CN102241885B - Composite material of polyphthalamide (PPA) and polyphenylene sulfide (PPS) and preparation method thereof - Google Patents
Composite material of polyphthalamide (PPA) and polyphenylene sulfide (PPS) and preparation method thereof Download PDFInfo
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- CN102241885B CN102241885B CN2010102896542A CN201010289654A CN102241885B CN 102241885 B CN102241885 B CN 102241885B CN 2010102896542 A CN2010102896542 A CN 2010102896542A CN 201010289654 A CN201010289654 A CN 201010289654A CN 102241885 B CN102241885 B CN 102241885B
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- lubricant
- polyphenylene sulfide
- polyphthalamide
- matrix material
- ppa
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- 239000004954 Polyphthalamide Substances 0.000 title claims description 44
- 229920006375 polyphtalamide Polymers 0.000 title claims description 44
- 239000004734 Polyphenylene sulfide Substances 0.000 title claims description 39
- 229920000069 polyphenylene sulfide Polymers 0.000 title claims description 39
- 238000002360 preparation method Methods 0.000 title abstract description 14
- 239000002131 composite material Substances 0.000 title abstract description 8
- 239000000314 lubricant Substances 0.000 claims abstract description 43
- 239000011159 matrix material Substances 0.000 claims abstract description 26
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 22
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 22
- 239000007822 coupling agent Substances 0.000 claims abstract description 21
- -1 siloxanes Chemical group 0.000 claims description 20
- 150000002148 esters Chemical group 0.000 claims description 16
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical group CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 claims description 10
- FJDLQLIRZFKEKJ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanamide Chemical compound CC(C)(C)C1=CC(CCC(N)=O)=CC(C(C)(C)C)=C1O FJDLQLIRZFKEKJ-UHFFFAOYSA-N 0.000 claims description 9
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 239000004610 Internal Lubricant Substances 0.000 claims description 5
- 239000004605 External Lubricant Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 abstract description 16
- 238000012545 processing Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 3
- 229920005989 resin Polymers 0.000 abstract description 3
- 239000011347 resin Substances 0.000 abstract description 3
- 239000003623 enhancer Substances 0.000 abstract 3
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 239000012745 toughening agent Substances 0.000 description 20
- 239000003513 alkali Substances 0.000 description 10
- 239000003365 glass fiber Substances 0.000 description 10
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 7
- 239000003063 flame retardant Substances 0.000 description 7
- 238000001035 drying Methods 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920006351 engineering plastic Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to the technical field of macromolecular materials, and particularly, discloses a composite material of PPA and PPS and a preparation method thereof. The PPA and the PPS, which are used as main raw materials, are modified under a melting state in combination with a filling enhancer, a lubricating agent, an antioxidant and a coupling agent. The filling enhancer is added to improve the mechanical and thermal properties of the composite material, the lubricating agent is added to improve the processability of the composite material, the antioxidant is added to improve the stability of the PPA during processing, and the coupling agent is added to reinforce the bonding between the filling enhancer and matrix resin.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to matrix material of a kind of polyphthalamide and polyphenylene sulfide and preparation method thereof, this matrix material is applicable to automotive part, aerospace, heat-resisting demanding mechanical component etc.
Background technology
Polyphthalamide (PPA) is a kind of hemicrystalline thermoplasticity aromatic polyamide, is commonly called as fragrant high-temperature nylon.PPA has very excellent resistance toheat, and long-term working temperature can be up to 180 ℃, and the short-term heatproof can reach 290 ℃; Simultaneously, PPA has high-modulus, high rigidity, high performance-price ratio, dimensional stability, low water absorption etc.Due to its excellent performance, PPA is with a wide range of applications in a lot of fields, but also there is the shortcoming that flame retardant properties is poor, the resin flows performance is lower in it, has limited the application of PPA.
Polyphenylene sulfide (PPS) is the special engineering plastics of present consumption maximum, is described as the sixth-largest general engineering plastic.Polyphenylene sulfide has very excellent mechanical property, but needs further to improve in a lot of its resistance toheats of occasion.
Summary of the invention
The present invention is directed to the problem that polyphthalamide flame retardant resistance and poor processability in prior art and polyphenylene sulfide resistance toheat have much room for improvement, under the prerequisite of the rigidity that guarantees the material excellence, intensity, provide the polyphthalamide of a kind of flame retardant properties, Good Heat-resistance and the matrix material of polyphenylene sulfide.
The technical problem that the present invention further will solve is to provide that a kind of preparation technology is simple, the polyphthalamide of strong operability and the composite manufacture method of polyphenylene sulfide.
For realizing above-mentioned the first goal of the invention, technical scheme of the present invention is:
The matrix material of a kind of polyphthalamide and polyphenylene sulfide, this matrix material comprises the component of following mass percent:
Polyphthalamide 29.6～36.5%,
Polyphenylene sulfide 31.7～38.2%,
Lubricant 0.2～0.4%,
Antioxidant 0.2～0.4%,
Coupling agent 0.2～0.4%,
And surplus is filled toughener.
Preferably, described filling toughener is alkali free glass fibre.
Preferably, described lubricant is one or both in internal lubricant and external lubricant, and described internal lubricant is ester lubricant, and described external lubricant is nonpolar lubricant.
Preferably, described ester lubricant is pentaerythritol stearate, and described nonpolar lubricant is siloxanes.
Preferably, described antioxidant is N, N-hexylidene-1, one or more in 6-two [3-(3,5-di-t-butyl-4-hydroxyphenyl) propionic acid amide] and three (2,4-di-tert-butyl-phenyl) phosphorous acid ester.
Preferably, described coupling agent is γ-Racemic glycidol oxygen propyl trimethoxy silicane.
For realizing the second goal of the invention of the present invention, the technical scheme that adopts is as follows:
A kind of composite manufacture method of polyphthalamide and polyphenylene sulfide comprises the following steps:
A: polyphthalamide and polyphenylene sulfide are carried out drying treatment stand-by under 100-150 ℃ of condition;
B: after lubricant, antioxidant are mixed, be placed in that to carry out drying treatment under 50-100 ℃ of condition stand-by;
C: four kinds of raw materials and coupling agent after drying in step a and b is processed evenly mix;
D: mixed raw material in step c is placed in twin screw extruder, and adds alkali free glass fibre in the twin screw extruder stage casing, by melt extrude, granulation.
Preferably, the complete processing of this twin screw extruder is a district 260-280 ℃, two district 280-300 ℃, three district 280-320 ℃, four district 290-320 ℃, five district 290-320 ℃, six district 290-310 ℃, seven district 290-310 ℃, total residence time is 3-6 minute in screw rod, and the total pressure of twin screw extruder is the 14-18 MPa.
The present invention adopts polyphthalamide and polyphenylene sulfide, is aided with to fill toughener, lubricant, antioxidant and coupling agent, makes PPA and PPS modification under molten state.Fill mechanical property and the thermal characteristics that has improved matrix material that add of toughener, lubricant add the processing characteristics that has improved matrix material, adding of antioxidant improved the stability of PPA in the course of processing, and adding of coupling agent strengthens the combination of filling between toughener and matrix resin.
In matrix material of the present invention, PPS and PPA learn from other's strong points to offset one's weaknesses, and have both improved the flame retardant properties of PPA, have improved again the resistance toheat of PPS, have good over-all properties.
Embodiment
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1:
The present embodiment discloses matrix material and the preparation method of a kind of polyphthalamide and polyphenylene sulfide.
The mass percent of its raw material is as follows:
Polyphthalamide 29.6%, polyphenylene sulfide 38.2%, filling toughener 31.3%, ester lubricant 0.2%, nonpolar lubricant 0.2%, antioxidant 0.2%, coupling agent 0.3%;
Above-mentionedly state nonpolar lubricant and be: siloxanes;
Above-mentioned ester lubricant is: pentaerythritol stearate;
Above-mentioned filling toughener is: alkali free glass fibre;
Above-mentioned antioxidant is: N, N-hexylidene-1,6-two [3-(3,5-di-t-butyl-4-hydroxyphenyl) propionic acid amide] 0.1%, three (2,4-di-tert-butyl-phenyl) phosphorous acid ester 0.1%;
Above-mentioned coupling agent is: γ-Racemic glycidol oxygen propyl trimethoxy silicane.
Its preparation method is as follows:
A: polyphthalamide and polyphenylene sulfide is stand-by about 6 hours 100-150 ℃ of lower forced air drying;
B: utilize homogenizer with pentaerythritol stearate, siloxanes, N, N-hexylidene-1,6-two [3-(3,5-di-t-butyl-4-hydroxyphenyl) propionic acid amide] and three (2, the 4-di-tert-butyl-phenyl) after phosphorous acid ester carries out high-speed mixing, stand-by about 2 hours 50-100 ℃ of drying;
C: the raw material that step a, b handle well is put in high-speed mixer, then added γ-Racemic glycidol oxygen propyl trimethoxy silicane evenly to mix 3 minutes;
D: mixed raw material in step c is mixed through twin screw extruder, and the stage casing adds alkali free glass fibre, through melt extruding, and granulation.The complete processing of twin screw extruder is: a district 260-280 ℃, two district 280-300 ℃, three district 280-320 ℃, four district 290-320 ℃, five district 290-300 ℃, six district 290-300 ℃, seven district 300-310 ℃, total residence time is 3-6 minute in screw rod, and the total pressure of twin screw extruder is the 14-18 MPa.
Embodiment 2:
The present embodiment also discloses matrix material and the preparation method of a kind of polyphthalamide and polyphenylene sulfide.
The different mass percents that are its raw material of the present embodiment and embodiment 1, the raw materials quality per-cent of the present embodiment is as follows:
Polyphthalamide 31.2%, polyphenylene sulfide 37.0%, filling toughener 31.0%, ester lubricant 0.2%, nonpolar lubricant 0.1%, antioxidant 0.3%, coupling agent 0.2%;
Above-mentionedly state nonpolar lubricant and be: siloxanes;
Above-mentioned ester lubricant is: pentaerythritol stearate;
Above-mentioned filling toughener is: alkali free glass fibre;
Above-mentioned antioxidant is: N, N-hexylidene-1,6-two [3-(3,5-di-t-butyl-4-hydroxyphenyl) propionic acid amide] 0.2%, three (2,4-di-tert-butyl-phenyl) phosphorous acid ester 0.1%;
Above-mentioned coupling agent is: γ-Racemic glycidol oxygen propyl trimethoxy silicane.
The preparation method of the present embodiment is identical with embodiment 1.
Embodiment 3:
The present embodiment also discloses matrix material and the preparation method of a kind of polyphthalamide and polyphenylene sulfide.
The different mass percents that are its raw material of the present embodiment and embodiment 1, the raw materials quality per-cent of the present embodiment is as follows:
Polyphthalamide 32.1%, polyphenylene sulfide 35.2%, filling toughener 31.6%, ester lubricant 0.2%, nonpolar lubricant 0.2%, antioxidant 0.4%, coupling agent 0.2%;
Above-mentionedly state nonpolar lubricant and be: siloxanes;
Above-mentioned ester lubricant is: pentaerythritol stearate;
Above-mentioned filling toughener is: alkali free glass fibre;
Above-mentioned antioxidant is: N, N-hexylidene-1,6-two [3-(3,5-di-t-butyl-4-hydroxyphenyl) propionic acid amide] 0.2%, three (2,4-di-tert-butyl-phenyl) phosphorous acid ester 0.2%;
Above-mentioned coupling agent is: γ-Racemic glycidol oxygen propyl trimethoxy silicane.
The preparation method of the present embodiment is identical with embodiment 1.
Embodiment 4:
The present embodiment also discloses matrix material and the preparation method of a kind of polyphthalamide and polyphenylene sulfide.
The different mass percents that are its raw material of the present embodiment and embodiment 1, the raw materials quality per-cent of the present embodiment is as follows:
Polyphthalamide 34.8%, polyphenylene sulfide 33.0%, filling toughener 31.3%, ester lubricant 0.2%, nonpolar lubricant 0.2%, antioxidant 0.2%, coupling agent 0.3%;
Above-mentionedly state nonpolar lubricant and be: siloxanes;
Above-mentioned ester lubricant is: pentaerythritol stearate;
Above-mentioned filling toughener is: alkali free glass fibre;
Above-mentioned antioxidant is: N, N-hexylidene-1,6-two [3-(3,5-di-t-butyl-4-hydroxyphenyl) propionic acid amide] 0.1%, three (2,4-di-tert-butyl-phenyl) phosphorous acid ester 0.1%;
Above-mentioned coupling agent is: γ-Racemic glycidol oxygen propyl trimethoxy silicane.
Embodiment 4:
The present embodiment also discloses matrix material and the preparation method of a kind of polyphthalamide and polyphenylene sulfide.
The different mass percents that are its raw material of the present embodiment and embodiment 1, the raw materials quality per-cent of the present embodiment is as follows:
Polyphthalamide 36.5%, polyphenylene sulfide 30.7%, filling toughener 32.0%, ester lubricant 0.1%, nonpolar lubricant 0.1%, antioxidant 0.2%, coupling agent 0.4%;
Above-mentionedly state nonpolar lubricant and be: siloxanes;
Above-mentioned ester lubricant is: pentaerythritol stearate;
Above-mentioned filling toughener is: alkali free glass fibre;
Above-mentioned antioxidant is: N, N-hexylidene-1,6-two [3-(3,5-di-t-butyl-4-hydroxyphenyl) propionic acid amide] 0.1%, three (2,4-di-tert-butyl-phenyl) phosphorous acid ester 0.1%;
Above-mentioned coupling agent is: γ-Racemic glycidol oxygen propyl trimethoxy silicane.
The comparative example 5:
The present embodiment also discloses matrix material and the preparation method of a kind of polyphthalamide and polyphenylene sulfide.
The different mass percents that are its raw material of the present embodiment and embodiment 1, the raw materials quality per-cent of the present embodiment is as follows:
Polyphthalamide 53.5%, polyphenylene sulfide 46.1%, ester lubricant 0.1%, nonpolar lubricant 0.1%, antioxidant 0.2%;
Above-mentionedly state nonpolar lubricant and be: siloxanes;
Above-mentioned ester lubricant is: pentaerythritol stearate;
Above-mentioned antioxidant is: N, N-hexylidene-1,6-two [3-(3,5-di-t-butyl-4-hydroxyphenyl) propionic acid amide] 0.1%, three (2,4-di-tert-butyl-phenyl) phosphorous acid ester 0.1%.
Now with the matrix material that obtains in previous examples 1-5, carry out performance test according to following standard:
Tensile strength detects by ASTM D-638 standard.Specimen types is the I type, batten size (millimeter): 150 (length) * (20 ± 0.2) (end size) * (4 ± 0.2) (thickness), draw speed is 50 mm/min.
Flexural strength and modulus in flexure detect by ASTM D-790 standard.Specimen types is specimen size (millimeter): (80 ± 2) * (20 ± 0.2) * (4 ± 0.2), rate of bending are 20 mm/min.
The socle girder notched Izod impact strength detects by ASTM D-256 standard.Specimen types is the I type, batten size (millimeter): (80 ± 2) * (10 ± 0.2) * (4 ± 0.2); The breach type is category-A, and notch depth is 1/3 of thickness.
Heat-drawn wire detects by ISO 75-2 standard.Specimen types is the I type, batten size (millimeter): 127 (length) * (13 ± 0.1) * (6.35 ± 0.1); Temperature rise rate is 120 ℃/h, pressure position 1.82MPa, and setting deformation quantity is 0.21 millimeter.
Flame retardant properties is pressed the UL-94 standard testing, and batten thickness is approximately 1.6 millimeters.
Get detected result such as following table according to above-mentioned standard testing:
| Form and test | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative Examples 5 |
| PPA | 29.6 | 31.2 | 32.1 | 36.5 | 53.5 |
| PPS | 38.2 | 37.0 | 35.2 | 30.7 | 46.1 |
| Fill toughener | 31.3 | 31.0 | 31.6 | 32.0 | 0 |
| Lubricant | 0.4 | 0.3 | 0.4 | 0.2 | 0.2 |
| Antioxidant | 0.2 | 0.3 | 0.4 | 0.2 | 0.2 |
| Coupling agent | 0.3 | 0.2 | 0.3 | 0.4 | 0 |
| Tensile strength (MPa) | 166 | 172 | 148 | 172 | 73 |
| Elongation at break (%) | 2.11 | 1.92 | 1.27 | 1.94 | 2.24 |
| Flexural strength (MPa) | 268 | 275 | 260 | 265 | 129 |
| Modulus in flexure (GPa) | 14.1 | 14.6 | 13.9 | 14.9 | 5.9 |
| Notched Izod impact strength | 140 | 136 | 118 | 129 | 76 |
| Heat-drawn wire (℃) | 267 | 281 | 275 | 280 | 167 |
| Flame retardant properties | V 0 | V 0 | V 0 | V 0 | V 0 |
As can be seen from the above table, when PPA, PPS, the filling toughener content that is alkali free glass fibre is respectively 29.6-36.5%, 30.7-38.2%, 31-32%, the tensile strength of matrix material, flexural strength and modulus all remain on a higher level, its heat-drawn wire can reach 280 ℃, and flame retardant properties also reaches the V0 level.And by with the Performance Ratio of Comparative Examples 5, can obviously find to fill the mechanical property that has improved to a great extent matrix material that adds of toughener.The present invention combines the advantage of PPS and PPA bi-material, and effective use of filling toughener, coupling agent, lubricant and antioxidant, prepare the very excellent polyphthalamide of a kind of over-all properties and polyphenyl thioether composite material, can satisfy the service requirements of automobile, aerospace, the heat-resisting product of having relatively high expectations.
In previous embodiment 1-5:
fill toughener and be the alkali free glass fibre that megalith group produces, coupling agent is the γ that produces of Chengdu Long March chemical reagents corporation-Racemic glycidol oxygen propyl trimethoxy silicane, internal lubricant is that the pentaerythritol stearate that Suzhou Xingtai state photochemistry auxiliary agent company limited produces is PETS, nonpolar lubricant is the siloxanes that Chengdu Long March chemical reagents corporation produces, oxidation inhibitor is the N that Chengdu Long March chemical reagents corporation produces, N-hexylidene-1, [3-(3 for 6-two, 5-di-t-butyl-4-hydroxyphenyl) propionic acid amide] and three (2, the 4-di-tert-butyl-phenyl) phosphorous acid ester is composite.
The above technical scheme that the embodiment of the present invention is provided is described in detail, used specific case herein principle and the embodiment of the embodiment of the present invention are set forth, the explanation of above embodiment is only applicable to help to understand the principle of the embodiment of the present invention; Simultaneously, for one of ordinary skill in the art, according to the embodiment of the present invention, all will change on embodiment and range of application, in sum, this description should not be construed as limitation of the present invention.
Claims (5)
1. the matrix material of a polyphthalamide and polyphenylene sulfide, is characterized in that, this matrix material comprises the component of following mass percent:
2. the matrix material of polyphthalamide according to claim 1 and polyphenylene sulfide is characterized in that:
Described lubricant is one or both in internal lubricant and external lubricant;
Described internal lubricant is ester lubricant;
Described external lubricant is nonpolar lubricant.
3. the matrix material of polyphthalamide according to claim 2 and polyphenylene sulfide is characterized in that:
Described ester lubricant is pentaerythritol stearate;
Described nonpolar lubricant is siloxanes.
4. the matrix material of polyphthalamide according to claim 1 and polyphenylene sulfide is characterized in that:
Described antioxidant is N, N-hexylidene-1, one or more in 6-two [3-(3,5-di-t-butyl-4-hydroxyphenyl) propionic acid amide] and three (2,4-di-tert-butyl-phenyl) phosphorous acid ester.
5. the matrix material of polyphthalamide according to claim 1 and polyphenylene sulfide is characterized in that:
Described coupling agent is γ-Racemic glycidol oxygen propyl trimethoxy silicane.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2010102896542A CN102241885B (en) | 2010-09-20 | 2010-09-20 | Composite material of polyphthalamide (PPA) and polyphenylene sulfide (PPS) and preparation method thereof |
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| CN2010102896542A CN102241885B (en) | 2010-09-20 | 2010-09-20 | Composite material of polyphthalamide (PPA) and polyphenylene sulfide (PPS) and preparation method thereof |
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| CN105694449B (en) * | 2016-04-06 | 2017-12-29 | 广东泰昊新材料科技有限公司 | A kind of PPS modified plastics for hot and cold water Mixed water valve and preparation method thereof |
| CN108659528A (en) * | 2018-04-24 | 2018-10-16 | 嘉兴希卡姆复合材料有限公司 | A kind of high-performance polyphenylene sulfide and polyamide alloy material and preparation method thereof |
| CN109251530B (en) * | 2018-07-17 | 2021-03-23 | 特塑（大连）高分子材料有限公司 | High-fluidity high-impact-resistance glass fiber reinforced PPS (polyphenylene sulfide) modified material |
| CN109320962A (en) * | 2018-09-13 | 2019-02-12 | 丹阳市三能电器配件有限公司 | PPS composite material and preparation method for air-conditioning supplementary heating element bracket |
| CN110003643B (en) * | 2019-03-01 | 2021-09-14 | 广东京兆工程塑料有限公司 | Anti-aging PPA composite material and preparation method thereof |
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|---|---|---|---|---|
| CN101099821A (en) * | 2007-06-08 | 2008-01-09 | 深圳市科聚新材料有限公司 | Poly (hexanediamine adipate) and polyphthalamide fiber-adding alloy and preparation method thereof |
| CN101134847A (en) * | 2007-09-30 | 2008-03-05 | 深圳市科聚新材料有限公司 | Polyphenylene sulfide/polyamide composite material and method for making same |
| CN101570633A (en) * | 2008-04-30 | 2009-11-04 | 第一毛织株式会社 | Flame retardant thermoplastic resin composition and mould product produced therefrom |
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| CN102241885A (en) | 2011-11-16 |
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