CN102249390A - Multi-field energy coordinating water body deoxidizing device - Google Patents

Multi-field energy coordinating water body deoxidizing device Download PDF

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Publication number
CN102249390A
CN102249390A CN 201110143518 CN201110143518A CN102249390A CN 102249390 A CN102249390 A CN 102249390A CN 201110143518 CN201110143518 CN 201110143518 CN 201110143518 A CN201110143518 A CN 201110143518A CN 102249390 A CN102249390 A CN 102249390A
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China
Prior art keywords
housing
sponge iron
coil
water body
ultrasonic radiation
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CN 201110143518
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Chinese (zh)
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CN102249390B (en
Inventor
张宗权
党积玉
杨宗立
任耀辉
鲁百佐
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Shaanxi Normal University
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Shaanxi Normal University
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Abstract

The invention relates to a multi-field energy coordinating water body deoxidizing device. According to the multi-field energy coordinating water body deoxidizing device: an upper portion of an outer side wall of a housing is provided with a water inlet valve communicated with the inner of the housing; an upper cover is arranged on an upper end of the housing; a middle portion of the outer side wall of the housing is provided with a winding set; a lower portion of the outer side wall of the housing is provided with a sewage discharging valve communicated with the inner of the housing and a water outlet valve communicated with the inner of the housing; sponge iron particles are arranged in the housing; the upper cover is provided with a power ultrasonic transducer with a downward radiation end; the downward radiation end of the power ultrasonic transducer is provided with a radial ultrasonic radiation tube, wherein the radial ultrasonic radiation tube extends to the inner of the housing, and the lower end of the radial ultrasonic radiation tube is connected with an ultrasonic radiation disc; the ultrasonic radiation disc is processed with permeable holes m; a filter is arranged on the inner wall of the housing and between the ultrasonic radiation disc in the housing and the bottom of the housing; the sponge iron particles are arranged on the ultrasonic radiation disc in the housing; the winding set is formed through connecting six or twelve coils, wherein the coils are connected with a programmable controller, and are arranged on coil frames; the programmable controller is connected with three-phase alternating current power supply through a conductor.

Description

Many field energys are worked in coordination with the water body de-aerator plant
Technical field
The invention belongs to process water deoxygenation technical field, be specifically related to adopt collaborative equipment or the device of removing dissolved oxygen in the water body of ultrasonic wave electromagnetism field energy.
Background technology
In process water,, must remove or reduce the content of oxygen in water gas in order to alleviate the corrosion of facilities such as Industrial Boiler and circulation cooling.Also therefore produced the method and apparatus of a series of removal water body dissolved oxygens.
Water body dissolved oxygen removal technology mainly contains thermal de-aeration, deaeration in condenser, parsing deoxygenation, chemical deoxidization etc. at present.Thermal de-aeration, deaeration in condenser, parsing deoxygenation are the physics water body dissolved oxygen removal methods of setting up according to the Henry principle, although these methods belong to the main method of present water body deoxygenation, the used equipment of these methods all exists complex structure, big, the working cost high-technology problem of energy consumption.It is very fast that chemistry water body dissolved oxygen is removed the technology development in recent years, wherein adopting vesicular, bigger serface, high reactivity sponge iron is the water body deoxygenation technology that water body filters the deoxygenation material, has obtained widespread use with its normal temperature and pressure, low level setting, efficient stable, simple and practical work characteristics.At present existing multinomial patented technology is open.But it still has following deficiency: one, and iron is very little in the amount that the normal condition lower surface forms chemisorption oxygen, and process is also very slow, thereby has restricted deoxygenation speed; Its two, during sponge iron water body deoxygenation filtering material used, dissolved oxygen content was very low in the filtering layer depths, can not make Fe (OH) 2All change into Fe (OH) 3, therefore in aquifer yield, contain a spot of F e + 2Ion; Its three, sponge iron water body deoxygenation resultant of reaction Fe (OH) 3Be floss, can lag deposit in the sponge iron hole and influence O in the follow-up water 2Contact with the sponge iron surface.Traditional method is to discharge Fe (OH) with water backwashing 3Floss, this had both caused the device structure complexity, must dispose the deaerating type of cycles that works alone more than two covers again and go out water problems to solve the interruption that causes because of flushing.Above-mentioned several respects have restricted applying of sponge iron deoxygenation technology.Therefore research can be strengthened the method and apparatus of sponge iron deoxygenation usefulness, has great Technological Economy meaning.
Summary of the invention
Technical problem to be solved by this invention is to overcome the shortcoming of above-mentioned de-aerator plant, provide a kind of simple in structure, deaerating effect good, can continuous dewatering esterase the collaborative water body de-aerator plant of many field energys of dissolved oxygen in the body.
Solving the problems of the technologies described above the technical scheme that is adopted is: the outer upper side wall of housing be provided with housing in the inlet valve that links, the upper end of housing is provided with loam cake, housing outer wall middle part is provided with winding, the lower housing portion sidewall be provided with housing in the sewage draining valve and the flowing water Valve that link, be provided with sponge iron particle in the housing, loam cake is provided with the downward power ultrasonic transducer of spoke side, the spoke side of power ultrasonic transducer is provided with and extend in the housing, the radial ultrasonic radiator tube that the lower end connects with the ultrasonic radiation dish, be processed with permeable hole m on the ultrasonic radiation dish, inner walls is provided with filtering net between interior ultrasonic radiation dish of housing and the housing bottom.Sponge iron particle of the present invention is arranged on the interior ultrasonic radiation dish of housing.Winding of the present invention is connected and composed by 6 or 12 coils that are arranged on the coil rack that are connected with programmable logic controller, and programmable logic controller connects three-phase alternating-current supply by lead, and the outside of coil rack is equipped with iron core.
The number of turn of each coil of winding of the present invention with around to identical.
The loadings of sponge iron particle of the present invention is 50%~70% of the interior space of a housing cubic capacity.
Filtering net 10 of the present invention is 80~200 purpose stainless steel filtering nets.
Beneficial effect of the present invention is: the present invention adopts the winding that is connected with three-phase alternating-current supply is set on the outer wall of housing, in housing, produce travelling-magnetic-field, place near the gradient magnetic that points to pore surface that forms of sponge iron particle pore surface of travelling-magnetic-field, dissolved oxygen in the water body is under the effect of gradient magnetic power, assemble to the sponge iron particle surface transport, the deoxygenation ability of sponge iron particle is strengthened.Because sponge iron particle places pulsation travelling-magnetic-field from bottom to top, sponge iron particle is under the effect of pulsation travelling-magnetic-field power, water body buoyancy and gravity, up-down vibration is rolled in water body, make sponge iron particle all can be fully contact and produce oxidizing reaction, solved agglomeration problems and the sponge iron centre portions deoxygenation of existing sponge iron de-aerator plant in the water body oxygen removal process and reacted inadequate problem with dissolved oxygen in the water body; The present invention adopts in housing and is provided with and the joining radial ultrasonic radiator tube of ultrasonic transducer, under action of ultrasonic waves, can remove the resultant of reaction in the sponge iron particle hole, upgrade solid phase surface, make oxygen in water fully contact and sustained reaction with the sponge iron particle surface.The ultrasonic wave of the ultrasonic radiation dish downward radiation that connects with the radial ultrasonic radiator tube acts on the filtering net that is provided with under it, guarantees that the lasting low-resistance of deaerated water is passed through.That the present invention has is reasonable in design, simple in structure, deaerating effect is good, can the continuous dewatering esterase body in advantage such as dissolved oxygen, can be used as the deoxygenator of process water.
Description of drawings
Fig. 1 is the structural representation of the embodiment of the invention 1.
Fig. 2 is the structural representation of the embodiment of the invention 2.
Embodiment
The present invention is described in more detail with each embodiment below in conjunction with accompanying drawing, but the invention is not restricted to these embodiment.
Embodiment 1
In Fig. 1, the collaborative water body de-aerator plant of many field energys of present embodiment is made of housing 1, loam cake 2, power ultrasonic transducer 3, radial ultrasonic radiator tube 4, rubber gasket 5, sponge iron particle 6, inlet valve 7, sewage draining valve 8, ultrasonic radiation dish 9, filtering net 10, flowing water Valve 11, iron core 12, coil rack 13, coil 14, programmable logic controller 15 connections.
The housing 1 of present embodiment is a drum shape, outside housing 1, be installed into penstock 7 on the upper side wall, link in inlet valve 7 and the housing 1, the water for the treatment of deoxygenation enters in the housing 1 from inlet valve 7, the upper end of housing 1 is with the screw threads for fastening connecting parts loam cake 2 that has been fixedly connected, the central position of loam cake 2 is processed with through hole, be fixedly connected with the screw threads for fastening connecting parts at lead to the hole site power ultrasonic transducer 3 is installed, the spoke side of power ultrasonic transducer 3 is downward, the medullary ray of the medullary ray of power ultrasonic transducer 3 and loam cake 2 coincides, by thread connection radial ultrasonic radiator tube 4 is installed on the spoke side of power ultrasonic transducer 3, radial ultrasonic radiator tube 4 extend in the housing 1, power ultrasonic transducer 3, between radial ultrasonic radiator tube 4 and the housing 1 rubber gasket 5 is installed, ultrasonic wave radial radiation in water body that radial ultrasonic radiator tube 4 produces power ultrasonic transducer 3, radially the lower end of ultrasonic radiation pipe 4 is equipped with ultrasonic radiation dish 9 by thread connection in housing 1, ultrasonic radiation dish 9 is positioned at housing 1 bottom, be processed with permeable hole m on the ultrasonic radiation dish 9, water on the ultrasonic radiation dish 9 flows to the ultrasonic radiation dish 9 times by permeable hole m on the ultrasonic radiation dish 9, be filled with sponge iron particle 6 in ultrasonic radiation dish 9 upper body 1, the loadings of sponge iron particle 6 is 70% of housing 1 interior space cubic capacitys, sponge iron particle 6 is porous materials, have very big specific surface area and high reactivity, be filled in the sponge iron particle 6 in the housing 1, with the dissolved oxygen in the adsorpting aggregation water body, and carry out chemical reaction at sponge iron particle 6 pore surfaces and generate non magnetic floss Fe (OH) 3Thereby, remove oxygen in water.Under action of ultrasonic waves, can remove the resultant of reaction in sponge iron particle 6 holes, upgrade solid phase surface, make oxygen in water fully contact and sustained reaction with sponge iron particle 6 surfaces.
Be outside equipped with programmable logic controller 15 at housing 1, the commodity of programmable logic controller 15 for selling on the market, the model of programmable logic controller 15 is CPM1A-20CDR-D-V1, with housing 1 in 6 coil racks 13 are installed on sponge iron particle 6 corresponding housing 1 outer walls, be wound with 1 coil 14 on each coil rack 13, the number of turn of each coil 14 with around to all identical, coil 14 links to each other with three-phase alternating-current supply by programmable logic controller 15, coil 14 is used for producing travelling-magnetic-field from bottom to top in housing 1, programmable logic controller 15 produces pulsation travelling-magnetic-field from bottom to top according to the phase sequence of the program selecting three-phase alternating current of prior setting and being switched on or switched off of control coil 14 and power supply in housing 1.The outside of coil rack 13 is equipped with iron core 12, and iron core 12 sticks with glue the outside surface that is connected on housing.Present embodiment coil 14 is each other, the annexation between coil 14 and the programmable logic controller 15 is as follows:
Left side a, the b of 6 coils 14, c, d, e, f end are the head end of each coil 14, and right side a ', the b ' of 6 coil 14 correspondences, c ', d ', e ', f ' end are the tail end of each coil 14.Star-like connection method is adopted in its method of attachment, also can adopt the triangular form connection method.
Star-like connection method is: tail end a ', the d ' of coil 14 links to each other, and tail end b ', the e ' of coil 14 links to each other, and tail end c ', the f ' of coil 14 links to each other.Head end b, the d of coil 14, f link to each other, and head end a, the c of coil 14, e are connected with the output terminal of programmable logic controller 15 respectively.
The triangular form connection method is: the connection of coil 14 tail ends is identical with star-like connection method, head end a, the b of coil 14 links to each other with an output terminal of programmable logic controller 15, head end c, the d of coil 14 links to each other with another output terminal of programmable logic controller 15, and head end e, the f of coil 14 links to each other with the output terminal that also has of programmable logic controller 15.
Behind coil 14 and the power connection, in the system that sponge iron particle 6 and water constitute in housing 1, produce pulsation travelling-magnetic-field from bottom to top, sponge iron particle 6 is Vibrotumbling under the acting in conjunction of gravity, buoyancy of water and pulsation travelling-magnetic-field power, make sponge iron particle 6 all can fully contact the absorption dissolved oxygen, and solved the caking inefficacy of sponge iron in the existing sponge iron water body de-aerator plant and reacted inadequate technical problem with water.On housing 1 inwall in housing 1 between ultrasonic radiation dish 9 and housing 1 bottom with the screw threads for fastening connecting parts filtering net 10 that has been fixedly connected, filtering net 10 is 120 purpose stainless steel filtering nets, and filtering net 10 is used to filter the non magnetic floss Fe (OH) that sponge iron particle 6 deoxygenations generate 3By thread connection sewage draining valve 8 is installed on housing 1 bottom filtering net 10 upper body 1 sidewall, links the non magnetic floss Fe (OH) that is separated in sewage draining valve 8 and the housing 1 3Regularly outside sewage draining valve 8 flows to housing 1.Housing 1 bottom filtering net 10 lower housings 1 sidewall is equipped with flowing water Valve 11 by thread connection, link in flowing water Valve 11 and the housing 1, through the water after the deoxygenation outside flowing water Valve 11 outputs to housing 1.
Embodiment 2
In this example, with housing 1 in load corresponding housing 1 outer wall position, sponge iron particle 6 positions 12 coil racks 13 be installed, be wound with 1 coil 14 on each coil rack 13, the number of turn of each coil 14 with around to all identical, the coil 14 of present embodiment is connected by shown in Figure 2 with programmable logic controller 15 with coil 14, coil 14, and concrete grammar is as follows:
Left side a, the b of 12 coils 14, c, d, e, f, g, h, i, j, k, l end are the head end of each coil 14, and right side a ', the b ' of 12 coil 14 correspondences, c ', d ', e ', f ' g ', h ', i ', j ', k ', l ' end are the tail end of each coil 14.Star-like connection method is adopted in its method of attachment, also available triangular form connection method.
Star-like connection method is: tail end a ', the d ' of coil 14 links to each other, tail end b ', the e ' of coil 14 links to each other, and tail end c ', the f ' of coil 14 links to each other, and tail end g ', the j ' of coil 14 links to each other, tail end h ', the k ' of coil 14 links to each other, and tail end i ', the l ' of coil 14 links to each other.Head end d, the g of coil 14 links to each other, and head end e, the h of coil 14 links to each other, and head end f, the i of coil 14 links to each other.Head end b, the j of coil 14, l link to each other, and head end a, the c of coil 14, k are connected with the output terminal of programmable logic controller 15 respectively, the input termination three-phase supply of programmable logic controller 15.
The triangular form connection method is: the connection of coil 14 tail ends is identical with star-like connection method, and head end d, the g of coil 14 links to each other, and head end e, the h of coil 14 links to each other, and head end f, the I of coil 14 links to each other; Head end a, the b of coil 14 links to each other with an output terminal of programmable logic controller 15, head end c, the j of coil 14 links to each other with another output terminal of programmable logic controller 15 after linking to each other, head end k, the l of coil 14 links to each other the input termination three-phase supply of programmable logic controller 15 with the 3rd output terminal of programmable logic controller 15.
The connecting relation of other component and component is identical with embodiment 1.
Embodiment 3
In above embodiment 1,2, ultrasonic radiation dish 9 tops are filled with sponge iron particle 6 in the housing 1, and the loadings of sponge iron particle 6 is 50% of housing 1 interior space cubic capacitys.The connecting relation of other component and component is identical with respective embodiments.
Embodiment 4
In above embodiment 1,2, be filled with sponge iron particle 6 in ultrasonic radiation dish 9 upper body 1 in the housing 1, the loadings of sponge iron particle 6 is 60% of housing 1 interior space cubic capacitys.The connecting relation of other component and component is identical with respective embodiments.
Embodiment 5
In above example 1~4, in housing 1 between ultrasonic radiation dish 9 and housing 1 bottom on housing 1 inwall with the screw threads for fastening connecting parts filtering net 10 that has been fixedly connected, filtering net 10 is 80 purpose stainless steel filtering nets, and filtering net 10 is used to filter the non magnetic floss Fe (OH) that sponge iron particle 6 deoxygenations generate 3The connecting relation of other component and component is identical with respective embodiments.
Embodiment 6
In above example 1~4, in housing 1 between ultrasonic radiation dish 9 and housing 1 bottom on housing 1 inwall with the screw threads for fastening connecting parts filtering net 10 that has been fixedly connected, filtering net 10 is 200 purpose stainless steel filtering nets, and filtering net 10 is used to filter the non magnetic floss Fe (OH) that sponge iron particle 6 deoxygenations generate 3The connecting relation of other component and component is identical with respective embodiments.
Principle of work of the present invention is as follows:
The present invention adopts the winding that is connected with three-phase alternating-current supply is set on the outer wall of housing 1, in housing 1, produce travelling-magnetic-field, sponge iron particle 6 is a porous material, have big specific surface area and high reactivity, place near the gradient magnetic that points to pore surface that forms of sponge iron particle 6 pore surfaces of travelling-magnetic-field, owing to dissolved oxygen (X in the water Mass=1.07 * 10 -4CGS) be paramagnetic substance, magnetic field force suffered in sponge iron particle 6 pore surface gradient magnetics is than water (X Mass=-7.203 * 10 -7CGS) itself is much bigger, therefore enter the dissolved oxygen in the deoxygenation water body treated in the housing 1, under the effect of the sponge iron particle 6 pore surface magnetic field forces in being filled in housing 1, assemble to the migration of sponge iron particle 6 pore surfaces, and generate non magnetic floss Fe (OH) in the reaction of sponge iron particle 6 pore surfaces 3Thereby, remove oxygen in water.While sponge iron particle 6 Vibrotumbling under the acting in conjunction of gravity, buoyancy of water and pulsation travelling-magnetic-field power, sponge iron particle 6 all can fully be contacted with water and adsorb dissolved oxygen, inadequate problem is reacted in the caking Problem of Failure and the deoxygenation of sponge iron centre portions that have solved sponge iron particle 6 in the existing sponge iron water body de-aerator plant.
In said process, be arranged under the radial ultrasonic radiator tube 4 radiating action of ultrasonic waves on the cylindrical shell 1 interior axis, can remove the Fe (OH) of lag deposit in sponge iron particle 6 holes 3, guaranteed fully contacting of dissolved oxygen and sponge iron particle 6 pore surfaces in the flowing water.The ultrasonic wave that is connected ultrasonic radiation dish 9 downward radiations of radial ultrasonic radiator tube 4 bottoms simultaneously acts on the filtering net 10 that is provided with under it, guarantees that the lasting low-resistance of deaerated water is passed through.The sewage draining valve on the sidewall 8 regularly extracts Fe (OH) between ultrasonic radiation dish 9 and the filtering net 10 by being arranged at 3Deng residue, the usefulness that makes the more existing sponge iron deaeration plant of the present invention have fast, remove oxygen in water efficiently, continuously.

Claims (4)

1. field energy more than a kind is worked in coordination with the water body de-aerator plant, the outer upper side wall of housing (1) be provided with housing (1) in the inlet valve (7) that links, the upper end of housing (1) is provided with loam cake (2), housing (1) outer wall middle part is provided with winding, housing (1) lower sides be provided with housing (1) in the sewage draining valve (8) and the flowing water Valve (11) that link, be provided with sponge iron particle (6) in the housing (1), it is characterized in that: loam cake (2) is provided with the downward power ultrasonic transducer of spoke side (3), the spoke side of power ultrasonic transducer (3) is provided with and extend in the housing (1), the radial ultrasonic radiator tube (4) that the lower end connects with ultrasonic radiation dish (9), be processed with permeable hole (m) on the ultrasonic radiation dish (9), housing (1) inwall is provided with filtering net (10) between interior ultrasonic radiation dish of housing (1) (9) and housing (1) bottom; Described sponge iron particle (6) is arranged on the interior ultrasonic radiation dish of housing (1) (9); Described winding is connected and composed by 6 or 12 coils (14) that are arranged on the coil rack (13) that are connected with programmable logic controller (15), programmable logic controller (15) connects three-phase alternating-current supply by lead, and the outside of coil rack (13) is equipped with iron core (12).
2. according to the collaborative water body de-aerator plant of the described many field energys of claim 1, it is characterized in that: the number of turn of each coil (14) of described winding with around to identical.
3. according to claim 1 or the collaborative water body de-aerator plant of 2 described many field energys, it is characterized in that: the loadings of described sponge iron particle (6) is 50%~70% of the interior space of housing (a 1) cubic capacity.
4. according to the collaborative water body de-aerator plant of the described many field energys of claim 1, it is characterized in that: described filtering net (10) is 80~200 purpose stainless steel filtering nets.
CN201110143518A 2011-05-30 2011-05-30 Multi-field energy coordinating water body deoxidizing device Expired - Fee Related CN102249390B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190233312A1 (en) * 2018-01-31 2019-08-01 Organocat, LLC Method and System for Water Electromagnetic Activation and Active Metals Generation

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2851247Y (en) * 2005-11-25 2006-12-27 北京市中科天一环境技术有限公司 Ultrasonic vacuum oxygen removing device for boiler water
CN101699742A (en) * 2009-07-30 2010-04-28 北京国业世成科技发展有限公司 Ultrasonic full-effect antiscaling, descaling, disinfecting, algae removing and deaerating device
CN101857312A (en) * 2010-06-13 2010-10-13 刘利华 Method and device for preventing and removing scales, removing oxygen, cleaning, sterilizing and removing algal by using ultrasonic waves

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2851247Y (en) * 2005-11-25 2006-12-27 北京市中科天一环境技术有限公司 Ultrasonic vacuum oxygen removing device for boiler water
CN101699742A (en) * 2009-07-30 2010-04-28 北京国业世成科技发展有限公司 Ultrasonic full-effect antiscaling, descaling, disinfecting, algae removing and deaerating device
CN101857312A (en) * 2010-06-13 2010-10-13 刘利华 Method and device for preventing and removing scales, removing oxygen, cleaning, sterilizing and removing algal by using ultrasonic waves

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190233312A1 (en) * 2018-01-31 2019-08-01 Organocat, LLC Method and System for Water Electromagnetic Activation and Active Metals Generation
WO2019152473A1 (en) * 2018-01-31 2019-08-08 Organocat, LLC Method and system for water electromagnetic activation and active metals generation
US10899638B2 (en) 2018-01-31 2021-01-26 Organocat, LLC Method and system for water electromagnetic activation and active metals generation

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