sulfonate 3%, urea 3%, polyvinyl alcohol 0.5%, urea 2%, bentonite add to 100%, make 60% azoles humulone Flumetsulam water dispersible granules.
Embodiment 6 50% azoles humulone Flumetsulam water dispersible granules
Azoles humulone 30%, Flumetsulam 20%, SDS 6%, sodium lignin sulfonate 2%, ammonium sulfate 4%, polyethylene glycol 1%, aluminium chloride 2%, bentonite add to 100%, make 50% azoles humulone Flumetsulam water dispersible granules.
Embodiment 7 50% azoles humulone Flumetsulam oil-suspending agents
Azoles humulone 10%, Flumetsulam 40%, polycarboxylate 5%, lignosulfonates 4%, silicone defoamer 0.3%, aluminium-magnesium silicate 1%, phenyl phenol polyoxy ethyl ether phosphate 5%, vegetable oil add to 100%, the mixed 50% azoles humulone Flumetsulam oil-suspending agent that gets.
Embodiment 8 30% azoles humulone Flumetsulam oil-suspending agents
Azoles humulone 20%, Flumetsulam 10%, SDS 10%, draw back powder 5%, silicone oil 0.5%, methylcellulose 0.8%, vegetable oil and add to 100%, make 30% azoles humulone Flumetsulam oil-suspending agent.
Embodiment 9 50% azoles humulone Flumetsulam suspending agents
Azoles humulone 20%, Flumetsulam 30%, polycarboxylate 5%, lignosulfonates 4%, silicone defoamer 0.3%, aluminium-magnesium silicate 1%, phenyl phenol polyoxy ethyl ether phosphate 5%, deionized water add to 100%, the mixed 50% azoles humulone Flumetsulam suspending agent that gets.
Embodiment 10 30% azoles humulone Flumetsulam suspending agents
Azoles humulone 10%, Flumetsulam 20%, SDS 10%, draw back powder 5%, silicone oil 0.5%, methylcellulose 0.8%, deionized water and add to 100%, make 30% azoles humulone Flumetsulam suspending agent.
Embodiment 11 40% azoles humulone Flumetsulam suspension emulsions
Azoles humulone 20%, Flumetsulam 20%, octylphenol polyethylene oxyethylene group ether sulfate 6%, polyoxyethylene carboxylate 5%, sorbitan monostearate 3%, xanthans 2%, propane diols 8%, water adds to 100%, the aforementioned formula material is mixed, promptly make 40% azoles humulone Flumetsulam suspension emulsion.
Embodiment 12 30% azoles humulone Flumetsulam suspension emulsions
Azoles humulone 5%, Flumetsulam 25%, alkylbenzenesulfonate 3%, draw back powder 2%, polyoxyethylene nonylphenol ether phosphate 6%, polyvinyl alcohol 2%, water and add to 100% sodium lignin sulfonate 5%, mixed 30% azoles humulone Flumetsulam suspension emulsion.
Application Example three: azoles humulone and Flumetsulam control wheat weeds field control effectiveness test
The table 2 azoles humulone Flumetsulam control wheat paddock weeds test of pesticide effectiveness
The control medicament: azoles humulone and Flumetsulam complex composition are provided by Shaanxi Welch Crop Protection Co., Ltd.'s research and development;
Contrast medicament: 40% azoles humulone water dispersible granules (commercial);
80% Flumetsulam water dispersible granules (commercial);
Using method: convert behind 30 liters in the water evenly that cauline leaf sparges in each sub-district for every mu.
Spraying time:, the weeds in field 1-3 leaf phase, carry out cauline leaf spraying 1 time in the wheat 2-4 leaf phase.
Investigation weeds object is: weeds such as lamb's-quarters, clearvers, nutgrass flatsedge, investigate back 10 days, 30 days to strain preventive effect of weeds and 30 days fresh weight preventive effect.
The visual test medicament does not have poisoning to wheat to be taken place.
The table 2 azoles humulone Flumetsulam built composition for preventing and controlling wheat paddock weeds test of pesticide effectiveness
Azoles humulone and Flumetsulam are composite as shown in Table 2 has good control efficiency to lamb's-quarters, clearvers, nutgrass flatsedge etc., and wheat there is certain volume increase, preventive effect is better than single agent preventive effect, and contrast medicament, artificial weeding, with respect to significant difference between the rate of growth of clear water control treatment, and have quick-acting and lasting effect preferably, in this experimental drug scope, to wheat safety.
The table 3 azoles humulone Flumetsulam control of maize field weed test of pesticide effectiveness
The control medicament: azoles humulone and Flumetsulam complex composition are provided by Shaanxi Welch Crop Protection Co., Ltd.'s research and development;
Contrast medicament: 40% azoles humulone water dispersible granules (commercial);
80% Flumetsulam water dispersible granules (commercial)
If artificial weeding and clear water control treatment.
Using method: convert behind 30 liters in the water evenly that cauline leaf sparges in each sub-district for every mu.
Spraying time: before broadcasting the back seedling, carry out cauline leaf spraying 1 time.
Investigation weeds object is: weeds such as Veronica, black nightshade, Siberian cocklebur, 10 days, 30 days to strain preventive effect of weeds and 30 days fresh weight preventive effect.
The visual test medicament does not have poisoning to corn to be taken place.
The table 3 azoles humulone Flumetsulam built composition for preventing and controlling corn field weed test of pesticide effectiveness
Azoles humulone and Flumetsulam are composite as shown in Table 3 has good control efficiency to Veronica, black nightshade, Siberian cocklebur etc., and corn there is certain volume increase, preventive effect is better than single agent preventive effect, and contrast medicament, artificial weeding, with respect to significant difference between the rate of growth of clear water control treatment, and have quick-acting and lasting effect preferably, in this experimental drug scope, to corn safety.
Claims (6)
1. Herbicidal combinations that contains azoles humulone and Flumetsulam, it is characterized in that: Herbicidal combinations contains effective composition azoles humulone 1～60%, Flumetsulam 1～60%, auxiliary agent and excipient surplus.
2. Herbicidal combinations according to claim 1 is characterized in that: Herbicidal combinations contains effective composition azoles humulone 5～50%, Flumetsulam 5～50%, auxiliary agent and excipient surplus.
3. Herbicidal combinations according to claim 2 is characterized in that: Herbicidal combinations contains effective composition azoles humulone 10～40%, Flumetsulam 10～40%, auxiliary agent and excipient surplus.
4. Herbicidal combinations according to claim 1 is characterized in that: Herbicidal combinations is made wetting powder, water dispersible granules, suspending agent, suspension emulsion.
5. be used to prevent and treat the application of broad leaved weed and nutgrass flatsedge according to each described Herbicidal combinations in the claim 1 to 4.
6. Herbicidal combinations according to claim 5 is used to prevent and treat that nutgrass flatsedge, clearvers, white dead nettle, Veronica, blank pipe are led a cow, the application of red heart lamb's-quarters, shepherd's purse, lamb's-quarters, salsola collina, Wang grass, chickweed, descurainia sophia (l.) webb ex prantl, summer cypress, Commeline communis, knotweed, Siberian cocklebur, conical silene herb, corn gromwell, amaranth, black nightshade, corn-bind.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101588727A CN102265874A (en) | 2011-06-14 | 2011-06-14 | Weeding composition containing carfentrazone-ethyl and flumetsulam |
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|---|---|---|---|
| CN2011101588727A CN102265874A (en) | 2011-06-14 | 2011-06-14 | Weeding composition containing carfentrazone-ethyl and flumetsulam |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332608A (en) * | 1998-11-10 | 2002-01-23 | 辛根塔参与股份公司 | Herbicidal composition |
| CN101410015A (en) * | 2006-03-06 | 2009-04-15 | 伊萨罗里斯卡公司 | New synergistic herbicidal compositions |
-
2011
- 2011-06-14 CN CN2011101588727A patent/CN102265874A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332608A (en) * | 1998-11-10 | 2002-01-23 | 辛根塔参与股份公司 | Herbicidal composition |
| CN101410015A (en) * | 2006-03-06 | 2009-04-15 | 伊萨罗里斯卡公司 | New synergistic herbicidal compositions |
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Application publication date: 20111207 |