CN102226115A - Biological regeneration diesel oil produced by use of food waste grease and manufacturing method thereof - Google Patents
Biological regeneration diesel oil produced by use of food waste grease and manufacturing method thereof Download PDFInfo
- Publication number
- CN102226115A CN102226115A CN201110124746XA CN201110124746A CN102226115A CN 102226115 A CN102226115 A CN 102226115A CN 201110124746X A CN201110124746X A CN 201110124746XA CN 201110124746 A CN201110124746 A CN 201110124746A CN 102226115 A CN102226115 A CN 102226115A
- Authority
- CN
- China
- Prior art keywords
- grease
- oil
- food waste
- weight parts
- changing food
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Edible Oils And Fats (AREA)
- Fats And Perfumes (AREA)
Abstract
The invention relates to biological regeneration diesel oil produced by the use of food waste grease and a manufacturing method thereof. The manufacturing method is characterized by taking food waste grease, Jatropha curcas grease, rice bran grease, cottonseed grease, Chinese honey locust grease, camphor grease, methanol, tween T-80, span S-80, petroleum ether, acetone and sodium hydroxide as raw materials; uniformly mixing by the use of a paddle agitator and preheating while controlling the temperature within the range of 30 DEG C to 60 DEG C; adding the raw materials into a reaction vessel by a proportioning device to remove impurities, decolour, esterify and separate, separating by a centrifuge, filtering and purifying to produce the biological regeneration diesel oil product from food waste grease. The product provided by the invention has renewable performance so as to solve the problem of the food waste processing difficulty and realize the resource recycling and utilization of food wastes, and meets the relative rules of the state council 2010 thirty sixth document on the resource utilization and harmless treatments of food wastes.
Description
Technical field
The present invention relates to a kind of bio-regeneration diesel oil of producing with the changing food waste waste oil, specifically it is with the changing food waste refuse, the waste oil that carries out extracting after the oily water separation through machinery, Cortex jatrophae grease, rice bran grease, cottonseed grease, Chinese honey locust grease, camphor grease, methyl alcohol etc. be the bio-regeneration diesel oil of main material production, genus waste treatment field.
The invention still further relates to the manufacture method of this changing food waste waste oil bio-regeneration diesel oil.
Background technology
Along with the variation of global energy structure, the structural and strategic status of renewable energy source is determined.The prime mover of various countries' sustainable economic development mainly comes from the rationalization use of fossil energy and the exploitation energetically and effectively utilization of alternative energy product.Biofuel is paid much attention in the world as substitute energy a kind of cleaning, reproducible.Current, the energy occupy the first to the influence of world economy.The human main energy sources of using at present has 3 kinds of oil, Sweet natural gas and coals.According to the International Energy Agency statistics, these three kinds of energy are respectively for the time limit of human exploitation on the earth: oil 37 years, Sweet natural gas 57 years, coal 217 years.The human life that may face coal, the exhausted people of giving of oil brings harm and influences Economic development.Use coal, petroleum-based energy to cause serious environmental to pollute simultaneously and global warming also can not be ignored, with the new biomass energy epoch at hand.
China is a petroleum import big country, prospective oil is very limited again, biofuel is to be the liquid fuel that raw material is made with oilseed plants such as oil-yielding shrubs fruits such as oil crops, oil palm and Chinese pistache, Cortex jatrophae and animal grease, food garbage waste oil etc., is the substitute of fine petrifaction diesel.Have three big advantages such as recyclability, spatter property and security, extremely safe all aspect use, processing, transportation and storage; And the time do not discharge SO in burning
2, the obnoxious flavour of discharge also reduces about 90% than common petrifaction diesel; Biofuel does not contain the aromatic compound of contaminate environment, and infringement is lower than common petrifaction diesel to human body; Biofuel oxygen level height, smoke evacuation is lacked during burning, and the CO of discharging lacks 10% than ordinary diesel oil.Biofuel to sustainable economic development, advance energy substitution, alleviate global warming pressure, control urban atmospheric pollution have the important strategic meaning.The biofuel of utilizing oilseed plants such as changing food waste waste oil, Cortex jatrophae, Chinese pistache, Semen Brassicae campestris, cottonseed to make is good by many countries.China is again oilseed plant plantation big countries such as a Cortex jatrophae, Chinese pistache, rape, cottonseed, should greatly develop the biofuel energy.
Along with China's rapid development of economy, the high concentration of continuous expansion of scale of urbanization and urban population, people's the level of consumption improves constantly, and the fast development of catering trade, simultaneously, also caused a large amount of generations of changing food waste, the generation of changing food waste is increased day by day, also more and more serious by the environmental pollution that changing food waste causes.The most of cities of China are relatively more chaotic to restaurant and Kitchen Swill Management at present, had a strong impact on food safety and HUMAN HEALTH, influenced effective utilization of urban environment and urban infrastructure.Show that according to the nearest statistical figure of house and town and country construction portion at present the annual changing food waste that produces in 660 large-and-medium size cities of China is near 8,000 ten thousand tons, and just with the speed increment of about 8% annual growth.Changing food waste directly enters municipal sewage pipe network, can bring great disadvantageous effect to urban infrastructure and urban environment, contain a large amount of organic substances and food oils etc. in the meal kitchen sewage of discharging, the COD mean concns has surpassed municipal wastewater pipe network sewage and has allowed more than 3 times of emission concentration.Not only make the equipment maldigestion of sewage work, also caused water pollution simultaneously.How properly scientifically changing food waste to be carried out treatment and disposal, make it reach innoxious and recycling, the General Office of the State Council has issued No. 36 file on July 13rd, 2010, about strengthening the relevant regulations of sewer oil regulation and kitchen castoff management, become a big research topic of the science brainstrust extensive concern of China's environment circle.
Summary of the invention
Purpose of the present invention provides a kind of just and is the bio-regeneration diesel oil of main material production with changing food waste waste oil, Cortex jatrophae grease, rice bran grease, cottonseed grease, Chinese honey locust grease, camphor grease and methyl alcohol etc. for the problem that solves above-mentioned existence, thereby solved changing food waste to the harm of the underground sewage network in city and the pollution of environment generation, solved the resource regeneration of changing food waste again, turn waste into wealth, change evil and be benefit, realized that the resource benign cycle of waste utilizes.
The present invention also provides the manufacture method of this changing food waste waste oil bio-regeneration diesel oil.
The objective of the invention is by following technical proposal Shi Now's;
A kind of bio-regeneration diesel oil of producing with the changing food waste waste oil, it is made by the following weight proportion raw material;
Described changing food waste waste oil is food residues, swill, the discarded food oils of animals and plants that can not eat again and the oil-water mixture etc. that dining rooms such as hotel, hotel, catering trade, office, school, business unit produce in activity is served the meals in diet processing.Adopt machinery to carry out the grease that extracts after the oily water separation;
The seed of the fruit that described Cortex jatrophae grease is a Cortex jatrophae through drying the back, separating fried through pulverizing, heat, steaming, and adopts the grease of mechanical expression method processing extraction;
Described rice bran grease is that paddy carries out steam-heated cal(l)andria through a kind of rice bran of separating in the mechanical processing process, the grease that adopts the mechanical expression method to extract;
Described cottonseed grease is that the cotton process is dried the back, processed the cotton seed of separating, and through pulverizing, heat, steam stir-fry, adopts the grease of mechanical expression method processing extraction;
Described Chinese honey locust grease is a kind of seed that the fruit process of Chinese honey locust tree is dried the back, separated, and fries through pulverizing, heating, steaming, adopts the mechanical expression method to process and extracts grease;
A kind of seed of the fruit that described camphor grease is a camphor tree through drying the back, separating fried through pulverizing, heat, steaming, and adopts the grease of mechanical expression method processing extraction.
A kind of manufacture method of using the bio-regeneration diesel oil of changing food waste waste oil production, it is undertaken by following step:
Changing food waste waste oil with 30～40 weight parts, the Cortex jatrophae grease of 25～35 weight parts, the rice bran grease of 10～15 weight parts, the cottonseed grease of 15～25 weight parts, the Chinese honey locust grease of 5～8 weight parts, the camphor grease of 1～2 weight part, the methyl alcohol of 28～38 weight parts, 0.8 the tween T-80 of～1.5 weight parts, 0.5 the sapn S-80 of～1.0 weight parts, the sherwood oil of 1～2 weight part, the acetone of 1～2 weight part, the raw materials such as sodium hydroxide of 2～4 weight parts, adopt paddle stirrer to mix preheating, temperature is controlled at 30～60 ℃, adds in the reactor to carry out removal of impurities, decolouring, esterification, separate through whizzer, promptly make changing food waste waste oil bio-regeneration diesel product after filtering purification.
The present invention adopts changing food waste waste oil, Cortex jatrophae grease, rice bran grease, cottonseed grease, Chinese honey locust tree grease, camphor grease and methyl alcohol etc. to be the main raw material of changing food waste waste oil bio-regeneration diesel oil, be because the changing food waste waste oil itself contains Vegetable oil lipoprotein and animal grease, can be used as diesel regenerated raw material.
Cortex jatrophae is kind of plant seeds, has the numerous ability of extremely strong life, is thick with leaves, and the forest land closing are fast, and it is perishable nonflammable to fall leaves, and the ability of improving the soil is strong.The leprosy woods that are grown on the abrupt slope become good biological fire-blocking belt.Its seed oil length height of Cortex jatrophae, general oil length be 50～60%, industrial processes oil yield 40%～48%, its butyrous analytical parameters is an acid number 38.2, saponification value 195.0, iodine number 101.7, viscosity 40.4, acid amides 4.2%, stearic acid 6.9%, oleic acid 43.1%, linolic acid 34.3%, other lipid acid 1.4%, the Cortex jatrophae oil after modification is applicable to various diesel machineries.Simultaneously, Cortex jatrophae has very high economic worth, is universally acknowledged bioenergy seeds.Its kind benevolence is traditional soap and lube stock, and Cortex jatrophae is the biodiesel plants seeds that have DEVELOPMENT PROSPECT, is the good raw material of making biofuel.Have economy, society, ecological multiple benefit, have the wide development prospect.Biofuel is the renewable energy source of cleaning, is meant that plant quasi-grease and methyl alcohol carry out the fatty acid methyl ester that transesterify is made, and is a kind of biofuel of cleaning, also is referred to as regeneration fuel oil, green diesel etc.
Rice bran is a kind of byproduct that produces in the paddy course of processing, is rich in grease, protein, Mierocrystalline cellulose and multivitamin.For a long time, in the most areas of China only with rice bran as extensive forage feed livestock and poultry, make its nutritive value and economy of resources fail to bring into play well and utilize, caused great waste.The chemical structure of Rice pollard oil is formed very good, detects according to the study, and the oleaginousness of rice bran is generally at 15%-20%, in its lipid acid, saturated fatty acid accounts for 15-20%, and unsaturated fatty acids accounts for 80-85%, wherein segmentation gets up to have: tetradecanoic acid accounts for 0.4-1%, palmitinic acid accounts for 12-18%, and stearic acid accounts for 1-3%, and the C20-C22 saturated fatty acid accounts for 1%, oleic acid accounts for 40-50%, linolic acid accounts for 29-42%, and linolenic acid accounts for below 1%, and Zoomeric acid accounts for 0.2-0.4%.Rice pollard oil also contains vitamin-E, squalene, active lipase, Sitosterol, campesterol, Stigmasterol and three kinds of ferulic acid ester antioxidants and solid shape plant constituent etc., it is a kind of good antioxidant that content accounts for 2%～3% ferulic acid ester, has played vital role for the Rice pollard oil antioxidative stabilizer.Rice pollard oil has been subjected to the common concern of many developed countries in the world as the heat energy.The fragrant odour that it has, high temperature resistant, nondiscoloration and anti-permanent storage and advantage such as unharmful substance generation almost are that any vegetables oil is incomparable, Rice pollard oil is a kind of good bio-regeneration diesel raw material.Oleum Gossypii semen is the byproduct of cotton planting industry, and the cotton benevolence oil length 40% in back shells.Cotton growth is one of main cash crop of China in the torrid zone and subtropical zone, and Oleum Gossypii semen also is one of important edible oil of China.Hair cotton oil has undesirable smell and bitter taste, and color and luster is very dark.The major cause of hair cotton oil color depth is free gossypol and derivative, phosphatide and the sterol etc. of oil-containing about 1% in the oil.When carrying out refining, gossypol and resin, mucus etc. all can be removed substantially, content only surplus 0.01% or still less.Obtain faint yellowly, free from extraneous odour is suitable for edible cotton edible vegetable oil.The quality of hair cotton oil quality depends on the weather condition after the cotton maturation to a great extent.The oil quality that obtains during as drying is good, and oil was poor when moist or storage moisture was big.The physicochemical constant of Oleum Gossypii semen is: relative density (d
20 ℃4 ℃) 0.917～0.925; Refractive index (n
20 ℃D) 1.4675-1.4750; About 5 ℃ at zero pour; Lipid acid solidifies a 32-38 ℃; About 9 ℃ of viscosity; Iodine number 103-115; Saponification value 191～199; Unsaponifiables 0.5-1.5%; Total fatty acid content 95～96%; The lipid acid of Oleum Gossypii semen is formed: Palmiticacid 22%; Stearic acid 2%; Oleic acid 19%; Linolic acid 57%; Saturated fatty acid content is more in the Oleum Gossypii semen, so zero pour is higher, is retrogradation at a lower temperature and even solidifies.Through the Oleum Gossypii semen of the freezing filtering tristearin of winterization, at 0 ℃ of freezing 5 hours clear still, this Oleum Gossypii semen can be made cold and dressed with sauce grease the winterization cotton oil.
Chinese honey locust oil is the grease that the seed of a kind of leguminous plants seeds extracts, and it belongs to deciduous tree, and the height of tree can reach 15 meters-20 meters, and tree crown can reach 15 meters, quil is sturdy, sorrel, normal branch, even numbers pinnately compound leaf, leaflet 4-7 is right, and vanelets is avette, and there is serrulation at the edge.The flower polygamy, all there is fine and soft hair in flower portion, yellowish white, the pod angle is straight and flat, and is glossy, black purple, by white powder, the seed majority is flat, oblong, generally long 12 centimetres-30 centimetres, bloom the May in every year, October fruit maturation.The Chinese honey locust fruit: major ingredient has triterpenoid saponin, tannin, ceryl alcohol, nonacosane, Stigmasterol, Sitosterol etc., can extract grease and multiple industrial chemicals.Chinese honey locust tree, drought-resistant, able to endure hardships heat, cold-resistant, well developed root system, the age of tree 500 years, the height of tree and be preced with greatly is to concede the land to forestry, and preserves the ecological environment, especially the western preferred seeds of administering sandstorm of China.The grease that the Chinese honey locust seed extracts is the high quality raw material of bio-regeneration diesel oil.
White oil of camphor is a kind of colourless or faint yellow oily liquids to reddish-brown, and it also contains safrole except that containing camphor, Terpane, and camphorene, oxymethoxyallylbenzenes etc. are dissolved in ethanol, and strong camphor smell is arranged, can burn, be high ashy substance.Select it to be because the peculiar smell in its energy removal of oil and grease makes its limpid, delicate fragrance as additive.Methyl alcohol (CH
4CH
3OH) be achromaticity and clarification liquid, irritating smell is arranged, stability is preferably arranged, inflammable.
It is additive that the present invention adopts sherwood oil and acetone, and sodium hydroxide is catalyzer, and sapn S-80 and tween T-80 are emulsifying agent, and sapn S-80 is the yellowish brown oily liquids, is dissolved in deep fat and organic solvent, is senior lipophilic emulsifier.Tween T-80 is a hydrophilic tensio-active agent, soluble in water, ethanol, methyl alcohol.Have the effect of very strong ruptured cell film and cause pungency, hemolytic and histamine release sensitization.High purity tween T-80 is water white transparency or little yellowish brown, and the lipophilic composition comprises unsaturated fatty acids among the tween T-80, the very easy oxidative degradation of these unsaturated fatty acidss, and mix the use emulsifying effectiveness with sapn S-80 best.Sherwood oil is an oils, is the mixture of low relative molecular mass alkanes.Wherein contain a small amount of unsaturated hydrocarbons, boiling point and alkane are close, and main component is pentane, hexane.Be colourless transparent liquid, the kerosene smell is arranged.Acetone: having another name called DIMETHYL GLYOXIME, is a kind of colourless transparent liquid, and special pungent smell is arranged.Organic solvents such as soluble in water and methyl alcohol, ethanol, ether, chloroform, pyridine.Inflammable, volatile, chemical property is more active, can increase diesel regenerated fuel value.Sodium hydroxide (NaOH) is a kind of white crystal at normal temperatures, and is soluble in water, and its aqueous solution is strong basicity, and phenolphthalein is reddened.Sodium hydroxide is a kind of alkali extremely commonly used, and water white soda liquid dissolves among the Yi Zaishui, can with multiple organic and inorganic compound react with, corrodibility is very strong.Sodium hydroxide complete ionization in water goes out sodium ion and hydroxide ion, can carry out neutralization reaction with any protonic acid.
The manufacture method of changing food waste waste oil bio-regeneration diesel oil of the present invention, be with raw materials such as changing food waste waste oil, Cortex jatrophae grease, rice bran grease, cottonseed grease, Chinese honey locust grease, camphor grease, methyl alcohol, sapn S-80, tween T-80, sherwood oil, acetone, sodium hydroxide, adopt paddle stirrer to mix preheating, temperature is controlled at 30～60 ℃, joins by dosing device and carries out transesterification reaction in the reactor.The mixture liquid that various greases, methyl alcohol, additive and catalyzer are formed pumps in the reaction tower then.Carrying out whole process reactions such as removal of impurities, decolouring, esterification, separation all finishes in a reaction tower, methanol usage settles at one go, after whizzer is separated into heavy phase glycerine, methyl alcohol and light methyl esters mutually, filters purification, enter storage tank, promptly make changing food waste waste oil bio-regeneration diesel product.Thereby solved changing food waste and handled difficult problem, realized the resource utilization recycle of changing food waste, to reduce obstruction and environmental pollution to the underground blowdown pipe network in city.
The changing food waste waste oil bio-regeneration diesel oil of producing according to the technology of the present invention is checked through the relevant quality examination department of Country family's regulation, and every technical indicator all reaches the technical requirement of GB/T20828-2007 and GB16663-1996.It is as follows to detect graduate product quality inspection center detected result through the Guangzhou quality surveillance of Guangdong Province Administration of Quality and Technology Supervision:
Changing food waste waste oil bio-regeneration diesel oil detects: according to the blending of " State Standard of the People's Republic of China " GB/T20828-2007 diesel-fuel biofuel (BD100) and GB16663-1996 alcohol radical liquid fuel standard.
Name of product: changing food waste waste oil bio-regeneration diesel oil
Detected result:
Owing to take technique scheme the technology of the present invention to have following advantage and effect:
A) changing food waste waste oil bio-regeneration diesel oil of the present invention, be with changing food waste waste oil, Cortex jatrophae grease, rice bran grease,, cottonseed grease, Chinese honey locust grease, camphor grease, methyl alcohol etc. are main raw material, adopt the reaction of catalyst chemical ester-interchange method and make.Close with the carbon number in the petrifaction diesel molecule, can be used as the alternative articles for use of petrifaction diesel.It does not contain objectionable constituent such as aromatics, sulfide, and its oxygen level is far above petrifaction diesel.Therefore determine biofuel more fully to burn, thereby reduced the discharging of nuisance.
B) has good environmental-protecting performance.Because the sulphur content in this biofuel is lower, the quantity discharged of its sulfurous gas and sulfide is lower than common petrifaction diesel, can reduce by 50%～70% quantity discharged; Aromatic series alkane content is atomic in the biofuel, uses biofuel can reduce by 90% air toxicity and 94% cancer rate, helps Air quality and HUMAN HEALTH.Solved changing food waste again and handled difficult problem, realized the resource utilization recycle of changing food waste, to reduce obstruction and environmental pollution the underground blowdown pipe network in city.Meet the relevant regulations of State Council 2010 the 36th file about kitchen castoff recycling and harmless treatment.
C) has renewable performance.The raw material of this biofuel be with changing food waste waste oil and Vegetable oil lipoprotein as main raw material, belong to the recyclability energy.The energy dilemma that can solve some fossil energies exhaustions and cause guarantees energy security.
D) has good safety performance.Flash-point is an important indicator of weighing the security of biofuel in transportation, storage and use.The mean length of the carbochain of biofuel is longer than common petrifaction diesel, and flash-point is generally at 110～170 ℃, than common petrifaction diesel height.Because the flash-point height in transportation, storage and use, can not cause inflammable and explosive.
E) has good combustionproperty.Cetane value is the parameter of weighing the diesel oil ignition characteristic and influencing the diesel combustion characteristic.The cetane value of biofuel generally is higher than 45, and its burning is even, and the thermal power height can reduce fuel consumption, improves dynamic property, reduces the tail gas pollution discharging.Simultaneously, residue of combustion is subacidity, and prolonged the work-ing life of catalyzer and engine motor oil.
F) has lubricity preferably.The sulphur content of oil product is very big to the life-span influence of engine, the SO that mercaptan isoreactivity sulfur-bearing thing directly corrodes metal or its burning back produces
2And SO
3Sulfides is understood the body of heavy corrosion high-temperature zone, influences the work-ing life of engine.The sulphur content of biofuel is atomic, makes the life-span of diesel engine that better guarantee be arranged, because the excellent lubricity of biofuel reduces the wear rate of oil injection pump, engine cylinder-body and connecting rod, increases the service life.
G) production technique is simple, and three-waste free discharge meets national recycling economy and energy-saving and emission-reduction protection environment requirement spirit, and less investment, See imitate fast, cost is low, profitable, is fit to the factories that do at different levels.
Embodiment
Embodiment 1
Dining rooms such as hotel, hotel, catering trade, office, school, business unit are processed food residues, swill, the discarded food oils of animals and plants that can not eat again and the oil-water mixture etc. that produce in the activity of serving the meals at diet.It is stand-by to adopt machinery to carry out the changing food waste waste oil that extracts after the oily water separation;
With the seed of fruit of Cortex jatrophae through plucking, dry the back, separating, pulverize, heat, steam stir-fry, the Cortex jatrophae grease that adopts the processing of mechanical expression method to extract is stand-by;
Paddy is carried out steam-heated cal(l)andria through a kind of rice bran of separating in the mechanical processing process, and the rice bran grease that adopts the mechanical expression method to extract is stand-by;
Cotton is dried the back, processes the cotton seed of separating, pulverize, heat, steam stir-fry, the cottonseed grease that adopts the processing of mechanical expression method to extract is stand-by;
With the fruit of Chinese honey locust tree through drying after, a kind of seed of separating, pulverize, heat, steam stir-frys, it is stand-by that employing mechanical expression method is processed the Chinese honey locust grease of extraction;
With the fruit of camphor tree after drying, a kind of seed of separating, pulverize, heat, steam stir-fry, the camphor grease that adopts the processing of mechanical expression method to extract is stand-by,
Get changing food waste waste oil 30kg, Cortex jatrophae grease 25kg, rice bran grease 10kg, cottonseed grease 15kg, Chinese honey locust grease 5kg, camphor grease 1kg, methyl alcohol 28kg, tween T-80:0.8kg, sapn S-80:0.5kg, sherwood oil 1kg, acetone 1kg, the sodium hydroxide 2kg of above-mentioned preparation, adopt paddle stirrer to mix preheating above-mentioned raw materials, temperature is controlled at 38 ℃, pump into and carry out in the reactor entering storage tank after transesterification reaction, the filtration purification, promptly make changing food waste waste oil bio-regeneration diesel product.After testing:
Embodiment 2
Get changing food waste waste oil 40kg, Cortex jatrophae grease 35kg, rice bran grease 15kg, cottonseed grease 25kg, Chinese honey locust grease 8kg, camphor grease 2kg, methyl alcohol 38kg, tween T-80:1.5kg, sapn S-80:1.0kg, sherwood oil 2kg, acetone 2kg, the sodium hydroxide 4kg of embodiment 1, adopt paddle stirrer to mix preheating above-mentioned raw materials, temperature is controlled at 60 ℃, pump into and carry out in the reactor entering storage tank after transesterification reaction, the filtration purification, promptly make changing food waste waste oil bio-regeneration diesel product.After testing:
Embodiment 3
Get changing food waste waste oil 33kg, Cortex jatrophae grease 28kg, rice bran grease 11kg, cottonseed grease 18kg, Chinese honey locust grease 6kg, camphor grease 1.3kg, methyl alcohol 30kg, tween T-80:1.0kg, sapn S-80:0.6kg, sherwood oil 1.3kg, acetone 1.3kg, the sodium hydroxide 2.5kg of embodiment 1, adopt paddle stirrer to mix preheating above-mentioned raw materials, temperature is controlled at 30 ℃, pump into and carry out in the reactor entering storage tank after transesterification reaction, the filtration purification, promptly make changing food waste waste oil bio-regeneration diesel product.After testing:
Embodiment 4
Get changing food waste waste oil 35kg, Cortex jatrophae grease 30kg, rice bran grease 12kg, cottonseed grease 20kg, Chinese honey locust grease 7kg, camphor grease 1.5kg, methyl alcohol 33kg, tween T-80:1.2kg, sapn S-80:0.7kg, sherwood oil 1.6kg, acetone 1.6kg, the sodium hydroxide 3kg of embodiment 1, adopt paddle stirrer to mix preheating above-mentioned raw materials, temperature is controlled at 45 ℃, pump into and carry out in the reactor entering storage tank after transesterification reaction, the filtration purification, promptly make changing food waste waste oil bio-regeneration diesel product.After testing: all reach GB/T20828-2007 and GB16663-1996 State Standard of the People's Republic of China.Be qualified product.
Embodiment 5
Get changing food waste waste oil 35kg, Cortex jatrophae grease 30kg, rice bran grease 12kg, cottonseed grease 20kg, Chinese honey locust grease 7kg, camphor grease 1.5kg, methyl alcohol 33kg, tween T-80:1.2kg, sapn S-80:0.7kg, sherwood oil 1.6kg, acetone 1.6kg, the sodium hydroxide 3kg of embodiment 1, adopt paddle stirrer to mix preheating above-mentioned raw materials, temperature is controlled at 50 ℃, pump into and carry out in the reactor entering storage tank after transesterification reaction, the filtration purification, promptly make changing food waste waste oil bio-regeneration diesel product.After testing:
Claims (2)
1. bio-regeneration diesel oil of producing with the changing food waste waste oil is characterized in that it is made by the following weight proportion raw material;
Described changing food waste waste oil is food residues, swill, the discarded food oils of animals and plants that can not eat again and the oil-water mixture etc. that dining rooms such as hotel, hotel, catering trade, office, school, business unit produce in activity is served the meals in diet processing.Adopt machinery to carry out the grease that extracts after the oily water separation;
The seed of the fruit that described Cortex jatrophae grease is a Cortex jatrophae through drying the back, separating fried through pulverizing, heat, steaming, and adopts the grease of mechanical expression method processing extraction;
Described rice bran grease is that paddy carries out steam-heated cal(l)andria through a kind of rice bran of separating in the mechanical processing process, the grease that adopts the mechanical expression method to extract;
Described cottonseed grease is that the cotton process is dried the back, processed the cotton seed of separating, and through pulverizing, heat, steam stir-fry, adopts the grease of mechanical expression method processing extraction;
Described Chinese honey locust grease is a kind of seed that the fruit process of Chinese honey locust tree is dried the back, separated, and fries through pulverizing, heating, steaming, adopts the mechanical expression method to process and extracts grease;
A kind of seed of the fruit that described camphor grease is a camphor tree through drying the back, separating fried through pulverizing, heat, steaming, and adopts the grease of mechanical expression method processing extraction.
2. as the manufacture method of a kind of bio-regeneration diesel oil of producing with the changing food waste waste oil according to claim 1, it is characterized in that it is undertaken by following step:
Changing food waste waste oil with 30～40 weight parts, the Cortex jatrophae grease of 25～35 weight parts, the rice bran grease of 10～15 weight parts, the cottonseed grease of 15～25 weight parts, the Chinese honey locust grease of 5～8 weight parts, the camphor grease of 1～2 weight part, the methyl alcohol of 28～38 weight parts, 0.8 the tween T-80 of～1.5 weight parts, 0.5 the sapn S-80 of～1.0 weight parts, the sherwood oil of 1～2 weight part, the acetone of 1～2 weight part, the raw materials such as sodium hydroxide of 2～4 weight parts, adopt paddle stirrer to mix preheating, temperature is controlled at 30～60 ℃, adds in the reactor to carry out removal of impurities, decolouring, esterification, separate through whizzer, promptly make changing food waste waste oil bio-regeneration diesel product after filtering purification.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110124746XA CN102226115A (en) | 2011-05-16 | 2011-05-16 | Biological regeneration diesel oil produced by use of food waste grease and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110124746XA CN102226115A (en) | 2011-05-16 | 2011-05-16 | Biological regeneration diesel oil produced by use of food waste grease and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102226115A true CN102226115A (en) | 2011-10-26 |
Family
ID=44807113
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110124746XA Pending CN102226115A (en) | 2011-05-16 | 2011-05-16 | Biological regeneration diesel oil produced by use of food waste grease and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102226115A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103320182A (en) * | 2013-07-17 | 2013-09-25 | 汤永华 | Multipurpose low-carbon oil and its production method |
| CN103666593A (en) * | 2013-12-27 | 2014-03-26 | 山东易能生物能源有限公司 | Preparation method of composite biodiesel |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2363876Y (en) * | 1999-04-13 | 2000-02-16 | 埃克斯特鲁德尔科研生产有限公司 | Vegetable oil pressing machine |
| CN1958728A (en) * | 2006-10-30 | 2007-05-09 | 华中科技大学 | Method for refining biologic diesel oil, phospholipid and glycerin by using leftovers of vegetable oil |
| CN101085929A (en) * | 2007-02-12 | 2007-12-12 | 源华卓越能源科技（福建）有限公司 | Technique for producing biological diesel oil by Louis acid catalysis one-step method |
| CN101215484A (en) * | 2008-01-07 | 2008-07-09 | 刘振和 | Methanol gasoline additive |
| CN101372629A (en) * | 2007-08-20 | 2009-02-25 | 樊光利 | Biodiesel and preparation thereof |
| CN101586042A (en) * | 2009-07-03 | 2009-11-25 | 上海中器环保科技有限公司 | Method for producing biodiesel by utilizing waste oil recycled from kitchen waste |
-
2011
- 2011-05-16 CN CN201110124746XA patent/CN102226115A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2363876Y (en) * | 1999-04-13 | 2000-02-16 | 埃克斯特鲁德尔科研生产有限公司 | Vegetable oil pressing machine |
| CN1958728A (en) * | 2006-10-30 | 2007-05-09 | 华中科技大学 | Method for refining biologic diesel oil, phospholipid and glycerin by using leftovers of vegetable oil |
| CN101085929A (en) * | 2007-02-12 | 2007-12-12 | 源华卓越能源科技（福建）有限公司 | Technique for producing biological diesel oil by Louis acid catalysis one-step method |
| CN101372629A (en) * | 2007-08-20 | 2009-02-25 | 樊光利 | Biodiesel and preparation thereof |
| CN101215484A (en) * | 2008-01-07 | 2008-07-09 | 刘振和 | Methanol gasoline additive |
| CN101586042A (en) * | 2009-07-03 | 2009-11-25 | 上海中器环保科技有限公司 | Method for producing biodiesel by utilizing waste oil recycled from kitchen waste |
Non-Patent Citations (1)
| Title |
|---|
| 周岚: "《低碳时代的生态城市规划与建设》", 30 November 2010 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103320182A (en) * | 2013-07-17 | 2013-09-25 | 汤永华 | Multipurpose low-carbon oil and its production method |
| CN103320182B (en) * | 2013-07-17 | 2015-06-24 | 汤永华 | Multipurpose low-carbon oil and its production method |
| CN103666593A (en) * | 2013-12-27 | 2014-03-26 | 山东易能生物能源有限公司 | Preparation method of composite biodiesel |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Ewunie et al. | Factors affecting the potential of Jatropha curcas for sustainable biodiesel production: A critical review | |
| Demirbas et al. | Biodiesel production from non-edible plant oils | |
| Borugadda et al. | Biodiesel production from renewable feedstocks: Status and opportunities | |
| Meher et al. | Methanolysis of Pongamia pinnata (karanja) oil for production of biodiesel | |
| Demirbas | Progress and recent trends in biodiesel fuels | |
| Ong et al. | Comparison of palm oil, Jatropha curcas and Calophyllum inophyllum for biodiesel: a review | |
| Pinzi et al. | The ideal vegetable oil-based biodiesel composition: a review of social, economical and technical implications | |
| Ahmad et al. | Practical handbook on biodiesel production and properties | |
| Chapagain et al. | Desert date (Balanites aegyptiaca) as an arid lands sustainable bioresource for biodiesel | |
| Patel et al. | Biodiesel from plant oils | |
| Riayatsyah et al. | Current progress of jatropha curcas commoditisation as biodiesel feedstock: a comprehensive review | |
| Demirbas | Tea seed upgrading facilities and economic assessment of biodiesel production from tea seed oil | |
| Moser et al. | Preparation of fatty acid methyl esters from osage orange (Maclura pomifera) oil and evaluation as biodiesel | |
| Zaidel et al. | Production of biodiesel from rice bran oil | |
| Abdoli et al. | Effective parameters on biodiesel production from feather fat oil as a cost-effective feedstock | |
| Devarajan et al. | Inedible oil feedstocks for biodiesel production: A review of production technologies and physicochemical properties | |
| Thangaraj et al. | Scope of biodiesel from oils of woody plants: a review | |
| Adekanbi et al. | Utilizing cashew nut shell liquid for the sustainable production of biodiesel: A comprehensive review | |
| Negm et al. | Biofuels from Vegetable Oils as Alternative Fuels: Advantages and Disadvantages290 | |
| CN103834466B (en) | A kind of pistacia chinensis bge comprehensive processing and preparing takes edible oil and fat, biodiesel and the technique of the feedstuff dregs of rice | |
| CN102226115A (en) | Biological regeneration diesel oil produced by use of food waste grease and manufacturing method thereof | |
| Sharma et al. | Biodiesel production for sustainable agriculture | |
| Iglesias et al. | Biodiesel from waste oils and fats | |
| Gebre et al. | Valorization of tropical fruit‐processing wastes and byproducts for biofuel production | |
| Waidee et al. | Evaluation of Biodiesel Production from Pre-Heated Castor Oil (Ricinus communis) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20111026 |