CN102259837A - Particle used for hydrogen production and preparation method thereof - Google Patents
Particle used for hydrogen production and preparation method thereof Download PDFInfo
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- CN102259837A CN102259837A CN2011101242841A CN201110124284A CN102259837A CN 102259837 A CN102259837 A CN 102259837A CN 2011101242841 A CN2011101242841 A CN 2011101242841A CN 201110124284 A CN201110124284 A CN 201110124284A CN 102259837 A CN102259837 A CN 102259837A
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- particle
- hydrogen manufacturing
- hydrogen production
- hydrogen
- particle used
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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Abstract
The invention relates to a particle used for hydrogen production and a preparation method thereof, belonging to the technical field of hydrogen production. The invention is characterized in that the particle used for hydrogen production is prepared by pressing solid powder; components of the solid powder comprise A(MH4), wherein A is Li or Na, M is B or Al or NH3BH3; and the surface of the particle used for hydrogen production is coated with a thin film. The preparation method of the particle used for hydrogen production is characterized in that: the particle used for hydrogen production is prepared by pressing the solid powder by virtue of a pressing machine; and the surface of the particle used for hydrogen production is coated with resin by adopting a thin film coating process or is coated with a thermal shrinkage film by adopting a thermal shrinkage process. The particle in the invention has the advantages of good fluidity, stableness in a steam environment, controllable reaction process, stable hydrogen production speed, safe and reliable system, simple preparation process, low manufacturing cost, convenience in operation, stable product performance and the like and can be widely applied to hydrogen production devices in solid liquid reaction hydrolysis.
Description
Technical field
The invention belongs to technical field of hydrogen preparation, particularly relate to a kind of hydrogen manufacturing particle and preparation method thereof.
Background technology
At present, hydrogen is reproducible energy carrier, with A (MH
4) (A=Li, Na; M=B, Al) and NH
3BH
3For the IIIA family complex hydride of representative has theoretical hydrogen-storage amount height, advantage that proportion is low, adopt A (MH
4) (A=Li, Na; M=B, Al) and NH
3BH
3Can reduce the weight of storing up the hydrogen device Deng the novel light hydrogen storage material widely as hydrogen storage media, these novel light hydrogen storage materials can produce hydrogen with water generation chemical reaction under the catalyzer existence condition.Control the condition of reaction well, the hydrogen of generation just can directly offer fuel cell or other need hydrogen storage equipment.But this class new chemical hydrogen-preparing hydrogen-storing fuel system exists a lot of problems, and it is fashionable especially to be applied to field portable.As: 1) when the novel light hydrogen storage material was made into the liquid fuel use, effective volume and weight hydrogen-storage amount reduced greatly; 2) poor stability of storage hydrogen fuel solution is because NaBH
4In strong alkaline aqueous solution, be in a metastable state, be easy to spontaneous generation hydrolysis releasing hydrogen gas, have very large potential safety hazard, also be unfavorable for standing storage simultaneously; 3) palladium, precious metal catalyst cost height such as ruthenium, immobilized rear catalyst work-ing life short (because hydrolysis reaction is the very exothermic reaction that occurs in catalyst surface); 4) reaction product sodium metaborate (NaBO
2) easy blocking pipeline; These defectives make the widespread use of this technology be subjected to certain limitation.
Improve the volume and weight efficient of hydrogen storage system, a kind of way is to adopt the solid feed way, applies for a patent as 201010112800.4.But A (MH
4) (A=Li, Na; M=B, Al) and NH
3BH
3Exist the easy moisture absorption in air Deng the novel light hydrogen storage material, and hydrolysis reaction carries out technical problems such as strong heat release.
Summary of the invention
The present invention provides a kind of hydrogen manufacturing particle and preparation method thereof for solving the technical problem that exists in the known technology.
One of purpose of the present invention provides a kind of good fluidity that has, and is stable in steam ambient, can control extent of reaction, hydrogen-producing speed is stable, security of system is reliable, and characteristics such as low cost of manufacture can be widely used in the hydrogen manufacturing particle of the device for preparing hydrogen through hydrolysis of solid-liquid reaction.
Hydrogen manufacturing particle A (MH
4) (A=Li, Na; M=B, Al) and NH
3BH
3Under the catalyzer existence condition, can produce hydrogen Deng the novel light hydrogen storage material with the water reaction.With NaBH
4For example reacts as follows:
NaBH
4+2H
2O＝NaBO
2+4H
2
Liquid state storage hydrogen fuel reaction hydrogen producing technology commonly used relatively at present adopts the solid feed way can effectively improve the volume and weight efficient of hydrogen storage system.
Hydrogen manufacturing particle of the present invention is to solve the technical scheme that the technical problem that exists in the known technology takes to be:
A kind of hydrogen manufacturing particle is characterized in: the hydrogen manufacturing particle is that pressed powder is made by press; The pressed powder composition is A (MH
4), A is Li or Na, M is B or Al, or NH
3BH
3Hydrogen manufacturing is coated with film with particle surface.
Hydrogen manufacturing of the present invention can also be taked following technical scheme with particle:
Described hydrogen manufacturing particle is characterized in: the hydrogen manufacturing particle shape that pressed powder is made by press is spherical or square.
Described hydrogen manufacturing particle is characterized in: film is the resin-coated or heat shrink process coating heat shrinkage film of art for coating.
Described hydrogen manufacturing particle is characterized in: resin is PE, PP, PET or PVA.
Described hydrogen manufacturing particle is characterized in: heat shrinkage film is PE, PP or PET film.
It is simple that two of purpose of the present invention provides a kind of preparation technology of having, and low cost of manufacture is easy to operate, the hydrogen manufacturing particulate preparation method of particle characteristics such as stable in steam ambient.
Hydrogen manufacturing of the present invention with the technical scheme that the particulate preparation method is taked is:
A kind of hydrogen manufacturing particulate preparation method is characterized in: hydrogen manufacturing is formed by the press compacting by pressed powder with particle; The pressed powder composition is A (MH4), and A is Li or Na, and M is B or Al, or NH
3BH
3Hydrogen manufacturing is resin-coated or coat heat shrinkage film by heat shrink process by film coating procedure with particle surface.
Hydrogen manufacturing of the present invention can also be taked following technical scheme with the particulate preparation method:
Described hydrogen manufacturing particulate preparation method is characterized in: hydrogen manufacturing coats PE, PP, PET or PVA resin with particle surface by film coating procedure.
Described hydrogen manufacturing particulate preparation method, be characterized in: hydrogen manufacturing coats PE with particle surface by heat shrink process, PP or PET heat shrinkage film.
Advantage and positively effect that the present invention has are:
Owing to adopted brand-new technology scheme of the present invention, compared with prior art, the present invention adopts A (MH with particle and preparation method thereof in hydrogen manufacturing
4) (A=Li, Na; M=B, Al) and NH
3BH
3Deng the novel light hydrogen storage material, its solid materials can keep good flowability in damp and hot steam, can blocking pipe in the reinforced process; Adopt the solid feed way, improved the volume and weight efficient stream of system.
Advantages such as hydrogen manufacturing of the present invention has good fluidity with particle, and is stable in steam ambient, can control extent of reaction, and hydrogen-producing speed is stable, and security of system is reliable can be widely used in the device for preparing hydrogen through hydrolysis of solid-liquid reaction.Advantages such as it is simple that hydrogen manufacturing has technology with the particulate preparation method, and low cost of manufacture is easy to operate, and product performance are stable.
Embodiment
For further understanding technology contents of the present invention, characteristics and effect, exemplify following examples now, be described in detail as follows:
Embodiment 1
A kind of hydrogen manufacturing particle is that pressed powder is made spheroidal particle by press, and the pressed powder composition is LiBH
4, hydrogen manufacturing is coated with the PE heat shrinkage film that heat shrink process coats with the spheroidal particle surface.
Embodiment 2
A kind of hydrogen manufacturing particulate preparation method forms spheroidal particle by pressed powder by the press compacting, and the pressed powder composition is NaBH
4, hydrogen manufacturing coats the PVA resin with the spheroidal particle surface by film coating procedure.
Concrete preparation process:
Take by weighing NaBH
4Powder 0.5g is pressed into spheroidal particle with 50 tons of press.PVA is dissolved in the dehydrated alcohol, utilizes coating pan that PVA solution evenly is sprayed on NaBH
4Particle surface, the oven dry back obtains NaBH in 60 ℃ of baking ovens
4Make the hydrogen manufacturing spheroidal particle.
Embodiment 3
A kind of hydrogen manufacturing particulate preparation method, preparation process is: take by weighing NH
3BH
3Powder 1g is pressed into spheroidal particle with 50 tons of press.PE is dissolved in the dehydrated alcohol, utilizes coating pan that PE solution evenly is sprayed on NH
3BH
3Particle surface, the oven dry back obtains NH in 60 ℃ of baking ovens
3BH
3The hydrogen manufacturing spheroidal particle.
Embodiment 4
A kind of hydrogen manufacturing particulate preparation method, preparation process is: take by weighing NaBH
4Powder 2g is pressed into spheroidal particle with 50 tons of press.Utilize heat shrink process that the PE heat shrinkage film is coated on NaBH in the vacuum glove box
4Particle surface obtains NaBH
4The hydrogen manufacturing spheroidal particle.
Claims (8)
1. hydrogen manufacturing particle, it is characterized in that: the hydrogen manufacturing particle is that pressed powder is made by press; The pressed powder composition is A (MH
4), A is Li or Na, M is B or Al, or NH
3BH
3Hydrogen manufacturing is coated with film with particle surface.
2. according to the described hydrogen manufacturing particle of claim 1, it is characterized in that: the hydrogen manufacturing particle shape that pressed powder is made by press is spherical or square.
3. according to claim 1 or 2 described hydrogen manufacturing particles, it is characterized in that: film is the resin-coated or heat shrink process coating heat shrinkage film of art for coating.
4. according to the described hydrogen manufacturing particle of claim 3, it is characterized in that: resin is PE, PP, PET or PVA.
5. according to the described hydrogen manufacturing particle of claim 3, it is characterized in that: heat shrinkage film is PE, PP or PET film.
6. hydrogen manufacturing particulate preparation method is characterized in that: hydrogen manufacturing is formed by the press compacting by pressed powder with particle; The pressed powder composition is A (MH4), and A is Li or Na, and M is B or Al, or NH
3BH
3Hydrogen manufacturing is resin-coated or coat heat shrinkage film by heat shrink process by film coating procedure with particle surface.
7. according to the described hydrogen manufacturing of claim 6 particulate preparation method, it is characterized in that: hydrogen manufacturing coats PE, PP, PET or PVA resin with particle surface by film coating procedure.
8. according to the described hydrogen manufacturing of claim 6 particulate preparation method, it is characterized in that: hydrogen manufacturing coats heat shrinkage film with particle surface by heat shrink process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101242841A CN102259837B (en) | 2011-05-13 | 2011-05-13 | Particle used for hydrogen production and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101242841A CN102259837B (en) | 2011-05-13 | 2011-05-13 | Particle used for hydrogen production and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102259837A true CN102259837A (en) | 2011-11-30 |
| CN102259837B CN102259837B (en) | 2013-01-30 |
Family
ID=45006712
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011101242841A Expired - Fee Related CN102259837B (en) | 2011-05-13 | 2011-05-13 | Particle used for hydrogen production and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102259837B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014191682A1 (en) * | 2013-05-30 | 2014-12-04 | Herakles | Obtaining a solid form containing heat-stable borazane, said solid form, and the use thereof for generating hydrogen |
| CN104190916A (en) * | 2014-08-27 | 2014-12-10 | 厦门大学 | Oxidation resisting hydrolysis hydrogen generation composite powder and preparation method thereof |
| CN107324280A (en) * | 2017-07-04 | 2017-11-07 | 厦门大学 | The anti-oxidant coating of moisture-resistant and its processing method of aluminium base hydrolytic hydrogen production material |
| CN107470611A (en) * | 2017-08-25 | 2017-12-15 | 杭州氢源科技有限公司 | A kind of hydrogen manufacturing alumina particles and preparation method thereof |
| CN110200991A (en) * | 2019-07-10 | 2019-09-06 | 陈天朗 | Facilitate hydrogen manufacturing product and its application for remove human body active oxygen radical |
| WO2023050585A1 (en) * | 2021-09-29 | 2023-04-06 | 中国科学院深圳先进技术研究院 | Medical hydrogen storage material and preparation method therefor |
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| US20030228727A1 (en) * | 2002-05-07 | 2003-12-11 | Guerra John Michael | Stress-induced bandgap-shifted semiconductor photoelectrolytic/photocatalytic/photovoltaic surface and method for making same |
| CN101100285A (en) * | 2006-07-07 | 2008-01-09 | 中国科学院金属研究所 | Chemical hydride hydrogen storing material system, hydrogen preparing method and hydrogen preparing device |
| US20090110857A1 (en) * | 2006-04-20 | 2009-04-30 | Toyo Seikan Kaisha, Ltd. | Oxygen absorber for blending in a resin and method of producing the same |
| CN101906642A (en) * | 2010-08-30 | 2010-12-08 | 新奥科技发展有限公司 | Method for making photoelectric hydrogen production electrode and photoelectric hydrogen production electrode |
-
2011
- 2011-05-13 CN CN2011101242841A patent/CN102259837B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030228727A1 (en) * | 2002-05-07 | 2003-12-11 | Guerra John Michael | Stress-induced bandgap-shifted semiconductor photoelectrolytic/photocatalytic/photovoltaic surface and method for making same |
| US20090110857A1 (en) * | 2006-04-20 | 2009-04-30 | Toyo Seikan Kaisha, Ltd. | Oxygen absorber for blending in a resin and method of producing the same |
| CN101100285A (en) * | 2006-07-07 | 2008-01-09 | 中国科学院金属研究所 | Chemical hydride hydrogen storing material system, hydrogen preparing method and hydrogen preparing device |
| CN101906642A (en) * | 2010-08-30 | 2010-12-08 | 新奥科技发展有限公司 | Method for making photoelectric hydrogen production electrode and photoelectric hydrogen production electrode |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014191682A1 (en) * | 2013-05-30 | 2014-12-04 | Herakles | Obtaining a solid form containing heat-stable borazane, said solid form, and the use thereof for generating hydrogen |
| FR3006307A1 (en) * | 2013-05-30 | 2014-12-05 | Herakles | OBTAINING A SOLID FORM COMPRISING BORAZANE STABILIZED THERMALLY THERE SOLID FORM AND ITS USE TO GENERATE HYDROGEN |
| US9663360B2 (en) | 2013-05-30 | 2017-05-30 | Herakles | Obtaining a solid form containing heat-stabilized borazane, said solid form, and the use thereof for generating hydrogen |
| CN104190916A (en) * | 2014-08-27 | 2014-12-10 | 厦门大学 | Oxidation resisting hydrolysis hydrogen generation composite powder and preparation method thereof |
| CN107324280A (en) * | 2017-07-04 | 2017-11-07 | 厦门大学 | The anti-oxidant coating of moisture-resistant and its processing method of aluminium base hydrolytic hydrogen production material |
| CN107470611A (en) * | 2017-08-25 | 2017-12-15 | 杭州氢源科技有限公司 | A kind of hydrogen manufacturing alumina particles and preparation method thereof |
| CN110200991A (en) * | 2019-07-10 | 2019-09-06 | 陈天朗 | Facilitate hydrogen manufacturing product and its application for remove human body active oxygen radical |
| WO2023050585A1 (en) * | 2021-09-29 | 2023-04-06 | 中国科学院深圳先进技术研究院 | Medical hydrogen storage material and preparation method therefor |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102259837B (en) | 2013-01-30 |
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Granted publication date: 20130130 Termination date: 20140513 |