CN102260441A - High temperature resistant water-fast colorable varnish for fabric foil, and preparation method thereof - Google Patents
High temperature resistant water-fast colorable varnish for fabric foil, and preparation method thereof Download PDFInfo
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- CN102260441A CN102260441A CN201010587783XA CN201010587783A CN102260441A CN 102260441 A CN102260441 A CN 102260441A CN 201010587783X A CN201010587783X A CN 201010587783XA CN 201010587783 A CN201010587783 A CN 201010587783A CN 102260441 A CN102260441 A CN 102260441A
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Abstract
The invention relates to a high temperature resistant water-fast colorable varnish for fabric foils, and a preparation method thereof. The fabric foil high temperature resistant water-fast colorable varnish comprises a main agent, a curing agent and a diluent, wherein a weight ratio of the three is 4-5:1-2:3-4. The main agent comprises raw materials of, by weight: 5 to 10 parts of nitrocellulose, 5 to 10 parts of amino resin, 10 to 20 parts of acrylic resin, 2 to 5 parts of alkyd resin, 20 to 50 parts of an organic solvent, and 2 to 5 part of a stabilizer. A colored coating layer prepared from the colorable varnish provided by the invention has high temperature resistance and good thermosetting capacity. With the varnish, color changing and multicolor phenomenon do not occur under a temperature of 180 DEG C. the varnish can be used for coloring in cooperation with various organic dyes. After aluminum plating, the combination firmness of the colored layer and the aluminum layer is high. The invention also provides a preparation method of the high temperature resistant water-fast colorable varnish for fabric foils.
Description
Technical field
The present invention relates to a kind of varnish of painting, relate in particular to a kind of fabric paper tinsel with high temperature resistant, the laundry-resistant varnish and preparation method thereof of painting.
Background technology
The fabric paper tinsel claims to scald cloth electrification aluminium again, is widely used in the decoration and the decoration of cloth and household fabric.The making method that the fabric paper tinsel is general is at first to be coated with release layer and chromatograph on the PET basement membrane, and aluminize (also can not aluminizing) is coated with protection glue at last again.
There are two problems in most fabric paper tinsels of domestic production at present after being applied on the cloth product, and the one, non-refractory surpasses 140 ℃ and variable color, illusion-colour promptly occur, can't carry out the processing of hot iron and stamp; The 2nd, not water-fast washing uses washing powder to wash in the water of certain temperature, and coating will come off.The major cause that causes above two problems is that existing fabric paper tinsel chromatograph coating does not reach high temperature resistant, laundry-resistant requirement.Therefore, exploitation is a kind of is applicable to that having of fabric paper tinsel is high temperature resistant, the chromatograph coating of wash durability is one of this area problem demanding prompt solution.
Summary of the invention
For solving the problems of the technologies described above, the object of the present invention is to provide a kind of fabric paper tinsel chromatograph coating, the varnish of can painting, it is made up of host and solidifying agent, have characteristics such as high temperature resistant, the water-fast performance of washing, cut edge is outstanding, and with aluminium lamination can firm the combining of form, the chromatograph coating that is suitable for making the fabric paper tinsel.
The present invention also aims to provide the preparation method of the above-mentioned varnish of painting.
For achieving the above object, the painted varnish that the present invention at first provides a kind of fabric paper tinsel to wash with fire resistant water resistant, it comprises host, solidifying agent and thinner, and wherein, three's weight ratio is 4-5: 1-2: 3-4, is preferably 4: 1: 3-3.5.Wherein, described host comprises following raw material composition: nitro-cotton, 5-8 weight part, aminoresin, 5-10 weight part, acrylic resin, 10-20 weight part, Synolac, 2-5 weight part, organic solvent, 40-60 weight part, stablizer, 2-5 weight part.Where necessary, the varnish of painting provided by the invention can also comprise an amount of dyestuff.
In the varnish of painting provided by the invention, the nitro-cotton that is adopted can for coating with nitro-cotton etc., preferably, this coating is 1/4-1/16 second with the specification of nitro-cotton, its nitrogen content≤12%;
The aminoresin that is adopted can comprise one or two or more kinds the combination in methyl-etherified terpolycyantoamino-formaldehyde resin, butyl alcohol etherified melamine-formaldehyde resin and the alkylated melamine formaldehyde resin etc., preferably, the solid content of the aminoresin that is adopted is 60-80wt%;
The acrylic resin that is adopted can be solid thermoplastic acrylic resin of containing hydroxyl etc., preferably, the weight-average molecular weight of this solid thermoplastic acrylic resin can be 10000-30000, and hydroxyl value can be 5-10mgKOH/g, and second-order transition temperature can be 80-90 ℃;
The Synolac that is adopted can be short oil-ity alcohol acid resin etc., preferably, the acid value≤12mgKOH/g of this short oil-ity alcohol acid resin, hydroxyl value is 40-50mgKOH/g;
The solidifying agent that is adopted can be toluene diisocyanate trimer etc., and preferably, the solid content of this toluene diisocyanate trimer is 40-60wt%, and the content of isocyanato is 7-12wt%;
The stablizer that is adopted can be propyl carbinol, by adding the stability of stablizer raising coating;
The thinner that is adopted (solvent) can comprise the combination more than two or three in butanone, pimelinketone, toluene and the vinyl acetic monomer etc.
In the varnish of painting provided by the invention, the organic solvent that is adopted in the host preferably includes the combination more than two or three in butanone, vinyl acetic monomer and the pimelinketone etc.
The present invention also provides the preparation method of the painted varnish that the above-mentioned fabrics paper tinsel washes with fire resistant water resistant, and it may further comprise the steps:
Acrylic resin and 1/2 to 2/3 the organic solvent that occupies machine solvent gross weight mixed mutually (this step mainly is in advance acrylic resin to be mixed with organic solvent, the organic solvent that is added can be selected according to the amount of acrylic resin), be warming up to 50-60 ℃ and insulated and stirred 1-2 hour, add stablizer, obtain aqueous premix, standby;
Remaining organic solvent is added in the reactor (new reactor), when stirring, add nitro-cotton and Synolac, after interpolation finishes, stirred 1 hour at 25-30 ℃ of constant temperature, add aminoresin then and stirred 20-30 minute at 25-30 ℃ of constant temperature, add described aqueous premix again and, obtain host 25-30 ℃ of constant temperature stirring 20-30 minute;
With host, solidifying agent and mixing diluents, add an amount of dyestuff simultaneously, obtain the painted varnish that described fabric paper tinsel is washed with fire resistant water resistant.
In preparation process, the dyestuff that is added can be the dyestuff of being used always in the fabric paper tinsel, appropriate solvent shaped metal complexing transparency dye (as the product of public Longhua limited-liability company of BASF Aktiengesellschaft, Taiwan, Tianjin US business Jie Mei Science and Technology Ltd. etc.) for example, specifically addition can be controlled according to the common way in this area as required.
The present invention also provides a kind of fabric paper tinsel, the chromatograph that the painted varnish that its fabric paper tinsel provided by the invention is washed with fire resistant water resistant is made.Provided by the invention paint varnish with cellulose esters or release cooperation of acrylic resin resinoid can obtain reasonable effect.
Chromatograph in the above-mentioned fabrics paper tinsel can be to obtain according to the common coating process in this area according to following processing parameter:
Bake out temperature is the highest 165 ℃-180 ℃, surface covered 80-100 rice/minute, the order number of the anilox roll of coating machine is 200 orders-190 orders, drying coated amount 1.1-1.4 gram/square, cooperate the resin of suitable concn release (for example concentration is the release FAREL-110 of resin that produces of Kailanda Industry Co., Ltd., Shanghai of 1.5-2.0wt% etc.).
Fabric paper tinsel provided by the invention is a kind of fabric paper tinsel chromatograph coating with the varnish of can painting, and it has following characteristics:
1, the chromatograph coating for preparing can be high temperature resistant, nondiscoloration under 180 ℃ temperature, illusion-colour not, and have thermoset preferably;
2, the various organic dye processing of painting of can arranging in pairs or groups, and, aluminize back chromatograph and aluminium lamination combine the fastness height;
3, the fabric paper tinsel with chromatograph that this varnish of can painting forms on resin is release is cut edge neatly, and cloth shifts to add and is difficult for burr occurring man-hour, falls the bronze phenomenon;
4, after the fabric paper tinsel with chromatograph that the coating of this varnish obtains is transferred on the cloth, can in being the detergent solution of 5wt%, 50 ℃, concentration soak phenomenon such as do not occur more than 30 minutes fading, come off;
5, this varnish of can painting is used with host and the two components of solidifying agent, and having is heated preferably, and the performance of curing reaction takes place.
Embodiment
Understand for technical characterictic of the present invention, purpose and beneficial effect being had more clearly, existing technical scheme of the present invention is carried out following detailed description, but but can not be interpreted as qualification practical range of the present invention.
Embodiment 1
The painted varnish that present embodiment provides a kind of fabric paper tinsel to wash with fire resistant water resistant, its preparation method may further comprise the steps:
Preparation host:
1,15 kilograms of butanone, 8 kilograms of vinyl acetic monomers and 18 kilograms of solid thermoplastic acrylic resins (hydroxyl value is that 7.5mgKOH/g, molecular weight are 30000, second-order transition temperature be 90 ℃) are dropped in the reactor, stirred 2 hours at 50-60 ℃ of constant temperature, add 5 kilograms of propyl carbinols then, obtain aqueous premix, standby;
2,20 kilograms of butanone and 5 kilograms of pimelinketone are dropped in another reactor, add 8 kilograms of coating while stirring and use nitro-cotton (1/8 second, nitrogen content 11.3%) and 5 kilograms of short oil-ity alcohol acid resins (acid value is that 10mgKOH/g, hydroxyl value are 45mgKOH/g), stirred 1 hour at 25-30 ℃ of constant temperature;
3, in the mixture that step 2 obtains, add 6 kilograms of aminoresin (methyl-etherified terpolycyantoamino-formaldehyde resin, solid content are 80%), stirred 30 minutes at 25-30 ℃ of constant temperature;
4, the aqueous premix that 46 kilograms of steps 1 are obtained joins in the mixture that step 3 obtains, and stirs 30 minutes at 25-30 ℃ of constant temperature, filters discharging and obtains host;
The preparation varnish of can painting:
10 kilograms of hosts are cooperated 2.5 kilograms of toluene diisocyanate trimers, and (solid content is 50%, the content of isocyanato is 11%), add 8.75 kilograms of thinners (weight ratio of butanone and pimelinketone is 4: 1 a mixing solutions) again, (mixing colouring agent is BASF yellow dyes Y-157 and orange dyestuff O-251 to add 600 gram mixing colouring agents at last, the two mass ratio is 3: 1), stir after 20 minutes, obtain the painted varnish of present embodiment, it can be used as the machine material and uses, and the feed liquid for preparing is preferably in 6 hours with interior use.
Present embodiment also provides a kind of fabric paper tinsel, and it prepares in accordance with the following methods:
1, the painted varnish that present embodiment is provided is applied to the formed resin release surface formation of the FAREL-110 chromatograph that concentration is 1.8wt%, wherein, the processing parameter that is adopted during coating is as follows: anilox roll 200 orders, bake out temperature is controlled to be 100 ℃-150 ℃-165 ℃-170 ℃-150 ℃, surface covered is controlled to be 100 meters/minute, drying coated amount be controlled to be 1.2-1.4 gram/square;
2, aluminize according to the method for routine, and coating protection glue, the fabric paper tinsel obtained.
(difference of the two is to prepare the chromatograph coating difference that chromatograph adopts to utilize the fabric paper tinsel that general fabric paper tinsel and present embodiment provide, general fabric paper tinsel is made by common chromatograph coating) by heating and pressurizing that each layer information on the fabric paper tinsel is local or all transfer to fabric face behind the separate application fabric glue, after then the PET basement membrane being peeled off, form and shift fabric.
The transfer fabric for preparing is carried out performance test, and the content and the test result of performance test are as shown in table 1.
Table 1
Annotate: existing fabric paper tinsel coating is the FALAC-450 fabric paper tinsel coating that Kailanda Industry Co., Ltd., Shanghai produces.
When utilizing test tape that the fabric paper tinsel is cut edge property testing, the fabric paper tinsel that present embodiment provides has side cut property preferably, and does not have the burr appearance, and chromatograph combines the fastness height with the look aluminium of aluminium coated.The transfer fabric that the fabric paper tinsel that utilizes present embodiment to provide is made can nondiscoloration under 180 ℃ high temperature, soaks not occur fading in 30 minutes in 50 ℃, concentration are the detergent solution of 5wt%.The painted varnish that above test result explanation present embodiment provides has good performance than existing chromatograph coating, is suitable for preparing the chromatograph coating of fabric paper tinsel.
Embodiment 2
The painted varnish that present embodiment provides a kind of fabric paper tinsel to wash with fire resistant water resistant, its preparation method may further comprise the steps:
Preparation host:
1,15 kilograms of butanone, 15 kilograms of vinyl acetic monomers and 20 kilograms of solid thermoplastic acrylic resins (hydroxyl value is that 7.5mgKOH/g, molecular weight are 30000, second-order transition temperature be 90 ℃) are dropped in the reactor, stirred 2 hours at 50-60 ℃ of constant temperature, add 2 kilograms of propyl carbinols then, obtain aqueous premix, standby;
2,17 kilograms of butanone and 4 kilograms of pimelinketone are dropped in another reactor, add 8 kilograms of coating while stirring and use nitro-cotton (1/4 second, nitrogen content is 11.5%) and 3 kilograms of short oil-ity alcohol acid resins (acid value is that 10mgKOH/g, hydroxyl value are 45mgKOH/g), stirred 1 hour at 25-30 ℃ of constant temperature;
3, in the mixture that step 2 obtains, add 8 kilograms of aminoresin (methyl-etherified terpolycyantoamino-formaldehyde resin, solid content are 80%), stirred 30 minutes at 25-30 ℃ of constant temperature;
4, in the mixture that the aqueous premix adding step 3 that 52 kilograms of steps 1 is obtained obtains, stirred 30 minutes, filter discharging and obtain host at 25-30 ℃ of constant temperature;
The preparation varnish of can painting:
10 kilograms of hosts are cooperated 2.5 kilograms of toluene diisocyanate trimers, and (solid content is 50%, the content of isocyanato is 11%) ratio, add 8.75 kilograms of thinners (weight ratio of butanone and pimelinketone is 4: 1 a mixing solutions) again, (this mixing colouring agent is BASF yellow dyes Y-157 and orange dyestuff O-251 to add 600 gram mixing colouring agents at last, the weight ratio of the two is 3: 1), stirred 20 minutes, obtain the painted varnish of present embodiment, it can be used as the machine material and uses, and the feed liquid for preparing is preferably in 6 hours with interior use.
Present embodiment also provides a kind of fabric paper tinsel, and it prepares in accordance with the following methods:
1, the painted varnish that present embodiment is provided is applied to the formed resin release surface formation of the FAREL-110 chromatograph that concentration is 1.8wt%, wherein, the processing parameter that is adopted during coating is as follows: anilox roll 200 orders, bake out temperature is controlled to be 100 ℃-150 ℃-165 ℃-175 ℃-150 ℃, surface covered is controlled to be 100 meters/minute, drying coated amount be controlled to be 1.2-1.4 gram/square;
2, aluminize according to the method for routine, and coating protection glue, the fabric paper tinsel obtained.
(difference of the two is to prepare the chromatograph coating difference that chromatograph adopts to utilize the fabric paper tinsel that general fabric paper tinsel and present embodiment provide, general fabric paper tinsel is made by common chromatograph coating) by heating and pressurizing that each layer information on the fabric paper tinsel is local or all transfer to fabric face behind the separate application fabric glue, after then the PET basement membrane being peeled off, form and shift fabric.
The transfer fabric for preparing is carried out performance test, and the content and the test result of performance test are as shown in table 2.
Table 2
Annotate: existing fabric paper tinsel coating is the FALAC-450 fabric paper tinsel coating that Kailanda Industry Co., Ltd., Shanghai produces.
When utilizing test tape that the fabric paper tinsel is cut edge property testing, the fabric paper tinsel that present embodiment provides has side cut property preferably, and does not have the burr appearance, and chromatograph combines the fastness height with the look aluminium of aluminium coated.The transfer fabric that the fabric paper tinsel that utilizes present embodiment to provide is made can nondiscoloration under 180 ℃ high temperature, soaks not occur fading in 30 minutes in 50 ℃, concentration are the detergent solution of 5wt%.The painted varnish that above test result explanation present embodiment provides has good performance than existing chromatograph coating, is suitable for preparing the chromatograph coating of fabric paper tinsel.
Embodiment 3
The painted varnish that present embodiment provides a kind of fabric paper tinsel to wash with fire resistant water resistant, its preparation method may further comprise the steps:
Preparation host:
1,20 kilograms of butanone, 10 kilograms of vinyl acetic monomers and 15 kilograms of solid thermoplastic acrylic resins (hydroxyl value is that 7.5mgKOH/g, molecular weight are 30000, second-order transition temperature be 90 ℃) are dropped in the reactor, stirred 2 hours at 50-60 ℃ of constant temperature, add 2 kilograms of propyl carbinols then, obtain aqueous premix, standby;
2,15 kilograms of butanone and 3 kilograms of pimelinketone are dropped in another reactor, add 8 kilograms of coating while stirring and use nitro-cotton (1/8 second, nitrogen content is 11.3%) and 5 kilograms of short oil-ity alcohol acid resins (acid value is that 10mgKOH/g, hydroxyl value are 45mgKOH/g), stirred 1 hour at 25-30 ℃ of constant temperature;
3, in the mixture that step 2 obtains, add 10 kilograms of aminoresin (butyl alcohol etherified melamine-formaldehyde resin, solid content are 60%), stirred 30 minutes at 25-30 ℃ of constant temperature;
4, in the mixture that the aqueous premix adding step 3 that 47 kilograms of steps 1 is obtained obtains, stirred 30 minutes, obtain host at 25-30 ℃ of constant temperature;
The preparation varnish of can painting:
10 kilograms of hosts are cooperated 2.5 kilograms of toluene diisocyanate trimers, and (solid content is 50%, the content of isocyanato is 11%) ratio, add 8.75 kilograms of thinners (weight ratio of butanone and pimelinketone is 4: 1 a mixing solutions) again, (this mixing colouring agent is BASF yellow dyes Y-157 and orange dyestuff O-251 to add 600 gram mixing colouring agents at last, the weight ratio of the two is 3: 1), stirred 20 minutes, obtain the painted varnish of present embodiment, it can be used as the machine material and uses, and the feed liquid for preparing is preferably in 6 hours with interior use.
Present embodiment also provides a kind of fabric paper tinsel, and it prepares in accordance with the following methods:
1, the painted varnish that present embodiment is provided is applied to the formed resin release surface formation of the FAREL-110 chromatograph that concentration is 1.8wt%, wherein, the processing parameter that is adopted during coating is as follows: anilox roll 200 orders, bake out temperature is controlled to be 100 ℃-155 ℃-165 ℃-175 ℃-150 ℃, surface covered is controlled to be 100 meters/minute, drying coated amount be controlled to be 1.2-1.4 gram/square;
2, aluminize according to the method for routine, and coating protection glue, the fabric paper tinsel obtained.
(difference of the two is to prepare the chromatograph coating difference that chromatograph adopts to utilize the fabric paper tinsel that general fabric paper tinsel and present embodiment provide, general fabric paper tinsel is made by common chromatograph coating) by heating and pressurizing that each layer information on the fabric paper tinsel is local or all transfer to fabric face behind the separate application fabric glue, after then the PET basement membrane being peeled off, form and shift fabric.
The transfer fabric for preparing is carried out performance test, and the content and the test result of performance test are as shown in table 3.
Table 3
Annotate: existing fabric paper tinsel coating is the FALAC-450 fabric paper tinsel coating that Kailanda Industry Co., Ltd., Shanghai produces.
When utilizing test tape that the fabric paper tinsel is cut edge property testing, the fabric paper tinsel that present embodiment provides has side cut property preferably, and does not have the burr appearance, and chromatograph combines the fastness height with the look aluminium of aluminium coated.The transfer fabric that the fabric paper tinsel that utilizes present embodiment to provide is made can nondiscoloration under 180 ℃ high temperature, soaks not occur fading in 30 minutes in 50 ℃, concentration are the detergent solution of 5wt%.The painted varnish that above test result explanation present embodiment provides has good performance than existing chromatograph coating, is suitable for preparing the chromatograph coating of fabric paper tinsel.
Above-described specific embodiment; purpose of the present invention, technical scheme and beneficial effect are further described; institute is understood that; the above only is specific embodiments of the invention; and be not intended to limit the scope of the invention; within the spirit and principles in the present invention all, any modification of being made, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. painted varnish that the fabric paper tinsel is washed with fire resistant water resistant, it comprises host, solidifying agent and thinner, and wherein, three's weight ratio is 4-5: 1-2: 3-4;
Wherein, described host comprises following raw material composition: nitro-cotton, 5-10 weight part, aminoresin, 5-10 weight part, acrylic resin, 10-20 weight part, Synolac, 2-5 weight part, organic solvent, 20-50 weight part, stablizer, 2-5 weight part.
2. the varnish of painting as claimed in claim 1, wherein, described nitro-cotton is the coating nitro-cotton, this coating is 1/4-1/16 second with the specification of nitro-cotton, its nitrogen content≤12%.
3. the varnish of painting as claimed in claim 1, wherein, described aminoresin comprises one or two or more kinds the combination in methyl-etherified terpolycyantoamino-formaldehyde resin, butyl alcohol etherified melamine-formaldehyde resin and the alkylated melamine formaldehyde resin, and the solid content of described aminoresin is 60-80wt%.
4. the varnish of painting as claimed in claim 1, wherein, described acrylic resin is the solid thermoplastic acrylic resin that contains hydroxyl, and the weight-average molecular weight of this solid thermoplastic acrylic resin is 10000-30000, hydroxyl value is 5-10mgKOH/g, and second-order transition temperature is 80-90 ℃.
5. the varnish of painting as claimed in claim 1, wherein, described Synolac is a short oil-ity alcohol acid resin, the acid value≤12mgKOH/g of this short oil-ity alcohol acid resin, hydroxyl value is 40-50mgKOH/g.
6. the varnish of painting as claimed in claim 1, wherein, described solidifying agent is a toluene diisocyanate trimer, and the solid content of this toluene diisocyanate trimer is 40-60wt%, and the content of isocyanato is 7-12wt%.
7. the varnish of painting as claimed in claim 1, wherein, described stablizer is a propyl carbinol.
8. the varnish of painting as claimed in claim 1, wherein, described thinner comprises the combination more than two or three in butanone, pimelinketone, toluene and the vinyl acetic monomer.
9. the preparation method of the painted varnish washed with fire resistant water resistant of each described fabric paper tinsel of claim 1-8, it may further comprise the steps:
Acrylic resin is mixed mutually with 1/2 to 2/3 the organic solvent that occupies machine solvent gross weight, be warming up to 50-60 ℃ and insulated and stirred 1-2 hour, add stablizer, obtain aqueous premix, standby;
Remaining organic solvent is added in the reactor, when stirring, add nitro-cotton and Synolac, after interpolation finishes, stirred 1 hour at 25-30 ℃ of constant temperature, add aminoresin then and stirred 20-30 minute at 25-30 ℃ of constant temperature, add described aqueous premix again and, obtain host 25-30 ℃ of constant temperature stirring 20-30 minute;
With host, solidifying agent and mixing diluents, add an amount of dyestuff simultaneously, obtain the painted varnish that described fabric paper tinsel is washed with fire resistant water resistant.
10. fabric paper tinsel, it has the chromatograph that painted varnish that each described fabric paper tinsel of claim 1-8 washes with fire resistant water resistant is made.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103306143A (en) * | 2013-05-27 | 2013-09-18 | 桐乡市永盛织物整理有限公司 | Gold stamping glue solution and gold stamping method using same |
| CN103725107A (en) * | 2013-12-11 | 2014-04-16 | 上海嘉宝莉涂料有限公司 | Cellulose acetate butyrate modified thermoplastic acrylic resin woodenware varnish and preparation method thereof |
| CN104327644A (en) * | 2014-11-05 | 2015-02-04 | 侨健新能源科技（苏州）有限公司 | High-mechanical-property impact-resisting heat-preservation coating |
| CN106752974A (en) * | 2016-12-26 | 2017-05-31 | 东莞理工学院 | A kind of environment-friendly type nitrocotton leather gloss agent and preparation method thereof |
| US9914848B1 (en) | 2016-10-31 | 2018-03-13 | Ppg Architectural Finishes, Inc. | Refinish coating composition |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05320570A (en) * | 1992-05-15 | 1993-12-03 | Meidensha Corp | Application of coating resistant to perfluorocarbon |
| JPH08224829A (en) * | 1995-02-21 | 1996-09-03 | Nippon Steel Corp | Lubrication coating aluminum plating steel plate having excellent heat resistance |
| JP2002035676A (en) * | 2000-07-26 | 2002-02-05 | Kansai Paint Co Ltd | Coating finishing method |
| CN101085898A (en) * | 2007-07-17 | 2007-12-12 | 马鞍山采石矶涂料有限公司 | Environment-friendly type normal temperature solidifying water epoxy resin coating and preparation method thereof |
| CN101724325A (en) * | 2009-12-14 | 2010-06-09 | 上海维凯化学品有限公司 | Radar aluminum plating transfer coating suitable for seamless molding process and preparation method thereof |
-
2010
- 2010-12-14 CN CN201010587783XA patent/CN102260441B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05320570A (en) * | 1992-05-15 | 1993-12-03 | Meidensha Corp | Application of coating resistant to perfluorocarbon |
| JPH08224829A (en) * | 1995-02-21 | 1996-09-03 | Nippon Steel Corp | Lubrication coating aluminum plating steel plate having excellent heat resistance |
| JP2002035676A (en) * | 2000-07-26 | 2002-02-05 | Kansai Paint Co Ltd | Coating finishing method |
| CN101085898A (en) * | 2007-07-17 | 2007-12-12 | 马鞍山采石矶涂料有限公司 | Environment-friendly type normal temperature solidifying water epoxy resin coating and preparation method thereof |
| CN101724325A (en) * | 2009-12-14 | 2010-06-09 | 上海维凯化学品有限公司 | Radar aluminum plating transfer coating suitable for seamless molding process and preparation method thereof |
Cited By (12)
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|---|---|---|---|---|
| CN103306143A (en) * | 2013-05-27 | 2013-09-18 | 桐乡市永盛织物整理有限公司 | Gold stamping glue solution and gold stamping method using same |
| CN103725107A (en) * | 2013-12-11 | 2014-04-16 | 上海嘉宝莉涂料有限公司 | Cellulose acetate butyrate modified thermoplastic acrylic resin woodenware varnish and preparation method thereof |
| CN103725107B (en) * | 2013-12-11 | 2016-06-29 | 上海嘉宝莉涂料有限公司 | A kind of acetate butyrate fibre modification thermoplastic acrylic resin woodenware lacquer and preparation method thereof |
| CN104327644A (en) * | 2014-11-05 | 2015-02-04 | 侨健新能源科技（苏州）有限公司 | High-mechanical-property impact-resisting heat-preservation coating |
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