CN102259343A - Multilayer composite ceramic cutting tool - Google Patents

Multilayer composite ceramic cutting tool Download PDF

Info

Publication number
CN102259343A
CN102259343A CN2010101862394A CN201010186239A CN102259343A CN 102259343 A CN102259343 A CN 102259343A CN 2010101862394 A CN2010101862394 A CN 2010101862394A CN 201010186239 A CN201010186239 A CN 201010186239A CN 102259343 A CN102259343 A CN 102259343A
Authority
CN
China
Prior art keywords
layer
thulium
multilayer composite
cutting tool
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2010101862394A
Other languages
Chinese (zh)
Inventor
陶景超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI JINGWEN MATERIAL TECHNOLOGY DEVELOPMENT Co Ltd
Original Assignee
SHANGHAI JINGWEN MATERIAL TECHNOLOGY DEVELOPMENT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANGHAI JINGWEN MATERIAL TECHNOLOGY DEVELOPMENT Co Ltd filed Critical SHANGHAI JINGWEN MATERIAL TECHNOLOGY DEVELOPMENT Co Ltd
Priority to CN2010101862394A priority Critical patent/CN102259343A/en
Publication of CN102259343A publication Critical patent/CN102259343A/en
Pending legal-status Critical Current

Links

Images

Landscapes

  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention relates to the technical field of cutting tools, in particular to a multilayer composite ceramic cutting tool. The multilayer composite ceramic cutting tool is characterized in that: an upper layer is a nano thulium zirconium ceramic powder body layer; an intermediate layer is an Al2O3 composite material layer; and a lower layer is the nano thulium zirconium ceramic powder body layer. Compared with the prior art, the multilayer composite ceramic cutting tool has a simple and novel structure, high oxidation resistance, a stable chemical property and high corrosion resistance; and the nano thulium zirconium ceramic powder body layer on the outer layer has high intensity, and the intermediate layer is the Al2O3 composite material layer, so that the rigidity and the destruction resistance of the cutting tool are improved.

Description

A kind of MULTILAYER COMPOSITE sintex
[technical field]
The present invention relates to a kind of cutting-tool engineering field, specifically is a kind of MULTILAYER COMPOSITE sintex.
[background technology]
Existing alumina tool: adopt pure AL in the cutter material 2O 3Pottery reaches with AL 2O 3Be main and the ceramic material of a small amount of other elements of interpolation, as MgO, NiO, SiO 2, TiO 2And Cr 2O 3Deng.These additives help strengthening AL 2O 3Bending strength.The room temperature hardness and the high temperature hardness of this kind sintex all are higher than Hardmetal materials, especially can overcome the distortion and the shortcoming of subsiding that general high-speed steel tool and carbide cutting blade are prone to.In addition, AL 2O 3Anti-oxidant, the anti-cementability and the chemical inertness of sintex are better.
Stupalox has a fatal shortcoming, and fragility is big, and the performance that this has greatly limited the sintex premium properties limits its application in practice.
[summary of the invention]
The objective of the invention is to overcome the deficiencies in the prior art, the MULTILAYER COMPOSITE sintex of a kind of high tenacity and strong anti-destructive is provided.
For achieving the above object, design a kind of MULTILAYER COMPOSITE sintex, it is characterized in that described MULTILAYER COMPOSITE sintex upper strata is a nanometer thulium zircon ceramic powder layer, the intermediate layer is AL 2O 3Composite layer, lower floor is a nanometer thulium zircon ceramic powder layer.
Described nanometer thulium zircon ceramic its component of powder layer and mass percentage content are: thulium oxide 7%~38%, zirconia 62%~93% is fine and close spherical structure.
Described AL 2O 3Its component of composite layer and mass percentage content are: AL 2O 355%, TiC5%, MO powder 20%, Ni powder 20%, described MO powder and Ni powder average grain are less than 2 microns, and purity is greater than 99%.
The present invention compared with prior art, and is simple in structure, novel, and oxidation resistance is strong, stable chemical performance, and wearability is strong, and outer nanometer thulium zircon ceramic powder layer intensity is big, and the intermediate layer is AL 2O 3Composite layer increases cutter toughness and anti-destructive power.
[description of drawings]
Fig. 1 is a structural representation of the present invention;
1 is the upper strata among Fig. 1, and 2 is the intermediate layer, and 3 is lower floor
[specific embodiment]
The invention will be further described below in conjunction with embodiment.Production technology of the present invention is to implement easily to this professional people.
Described MULTILAYER COMPOSITE sintex upper strata is a nanometer thulium zircon ceramic powder layer, and the intermediate layer is AL 2O 3Composite layer, lower floor is a nanometer thulium zircon ceramic powder layer.
Described nanometer thulium zircon ceramic its component of powder layer and mass percentage content are: thulium oxide 7%~38%, zirconia 62%~93% is fine and close spherical structure.
The preparation method is as follows for nanometer thulium zircon ceramic powder layer:
Step 1 is dissolved in the water zirconium oxychloride in the measuring tank of polypropylene material, is heated to 60 ℃~80 ℃ then, adds thulium oxide subsequently, dissolves fully up to thulium oxide, adds urea again, stirs, and dissolves fully up to urea;
Step 2 joins the solution in the step 1 in the pressure reaction still by a PVC plastic conduit, and design pressure is 6.5Mpa, and design temperature is 300 ℃, adds acrylate again;
Step 3, reaction is finished the back and is taken out colloid, and by supercentrifuge, with the speed washing of 16000 rev/mins of rotating speeds, cyclic washing 3-5 time is up to using the detection of 1mol/l liquor argenti nitratis ophthalmicus, till the no chlorion.
Step 4 is squeezed into the colloid pastel in the step 4 in the high speed ball-grinding machine by membrane pump, and adds dispersant Macrogol 2000 0, ball milling 2-3 hour.
Step 5 is sent into the slurry behind the ball milling and is carried out granulation in the sponging granulator, and inlet temperature is between 200-250 ℃, and the discharging opening temperature is between 100-150 ℃.
Described AL 2O 3Its component of composite layer and mass percentage content are: AL 2O 355%, TiC5%, MO powder 20%, Ni powder 20%, described MO powder and Ni powder average grain are less than 2 microns, and purity is greater than 99%.

Claims (3)

1. a MULTILAYER COMPOSITE sintex is characterized in that described MULTILAYER COMPOSITE sintex upper strata is a nanometer thulium zircon ceramic powder layer, and the intermediate layer is AL 2O 3Composite layer, lower floor is a nanometer thulium zircon ceramic powder layer.
2. a kind of MULTILAYER COMPOSITE sintex according to claim 1 is characterized in that described nanometer thulium zircon ceramic its component of powder layer and mass percentage content are: thulium oxide 7%~38%, zirconia 62%~93% is fine and close spherical structure.
3. a kind of MULTILAYER COMPOSITE sintex according to claim 1 is characterized in that described AL 2O 3Its component of composite layer and mass percentage content are: AL 2O 355%, TiC5%, MO powder 20%, Ni powder 20%, described MO powder and Ni powder average grain are less than 2 microns, and purity is greater than 99%.
CN2010101862394A 2010-05-30 2010-05-30 Multilayer composite ceramic cutting tool Pending CN102259343A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010101862394A CN102259343A (en) 2010-05-30 2010-05-30 Multilayer composite ceramic cutting tool

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010101862394A CN102259343A (en) 2010-05-30 2010-05-30 Multilayer composite ceramic cutting tool

Publications (1)

Publication Number Publication Date
CN102259343A true CN102259343A (en) 2011-11-30

Family

ID=45006274

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010101862394A Pending CN102259343A (en) 2010-05-30 2010-05-30 Multilayer composite ceramic cutting tool

Country Status (1)

Country Link
CN (1) CN102259343A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110114196A (en) * 2016-12-26 2019-08-09 京瓷株式会社 Cutter

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110114196A (en) * 2016-12-26 2019-08-09 京瓷株式会社 Cutter
CN110114196B (en) * 2016-12-26 2021-04-20 京瓷株式会社 Cutting tool

Similar Documents

Publication Publication Date Title
CN103708832B (en) Nano ceramic cutter and preparation method thereof
CN102390998B (en) Tungsten carbide composite material containing aluminum oxide particles and silicon nitride whiskers, and preparation method thereof
CN104018052B (en) A kind of TiC whisker reinforcedmetal pottery and preparation method thereof
CN103044014B (en) Preparation method of graphene-nanosheet-reinforced alumina ceramic
CN100417624C (en) Multi-component multi-dimension nano composite ceramics cutting tool material and preparation technique thereof
CN101333616B (en) Whisker- toughened cermet cutting tool and method for preparing same
CN102167346B (en) Kaolin nanotube and preparation method thereof
AU2022224725B2 (en) Preparation method of in-situ synthesized zirconia toughened alumina (ZTA) ceramic particles-reinforced steel matrix structural composite
CN100534952C (en) Method for fabricating ceramics of silicon carbide toughened by Nano bars of alumina
CN103540783B (en) A kind of titanium aluminium carbon granule strengthens Zn Al Alloy Matrix Composites and pressureless sintering preparation method thereof
CN103834842A (en) TiCN-based metal ceramic numerical control tool material with nanocrystalline grain size and preparation method thereof
Dong et al. High content SiC nanowires reinforced Al composite with high strength and plasticity
CN101913876A (en) Method for preparing zirconium boride-tungsten titanium carbide self-lubricating composite ceramic material
CN107032826A (en) A kind of preparation method of hollow alumina ball/SiC reinforcement Cu-base composites
CN103192082B (en) Preparation method for light metal matrix composite material product and slurry of light metal matrix composite material product
CN103056376B (en) Method for preparing spherical nanostructure tungsten/cobalt carbide compound powder
CN101628812A (en) Method for preparing compact yttria ceramics
CN104480334A (en) Preparation method of nanoscale hard alloy
CN106986630A (en) Sandwich structure compound zirconia alumina zirconia ceramics and preparation method thereof
CN102259343A (en) Multilayer composite ceramic cutting tool
CN103922399A (en) Preparation method of zirconium oxide nanospheres
CN104630591A (en) Stripe type ternary boride reinforced and toughened Ti(C, N)-based metal ceramic and preparation method thereof
CN107473737B (en) Composite zirconia powder for solid oxide fuel cell and preparation method thereof
CN102863218B (en) Tungsten carbide composite material containing zirconium oxide particles and silicon nitride whiskers and preparation method thereof
CN105039763A (en) Powder metallurgical preparing method of titanium-based composite cutter material

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20111130